CN106520218B - Ecological fuel oil and preparation method thereof - Google Patents
Ecological fuel oil and preparation method thereof Download PDFInfo
- Publication number
- CN106520218B CN106520218B CN201610985002.XA CN201610985002A CN106520218B CN 106520218 B CN106520218 B CN 106520218B CN 201610985002 A CN201610985002 A CN 201610985002A CN 106520218 B CN106520218 B CN 106520218B
- Authority
- CN
- China
- Prior art keywords
- oil
- alcohol
- carbon
- low
- fuel oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
Abstract
The present invention relates to a kind of ecological fuel oils and preparation method thereof, belong to new energy field.Ecological fuel oil, it is characterised in that it is prepared by bioliquid fuels, mineral oil, low-carbon without sulphur synthetic and adhesive；Wherein bioliquid fuels, mineral oil, low-carbon are without weight percent shared by sulphur synthetic：Bioliquid fuels 20~25%, mineral oil 30~40%, low-carbon are without sulphur synthetic 40~45%；The addition of adhesive is 0.3~0.8% of bioliquid fuels, mineral oil and low-carbon without sulphur synthetic total weight.The ecology fuel oil low-carbon, low-sulfur, production cost are low.
Description
Technical field
The present invention relates to a kind of ecological fuel oils and preparation method thereof, belong to new energy field.
Background technology
China is in industrialization, High-speed Urbanization stage, energy-consuming rapid growth, makes holding for resource and environment
Several near limits of stress, energy external dependence degree is surging, and energy security guarantee faces a severe challenge, and energy and environmental problem has become
An important factor for restrict socio-economic development.With petering out for the traditional fossil energies such as oil, coal, environmental problem day
Become serious, the research and popularization and application of new energy (especially cleaning new energy) have become the necessary policy of national governments.
Invention content
The object of the present invention is to provide a kind of ecological fuel oils, and the ecology fuel oil low-carbon, low-sulfur, production cost are low.
To achieve these goals, the technical solution used in the present invention is：Ecological fuel oil, it is characterised in that it is by biology
Liquid fuel, mineral oil, low-carbon are prepared without sulphur synthetic and adhesive；Wherein bioliquid fuels, mineral oil,
Low-carbon is without weight percent shared by sulphur synthetic：Bioliquid fuels 20~25%, mineral oil 30~40%, low-carbon without
Sulphur synthetic 40~45%；The addition of adhesive is total without sulphur synthetic for bioliquid fuels, mineral oil and low-carbon
The 0.3~0.8% of weight；
The bioliquid fuels (or bio-fuel) are by animal and plant fat, tetrahydrofurfuryl oleate and oleic acid fourth
Lipase absobed, weight percent shared by each raw material are：Animal and plant fat 90~95%, tetrahydrofurfuryl oleate 3~6%, oleic acid
Butyl ester 2~4%；
The mineral oil is by following Material synthesis：1. (it is oily, useless that waste oil includes Waste gasoline, waste coal for fuel oil and waste oil
One or more mixing in diesel oil, by arbitrary quality proportioning during mixing, i.e. ratio is unlimited, and lower limit is more than the 0%, upper limit and is less than
100%), 2. n-butanol, 3. acetic acid, 4. diethylene glycol monobutyl ether, weight percent shared by each raw material are：Fuel oil and useless
(ratio between fuel oil and waste oil is unlimited, as arbitrary quality proportioning, and the lower limit of fuel oil or waste oil is more than the 0%, upper limit for oil
Less than 100%) 90~95%, n-butanol 0.5~3%, acetic acid 3~6%, diethylene glycol monobutyl ether 1~1.5%；
The low-carbon synthesizes (mixing) without sulphur synthetic (or synthetic) by alcohol, candy, ketone and four class substance of ester,
Alcohol, candy, ketone, ester weight ratio=5:0.3:0.2:0.1；
The adhesive by alcohol water (alcohol water is made of alcohol and water, the quality of alcohol and water respectively account for 50%), it is bubble adhesive material, anti-
Rotten agent and antioxidant synthesis, weight percent shared by each raw material are：Alcohol water 55~60%, bubble adhesive material 20~25%, preservative
10~15%, antioxidant 5~10%.
By above-mentioned technical proposal, the animal and plant fat synthesizes (mixing), ground by gutter oil, turpentine oil, castor oil etc.
