CN107651909A - The production method of baking-free gravel goldleaf light ceramic - Google Patents

The production method of baking-free gravel goldleaf light ceramic Download PDF

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Publication number
CN107651909A
CN107651909A CN201710872434.4A CN201710872434A CN107651909A CN 107651909 A CN107651909 A CN 107651909A CN 201710872434 A CN201710872434 A CN 201710872434A CN 107651909 A CN107651909 A CN 107651909A
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goldleaf
baking
light ceramic
gravel
free
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CN201710872434.4A
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Inventor
黄允金
王鲁海
蒋文兰
袁欣
王雨润
金白云
吴青
吴一青
许庆华
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a kind of production method of baking-free gravel goldleaf light ceramic, the main points of its technical scheme are that the dispensing of baking-free gravel goldleaf light ceramic is stirred after mixing, extruder grain, steam curing, steam drying, crushing, screening and is packaged as baking-free gravel goldleaf light ceramic.The dispensing of baking-free gravel goldleaf light ceramic is made up of the Concave-convex clay rod after goldleaf, white cement, acidifying, zeolite, powdery attapulgite foaming agent, precipitated calcium carbonate, hollow glass micropearl and titanium dioxide after acidifying.The baking-free gravel light ceramic produced using the production method of the present invention, has the characteristics of glittering, lightweight intensity is good, specific surface area is big, permeability is superior, porosity and water absorption rate are high;Baking-free gravel goldleaf light ceramic can ensure that growth and development of plants is good, and survival rate is high and the life-span is longer, and can greatly reduce the number of moisturizing, suitable for garden landscape engineering, home gardening and prepare soilless culture substrate.

Description

The production method of baking-free gravel goldleaf light ceramic
Technical field
The present invention relates to haydite, and in particular to a kind of production method of baking-free gravel goldleaf light ceramic.
Background technology
Colored haydite on the market, it is to be granulated to be made after mixing using cement, fine sand and dyestuff, proportion and heap Product density is all very big, and water absorption rate is smaller, it is impossible to the normal growth and development of plant is ensured, also without the work(for adsorbing and purifying air Energy.
Tested through multiple sampling:Colored haydite average bulk density >=1200kg/m3 on the market, mean water absorption rate ≤ 20%.
The content of the invention
The purpose of the present invention is to overcome weak point in the prior art, there is provided a kind of baking-free gravel goldleaf light ceramic Production method.
The production method of baking-free gravel goldleaf light ceramic:The dispensing of baking-free gravel goldleaf light ceramic is stirred Baking-free gravel goldleaf light ceramic is packaged as after mixing mixing, extruder grain, steam curing, steam drying, crushing, screening.
After the dispensing of baking-free gravel goldleaf light ceramic is by the Concave-convex clay rod after goldleaf, white cement, acidifying, acidifying Zeolite, powdery attapulgite foaming agent, precipitated calcium carbonate, hollow glass micropearl and titanium dioxide composition.
Goldleaf production is China's special type traditional handicraft, and the history of more than 2,000 years, traditional handicraft make goldleaf, be according to legend Using the gold bar that gold content is 99.99% as primary raw material, through changing the special processing for washing, beating, cutting the multiple working procedure of paper tinsel etc. ten, make it Golden yellow color is presented, bright soft is as light as a feather, as thin as cicada's wings, and for thickness less than 0.12 micron, the present invention selects the area of goldleaf ≤ 1.0 square millimeters.
White portland cement abbreviation white cement, it is that gypsum, levigate manufactured water are added by white portland cement clinker Hydraulic cement, it is typically characterised by that there is very high whiteness, bright color, quality needs to meet " GB/T2015-2005 whites The standard of portland cement ".
Attapulgite also known as palygorskite or Palygorskite, it is the clay pit of zeopan containing Shuifu County of a kind of layer of chain structure Thing, Concave-convex clay rod have unique layer chain structure feature, and crystal is in needle-like, threadiness or fiber collection shape.Concave convex rod Stone clay has good colloidal nature and the higher adsorption capacities such as unique scattered, high temperature resistant, salt resistance alkali.
Concave-convex clay rod after acidifying is made in the absorption property, percent of decolourization, catalysis for increasing substantially Concave-convex clay rod With, specific surface area, porosity while, can increase acidifying after Concave-convex clay rod colloid viscosity and adjustment acidifying after it is recessed Convex rod stone clay pH value.
