CN107629823A - A kind of environmentally friendly synthetic liquid fuel - Google Patents
A kind of environmentally friendly synthetic liquid fuel Download PDFInfo
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- CN107629823A CN107629823A CN201610562733.3A CN201610562733A CN107629823A CN 107629823 A CN107629823 A CN 107629823A CN 201610562733 A CN201610562733 A CN 201610562733A CN 107629823 A CN107629823 A CN 107629823A
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- liquid fuel
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Abstract
A kind of environmentally friendly synthetic liquid fuel, is consisted of the following composition：The ethanol of 40~60 parts by weight；The diesel oil of 10~30 parts of parts by weight；The butane of 6.5~17 parts by weight；The methyl methacrylate of 1~5 part of parts by weight；The barium sulfonate of 0.2~1 part of parts by weight；The stabilizer of 0.8 1.5 parts by weight；The aliphatic acid of 1~3 part of parts by weight；The phosphate of 0.2~1 part of parts by weight；The vulcanization butylene of 0.2~1 part of parts by weight；The methyl-silicone oil of 1.2~2 parts of parts by weight；1~5 part of parts by weight of phosphoric acid sodium；The active nano ion of 0.25 0.5 parts by weight, the hydrogen peroxide of 0.5 0.9 parts by weight, the temperature range of preparation is+20 DEG C~20 DEG C.
Description
Technical field
It is specifically a kind of to use ethanol to be closed for ethanol prepared by primary raw material the invention discloses a kind of liquid fuel
Into fuel and preparation method thereof.
Background technology
With the development of national economy, it is indispensable that the energy turns into field of industrial production, yet with a large amount of consumption with
And its it is non-renewable, countries in the world all suffer from energy crisis.In general fuel oil be by air-distillation refined and
, this fuel oils can discharge many waste gas in process of production, while contain substantial amounts of combustible in waste gas, cause the energy
Waste.And fuel oil can discharge a large amount of oxysulfides, nitrogen oxides pollution environment in combustion.
Patent CN202658134 discloses a kind of atmospheric and vacuum distillation oil refining apparatus, and the device is the profit that can improve waste oil
With rate, environment protection clean fuel oil can not be produced.Patent CN202089933 discloses a kind of dress of extracting fuel oil from ethylene tar
Put, the device is although simple in construction, but is also pertaining only to the production equipment of general fuel oil.Patent CN200820007877.3 is disclosed
Apparatus for preparing biomass fuel oil, the device can change into biomass resource fuel oil, but need to thermally decompose, at atomization
The means such as reason, huge structure, complex operation.
The content of the invention
The purpose of invention be to provide for it is a kind of based on regenerated resources, reduce atmosphere pollution, save national foreign exchange and disappear
Alcohol synthetic fuel consume, used ethanol to be prepared for primary raw material and preparation method thereof.
The object of the present invention is achieved like this, a kind of environmentally friendly synthetic liquid fuel, consists of the following composition：40~60 weights
Measure the ethanol of part；The diesel oil of 10~30 parts of parts by weight；The butane of 6.5~17 parts by weight；The dimethyl allene of 1~5 part of parts by weight
Sour methyl esters；The barium sulfonate of 0.2~1 part of parts by weight；The stabilizer of 0.8-1.5 parts by weight；The aliphatic acid of 1~3 part of parts by weight；0.2
The phosphate of~1 part of parts by weight；The vulcanization butylene of 0.2~1 part of parts by weight；The methyl-silicone oil of 1.2~2 parts of parts by weight；1~5 part
Parts by weight of phosphoric acid sodium；The ferrocene of 0.25-0.5 parts by weight, the hydrogen peroxide of 0.5-0.9 parts by weight, the 2 of 0.5-0.9 parts by weight,
6- BHTs, the temperature range of preparation is+20 DEG C~-20 DEG C.
Described environmentally friendly synthetic liquid fuel preparation method step is as follows：
The ethanol of concentration more than 95% is put into closed agitator tank first, being then injected into butane reaches pressure inside the tank
0.2MPa, shutoff valve swing stirring tank 30 minutes behind the door, are allowed to uniformly mix；
Other above-mentioned raw materials are put into agitator tank together by weight feeding and are uniformly mixed；
The compound to stir is put into reactor to be heated to 350 DEG C and stir；
Compound after heating is excluded into gas through gas-liquid separator, liquid is directly entered catalytic tower, then by every
1000kg injects 4m3Hydrogen, then normal temperature is down to by tubulation device；
It is then shut off pressure reaction still and is stirred mixing 1-4h, environmentally friendly synthetic liquid fuel is obtained after filtering.