Weight percent shared by ditch oil is：85%~95%, weight percent shared by turpentine oil and castor oil is：5%~15%, turpentine
(i.e. ratio is unlimited, and the lower limit of turpentine oil or castor oil is more than the 0%, upper limit and is less than in arbitrary quality proportioning for oil and castor oil
100%) it mixes.
By above-mentioned technical proposal, the alcohol is the one or two or more kinds (containing two kinds) in methanol, ethyl alcohol, sorbierite etc.
In the mixing of arbitrary quality proportioning, (two kinds or more ratios are unlimited, and the lower limit of each raw material is more than the 0%, upper limit and is less than 100%)；Candy is
One kind in xylose, glucose etc., ketone are one kind in acetone, 2- butanone etc., and ester is n-butyl acetate.
By above-mentioned technical proposal, the bubble adhesive material (or bubble dissipates thick substances) is sodium alginate, coconut acid diethyl
One or two or more kinds (containing two kinds) in hydramine condensation product, tri-n-butyl citrate, an ancient wind instrument alkene, glue acid etc. are by arbitrary quality proportioning
Mixing (two kinds or more ratios are unlimited, and the lower limit of each raw material is more than the 0%, upper limit and is less than 100%).
By above-mentioned technical proposal, the preservative is one kind in sorbic acid, sodium benzoate etc..
By above-mentioned technical proposal, the antioxidant is 2,6-di-tert-butyl p-cresol.
By above-mentioned technical proposal, the maximum weight dosage of bioliquid fuels and the minimum weight dosage of mineral oil must not
Less than 1:1.35 (must not be less than 1.35 kilograms with 1 kilogram of matched mineral oil of bioliquid fuels).
The preparation method of above-mentioned ecology fuel oil, it is characterised in that it includes the following steps：
1) bioliquid fuels are prepared：The weight percent as shared by each raw material is：Animal and plant fat 90~95%, oleic acid four
Hydrogen furans methyl esters 3~6%, butyl oleate 2~4% choose animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate；
Animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate are mixed, stirring obtains bioliquid fuels；
2) mineral oil is prepared：The weight percent as shared by each raw material is：Fuel oil and waste oil are (between fuel oil and waste oil
Ratio it is unlimited, as arbitrary quality proportioning) 90~95%, n-butanol 0.5~3%, acetic acid 3~6%, diglycol list
Butyl ether 1~1.5%；Choose the following raw material：1. (including Waste gasoline, waste coal oil, waste diesel --- ratio is or not fuel oil and waste oil
Limit), 2. n-butanol, 3. acetic acid, 4. diethylene glycol monobutyl ether；
It will 1. fuel oil and waste oil (including Waste gasoline, waste coal oil, waste diesel), 2. n-butanol, 3. acetic acid and a 4. contracting two
Ethylene glycol monobutyl ether mixes, and stirring obtains mineral oil；
3) low-carbon is prepared without sulphur synthetic：By alcohol, candy, ketone, ester weight ratio=5:0.3:0.2:0.1, selection alcohol,
Candy, ketone and ester；
Alcohol, candy, ketone and ester are mixed, stirring obtains low-carbon without sulphur synthetic；
4) adhesive is prepared：The weight percent as shared by each raw material is：Alcohol water 55~60%, bubble adhesive material 20~25%,
Preservative 10~15%, antioxidant 5~10%；Choose alcohol water, bubble adhesive material, preservative and antioxidant；
Wherein, alcohol water is made of alcohol and water, the quality of alcohol and water respectively account for 50% (alcohol can be that methanol can also be ethyl alcohol,
If simultaneously using methanol and ethyl alcohol, the two can disregard ratio, and the lower limit of each raw material is more than the 0%, upper limit and is less than 100%)；
Bubble adhesive material, preservative and antioxidant are dissolved separately in alcohol water, stirs, obtains adhesive；
5) ecological fuel oil is prepared：The weight percent as shared by bioliquid fuels, mineral oil, low-carbon without sulphur synthetic
For：Bioliquid fuels 20~25%, mineral oil 30~40%, low-carbon choose biological fluids without sulphur synthetic 40~45%
State fuel, mineral oil and low-carbon are without sulphur synthetic；
It is 0.3 of bioliquid fuels, mineral oil and low-carbon without sulphur synthetic total weight by the addition of adhesive
~0.8%, choose adhesive；
Bioliquid fuels, mineral oil, low-carbon without sulphur synthetic and adhesive are mixed, stirring, then pass through homogeneous
Machine will homogenize liquid and be sent in precipitation knockout drum, and supernatant liquor is finished product ecology fuel oil by filter device purification after 12~24 hours
Storage storage, lower floor's viscous fluid then return to reaction kettle as semi-finished product and reconcile into liquid fuel, then pass through homogeneous with fuel oil with new
Machine is homogenized as ecological fuel oil.