Natural zeolite has unique internal structure and Crystallochemical Properties, makes it have water suction, absorption, selectivity suction The excellent physicochemical properties such as attached, ion exchange, catalytic reaction, acidproof and radiation hardness, it is a kind of new nonmetallic ore raw material, this Granularity≤0.42 millimeter of the invention from zeolite.
After the acidified processing of zeolite, loose porous cavernous body is formed, enables the characteristics such as absorption and cation exchange Play, and after the water in zeolite crystal structure is heated effusion, passage and hole are more spacious, and respective inner surfaces product is huger Greatly, zeolite is made to show strong adsorptivity.
Powdery attapulgite foaming agent has that foaming capacity is strong, coefficient of foaming is high, unit volume bubble production volume is big, foam outer membrane is tough Property it is good non-breakable, foam stability is good, can not defoam for a long time, foam is fine and smooth, the hole size that is generated in medium uniformly, The advantages that bleeding quantity is low and good using the compatibility of medium.
Precipitated calcium carbonate is a kind of white powder, and odorlessness is tasteless, and precipitated calcium carbonate fine particles, surface are rougher, than Surface area is big, and the present invention selects granularity≤0.074 millimeter of precipitated calcium carbonate.
Hollow glass micropearl(Hollow glass microbead)It is a kind of small, hollow ball sprills, particle diameter can be as needed Arbitrarily selected between 30-100 microns, have lightweight is big, thermal conductivity factor is low, compression strength is high, dispersiveness, flowing Property, the advantages of stability is good, the present invention selects particle diameter≤0.1 millimeter of hollow glass micropearl.
Anatase thpe white powder is a kind of excellent white powder pigment, has good light scattering ability, thus whiteness is good, Tinting strength, tinting power is high, strong covering power, while has higher chemical stability and preferable weatherability, nonpoisonous and tasteless, stingless to human body Swash effect.
The technical scheme is that:
1st, the production method of baking-free gravel goldleaf light ceramic:(1) by the dispensing input of baking-free gravel goldleaf light ceramic In stirring mixer through operating, it is stirred as the mixture of baking-free gravel goldleaf light ceramic;(2) by baking-free gravel The mixture of color attapulgite light ceramic is transported in Squeezinggranulator, and extruder grain is that cylindrical sintering-free color attapulgite is light Matter semi-finished product, the diameter controls of the semi-finished product of cylindrical sintering-free color attapulgite light ceramic is at 10~25 millimeters, length Control is at 20~60 millimeters;(3) baking-free gravel goldleaf light ceramic semi-finished product are transported into steam-curing chamber's progress steam to support Protect, at 55~75 DEG C, curing time controlled at 7~15 days temperature control in steam curing room;(4) will be unburned after steam curing Gravel goldleaf light ceramic semi-finished product, are transported in steam rotary dryer and processing are dried, and drying temperature is controlled 60 ~100 DEG C, drying time was controlled at 1~5 hour;(5) by the baking-free gravel color attapulgite light ceramic after drying process half Finished product is transported in pulverizer and crushed;(6) the baking-free gravel color attapulgite light ceramic semi-finished product after crushing are conveyed Sieved into vibratory sieve, the grain graininess control of the baking-free gravel color attapulgite light ceramic semi-finished product after screening exists 0.5~5 millimeter;(7), by the baking-free gravel goldleaf light ceramic semi-finished product after crushing, baking-free gravel goldleaf lightweight is packaged as The finished product of haydite.
2nd, the dispensing of baking-free gravel goldleaf light ceramic is made up of following component by weight percentage:Goldleaf 2~15%, The zeolite 2~25% after Concave-convex clay rod 5~30%, acidifying after white cement 15~35%, acidifying, powdery attapulgite foaming Agent 2~10%, precipitated calcium carbonate 1~10%, hollow glass micropearl 1~8%, titanium dioxide 0.5~5% and water 5~40%.