The agitator mixing speed of agitator tank is 3000-5000r/min；Pressure reaction still agitator mixing speed is
3000-5000r/min, the pressure in pressure reaction still are consistent with external atmosphere pressure.
Institute's Pass through above-mentioned technical proposal of the present invention, because the main component in raw material employs reproducible methanol and second
Alcohol, and be incorporated a small amount of industrial chemicals, then synthesis is simply made by science, produced thing fuel after testing, its fuel value
1.1 ten thousand kilocalories are can reach, hydrocarbon and a discharge capacity aoxidized are extremely low, and calorific value is suitable with current gasoline, can directly apply
Used in existing automobile engine as power fuel, raw material needed for the present invention easily obtains, and manufacturing process is simple, has fabulous
Popularizing application prospect.
Embodiment
It is as follows for the more detailed elaboration present invention, the one embodiment of the invention：
Embodiment 1
The ethanol of 40 parts by weight；The diesel oil of 10 parts of parts by weight；The butane of 6.5 parts by weight；The dimethyl allene of 1 part of parts by weight
Sour methyl esters；The barium sulfonate of 0.2 part of parts by weight；The stabilizer of 0.8 parts by weight；The aliphatic acid of 1 part of parts by weight；0.2 part of parts by weight
Phosphate；The vulcanization butylene of 0.2 part of parts by weight；The methyl-silicone oil of 1.2 parts of parts by weight；1 part of parts by weight of phosphoric acid sodium；0.25 parts by weight
Ferrocene, the hydrogen peroxide of 0.5 parts by weight, the BHT of 0.5 parts by weight, the temperature range of preparation for+
20 DEG C~-20 DEG C.
Described environmentally friendly synthetic liquid fuel preparation method step is as follows：
The ethanol of concentration more than 95% is put into closed agitator tank first, being then injected into butane reaches pressure inside the tank
0.2MPa, shutoff valve swing stirring tank 30 minutes behind the door, are allowed to uniformly mix；
Other above-mentioned raw materials are put into agitator tank together by weight feeding and are uniformly mixed；
The compound to stir is put into reactor to be heated to 350 DEG C and stir；
Compound after heating is excluded into gas through gas-liquid separator, liquid is directly entered catalytic tower, then by every
1000kg injects 4m3 hydrogen, then is down to normal temperature by tubulation device；
It is then shut off pressure reaction still and is stirred mixing 1-4h, environmentally friendly synthetic liquid fuel is obtained after filtering, measures heat
Be worth for 12500 card/gram/.
Embodiment 2
The ethanol of 60 parts by weight；The diesel oil of 30 parts of parts by weight；The butane of 17 parts by weight；The dimethyl allene of 5 parts of parts by weight
Sour methyl esters；The barium sulfonate of 1 part of parts by weight；The stabilizer of 1.5 parts by weight；The aliphatic acid of 3 parts of parts by weight；The phosphoric acid of 1 part of parts by weight
Ester；The vulcanization butylene of 1 part of parts by weight；The methyl-silicone oil of 2 parts of parts by weight；5 parts of parts by weight of phosphoric acid sodium；The ferrocene of 0.5 parts by weight,
The hydrogen peroxide of 0.9 parts by weight, the BHT of 0.9 parts by weight, the temperature range of preparation is+20 DEG C~-20
℃。
Described environmentally friendly synthetic liquid fuel preparation method step is as follows：
The ethanol of concentration more than 95% is put into closed agitator tank first, being then injected into butane reaches pressure inside the tank
0.2MPa, shutoff valve swing stirring tank 30 minutes behind the door, are allowed to uniformly mix；
Other above-mentioned raw materials are put into agitator tank together by weight feeding and are uniformly mixed；
The compound to stir is put into reactor to be heated to 350 DEG C and stir；
Compound after heating is excluded into gas through gas-liquid separator, liquid is directly entered catalytic tower, then by every
1000kg injects 4m3Hydrogen, then normal temperature is down to by tubulation device；
Be then shut off pressure reaction still be stirred mixing 1-4h, environmentally friendly synthetic liquid fuel is obtained after filtering, geodetic its
Calorific value be 11500 card/gram.