Prepare rule：
1st, the dosage of bioliquid fuels and mineral oil should be coordinated, i.e. the research on maximum utilized quantity and mineral of bioliquid fuels
The minimum amount of oil plant must not be less than 1:1.35 (must not be less than with 1 kilogram of matched mineral oil of bioliquid fuels
1.35 kilogram).
2nd, adhesive is individually prepared spare.
3rd, low-carbon is without the alcohol in sulphur synthetic based on methanol, ethyl alcohol, and the selection of candy ketone Ester is can dissolve
In methanol or ethyl alcohol or can with its it is miscible be principle.Four class raw materials can be directly dissolved in cylinder in proportion stirs into uniform liquid
It is spare.
4th, bioliquid fuels (or bio-fuel) are (i.e. oily by bottom material (i.e. animal and plant fat) and auxiliary material by agitator
Sour tetrahydrofuran methyl esters and butyl oleate) to be fused into liquid fuel spare.
5th, when preparing, by bottom material (fuel oil and waste oil) and auxiliary material, (n-butanol, acetic acid and one contract two to mineral oil
Ethylene glycol monobutyl ether) it is placed directly in reaction kettle and stirs 6~8 minutes in proportion, then while stirring in proportion successively by biological fluids
State fuel, low-carbon continue stirring 6~8 minutes, then pass through without in sulphur synthetic, adhesive input reaction kettle after feeding intake
Homogenizer will homogenize liquid and be sent in precipitation knockout drum, and supernatant liquor can be purified by filter device and be given birth to for finished product after 12~24 hours
The storage storage of state fuel oil, lower floor's viscous fluid then return to reaction kettle as semi-finished product and reconcile into liquid fuel, then lead to fuel oil with new
Homogenizer is crossed to homogenize as ecological fuel oil.
The beneficial effects of the invention are as follows：Low-carbon and low-sulphur, sustainable cycle, and raw material sources extensively (bio-fuel is renewable,
Low-carbon is not only renewable without sulphur synthetic, can also make full use of the slag liquid of sugar wine factory, mineral oil that can utilize waste oil), production
It does not heat up in the process and does not cool down, is not pressurized and do not depressurize, slag liquid is reusable, and non-exhaust emission, energy consumption is extremely low, production cost
It is low.Ecological fuel oil is not only the power fuel of clean and effective, and is that (such as mineral oil is without using combustion for the very outstanding oil that makes a fire
Material oil, bio-oil materials dosage are no more than 10%, can also prepare the motor petrol that octane number is up to more than 93).
Specific embodiment
For a better understanding of the present invention, with reference to the embodiment content that the present invention is furture elucidated, but the present invention
Content is not limited solely to the following examples.
Embodiment 1：
Ecological fuel oil, it is prepared by bioliquid fuels, mineral oil, low-carbon without sulphur synthetic and adhesive；
Wherein bioliquid fuels, mineral oil, low-carbon are without weight percent shared by sulphur synthetic：Bioliquid fuels 20%,
Mineral oil 40%, low-carbon are without sulphur synthetic 40%；The addition of adhesive is bioliquid fuels, mineral oil and low-carbon
0.3% without sulphur synthetic total weight；
The bioliquid fuels are synthesized by animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate, each raw material
Shared weight percent is：Animal and plant fat 90%, tetrahydrofurfuryl oleate 6%, butyl oleate 4%；
The mineral oil is by following Material synthesis：1. (quality of fuel oil and waste oil respectively accounts for for fuel oil and waste oil
50%, waste oil is Waste gasoline), 2. n-butanol, 3. acetic acid, 4. diethylene glycol monobutyl ether, weight percent shared by each raw material
For：Fuel oil and waste oil 90%, n-butanol 2.5%, acetic acid 6%, diethylene glycol monobutyl ether 1.5%；
The low-carbon is synthesized without sulphur synthetic by alcohol, candy, ketone and four class substance of ester, alcohol, candy, ketone, ester weight ratio
=5:0.3:0.2:0.1；
The adhesive by alcohol water (alcohol water is made of alcohol and water, the quality of alcohol and water respectively account for 50%), it is bubble adhesive material, anti-
Rotten agent and antioxidant synthesis, weight percent shared by each raw material are：Alcohol water 55%, bubble adhesive material 25%, preservative 15%, antioxygen
Agent 5%.