3rd, the Concave-convex clay rod dispensing after being acidified is made up of following component by weight percentage:Attapulgite after acidifying Clay semi-finished product 90~98%, quick dissolved sodium silicate 0.1~5%, polyvinyl alcohol 0.1~5%, hydroxypropyl methyl cellulose 0.01~ 3% and sodium carbonate 0~3%;The production method of Concave-convex clay rod after acidifying:Concave-convex clay rod dispensing after acidifying is defeated Enter in grinding machine and be milled, grain fineness≤0.074 millimeter, the powder after milling is the Concave-convex clay rod after acidifying;
The production method of Concave-convex clay rod semi-finished product after acidifying:(1) first the Concave-convex clay rod after weathering is inputted In mixer through operating, then dilute sulfuric acid is slowly added to carry out acidification in the Concave-convex clay rod after weathering;⑵ By the Concave-convex clay rod after acidification, it is Concave-convex clay rod tablet to be extruded by twin rollers, Concave-convex clay rod piece Thickness≤3 millimeter of shape thing;(3) Concave-convex clay rod tablet is transported in swinging drying oven and be calcined, roasting time 1 ~3 hours, sintering temperature was controlled at 250~350 DEG C, Concave-convex clay rod tablet water content≤5% after roasting, after roasting Concave-convex clay rod tablet for acidifying after Concave-convex clay rod semi-finished product;
The dispensing of Concave-convex clay rod tablet is made up of following component by weight percentage:Attapulgite after weathering glues Soil 55~75% and dilute sulfuric acid 25~45%;The dispensing of dilute sulfuric acid is made up of following component by weight percentage:The ﹪'s of concentration 98 Sulfuric acid 1~5%, water 95~99%;Concave-convex clay rod raw ore is needed by two time weatherings more than winter, from big The fine and close raw ore disintegration of block is the Concave-convex clay rod after the weathering of fine particle, picks and is evident that barren rock block, plants Fibres and other soil impurity, Concave-convex clay rod grain fineness≤5 millimeter after weathering.
Concave-convex clay rod after acidifying is " recessed after acidifying using being applied by the present inventor on 06 01st, 2014 Convex rod stone clay ", Chinese patent Authorization Notice No. is:CN 104016366B, authorized announcement date:On December 02nd, 2015.
4th, the zeolite dispensing after being acidified is made up of following component by weight percentage:Zeolite semi-finished product 90 after acidifying~ 98%th, quick dissolved sodium silicate 0.1~5%, polyvinyl alcohol 0.1~5%, hydroxypropyl methyl cellulose 0.01~3% and sodium carbonate 0~ 3%;The production method of zeolite after acidifying:It will be milled in zeolite dispensing after acidifying input grinding machine, grain fineness≤0.074 is in the least Meter, the powder after milling is the zeolite finished product after acidifying.
The production method of zeolite semi-finished product after acidifying:(1) the mixer dispensing input of zeolite mixture operated Middle stirring, then watery hydrochloric acid is slowly added to carry out acidification in zeolite mixture;(2) by the zeolite mixture after acidification, It is zeolite tablet to be extruded by twin rollers, thickness≤3 millimeter of zeolite tablet;(3) zeolite tablet is transported to swinging It is calcined in drying oven, roasting time is 1~3 hour, and sintering temperature is controlled at 300~400 DEG C, and the zeolite tablet after roasting contains Water≤2%, the zeolite tablet after roasting is the zeolite semi-finished product after acidifying, and percentage of water content is weight percentage.
The dispensing of zeolite tablet is made up of following component by weight percentage:Zeolite mixture 75~95% and watery hydrochloric acid 5~25%, the dispensing of zeolite mixture is made up of following component by weight percentage:Zeolite 68~92%, Concave-convex clay rod 5 ~30% and magnesia 0.1~3%, the dispensing of watery hydrochloric acid be made up of by weight percentage following component:Concentration is 37% dense salt Acid 1~25% and water 75~99%, the concentrated hydrochloric acid percentage that concentration is 37% are weight percentage.
Zeolite after acidifying was applied " zeolite after acidifying " using by the present inventor on 06 01st, 2014, Chinese License notification number is:CN 103979573B, authorized announcement date:On 2 17th, 2016.
5th, powdery attapulgite foaming agent dispensing is made up of following component by weight percentage:Activated attapulgite 45~ 95%th, lauryl sodium sulfate 1~35%, SODIUM PERCARBONATE 1~25%, Sodium Polyacrylate 0.01~5%, sodium pyrophosphate 0.01~ 5% and poly- naphthalene formaldehyde sulfonate salt 0.01~5%;The production method of powdery attapulgite foaming agent:By powdery attapulgite foaming agent It is stirred in dispensing input mixer, inputs in grinding machine and be milled after stirring, grain fineness≤0.074 millimeter.
Powdery attapulgite foaming agent using applied by the present inventor on 05 26th, 2013 " powdery attapulgite foam Agent ", Chinese patent Authorization Notice No. are:The B of CN 103265213, authorized announcement date:On 09 24th, 2014.
6th, the production method of baking-free gravel colour goldleaf light ceramic of the invention, it is also applied for producing cylindrical sintering-free Colored goldleaf light ceramic and unburned spheroidal colour goldleaf light ceramic.