Claims (3)
1. a kind of environmentally friendly synthetic liquid fuel, is consisted of the following composition：The ethanol of 40~60 parts by weight；10~30 parts of parts by weight
Diesel oil；The butane of 6.5~17 parts by weight；The methyl methacrylate of 1~5 part of parts by weight；The sulfonic acid of 0.2~1 part of parts by weight
Barium；The stabilizer of 0.8-1.5 parts by weight；The aliphatic acid of 1~3 part of parts by weight；The phosphate of 0.2~1 part of parts by weight；0.2~1 part
The vulcanization butylene of parts by weight；The methyl-silicone oil of 1.2~2 parts of parts by weight；1~5 part of parts by weight of phosphoric acid sodium；0.25-0.5 parts by weight
Ferrocene, the hydrogen peroxide of 0.5-0.9 parts by weight, the BHT of 0.5-0.9 parts by weight, the temperature model of preparation
Enclose for+20 DEG C~-20 DEG C.
2. the environmentally friendly synthetic liquid fuel preparation method step described in claim 1 is as follows：
1) ethanol of concentration more than 95% is put into closed agitator tank first, being then injected into butane reaches pressure inside the tank
0.2MPa, shutoff valve swing stirring tank 30 minutes behind the door, are allowed to uniformly mix；
2) other above-mentioned raw materials are put into agitator tank together by weight feeding and be uniformly mixed；
3) compound to stir is put into reactor to be heated to 350 DEG C and stir；
3) compound after heating is excluded into gas through gas-liquid separator, liquid is directly entered catalytic tower, then presses per 1000kg
Inject 4m3Hydrogen, then normal temperature is down to by tubulation device；
4) it is then shut off pressure reaction still and is stirred mixing 1-4h, environmentally friendly synthetic liquid fuel is obtained after filtering.
3. preparation method according to claim 2, it is characterised in that the agitator mixing speed of agitator tank is 3000-
5000r/min；Pressure reaction still agitator mixing speed is 3000-5000r/min, and the pressure and the external world in pressure reaction still are big
Air pressure is consistent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610562733.3A CN107629823A (en) | 2016-07-18 | 2016-07-18 | A kind of environmentally friendly synthetic liquid fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610562733.3A CN107629823A (en) | 2016-07-18 | 2016-07-18 | A kind of environmentally friendly synthetic liquid fuel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107629823A true CN107629823A (en) | 2018-01-26 |
Family
ID=61112626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610562733.3A Pending CN107629823A (en) | 2016-07-18 | 2016-07-18 | A kind of environmentally friendly synthetic liquid fuel |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1139148A (en) * | 1995-06-29 | 1997-01-01 | 张卫东 | Additive composite raising octane value of hydrocarbon fuels |
| CN102373101A (en) * | 2010-08-20 | 2012-03-14 | 白玉林 | High-cleaning aged fuel |
| CN102477319A (en) * | 2010-11-21 | 2012-05-30 | 张朝斌 | Emulsion cleaning gasoline with environmental protection and energy saving |
| CN103131481A (en) * | 2011-11-22 | 2013-06-05 | 襄樊同康实业有限公司 | Biosynthetic fuel |
| CN103436306A (en) * | 2013-07-19 | 2013-12-11 | 济南开发区星火科学技术研究院 | Fuel oil composition |
| CN103623736A (en) * | 2013-12-02 | 2014-03-12 | 济南开发区星火科学技术研究院 | Environment-friendly clean fuel oil production equipment and using method thereof |
| CN103627446A (en) * | 2013-12-02 | 2014-03-12 | 济南开发区星火科学技术研究院 | Environment-friendly clean fuel oil and preparation method thereof |
-
2016
- 2016-07-18 CN CN201610562733.3A patent/CN107629823A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1139148A (en) * | 1995-06-29 | 1997-01-01 | 张卫东 | Additive composite raising octane value of hydrocarbon fuels |
| CN102373101A (en) * | 2010-08-20 | 2012-03-14 | 白玉林 | High-cleaning aged fuel |
| CN102477319A (en) * | 2010-11-21 | 2012-05-30 | 张朝斌 | Emulsion cleaning gasoline with environmental protection and energy saving |
| CN103131481A (en) * | 2011-11-22 | 2013-06-05 | 襄樊同康实业有限公司 | Biosynthetic fuel |
| CN103436306A (en) * | 2013-07-19 | 2013-12-11 | 济南开发区星火科学技术研究院 | Fuel oil composition |
| CN103623736A (en) * | 2013-12-02 | 2014-03-12 | 济南开发区星火科学技术研究院 | Environment-friendly clean fuel oil production equipment and using method thereof |
| CN103627446A (en) * | 2013-12-02 | 2014-03-12 | 济南开发区星火科学技术研究院 | Environment-friendly clean fuel oil and preparation method thereof |
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Application publication date: 20180126 |