The animal and plant fat is mixed by gutter oil, turpentine oil and castor oil, and weight percent is shared by gutter oil：
85%th, turpentine oil and castor oil 15%；Wherein weight percent shared by each raw material of turpentine oil and castor oil is：Turpentine oil 5%, castor
Sesame oil 95%.
The alcohol is methanol；Candy is xylose, and ketone is acetone, and ester is n-butyl acetate.
The bubble adhesive material is sodium alginate.
The preservative is sorbic acid.
The antioxidant is DBPC 2,6 ditertiary butyl p cresol.
The preparation method of above-mentioned ecology fuel oil, it includes the following steps：
1) bioliquid fuels are prepared：By above-mentioned raw materials and proportioning, choose animal and plant fat, tetrahydrofurfuryl oleate and
Butyl oleate；Animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate are mixed, stirring obtains bioliquid fuels；
2) mineral oil is prepared：By above-mentioned raw materials and proportioning, the following raw material is chosen：1. fuel oil and waste oil, 2. n-butanol,
3. acetic acid, 4. diethylene glycol monobutyl ether；It will 1. fuel oil and waste oil, 2. n-butanol, 3. acetic acid and 4. diglycol
Monobutyl ether mixes, and stirring obtains mineral oil；
3) low-carbon is prepared without sulphur synthetic：By above-mentioned raw materials and proportioning, alcohol, candy, ketone and ester are chosen；By alcohol, candy, ketone and
Ester mixes, and stirring obtains low-carbon without sulphur synthetic；
4) adhesive is prepared：By above-mentioned raw materials and proportioning, alcohol water, bubble adhesive material, preservative and antioxidant are chosen；Bubble is viscous
Substance, preservative and antioxidant are dissolved separately in alcohol water, and stirring obtains adhesive；
5) ecological fuel oil is prepared：By above-mentioned raw materials and proportioning, choose bioliquid fuels, mineral oil and low-carbon and closed without sulphur
Into solvent and adhesive；
Bioliquid fuels, mineral oil, low-carbon without sulphur synthetic and adhesive are mixed, stirring, then pass through homogeneous
Machine will homogenize liquid and be sent in precipitation knockout drum, and supernatant liquor is finished product ecology fuel oil by filter device purification after 12~24 hours
Storage storage, lower floor's viscous fluid then return to reaction kettle as semi-finished product and reconcile into liquid fuel, then pass through homogeneous with fuel oil with new
Machine is homogenized as ecological fuel oil.
The important technological parameters of product：38~45MJ/Kg of calorific value, 58~80 DEG C of flash-point, Cetane number 45~49, density
0.83~0.85, subzero 15~25 degree Celsius of freezing temperature, carbon dioxide, sulfur dioxide, oxynitrides discharge capacity difference
Lower than diesel oil 25% or so, 30% or so, 5% or so, kinematic viscosity (20 DEG C) 5.2mm2/s。
Embodiment 2：
Ecological fuel oil, it is prepared by bioliquid fuels, mineral oil, low-carbon without sulphur synthetic and adhesive；
Wherein bioliquid fuels, mineral oil, low-carbon are without weight percent shared by sulphur synthetic：Bioliquid fuels 23%,
Mineral oil 33%, low-carbon are without sulphur synthetic 44%；The addition of adhesive is bioliquid fuels, mineral oil and low-carbon
0.8% without sulphur synthetic total weight；
The bioliquid fuels are synthesized by animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate, each raw material
Shared weight percent is：Animal and plant fat 95%, tetrahydrofurfuryl oleate 3%, butyl oleate 2%；
The mineral oil is by following Material synthesis：1. (weight percent shared by each raw material is for fuel oil and waste oil：Combustion
Material oil 5%, waste oil 95%, waste oil are waste coal oil), 2. n-butanol, 3. acetic acid, 4. diethylene glycol monobutyl ether, each raw material institute
Accounting for weight percent is：Fuel oil and waste oil 95%, n-butanol 0.5%, acetic acid 3%, diethylene glycol monobutyl ether 1.5%；
The low-carbon is synthesized without sulphur synthetic by alcohol, candy, ketone and four class substance of ester, alcohol, candy, ketone, ester weight ratio
=5:0.3:0.2:0.1；
The adhesive by alcohol water (alcohol water is made of alcohol and water, the quality of alcohol and water respectively account for 50%), it is bubble adhesive material, anti-
Rotten agent and antioxidant synthesis, weight percent shared by each raw material are：Alcohol water 58%, bubble adhesive material 22%, preservative 13%, antioxygen
Agent 7%.