The production method of the baking-free gravel goldleaf light ceramic of the present invention, the principal ingredients of selection are not limited to after being acidified Zeolite after Concave-convex clay rod and acidifying, it is kaolin, diatomite, sepiolite clay, activated carbon, volcanic ash after acidifying, tired Hold in the palm stone clay, green illiteracy mixed-layer clay, chlorite, medical stone, bentonite, illite clay, her green mixed-layer clay and illite/smectite mixed layer Clay is equally applicable to produce baking-free gravel goldleaf light ceramic.
Goldleaf golden yellow color, bright soft is as light as a feather, as thin as cicada's wings, and thickness is less than 0.12 micron, goldleaf and white cement It can ensure that the color of baking-free gravel goldleaf light ceramic is more glittering.
The zeolite after Concave-convex clay rod and acidifying after acidifying can increase substantially baking-free gravel goldleaf light ceramic Absorption and purify air function.
Powdery attapulgite foaming agent be stirred for baking-free gravel goldleaf light ceramic mixture when, it will produce one Quantitative bubble, be advantageous to increase baking-free gravel goldleaf light ceramic surface and internal porosity.
White cement, precipitated calcium carbonate, hollow glass micropearl and titanium white are used in baking-free gravel goldleaf light ceramic dispensing Powder, it is ensured that baking-free gravel goldleaf light ceramic color is more bright-coloured, increases baking-free gravel goldleaf light ceramic surface and interior The porosity in portion, improve the specific surface area and intensity of baking-free gravel goldleaf light ceramic.
Baking-free gravel goldleaf light ceramic is advantageous to increase the mutual space of baking-free gravel goldleaf light ceramic Rate and the bulk density for reducing baking-free gravel goldleaf light ceramic.
Baking-free gravel goldleaf light ceramic surface and it is internal have largely interconnected micropore, be advantageous to increase unburned broken Effective ratio area, intensity and the reduction bulk density of stone shape goldleaf light ceramic.
Baking-free gravel goldleaf light ceramic is put into water, baking-free gravel goldleaf light ceramic can sink to water rapidly Bottom, while large quantity of moisture is sucked, the air in baking-free gravel goldleaf light ceramic internal capillary can be cemented out.
When baking-free gravel goldleaf light ceramic water absorption rate >=25%, the appearance of baking-free gravel goldleaf light ceramic is only It is a kind of state of moistening, not obvious water leaks out, and baking-free gravel goldleaf light ceramic is packed together, phase Numerous spaces is formed between mutually, will not be bonded together, permeability is good, and baking-free gravel goldleaf light ceramic is drying shape There is no dust under state, disintegration will not also be produced by being immersed in all the year round in water.
Using the present invention production method produce baking-free gravel light ceramic, have it is glittering, lightweight intensity Well, the characteristics of specific surface area is big, permeability is superior, porosity and water absorption rate are high.
In order to ensure the normal growth and development of plant, water, the organic fertilizer of liquid or inorganic fertilizer are sprayed at baking-free gravel In goldleaf light ceramic, or baking-free gravel goldleaf light ceramic is immersed in the solution of water, organic fertilizer or inorganic fertilizer, it is unburned Gravel goldleaf light ceramic takes out after absorbing a certain amount of water of storage or liquid fertilizer, for cultivating or planting various nursery stocks, flower When grass and vegetables, the root of plant will absorb the nutritional ingredient of water or liquid fertilizer in baking-free gravel goldleaf light ceramic, Ensure that growth and development of plants is good, survival rate is high and the life-span is longer, and can greatly reduce the number of moisturizing.
Baking-free gravel goldleaf light ceramic is applied to garden landscape engineering, home gardening and prepares soilless culture substrate.
Embodiment
With reference to embodiment, the invention will be further described:
1st, the production method of baking-free gravel goldleaf light ceramic:(1) by the dispensing input of baking-free gravel goldleaf light ceramic In stirring mixer through operating, it is stirred as the mixture of baking-free gravel goldleaf light ceramic;(2) by baking-free gravel The mixture of color attapulgite light ceramic is transported in Squeezinggranulator, and extruder grain is that cylindrical sintering-free color attapulgite is light Matter semi-finished product, at 20 millimeters, length controls the diameter control of the semi-finished product of cylindrical sintering-free color attapulgite light ceramic At 40 millimeters;(3) baking-free gravel goldleaf light ceramic semi-finished product are transported to steam-curing chamber and carry out steam curing, steam is supported Indoor temperature control is protected at 65~75 DEG C, curing time was controlled at 12 days;(4) it is the baking-free gravel goldleaf after steam curing is light Matter semi-finished product, it is transported in steam rotary dryer and processing is dried, drying temperature is controlled at 80~90 DEG C, when drying Between control at 2 hours;(5) the baking-free gravel color attapulgite light ceramic semi-finished product after drying process are transported to pulverizer In crushed;(6) the baking-free gravel color attapulgite light ceramic semi-finished product after crushing are transported in vibratory sieve and sieved Point, the grain graininess of the baking-free gravel color attapulgite light ceramic semi-finished product after screening is controlled at 0.5~5 millimeter;(7) will Baking-free gravel goldleaf light ceramic semi-finished product after crushing, it is packaged as the finished product of baking-free gravel goldleaf light ceramic.