The animal and plant fat is mixed by gutter oil, turpentine oil and castor oil, and weight percent is shared by gutter oil：
95%th, turpentine oil and castor oil 5%.Wherein weight percent shared by each raw material of turpentine oil and castor oil is：Turpentine oil 95%, castor
Sesame oil 5%.
The alcohol is ethyl alcohol；Candy is glucose, and ketone is 2- butanone, and ester is n-butyl acetate.
The bubble adhesive material is coconut acid diethanolamine condensates.
The preservative is sodium benzoate.
The antioxidant is DBPC 2,6 ditertiary butyl p cresol.
The preparation method of above-mentioned ecology fuel oil, with embodiment 1, only raw material and proportioning are different.
The important technological parameters of product：38~45MJ/Kg of calorific value, 58~80 DEG C of flash-point, Cetane number 45~49, density
0.83~0.85, subzero 15~25 degree Celsius of freezing temperature, carbon dioxide, sulfur dioxide, oxynitrides discharge capacity difference
Lower than diesel oil 25% or so, 30% or so, 5% or so, kinematic viscosity (20 DEG C) 5.2mm2/s。
Embodiment 3：
Ecological fuel oil, it is prepared by bioliquid fuels, mineral oil, low-carbon without sulphur synthetic and adhesive；
Wherein bioliquid fuels, mineral oil, low-carbon are without weight percent shared by sulphur synthetic：Bioliquid fuels 22%,
Mineral oil 35%, low-carbon are without sulphur synthetic 43%；The addition of adhesive is bioliquid fuels, mineral oil and low-carbon
0.5% without sulphur synthetic total weight；
The bioliquid fuels are synthesized by animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate, each raw material
Shared weight percent is：Animal and plant fat 92%, tetrahydrofurfuryl oleate 4%, butyl oleate 4%；
The mineral oil is by following Material synthesis：1. (weight percent shared by each raw material is for fuel oil and waste oil：Combustion
Material oil 95%, waste oil 5%, waste oil is waste diesel), 2. n-butanol, 3. acetic acid, 4. diethylene glycol monobutyl ether, each raw material institute
Accounting for weight percent is：Fuel oil and waste oil 93%, n-butanol 3%, acetic acid 3%, diethylene glycol monobutyl ether 1%；
The low-carbon is synthesized without sulphur synthetic by alcohol, candy, ketone and four class substance of ester, alcohol, candy, ketone, ester weight ratio
=5:0.3:0.2:0.1；
The adhesive by alcohol water (alcohol water is made of alcohol and water, the quality of alcohol and water respectively account for 50%), it is bubble adhesive material, anti-
Rotten agent and antioxidant synthesis, weight percent shared by each raw material are：Alcohol water 60%, bubble adhesive material 20%, preservative 10%, antioxygen
Agent 10%.
The animal and plant fat is mixed by gutter oil, turpentine oil and castor oil, and weight percent is shared by gutter oil：
90%th, turpentine oil and castor oil 10%.Wherein weight percent shared by each raw material of turpentine oil and castor oil is：Turpentine oil 40%,
Castor oil 60%.
The alcohol is sorbierite；Candy is xylose, and ketone is acetone, and ester is n-butyl acetate.
The bubble adhesive material is tri-n-butyl citrate.
The preservative is sorbic acid.
The antioxidant is DBPC 2,6 ditertiary butyl p cresol.
The preparation method of above-mentioned ecology fuel oil, with embodiment 1, only raw material and proportioning are different.
The important technological parameters of product：38~45MJ/Kg of calorific value, 58~80 DEG C of flash-point, Cetane number 45~49, density
0.83~0.85, subzero 15~25 degree Celsius of freezing temperature, carbon dioxide, sulfur dioxide, oxynitrides discharge capacity difference
Lower than diesel oil 25% or so, 30% or so, 5% or so, kinematic viscosity (20 DEG C) 5.2mm2/s。
Embodiment 4：
Ecological fuel oil, it is prepared by bioliquid fuels, mineral oil, low-carbon without sulphur synthetic and adhesive；
Wherein bioliquid fuels, mineral oil, low-carbon are without weight percent shared by sulphur synthetic：Bioliquid fuels 21%,
Mineral oil 36%, low-carbon are without sulphur synthetic 43%；The addition of adhesive is bioliquid fuels, mineral oil and low-carbon
0.6% without sulphur synthetic total weight；
The bioliquid fuels are synthesized by animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate, each raw material
Shared weight percent is：Animal and plant fat 92%, tetrahydrofurfuryl oleate 5%, butyl oleate 3%；
The mineral oil is by following Material synthesis：1. (weight percent shared by each raw material is for fuel oil and waste oil：Combustion
Material oil 65%, waste oil 35%；Waste oil is Waste gasoline, waste coal is oily and the mixing of waste diesel, weight percent shared by each raw material are：It is useless
Gasoline 20%, waste coal oil 40%, waste diesel 40%), 2. n-butanol, 3. acetic acid, 4. diethylene glycol monobutyl ether, each raw material institute
Accounting for weight percent is：Fuel oil and waste oil 91%, n-butanol 2.7%, acetic acid 5%, diethylene glycol monobutyl ether 1.3%；
The low-carbon is synthesized without sulphur synthetic by alcohol, candy, ketone and four class substance of ester, alcohol, candy, ketone, ester weight ratio
=5:0.3:0.2:0.1；
The adhesive by alcohol water (alcohol water is made of alcohol and water, the quality of alcohol and water respectively account for 50%), it is bubble adhesive material, anti-
Rotten agent and antioxidant synthesis, weight percent shared by each raw material are：Alcohol water 60%, bubble adhesive material 20%, preservative 12%, antioxygen
Agent 8%.
The animal and plant fat is mixed by gutter oil, turpentine oil and castor oil, and weight percent is shared by gutter oil：
88%th, turpentine oil and castor oil 12%.Wherein weight percent shared by each raw material of turpentine oil and castor oil is：Turpentine oil 60%,
Castor oil 40%.
The alcohol is methanol, ethyl alcohol and sorbierite, and shared weight percent is：Methanol 20%, ethyl alcohol 20%, sorbierite
60%；Candy is glucose, and ketone is 2- butanone, and ester is n-butyl acetate.
The bubble adhesive material is sour for an ancient wind instrument alkene and glue, and the quality of an ancient wind instrument alkene and glue acid respectively accounts for 50%.
The preservative is sodium benzoate.
The antioxidant is DBPC 2,6 ditertiary butyl p cresol.
The preparation method of above-mentioned ecology fuel oil, with embodiment 1, only raw material and proportioning are different.
The important technological parameters of product：38~45MJ/Kg of calorific value, 58~80 DEG C of flash-point, Cetane number 45~49, density
0.83~0.85, subzero 15~25 degree Celsius of freezing temperature, carbon dioxide, sulfur dioxide, oxynitrides discharge capacity difference
Lower than diesel oil 25% or so, 30% or so, 5% or so, kinematic viscosity (20 DEG C) 5.2mm2/s。
Claims (9)
1. ecological fuel oil, it is characterised in that it is by bioliquid fuels, mineral oil, low-carbon without sulphur synthetic and adhesive system
It is standby to form；Wherein bioliquid fuels, mineral oil, low-carbon are without weight percent shared by sulphur synthetic：Biological liquid fires
Material 20~25%, mineral oil 30~40%, low-carbon are without sulphur synthetic 40~45%；The addition of adhesive is biological liquid
Fuel, mineral oil and low-carbon without sulphur synthetic total weight 0.3~0.8%；
The bioliquid fuels are synthesized by animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate, shared by each raw material
Weight percent is：Animal and plant fat 90~95%, tetrahydrofurfuryl oleate 3~6%, butyl oleate 2~4%；
The mineral oil is by following Material synthesis：1. fuel oil and waste oil, 2. n-butanol, 3. acetic acid, 4. a contracting diethyl two
Alcohol monobutyl ether, weight percent shared by each raw material are：Fuel oil and waste oil 90~95%, n-butanol 0.5~3%, acetic acid 3~
6%th, diethylene glycol monobutyl ether 1~1.5%；Ratio wherein between fuel oil and waste oil is arbitrary quality proportioning；
The low-carbon is synthesized without sulphur synthetic by alcohol, candy, ketone and four class substance of ester, alcohol, candy, ketone, ester weight ratio=5:
0.3:0.2:0.1；
The adhesive is synthesized by alcohol water, bubble adhesive material, preservative and antioxidant, and weight percent shared by each raw material is：Alcohol
Water 55~60%, bubble adhesive material 20~25%, preservative 10~15%, antioxidant 5~10%；Wherein, alcohol water is by alcohol and water group
Into the quality of alcohol and water respectively accounts for 50%；
The bubble adhesive material is sodium alginate, in coconut acid diethanolamine condensates, tri-n-butyl citrate, an ancient wind instrument alkene, glue acid
One or two or more kinds press arbitrary quality proportioning mixing.