2nd, the dispensing of baking-free gravel goldleaf light ceramic is made up of following component by weight percentage:Goldleaf 5%, plain boiled water The zeolite 12% after Concave-convex clay rod 16%, acidifying, powdery attapulgite foaming agent 8%, lightweight carbonic acid after mud 26%, acidifying Calcium 6%, hollow glass micropearl 4%, titanium dioxide 3% and water 20%.
3rd, baking-free gravel goldleaf light ceramic average bulk density is 840kg/m3, water absorption rate 66%.

Claims (4)

  1. A kind of 1. production method of baking-free gravel goldleaf light ceramic, it is characterised in that baking-free gravel goldleaf light ceramic Production method:(1) in the stirring mixer dispensing input of baking-free gravel goldleaf light ceramic operated, stirring is mixed It is combined into the mixture of baking-free gravel goldleaf light ceramic;(2) it is the mixture of baking-free gravel color attapulgite light ceramic is defeated It is sent in Squeezinggranulator, extruder grain is cylindrical sintering-free color attapulgite light ceramic semi-finished product, and cylindrical sintering-free is colored At 10~25 millimeters, length controls at 20~60 millimeters the diameter control of the semi-finished product of concave convex rod light ceramic;(3) will be unburned broken Stone shape goldleaf light ceramic semi-finished product are transported to steam-curing chamber and carry out steam curing, in steam curing room temperature control 55~ 75 DEG C, curing time was controlled at 7~15 days;(4) by the baking-free gravel goldleaf light ceramic semi-finished product after steam curing, conveying Processing is dried into steam rotary dryer, at 60~100 DEG C, drying time control is small 1~5 for drying temperature control When;(5) the baking-free gravel color attapulgite light ceramic semi-finished product after drying process are transported in pulverizer and crushed; (6) the baking-free gravel color attapulgite light ceramic semi-finished product after crushing are transported in vibratory sieve and sieved, after screening The grain graininess of baking-free gravel color attapulgite light ceramic semi-finished product is controlled at 0.5~5 millimeter;(7) will be unburned after crushing Gravel goldleaf light ceramic semi-finished product, it is packaged as the finished product of baking-free gravel goldleaf light ceramic.
  2. 2. the production method of a kind of baking-free gravel goldleaf light ceramic according to claim 1, it is characterised in that unburned The dispensing of gravel goldleaf light ceramic is made up of following component by weight percentage:Goldleaf 2~15%, white cement 15~ 35%th, be acidified after Concave-convex clay rod 5~30%, acidifying after zeolite 2~25%, powdery attapulgite foaming agent 2~10%, Precipitated calcium carbonate 1~10%, hollow glass micropearl 1~8%, titanium dioxide 0.5~5% and water 5~40%.
  3. A kind of 3. production method of baking-free gravel goldleaf light ceramic according to claim 1, it is characterised in that this hair Bright area≤1.0 square millimeter from goldleaf.
  4. 4. the production method of a kind of baking-free gravel goldleaf light ceramic according to claim 1, it is characterised in that select Principal ingredients be not limited to acidifying after Concave-convex clay rod and the zeolite after acidifying, kaolin, diatomite, Hai Pao after acidifying Stone clay, activated carbon, volcanic ash, Rectorite, it is green illiteracy mixed-layer clay, chlorite, medical stone, bentonite, illite clay, Her green mixed-layer clay and illite/smectite mixed layer clay is equally applicable to produce baking-free gravel goldleaf light ceramic.
CN201710872434.4A 2017-09-25 2017-09-25 The production method of baking-free gravel goldleaf light ceramic Withdrawn CN107651909A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109776068A (en) * 2019-02-28 2019-05-21 兰州理工大学 A kind of preparation method for the modified Loess base haydite handling rainwater

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109776068A (en) * 2019-02-28 2019-05-21 兰州理工大学 A kind of preparation method for the modified Loess base haydite handling rainwater

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