2. it is according to claim 1 ecology fuel oil, which is characterized in that the animal and plant fat by gutter oil, turpentine oil,
Castor oil synthesizes, and weight percent shared by gutter oil is：85%~95%, weight percent shared by turpentine oil and castor oil is：
5%~15%, turpentine oil and castor oil are mixed by arbitrary quality proportioning.
3. ecology fuel oil according to claim 1, which is characterized in that the low-carbon is first without the alcohol in sulphur synthetic
One or two or more kinds in alcohol, ethyl alcohol, sorbierite press the mixing of arbitrary quality proportioning；Candy is xylose, one kind in glucose,
Ketone is acetone, one kind in 2- butanone, and ester is n-butyl acetate.
4. ecology fuel oil according to claim 1, which is characterized in that the preservative is sorbic acid, in sodium benzoate
One kind.
5. ecology fuel oil according to claim 1, which is characterized in that the antioxidant is 2,6- di-t-butyls to first
Phenol.
6. ecology fuel oil according to claim 1, which is characterized in that waste oil is included in Waste gasoline, waste coal oil, waste diesel
Arbitrary quality proportioning is pressed in one or more mixing during a variety of mixing.
7. ecology fuel oil according to claim 1, which is characterized in that the maximum weight dosage and mineral of biological liquid fuel
The minimum weight dosage of oil plant must not be less than 1:1.35.
8. the preparation method of ecology fuel oil as described in claim 1, it is characterised in that it includes the following steps：
1) bioliquid fuels are prepared：The weight percent as shared by each raw material is：Animal and plant fat 90~95%, oleic acid tetrahydrochysene furan
It mutters methyl esters 3~6%, butyl oleate 2~4%, chooses animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate；
Animal and plant fat, tetrahydrofurfuryl oleate and butyl oleate are mixed, stirring obtains bioliquid fuels；
2) mineral oil is prepared：The weight percent as shared by each raw material is：Fuel oil and waste oil 90~95%, n-butanol 0.5~
3%th, acetic acid 3~6%, diethylene glycol monobutyl ether 1~1.5%；Choose the following raw material：1. fuel oil and waste oil, 2. positive fourth
Alcohol, 3. acetic acid, 4. diethylene glycol monobutyl ether；
Ratio wherein between fuel oil and waste oil is arbitrary quality proportioning；
1. fuel oil and waste oil, 2. n-butanol, 3. acetic acid and 4. diethylene glycol monobutyl ether mixing are incited somebody to action, stirs, obtains mineral
Oil plant；
3) low-carbon is prepared without sulphur synthetic：By alcohol, candy, ketone, ester weight ratio=5:0.3:0.2:0.1, choose alcohol, candy, ketone
And ester；
Alcohol, candy, ketone and ester are mixed, stirring obtains low-carbon without sulphur synthetic；
4) adhesive is prepared：The weight percent as shared by each raw material is：Alcohol water 55~60%, bubble adhesive material 20~25%, anti-corrosion
Agent 10~15%, antioxidant 5~10%；Choose alcohol water, bubble adhesive material, preservative and antioxidant；
Wherein, alcohol water is made of alcohol and water, and the quality of alcohol and water respectively accounts for 50%；
The bubble adhesive material is sodium alginate, in coconut acid diethanolamine condensates, tri-n-butyl citrate, an ancient wind instrument alkene, glue acid
One or two or more kinds press arbitrary quality proportioning mixing；
Bubble adhesive material, preservative and antioxidant are dissolved separately in alcohol water, stirs, obtains adhesive；
5) ecological fuel oil is prepared：The weight percent as shared by bioliquid fuels, mineral oil, low-carbon without sulphur synthetic is：
Bioliquid fuels 20~25%, mineral oil 30~40%, low-carbon choose biological liquid combustion without sulphur synthetic 40~45%
Material, mineral oil and low-carbon are without sulphur synthetic；
By adhesive addition for bioliquid fuels, mineral oil and low-carbon without sulphur synthetic total weight 0.3~
0.8%, choose adhesive；
Bioliquid fuels, mineral oil, low-carbon are mixed without sulphur synthetic and adhesive, stirring, then will by homogenizer
It homogenizes liquid to be sent in precipitation knockout drum, supernatant liquor is put in storage by filter device purification for finished product ecology fuel oil after 12~24 hours
Storage.
9. the preparation method of ecology fuel oil as claimed in claim 8, it is characterised in that the alcohol in step 4) is in methanol, ethyl alcohol
One kind or two kinds press arbitrary quality proportioning mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610985002.XA CN106520218B (en) | 2016-10-29 | 2016-10-29 | Ecological fuel oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610985002.XA CN106520218B (en) | 2016-10-29 | 2016-10-29 | Ecological fuel oil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106520218A CN106520218A (en) | 2017-03-22 |
| CN106520218B true CN106520218B (en) | 2018-06-08 |
Family
ID=58350502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610985002.XA Active CN106520218B (en) | 2016-10-29 | 2016-10-29 | Ecological fuel oil and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106520218B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189829A (en) * | 2017-04-25 | 2017-09-22 | 南宁市钱隆汽车租赁有限公司 | Gasoline additive |
| CN113061473A (en) * | 2021-03-15 | 2021-07-02 | 浙江顺航能源有限公司 | Methanol-ethanol vehicle gasoline additive and production process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339566A (en) * | 2000-08-04 | 2002-03-13 | 滨田敬郎 | Low pollution fuel |
| CN1616605A (en) * | 2004-10-15 | 2005-05-18 | 骆成元 | Smelting fuel oil |
| CN103666603A (en) * | 2013-12-19 | 2014-03-26 | 关平 | Environment friendly low-sulfur diesel antiwear agent |
| CN103992828A (en) * | 2014-05-20 | 2014-08-20 | 泉州市欧美润滑油制品有限公司 | Lubricating anti-wear diesel start protection additive |
-
2016
- 2016-10-29 CN CN201610985002.XA patent/CN106520218B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339566A (en) * | 2000-08-04 | 2002-03-13 | 滨田敬郎 | Low pollution fuel |
| CN1616605A (en) * | 2004-10-15 | 2005-05-18 | 骆成元 | Smelting fuel oil |
| CN103666603A (en) * | 2013-12-19 | 2014-03-26 | 关平 | Environment friendly low-sulfur diesel antiwear agent |
| CN103992828A (en) * | 2014-05-20 | 2014-08-20 | 泉州市欧美润滑油制品有限公司 | Lubricating anti-wear diesel start protection additive |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106520218A (en) | 2017-03-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102304289B (en) | Road asphalt prepared by adding plant asphalt to petroleum asphalt and production method thereof | |
| EP2883914B1 (en) | Biological asphalt and preparation method thereof | |
| CN103642541B (en) | A kind of environment protection gasoline additive and preparation method thereof | |
| CN102660337A (en) | Method for preparing novel clean synthetic diesel oil | |
| Zulqarnain et al. | Overview of feedstocks for sustainable biodiesel production and implementation of the biodiesel program in Pakistan | |
| CN106520218B (en) | Ecological fuel oil and preparation method thereof | |
| CN104087351A (en) | Improved biodiesel and preparation method thereof | |
| CN103122257B (en) | Bio-oil heavy constituent and the mixing method of oil secondary processing mink cell focus | |
| CN106609168A (en) | Coal based biofuel | |
| CN106316727B (en) | A kind of porous particulated ammonium oil explosive and preparation method thereof | |
| CN103013554A (en) | Device and method for producing biodiesel with illegal cooking oil and waste engine oil | |
| CN102876403A (en) | Alcohol ether diesel fuel for new-energy-resource vehicle | |
| CN101402888A (en) | Composite additive and process for producing methanol diesel oil thereof | |
| CN101173175A (en) | Method for producing biological diesel oil with waste propagation oil and fat | |
| CN103695045B (en) | Alcohol ether fuel and preparation method thereof | |
| CN101838562B (en) | Proportional bio-diesel and preparation method thereof | |
| CN101215482A (en) | Fluid fuel for alcohol hydrocarbon diesel engine and preparation method thereof | |
| CN105132043B (en) | A kind of bio-fuel-oil and preparation method thereof | |
| CN102229821A (en) | Micro-emulsified methanol diesel and preparation method thereof | |
| CN103756791B (en) | The synthetic method of biofuel | |
| CN202555213U (en) | Production device for clean environment-friendly dimethyl carbonate diesel oil | |
| CN106318493A (en) | Compound gasoline additive | |
| CN106281503A (en) | A kind of composite fuel additive | |
| CN106635192A (en) | Preparation method of alcohol-based fuel | |
| CN103666593A (en) | Preparation method of composite biodiesel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |