CN107614089A - Humidity Control Device - Google Patents
Humidity Control Device Download PDFInfo
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- CN107614089A CN107614089A CN201680013181.9A CN201680013181A CN107614089A CN 107614089 A CN107614089 A CN 107614089A CN 201680013181 A CN201680013181 A CN 201680013181A CN 107614089 A CN107614089 A CN 107614089A
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- hygroscopic material
- moisture absorption
- air
- processing unit
- moisture
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/28—Selection of materials for use as drying agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F3/00—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
- F24F3/12—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
- F24F3/14—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
- F24F3/147—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification with both heat and humidity transfer between supplied and exhausted air
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Drying Of Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Central Air Conditioning (AREA)
Abstract
The humidity control device of the present invention can reduce the energy-output ratio needed for the regeneration treatment of hygroscopic material.The humidity control device possesses：Moisture absorption portion (42a, 42b), have containing outside stimulus as defined in response and reversibly become and turn to hydrophily and the high molecular hygroscopic material of hydrophobic stimulating responsive；Assigning unit (heating part 22) is stimulated, assigns outside stimulus so that the hygroscopic material is switched into hydrophobicity from hydrophily；And heating part (heating part 22), heat is assigned so that the water evaporation discharged from the hygroscopic material.
Description
Technical field
The present invention relates to a kind of humidity control device using hygroscopic material adjusting air humidity.
Background technology
At present, the humidity control device as the humidity in adjustment air, it is known to use zeolite (hygroscopicity porous material) etc.
The humidity control device of hygroscopic material (referring for example to patent document 1,2).
In such a humidity control device, make the moisture in the hygroscopic material temporary absorption room air such as zeolite and room air is carried out
Dehumidifying, and by making to have absorbed the hygroscopic material of moisture against the hot blast of high temperature, so that the moisture evaporation that hygroscopic material is absorbed
And as high temperature, high humidity air and take out, using room air make the high temperature, high humidity air cool down, thus make high temperature, height
Moisture in wet air condenses and reclaims moisture.
Prior art literature
Patent document
Patent document 1:Japanese Laid-Open Patent Publication " JP 2003-144833 publications "
Patent document 2:Japanese Laid-Open Patent Publication " JP 2001-259349 publications "
The content of the invention
The technical problems to be solved by the invention
However, in the conventional humidity control device using hygroscopic material, hygroscopic material (zeolite etc.) and the hydrone shape absorbed
Into silanol key and strong bonded, thus, hygroscopic material catches the moisture in air.
Therefore, in order to discharge moisture that hygroscopic material adsorbed and regenerate hygroscopic material, it is necessary to be heated at high temperature to cut off
The strong bond of hygroscopic material and hydrone, so as to the energy-intensive needed for the regeneration treatment of hygroscopic material be present.
For example, when using zeolite as hygroscopic material, in order to carry out regeneration treatment, hygroscopic material must be heated to 200 DEG C with
The high temperature of upper (local is 400 DEG C or so).Moreover, contain when using to be referred to as based on the PAA of polymeric sorbent
During the hygroscopic material of hydrophilic macromolecule, it must also make to be evaporated from the inside of hygroscopic material by the water that hygroscopic material is caught in regeneration treatment,
And it must be also heated at high temperature.
The present invention be in view of described problem and complete, its object is to reduce use hygroscopic material humidity control device in hygroscopic material
Regeneration treatment needed for energy-output ratio.
The means solved the problems, such as
Humidity control device in the form of the present invention is characterised by possessing：Hygroscopic material, pierced containing outside as defined in response
Swash and reversibly become and turn to hydrophily and hydrophobic stimulating responsive macromolecule；Assigning unit is stimulated, assigns outside stimulus to incite somebody to action
The hygroscopic material switches to hydrophobicity from hydrophily；And heating part, heat is assigned so that thin by the way that the hygroscopic material is switched to
It is water-based and from the hygroscopic material release water evaporation.
Invention effect
According to the composition, can by outside stimulus as defined in being assigned to hygroscopic material by hygroscopic material switch to hydrophobicity from
And the moisture for being absorbed hygroscopic material oozes out, and can be carried out by the water oozed out to driven hygroscopic material heating make its evaporate so that
Hygroscopic material is regenerated as drying regime.So, when making from the moisture evaporation that hygroscopic material oozes out, with making to be adsorbed in boiling as in the past
Compare, can be evaporated the water with less heat during the moisture evaporation of the hygroscopic materials such as stone.Thus, the regeneration treatment of hygroscopic material can be reduced
Required energy-output ratio.
Brief description of the drawings
Fig. 1 is the explanation figure of the schematic configuration for the humidity control device for representing the first embodiment of the present invention.
Fig. 2 is the top view of the moisture absorption unit possessed in the humidity control device shown in Fig. 1.
Fig. 3 (a)~(c) is the explanation figure of the characteristic in moisture absorption portion for representing to possess in the moisture absorption unit shown in Fig. 2.
Fig. 4 is the top view of the moisture absorption unit possessed in the humidity control device of second embodiment of the present invention.
Fig. 5 is the explanation figure of the schematic configuration for the humidity control device for representing third embodiment of the present invention.
Fig. 6 is the explanation figure of the schematic configuration for the humidity control device for representing the 4th embodiment of the present invention.
Fig. 7 is the explanation figure of the schematic configuration for the humidity control device for representing the 5th embodiment of the present invention.
Embodiment
(first embodiment)
One embodiment of the present invention is illustrated.
Fig. 1 is the explanation figure of the schematic configuration for the humidity control device 1 for representing present embodiment.As shown in the drawing, humidity control device 1
Possess the air road (the 2nd processing unit) 20 of the 1st air road (the 1st processing unit) the 10, the 2nd, cooling air road 30, moisture absorption unit 40 and row
Tank 50.
Fig. 2 is the top view of moisture absorption unit 40.As shown in Figures 1 and 2, moisture absorption unit 40 possesses generally cylindrical support
Portion 41, by the rotary shaft 43 at the center of supporting part 41, with rotary shaft 43 be configured at substantially in parallel with rotary shaft 43 be axle and
The position of rotational symmetry and 2 moisture absorption portion 42a, 42b through supporting part 41 and it is connected to the motor (switching part) of rotary shaft 43
44.In addition, it is filled with hygroscopic material described later in moisture absorption portion 42a, 42b.
The rotation driving rotary shaft 43 according to the instruction of control unit (not shown) of motor 44, thus, by moisture absorption unit 40
Position switches to the 1st state and the 2nd state, and the 1st state refers to that moisture absorption portion 42a is configured at the 1st air road 10, moisture absorption portion 42b
The state on the 2nd air road 20 is configured at, the 2nd state refers to that moisture absorption portion 42a is configured at the 2nd air road 20, moisture absorption portion 42b configurations
State in the 1st air road 10.
The control unit switches the 1st state and the 2nd state at the time of each regulation.For example, can be whenever run time
Switch when reaching the stipulated time, can also be switched according to the instruction of user, also settable sensing moisture absorption portion 42a, 42b hygroscopic capacity
Sensor and switched over when being configured at the hygroscopic capacity in moisture absorption portion on the 1st air road 10 and reaching more than setting.It is in addition, described
Control unit can be the logic circuit (hardware) for being formed at integrated circuit (IC chip) etc., also can be by by including CPU (Central
Processing Unit) or the computer of the processor such as DSP (Digital Signal Processor) perform software and realize.
When moisture absorption portion 42a, 42b are configured at the 1st air road 10, be arranged in the 1st air road 10 perpendicular to rotary shaft 43
Direction on whole region, therefore, the air for flowing through the 1st air road 10 be with general full dose by moisture absorption portion 42a (or
42b).Equally, when moisture absorption portion 42a, 42b is configured at the 2nd air road 20, be arranged in the 2nd air road 20 perpendicular to rotary shaft
Whole region on 43 direction, therefore, the air for flowing through the 2nd air road 20 be with general full dose by moisture absorption portion 42a (or
42b)。
In addition, also can the 1st air road 10 wall portion and be configured at the 1st air road 10 moisture absorption portion 42a (or 42b) it
Between, it is configured to prevent the seal member that the air in the 1st air road 10 is leaked into outside the 1st air road 10.Equally, also can be
Between 2nd air road 20 and the moisture absorption portion 42b (or 42a) for being configured at the 2nd air road 20, it is configured to prevent the 2nd air road
The seal member that air in 20 is leaked into outside the 2nd air road 20.
Moreover, moisture absorption portion 42a, 42b may be configured as, possess：Be centered around the moisture absorption portion 42a, 42b outer peripheral face base material and
The moisture absorption portion 42a, 42b that the base material is surrounded inside division are the partition member (not shown) in multiple areas, and are utilized
The partition member stably keeps forming the powder of hygroscopic material or the macromolecule of particle shape.
As the hygroscopic material for being filled in moisture absorption portion 42a, 42b, it can be used and contain the high molecular hirudo leech of stimulating responsive
Hygroscopic material, the stimulating responsive macromolecule can response external stimulate and make can between hydrophily and hydrophobicity with the compatibility of water
Change inversely.In addition, in present embodiment, make the parent with water for using response heat as the stimulating responsive macromolecule
The composition of the temperature-responsive macromolecule (thermo-responsive macromolecule) reversibly changed with property illustrates.Temperature-responsive high score
Son can make temperature change by using easy heater, and reversibly carry out the absorption of the moisture in air with being absorbed
The release of moisture, therefore, it is especially suitable for damping machine.In addition, on the specific of the hygroscopic material that is used in moisture absorption portion 42a, 42b
Example and its manufacture method, will be in description.
Fig. 3 (a)~(c) is the characteristic for schematically showing moisture absorption portion 42a, 42b for being made up of temperature-responsive macromolecule
Illustrate figure.
As shown in Fig. 3 (a), temperature-responsive macromolecule is in unheated state (lower critical solution temperature (LCST (Lower
Critical Solution Temperature) following low-temperature condition)) under show hydrophily, the moisture in absorption air.
In addition, so-called LCST refers to the temperature of the boundary switched as temperature-responsive macromolecule between hydrophily and hydrophobicity.
On the other hand, as shown in Fig. 3 (b), if carrying out being heated to more than LCST to temperature-responsive macromolecule, then meeting
Hydrophobicity is switched to from hydrophily, the moisture that temperature-responsive macromolecule is absorbed can be released.Therefore, without as conventional boiling
The hygroscopic materials such as stone apply significantly heat to the moisture adsorbed like that and make its evaporation, can make it with relatively small number of heat with liquid
The form of body water is directly taken out from hygroscopic material.For example, by using temperature (such as 40 DEG C of left sides that LCST is the degree more than room temperature
It is right) temperature-responsive macromolecule, be heated at high temperature without as the dehumidifier using hygroscopic materials such as zeolites, only in the past
The temperature that hygroscopic material reaches more than LCST degree must be heated to, just can take out absorbed moisture.
Moreover, as shown in Fig. 3 (c), also continued to heating after temperature-responsive macromolecule switches to hydrophobicity (or to suction
Moist wood supplies hot blast), thus, the water evaporation oozed out on the surface of hygroscopic material can be easily made with relatively small number of heat.In addition,
Hygroscopic material switches to the water oozed out after hydrophobicity in the outside of hygroscopic material will not be as being adsorbed on the hygroscopic materials such as conventional zeolite
Water is bonded with silanol key etc. like that, but is liberated and footloose state is (almost without fettering the water that is adsorbed of hygroscopic material
Power or the few state of the power), accordingly, it is capable to efficiently make its evaporation at relatively low temperatures.For example, only set by assigning
The air of set point of temperature more than 40 DEG C within the scope of less than 70 DEG C of temperature, it is efficient like that when just can be heated to the water to medicinal cupping
Evaporate on ground.
1st air road 10 possesses suction unit 11, fan 12 and exhaust portion 13.If driving fan 12, then as dehumidifying
The air of object can be taken into the 1st air road 10 by the attraction of fan 12 from suction unit 11, and passes through moisture absorption portion
42a (or 42b) and dehumidify after discharged from exhaust portion 13.
2nd air road 20 possesses suction unit 21, heating part 22, fan 23, cooling end 24, Drainage Division 25 and exhaust portion 26.
Moreover, possesses heater 22a in heating part 22.
If driving fan 23, then the air as dehumidifying object can be taken by the attraction of fan 23 from suction unit 21
Enter into the 2nd air road 20, and heated and by moisture absorption portion 42b (or 42a) by heating part 22.Thus, by moisture absorption portion 42b (or
42a) absorb moisture by being heated to more than LCST, oozed out on moisture absorption portion 42b (or 42a) surface in the form of water droplet and
It is evaporated in air.Therefore, moisture absorption portion 42b (or 42a) is regenerated as drying regime (or state of hygroscopic capacity decline).
In addition, as long as heating part 22 is that moisture absorption portion 42b (or 42a) can be heated into hygroscopic material to the heating-up temperature of air
The temperature that the water droplet oozed out on more than LCST and moisture absorption portion 42b (or 42a) surface can evaporate, then be not particularly limited, this implementation
It is set as in mode in the range of 40 DEG C~70 DEG C.
Cooling end 24 is sent to by the air-supply power of fan 23 by moisture absorption portion 42b (or 42a) air.Moreover, cooling end
24 outer surface touches the air for flowing through cooling air road 30, thus, flows through the sky as dehumidifying object in cooling end 24
Gas (by moisture absorption portion 42b (or 42a) air) is cooled, and the moisture in the air condenses and separated with the air, and adheres to
In the inwall of cooling end 24.
Moreover, the 2nd air road 20 tilts downwards from cooling end 24 to Drainage Division 25, condensed in the inwall of cooling end 24
Inwall transmission of the water droplet along the 2nd air road 20 and from the row of Drainage Division 25 to rhone 50.Moreover, after being dehumidified by cooling end 24
Air discharged from exhaust portion 26.
Cooling air road 30 possesses suction unit 31, fan 32 and exhaust portion 33.If driving fan 32, then cooling is used
Air is taken into cooling air road 30 by the attraction of fan 32 from suction unit 31, the cooling with the 2nd air road 20
The wall contacts in portion 24 and cool down cooling end 24, discharged afterwards from exhaust portion 33.In addition, pass through moisture absorption in the 2nd air road 20
Portion 42b (or 42a) and reach cooling end 24 air be comprising from moisture absorption portion 42b (or 42a) evaporation moisture high humility shape
State, therefore, the vapor in the air is easily set to turn into water droplet using the cooling of room temperature degree.Accordingly, it is capable to efficiently inhaled
Wet end 42a, 42b regeneration and the recovery of the water from moisture absorption portion 42a, 42b discharge.In addition, in the outer wall of cooling end 24 and/or interior
Wall, fan etc. is may also set up, to promote the heat exchange of air of the air in the 2nd air road 20 with flowing through cooling air road 30.
As previously discussed, the humidity control device 1 of present embodiment possesses：Moisture absorption portion 42a, 42b, comprising containing temperature-responsive
The hygroscopic material of macromolecule (stimulating responsive macromolecule), the temperature-responsive macromolecule can be made according to temperature (outside stimulus) with
The compatibility of water reversibly changes between hydrophily and hydrophobicity；And heating part (stimulating assigning unit, heater) 22, pass through
The hygroscopic material for having absorbed water is heated and the hygroscopic material is switched into hydrophobicity, so as to which the moisture absorbed be released
Put and evaporate.
Thus, without as the hygroscopic materials such as conventional zeolite, significantly heat is applied to the moisture of absorption and makes its steaming
Hair, can be directly taken out in the form of liquid water by the moisture that relatively small number of heat is absorbed hygroscopic material, evaporated.That is, it is only logical
Cross and hygroscopic material be heated to be more than LCST (such as 40 DEG C or so), the moisture that hygroscopic material is absorbed can just discharged from hygroscopic material,
And easily make its evaporation.Therefore, compared with using the situation of the hygroscopic materials such as conventional zeolite, the regeneration treatment of hygroscopic material can be reduced
Required energy-output ratio.
It is to utilize the air being taken into via suction unit 31 from outside for cooling air road 30 in addition, in present embodiment
The composition for carrying out the cooling of cooling end 24 illustrates, but is not limited to this.For example, air-conditioning device (not shown), which can also be used, to be made
The air cooling being taken into from outside, and carry out cooling end 24 using the air being cooled to than extraneous gas temperature lower temperature
Cooling.And, however it is not limited to there is the composition of air as cooling flow of fluid in cooling air road 30, also may be, for example, to make
The cooling of cooling end 24 is carried out with other coolings such as water with fluid.
It is (cold using the air being taken into via suction unit 31 from outside to cooling air road 30 moreover, in present embodiment
But with fluid) carry out the cooling of cooling end 24 after, the composition that the air is discharged from exhaust portion 33 illustrates, but and unlimited
In this.For example, or, using cooling way (not shown), make to pass through the air with flowing through the 2nd air road 20 in cooling end 24
Carry out heat exchange and make temperature rise cooling air road 30 in air (cooling fluid) cool down, and make its again with it is cold
But circulated in the heat exchange department in portion 24.Moreover, as long as the composition of the cooling way can make the air in cooling air road 30 (cold
But fluid is used) cooling, then it is not particularly limited, for example, also may be configured as, with flowing through the air on the 1st air road 10 or flowing through
Air before the heated portion 22 on the 2nd air road 20 is heated carries out heat exchange.
It is that the composition for possessing 2 moisture absorption portions 42a, 42b for moisture absorption unit 40 illustrates moreover, in present embodiment,
But the quantity in moisture absorption portion is not limited to this, can also possess the moisture absorption portion of more than 3, and by any one in these multiple moisture absorption portions
The 1st air road 10 is configured at, any one is configured at the 2nd air road 20 by other.
Moreover, also can moisture absorption portion 42a, 42b upstream side (between suction unit 11 and moisture absorption unit 40 and suction unit 21 with
Between moisture absorption unit) and downstream (between moisture absorption unit 40 and exhaust portion 13 and between moisture absorption unit 40 and cooling end 24) setting
For switching the air door (damper) (not shown) of air flow circuit, using these each air doors, moisture absorption portion 42a, 42b wind will be passed through
Switched between the air roads 10 of Lu 1 and the 2nd air road 20.That is, also can by controlling the action of each air door, switch to as
Under (i), (ii) state：(i) moisture absorption portion 42a is configured with the 1st air road 10 from suction unit 11 to exhaust portion 13, from air-breathing
Portion 21 is configured with moisture absorption portion 42b state to the 2nd air road 20 of cooling end 24；And (ii) from suction unit 11 to exhaust portion 13
The 1st air road 10 be configured with moisture absorption portion 42b, be configured with moisture absorption portion on the 2nd air road 20 from suction unit 21 to cooling end 24
42a state.As the air door, can be used such as valve or portable plate.
Moreover, in present embodiment, it is the columned shape (flow direction with air for moisture absorption portion 42a, 42b to be
Parallel section is shaped as circle) composition illustrate, but moisture absorption portion 42a, 42b shape are not limited to this, also can root
Suitably changed according to the cross sectional shape on the 1st air road 10 and the 2nd air road 20.
Moreover, in present embodiment, moisture absorption portion is sent to by the air after the heated portion 22 on the 2nd air road 20 is heated
42a, 42b, and carry out (i) and be used to make possessed hygroscopic material in moisture absorption portion 42a, 42b to switch to hydrophobic add from hydrophily
Heat treatment (stimulating imparting to handle) and (ii) are used for the heating for making the water evaporation from hygroscopic material release.That is, described (i),
(ii) heating is by common heater meanses progress.However, the composition of humidity control device 1 is not limited to this, can set respectively
Put and be mainly used in the heater meanses (stimulation assigning unit) of the heating of (i) described in progress and be mainly used in (ii) described in progress
The heater meanses of heating.
(second embodiment)
Another embodiment of the present invention is illustrated.In addition, for convenience of description, for there is phase with first embodiment
The part mark same-sign of congenerous, and the description thereof will be omitted.
In the humidity control device 1 of present embodiment, possess instead of the moisture absorption unit 40 in first embodiment shown in Fig. 4
Moisture absorption unit 40b.Fig. 4 is moisture absorption unit 40b top view.
In first embodiment, illustrated for following composition：Columned supporting part 41 possesses 2 moisture absorption portions
42a, 42b, these each moisture absorption portion 42a, 42b allocation position are switched into the 1st state and the 2nd state at the time of regulation.
On the other hand, in present embodiment, as shown in figure 4, using the cylindrical shape (roller possessed centered on rotary shaft 43
Shape) moisture absorption portion 42c moisture absorption unit 40b.That is, it is filled with hygroscopic material in moisture absorption unit 40b substantially whole region.Moreover,
The action of control unit controlled motor 44, make moisture absorption unit 40b centered on rotary shaft 43 and with defined rotary speed (for example,
A few minutes~dozens of minutes rotates the speed of 1 time) rotation.
In addition, as the hygroscopic material for being filled in moisture absorption portion 42c, moisture absorption portion 42a, 42b with first embodiment can be used
The hygroscopic material identical hygroscopic material of middle filling.
According to the composition of present embodiment, a moisture absorption portion 42c part is configured at the 1st air road 10, another part configuration
In the 2nd air road 20, and moisture absorption portion 42c becomes as follows relative to the relative position on the 1st air road 10 and the 2nd air road 20
Change：Moisture absorption portion 42c's moves from the part of the moisture absorption of the 1st air road 10 to the 2nd air road 20 and regenerates the (water that release has absorbed
Point), and moved again to the 1st air road 10.Thus, can be carried out continuously at the 1st of the air made in moisture absorption portion 42c absorption airs
Manage and make the 2nd processing of the water release absorbed in moisture absorption portion 42c, evaporation.
(the 3rd embodiment)
Another embodiment of the invention is illustrated.In addition, for convenience of description, for there is phase with the embodiment
The part mark same-sign of congenerous, and the description thereof will be omitted.
Fig. 5 is the explanation figure of the schematic configuration for the humidity control device 1 for representing present embodiment.In addition, in example shown in Fig. 5,
The moisture absorption unit 40b shown in Fig. 4 is used, but is not limited to this, it is possible to use the moisture absorption unit 40 for example shown in Fig. 2.
In first embodiment, second embodiment, the 2nd air road 20 possesses suction unit 21 and exhaust portion 26, using adding
Hot portion 22 is heated to the air being taken into from suction unit 21, is cooled down after by moisture absorption portion using cooling end 24, thus
Moisture condensation is set to be discharged to air dewetting, and from exhaust portion 26.
On the other hand, in present embodiment, as shown in figure 5, not possessing suction unit 21 and exhaust portion 26, and make cold through cooling end 24
But the air after is circulated again into heating part 22.
In this composition, the effect roughly the same with first embodiment, second embodiment can be also obtained.
(the 4th embodiment)
Another embodiment of the invention will be illustrated.In addition, for convenience of description, for having with the embodiment
The part mark same-sign of identical function, and the description thereof will be omitted.
Fig. 6 is the explanation figure of the schematic configuration for the humidity control device 1 for representing present embodiment.
It is that following composition is illustrated in first embodiment：Possess the 1st air road 10, the 2nd air road 20, have
Moisture absorption portion 42a, 42b moisture absorption unit 40, switch to moisture absorption portion 42a to be configured at the 1st air road 10, and moisture absorption portion 42b is configured at the 2nd
1st state on air road 20 is configured at the 2nd air road 20 with moisture absorption portion 42a, and moisture absorption portion 42b is configured at the 2nd of the 1st air road 10
State.
On the other hand, in present embodiment, do not possess the 1st air road 10, moreover, possessing moisture absorption unit instead of moisture absorption unit 40
40c.Moisture absorption unit 40c is different from the moisture absorption unit 40 of first embodiment, does not possess rotary shaft 43 and motor 44, but
The fixed configurations of 2 air road 20 have moisture absorption portion 42d.As the hygroscopic material for being filled in moisture absorption portion 42d, usable and first embodiment
Identical hygroscopic material.
Moreover, in present embodiment, control unit control heater 22a action, the 1st shape is switched at the time of regulation
State and the 2nd state, the 1st state refer to the heating for stopping heater 22a, for the air that is taken into from suction unit 21 without adding
Heat is just sent to moisture absorption portion 42d, and the 2nd state is referred to for being heated from the air that suction unit 21 is taken into using heater 22a
After be sent to moisture absorption portion 42d.That is, control unit is made at moisture absorption portion 42d by controlling heater 22a unlatching/closing so as to switch to
In hydrophilic state and the 1st state of the moisture in absorption air and moisture absorption portion 42d is in hydrophobic state and will be heated
Air supply to moisture absorption portion 42d and make the 2nd state from the moisture absorption portion 42d water evaporations oozed out.Thus, can obtain with first in fact
Apply the roughly the same effect of mode.
(the 5th embodiment)
Another embodiment of the invention is illustrated.In addition, for convenience of description, for there is phase with the embodiment
The part mark same-sign of congenerous, and the description thereof will be omitted.
It is for as the high molecular composition of stimulating responsive macromolecule temperature in use response in each embodiment
Illustrate.On the other hand, in present embodiment, as stimulating responsive macromolecule, using response light, electric field or pH value (hydrogen from
Subindex) change etc. stimulation and the stimulating responsive macromolecule that makes the compatibility with water reversibly change.In addition, on this
The high molecular concrete example of a little stimulating responsives, will be in description.
Fig. 7 is the explanation figure of the schematic configuration for the humidity control device 1 for representing present embodiment.As shown in the drawing, this embodiment party
The humidity control device 1 of formula is also equipped with stimulating assigning unit 45 in addition to the composition of the humidity control device 1 shown in Fig. 1.
Stimulating assigning unit 45 to be assigned for moisture absorption portion 42b (or 42a) stimulates, so that in hygroscopic material used in the moisture absorption portion
Contained stimulating responsive macromolecule switches to hydrophobicity from hydrophily.
For example, when the stimulating responsive macromolecule for making the compatibility with water reversibly change for response light, light is assigned
So that the stimulating responsive macromolecule switches to hydrophobicity from hydrophily.Moreover, work as to make the compatibility with water in response to electric field
During the stimulating responsive macromolecule reversibly changed, assign electric field so that the stimulating responsive macromolecule switched to from hydrophily it is thin
It is water-based.Moreover, work as the stimuli responsive to make the compatibility with water reversibly change in response to the change of pH value (hydrogen ion exponent)
During property macromolecule, the change of pH value is assigned so that the stimulating responsive macromolecule switches to hydrophobicity from hydrophily.
In addition, in heating part 22, for the air being taken into from suction unit 21, be heated to make by moisture absorption portion 42b (or
42a) assign the temperature of the degree for the moisture evaporation for stimulating and being discharged from hygroscopic material.
Thus, it is identical with each embodiment, moisture absorption portion 42b (or 42a) can be carried out again with few energy-output ratio
Raw processing.
It is for stimulating responsive macromolecule will be used as to use response light, electric field or pH value in addition, in present embodiment
Change etc. stimulation and make the stimulating responsive macromolecule that the compatibility with water reversibly changes and additional stimulate assigning unit 45
Composition, the example combined with the humidity control device 1 of first embodiment (Fig. 1) illustrates, but is not limited to this, also may be used
The composition is combined with the humidity control device 1 shown in any one in the embodiment of second embodiment~the 4th.
(details with the high molecular hygroscopic material of stimulating responsive)
Then, said for the details with the high molecular hygroscopic material of stimulating responsive used in described each embodiment
It is bright.In addition, in this specification, as long as being recorded without special, then it represents that " the A~B " expressions " more than A, below B " of number range.And
And when representing any one of " acrylic acid " or " methacrylic acid ", it is written as " (methyl) acrylic acid ".
(I) hygroscopic material
As the hygroscopic material used in described each embodiment, can be used stimulates containing response external and makes the compatibility with water
The hygroscopic material of the high molecular hirudo leech of stimulating responsive reversibly changed between hydrophily and hydrophobicity.In addition, hygroscopic material
Shape there is no particular restriction, for example, may be either tabular, sheet, membranaceous, block etc., or particle shape.The moisture absorption of particle shape
The shape of material is also not particularly limited, and can be the shape such as substantially spherical, bar-shaped.Moreover, the size of the hygroscopic material of the present invention
It is not particularly limited, can be suitably selected according to the composition of humidity control device.
(the high molecular hirudo leech of stimulating responsive)
In the present invention, the high molecular hirudo leech of stimulating responsive are used.
When especially stimulating responsive macromolecule is crosslinked, high molecular crosslink and the three-dimensional network structure that is formed are being inhaled
The high-molecular gels for forming swellings after receipts water, organic solvent equal solvent more.In this case, in the present invention, high-molecular gel is used
Hirudo leech as hygroscopic material.Herein, the hirudo leech of high-molecular gel refer to remove solvent by making high-molecular gel dry
The material of gained afterwards.In addition, in the present invention, the hirudo leech of high-molecular gel need not remove solvent completely from high-molecular gel,
As long as the moisture in energy absorption air, then can also contain solvent or water.Contain accordingly, with respect to the hirudo leech of the high-molecular gel
Water rate, if the moisture in the drying physical efficiency absorption air, then be not particularly limited, such as more preferably below 40 weight %.Separately
Outside, moisture content herein refers to ratio of the moisture relative to the dry weight of high-molecular gel.
(stimulating responsive macromolecule)
Stimulating responsive macromolecule refers to the macromolecule that its property response external is stimulated and reversibly changed.In the present invention, use
Response external stimulates and makes the stimulating responsive macromolecule reversibly changed between hydrophily and hydrophobicity with the compatibility of water.
As the outside stimulus, there is no particular restriction, can enumerate for example hot, light, electric field, pH value (hydrogen ion exponent)
Deng.
Moreover, response external stimulates and makes reversibly to change with the compatibility of water to refer to, response external stimulates, and makes by this
The macromolecule of outside stimulus reversibly changes between hydrophily and hydrophobicity.
Wherein, the stimulating responsive macromolecule for responding heat and making the compatibility with water reversibly change, i.e. temperature-responsive
Macromolecule (thermo-responsive macromolecule) can make temperature change so as to reversibly carry out in air by using easy heater
Moisture absorption and the release of moisture absorbed, therefore, be especially suitable for humidity control device.
As long as the temperature-responsive macromolecule is with lower critical solution temperature (LCST (Lower Critica L
Solution Temperature)) macromolecule be then not particularly limited.Macromolecule with LCST is hydrophily at low temperature,
It is hydrophobicity when the temperature in more than LCST.In addition, LCST refers to, it is at low temperature parent when macromolecule dissolution is in water
It is water-based and water-soluble, and be changed into when more than certain temperature hydrophobicity and it is not soluble in water in the case of as its boundary
Temperature.
As the temperature-responsive macromolecule, more specifically, can enumerate for example, poly- (N- isopropyls (methyl) propylene
Acid amides), poly- (N- n-propyls (methyl) acrylamide), poly- (N- methyl (methyl) acrylamide), poly- (N- ethyls (methyl)
Acrylamide), poly- (N- normal-butyls (methyl) acrylamide), poly- (N- isobutyl groups (methyl) acrylamide), poly- (the tertiary fourths of N-
Base (methyl) acrylamide) etc. poly- (N- alkyl (methyl) acrylamide)；Poly- (N- vinyl Isopropyl amide), poly- (N- second
Alkenyl n-propyl acid amides), poly- (N- vinyl butylamide), poly- (N- vinyl iso-butyl bases acid amides), poly- (N- ethene
Base-tert-butylamides) etc. poly- (N- vinyl alkyls acid amides)；Poly- (NVP)；Poly- (2- ethyls -2-
Oxazoline), poly- (2- isopropyl -2- oxazolines), poly- (2- n-propyl -2- oxazolines) etc. poly- (2- alkyl -2- oxazolines)；It is poly-
The Polyvinylalkylethers such as methoxy ethylene, polyvinyl ethyl ether；The copolymer of PEO and PPOX；Poly- (oxygen
Ethylene vinyl ether)；The cellulose derivatives such as methylcellulose, ethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose
Deng, and the copolymer of these high-molecular compounds.
Moreover, temperature-responsive macromolecule is alternatively the crosslinked of these high-molecular compounds.When temperature-responsive high score
When son is crosslinked, as the crosslinked, it can enumerate for example, N- isopropyls (methyl) acrylamide, N- n-propyls (methyl)
Acrylamide, N- methyl (methyl) acrylamide, N- ethyls (methyl) acrylamide, N- normal-butyls (methyl) acrylamide,
N- alkyl (methyl) acrylamides such as N- isobutyl groups (methyl) acrylamide, the N- tert-butyl groups (methyl) acrylamide；N- second
Alkenyl Isopropyl amide, N- vinyl n-propyls acid amides, N- vinyl butylamide, N- vinyl iso-butyl bases acid amides,
The N- vinyl alkyl acid amides such as N- vinyl-tert-butylamides；The vinyl alkyl ethers such as methoxy ethylene, vinyl ethyl ether；
Oxirane and expoxy propane；2- ethyl -2- oxazolines, 2- isopropyl -2- oxazolines, 2- n-propyl -2- oxazolines etc.
The monomer of 2- alkyl -2- oxazolines etc., or obtained by two or more in these monomers polymerize under conditions of it crosslinking agent be present
High-molecular compound.
As the crosslinking agent, it can suitably select currently known species and use, suitably use for example, ethylene glycol two
(methyl) acrylate, propane diols two (methyl) acrylate, N, N '-di-2-ethylhexylphosphine oxide (methyl) acrylamide, toluene diisocyanate
Acid esters, divinylbenzene, polyethylene glycol two (methyl) acrylate etc. have the cross-linkable monomer of polymerizable functional groups；Penta 2
Aldehyde；Polyalcohol；Polyamine；Polybasic carboxylic acid；Metal ions such as calcium ion, zinc ion etc..These crosslinking agents both can be used alone,
Two or more can be applied in combination.
Or when temperature-responsive macromolecule is crosslinked, it is high that the crosslinked is alternatively uncrosslinked temperature-responsive
Molecule, e.g. reacted by the temperature-responsive macromolecule for making above to illustrate with the crosslinking agent to form network structure institute
The crosslinked obtained.
Moreover, the stimulating responsive macromolecule for making the compatibility with water reversibly change as response light, can enumerate idol
High-molecular compound, the macromolecule that the hydrophilies such as pyridine derivative, spiropyran derivatives or polarity can change according to light
Compound and temperature-responsive macromolecule and at least any of copolymer, the light in pH value response high-molecular compound
The crosslinked of response polymer crosslinking body or the copolymer.
Moreover, as the stimulating responsive macromolecule for making the compatibility with water reversibly change in response to electric field, can enumerate
High-molecular compound, carboxylic high-molecular compound with the dissociation base such as carboxyl, sulfonic group, phosphate, amino are with containing ammonia
The such macromolecule chemical combination that complex is formed using electrostatic interaction or hydrogen bond etc. of the complex of the high-molecular compound of base
Thing or their crosslinked.
Moreover, as the stimulating responsive macromolecule for making the compatibility with water reversibly change in response to pH value, can enumerate
High-molecular compound, carboxylic high-molecular compound with the dissociation base such as carboxyl, sulfonic group, phosphate, amino are with containing ammonia
The such macromolecule chemical combination that complex is formed using electrostatic interaction or hydrogen bond etc. of the complex of the high-molecular compound of base
Thing or their crosslinked.
Moreover, stimulating responsive macromolecule may be either the high molecular derivative of described stimulating responsive, or and its
The copolymer of his monomer.In addition, there is no particular restriction for the other monomers, can be any monomer.It is adapted to use for example, (first
Base) acrylic acid, allylamine, vinylacetate, (methyl) acrylamide, N, N '-dimethyl (methyl) acrylamide, 2- hydroxyl second
Methyl acrylate, alkyl (methyl) acrylate, maleic acid, vinyl sulfonic acid, vinylbenzenesulfonic acid, acrylamide alkane sulphur
The monomer such as acid, dimethylaminopropyl (methyl) acrylamide, (methyl) acrylonitrile.
Or stimulating responsive macromolecule is alternatively the macromolecule being crosslinked with other or uncrosslinked macromolecule is formed mutually
Wear the macromolecule that polymer mesh structure or Semi-IPN polymer mesh structure form.
There is no particular restriction for the high molecular molecular weight of stimulating responsive, is preferably determined by gel permeation chromatography (GPC)
Number-average molecular weight be more than 3000.
((partly) interpenetrating polymer)
Wherein, in the present invention, stimulating responsive macromolecule more preferably described stimulating responsive macromolecule and hydrophilic macromolecule
Form (partly) interpenetrating polymer that interpenetrating polymer network structure or Semi-IPN polymer mesh structure form.It is high to be somebody's turn to do (partly) IPN
The stimulation that there is response external to stimulate and change between the state for the moisture that the state of absorption moisture and release have absorbed for molecule
The high molecular function of response, and have highly hygroscopic ability concurrently, therefore it is especially suited as hygroscopic material.In addition, in this specification,
(partly) interpenetrating polymer refers to interpenetrating polymer and/or Semi-IPN macromolecule.
Herein, interpenetrating polymer network structure refers to, different types of macromolecule is cross-linked polymer, and each high score
The cross-linked network of son not chemical bonded refractory but the structure that is cross-linked to each other in the state of being individually present.Moreover, Semi-IPN high score
Sub-network structure refers to that one kind in different types of macromolecule is cross-linked polymer, and another kind is straight-chain macromolecule, each
Macromolecule not chemical bonded refractory, but the structure being cross-linked to each other in the state of being individually present.
For the former, the stimulating responsive macromolecule is that the crosslinking with cross-linked network is high with hydrophilic macromolecule
Molecule, the cross-linked network of the stimulating responsive polymer crosslinking network and hydrophilic macromolecule not chemical bonded refractory and formed
The structure being cross-linked to each other, that is, form interpenetrating polymer network structure.
For the latter, any one in the stimulating responsive macromolecule and the hydrophilic macromolecule is with crosslinking
The cross-linked polymer of network, another is straight-chain macromolecule, and the stimulating responsive macromolecule and hydrophilic macromolecule are not
Chemical bonded refractory and form the structure being cross-linked to each other, that is, form Semi-IPN polymer mesh structure.
As the hydrophilic macromolecule, can enumerate for example has hydroxyl, carboxyl, sulfonic group, phosphoric acid in side chain or main chain
The macromolecule of the hydrophily base such as base, amino.As more specifically one of the hydrophilic macromolecule, can enumerate for example, marine alga
The polysaccharides such as acid, hyaluronic acid；Chitosan；Carboxy methyl cellulose, methylcellulose, ethyl cellulose, hydroxyethyl cellulose
Deng cellulose derivative；Poly- (methyl) acrylic acid, poly, polyvinylsulfonic acid, polyvinylbenzenesulfonic acid, polyacrylamide
Alkyl sulfonic acid, poly dimethyl aminopropyl (methyl) acrylamide, they are with (methyl) acrylamide, ethoxy (methyl) acrylic acid
The copolymer of ester, (methyl) alkyl acrylate etc., poly dimethyl aminopropyl (methyl) acrylamide and polyvinyl alcohol are answered
The complex of fit, polyvinyl alcohol and poly- (methyl) acrylic acid, poly- (methyl) acrylonitrile, polyallylamine, polyvinyl alcohol, poly- second
Glycol, polypropylene glycol, poly- (methyl) acrylamide, poly- N, N '-dimethyl (methyl) acrylamide, poly- 2- hydroxyethyl methyls
Acrylate, poly- alkyl (methyl) acrylate, poly dimethyl aminopropyl (methyl) acrylamide, poly- (methyl) acrylonitrile
And copolymer of the polymer etc..
Moreover, hydrophilic macromolecule is alternatively crosslinked.When hydrophilic macromolecule is crosslinked, as the crosslinked,
It can enumerate for example, making (methyl) acrylic acid, allylamine, vinylacetate, (methyl) acrylamide, N, N'- dimethyl (methyl)
Acrylamide, HEMA, alkyl (methyl) acrylate, maleic acid, vinyl sulfonic acid, vinyl benzene
Crosslinking be present in the monomers such as sulfonic acid, acrylamide alkyl sulfonic acid, dimethylaminopropyl (methyl) acrylamide, (methyl) acrylonitrile
Macromolecule obtained by polymerization under conditions of agent.
As the crosslinking agent, currently known species can be suitably selected to use, but suitably use for example, ethylene glycol two
(methyl) acrylate, propane diols two (methyl) acrylate, N, N '-di-2-ethylhexylphosphine oxide (methyl) acrylamide, toluene diisocyanate
Acid esters, divinylbenzene, polyethylene glycol two (methyl) acrylate etc. have the cross-linkable monomer of polymerizable functional groups；Penta 2
Aldehyde；Polyalcohol；Polyamine；Polybasic carboxylic acid；Metal ions such as calcium ion, zinc ion etc..These crosslinking agents both can be used alone,
Two or more can be applied in combination.
Or when temperature-responsive macromolecule is cross-linking agent, the cross-linking agent, which is alternatively, makes the uncrosslinked hydrophily
Macromolecule, such as macromolecule obtained by monomer polymerization, or the polysaccharide such as alginic acid, hyaluronic acid；Chitosan；Carboxymethyl group
The cellulose derivatives such as cellulose, methylcellulose, ethyl cellulose, hydroxyethyl cellulose, reacted and shape with the crosslinking agent
The crosslinked of gained after into network structure.
The molecular weight of the hydrophilic macromolecule is also not particularly limited, and the number-average molecular weight preferably determined by GPC is 3000
More than.
(summary)
The humidity control device 1 of the first form of the present invention is characterised by possessing：Moisture absorption portion 42a, 42b, 42c, 42d, have and contain
Outside stimulus as defined in response and reversibly become and turn to hydrophily and the high molecular hygroscopic material of hydrophobic stimulating responsive；Stimulate
Assigning unit (heating part 22, stimulates assigning unit 45), assigns outside stimulus so that the hygroscopic material switches to hydrophobicity from hydrophily；
And heating part 22, heat is assigned so as to be steamed by the water that the hygroscopic material is switched into hydrophobicity to be discharged from the hygroscopic material
Hair.
According to the composition, can by outside stimulus as defined in being assigned to hygroscopic material by hygroscopic material switch to hydrophobicity from
And the water release for being absorbed hygroscopic material, and by discharged from hygroscopic material water heating make its evaporate so that hygroscopic material again
Life is drying regime.So, when making from the moisture evaporation of hygroscopic material release, with making to be adsorbed in the moisture absorptions such as zeolite as in the past
The situation of the moisture evaporation of material is compared, and can be evaporated the water with few heat.Thus, can reduce needed for the regeneration treatment of hygroscopic material
Energy-output ratio.
According to first form, the humidity control device 1 of the second form of the invention is configured to possess cooling end 24, the cooling
Portion 24 cools down the air of the vapor containing the thermal evaporation assigned using the heating part 22, and makes in the air contained
Vapor dew with the air so as to separate.
According to the composition, the moisture for discharging and evaporating from hygroscopic material can be easily reclaimed.
According to first form or the second form, the humidity control device 1 of the 3rd form of the invention is configured to, and possesses：1st
Processing unit (the 1st air road 10), makes the moisture in the hygroscopic material absorption air of hydrophilic state；(the 2nd is empty for 2nd processing unit
Gas circuit 20), make the hygroscopic material institute using the stimulation assigning unit (heating part 22, stimulating assigning unit 45) and the heating part 22
The moisture of absorption is discharged so that the hygroscopic material is regenerated as drying regime；And switching part (motor 44), the hygroscopic material is cut
It is changed to the 1st state for being configured at the 1st processing unit (the 1st air road 10) and is configured at the 2nd processing unit (the 2nd air road
20) the 2nd state；And possessing multiple described moisture absorption portion 42a, 42b, the switching part (motor 44) is configured to switch each suction
Wet end 42a, 42b position, so that any one moisture absorption portion (one in 42a, 42b) in multiple described moisture absorption portion 42a, 42b
It is configured at the 1st processing unit (the 1st air road 10), other any one moisture absorption portion (in 42a, 42b another) is configured at
2nd processing unit (the 2nd air road 20).
According to the composition, by the way that hygroscopic material is configured at into the 1st processing unit (the 1st air road 10) hygroscopic material can be utilized to inhale
The moisture in the air in the 1st processing unit (the 1st air road 10) is received so as to carry out the damping of the air, and by by moisture absorption
Hygroscopic material be configured at the 2nd processing unit (the 2nd air road 20) and make the water release, evaporation that hygroscopic material absorbed so that moisture absorption
Material is regenerated as drying regime.Thus, the damping of air and the regeneration of hygroscopic material can be repeated.Moreover, can concurrently it carry out
1st processing unit (the 1st air road 10) carries out the processing of damping to air with making hygroscopic material in the 2nd processing unit (the 2nd air road 20)
The processing of regeneration.
According to first form or the second form, the humidity control device 1 of the 4th form of the invention is configured to, and possesses：1st
Processing unit (the 1st air road 10), makes the moisture in the hygroscopic material absorption air of hydrophilic state；(the 2nd is empty for 2nd processing unit
Gas circuit 20), make the hygroscopic material institute using the stimulation assigning unit (heating part 22, stimulating assigning unit 45) and the heating part 22
The moisture of absorption is discharged so that the hygroscopic material is regenerated as drying regime；And switching part (motor 44), the hygroscopic material is cut
It is changed to the 1st state for being configured at the 1st processing unit (the 1st air road 10) and is configured at the 2nd processing unit (the 2nd air road
20) the 2nd state；The switching part (motor 44) is configured to, and makes the moisture absorption portion 42c relative to the 1st processing unit the (the 1st
Air road 10) and the relative position of the 2nd processing unit (the 2nd air road 20) change as follows：The moisture absorption portion 42c's
A part is configured at the 1st processing unit (the 1st air road 10), and another part is configured at the 2nd processing unit (the 2nd air road
20)。
According to the composition, by the way that hygroscopic material is configured at into the 1st processing unit (the 1st air road 10) hygroscopic material can be utilized to inhale
The moisture in the air in the 1st processing unit (the 1st air road 10) is received so as to carry out the damping of the air, and by that will absorb
Hygroscopic material be configured at the 2nd processing unit (the 2nd air road 20) and make the water release, evaporation that hygroscopic material absorbed so that moisture absorption
Material is regenerated as drying regime.Thus, the damping of air and the regeneration of hygroscopic material can be repeated.Moreover, can concurrently it carry out
1st processing unit (the 1st air road 10) carries out the processing of damping to air with making hygroscopic material in the 2nd processing unit (the 2nd air road 20)
The processing of regeneration.
According to any one of described first form to the 4th form, the humidity control device 1 of the 5th form of the invention is configured to,
The outside stimulus is heat, and the stimulation assigning unit (heating part 22) and the heating part 22 are common heaters.
According to the composition, assigning unit 45 is stimulated to make humidity control device 1 compared with the situation of heating part 22 with possessing respectively
Composition simplify, and the manufacturing cost of humidity control device 1 can be reduced.
According to any one of described first form to the 4th form, the humidity control device 1 of the 6th form of the invention is configured to,
The outside stimulus is the change of heat, light, electric field or hydrogen ion exponent (pH value).
According to the composition, by the change of heat as defined in imparting, light, electric field or hydrogen ion exponent, hygroscopic material can be cut
Hydrophobicity is changed to so that the water release that hygroscopic material is absorbed.
According to any one of described first form to the 6th form, the humidity control device 1 of the 7th form of the invention is configured to,
The heating part 22 by would be heated to the air for the set point of temperature being set in less than more than 40 DEG C 70 DEG C of scope supply to
Described moisture absorption portion 42a, 42b, 42c, 42d, and make the water evaporation from hygroscopic material release.
It is not conventional as being adsorbed in by the water that the hygroscopic material is switched into hydrophobicity to be discharged from the hygroscopic material
The water of the hygroscopic materials such as zeolite utilizes the bond such as silanol key like that.Therefore, by the way that less than more than 40 DEG C 70 DEG C of temperature will be set in
The air of the set point of temperature of scope is supplied to described moisture absorption portion 42a, 42b, 42c, 42d, can easily make from moisture absorption portion 42a,
The water evaporation that hygroscopic material described in 42b, 42c, 42d possessed discharges.
The present invention is not limited to the embodiment, and various changes can be carried out in the scope shown in claims.That is,
Embodiment obtained by technological means combination in the scope shown in claims after appropriate change falls within the present invention's
Technical scope.
Industrial utilizability
Present invention can apply to the humidity control device using hygroscopic material adjustment air humidity.
Symbol description
1 humidity control device
10 the 1st air roads (the 1st processing unit)
11 suction units
12 fans
13 exhaust portions
20 the 2nd air roads (the 2nd processing unit)
21 suction units
22 heating parts (stimulate assigning unit, heater)
22a heaters
23 fans
24 cooling ends
25 Drainage Divisions
26 exhaust portions
30 cooling air roads
31 suction units
32 fans
33 exhaust portions
40th, 40b, 40c moisture absorption unit
41 supporting parts
42a, 42b, 42c, 42d moisture absorption portion
43 rotary shafts
44 motors (switching part)
45 stimulate assigning unit
50 rhones
Claims (5)
1. a kind of humidity control device, it is characterised in that possess：
Moisture absorption portion, have containing outside stimulus as defined in response and reversibly become and turn to hydrophily and hydrophobic stimulating responsive
High molecular hygroscopic material；
Assigning unit is stimulated, assigns outside stimulus so that the hygroscopic material is switched into hydrophobicity from hydrophily；And
Heating part, heat is assigned so as to be steamed by the water that the hygroscopic material is switched into hydrophobicity to be discharged from the hygroscopic material
Hair.
2. humidity control device according to claim 1, it is characterised in that possess cooling end, the cooling end makes containing utilizing institute
The air cooling for the vapor stated the heat of heating part imparting and evaporated, make in the air contained vapor dew and with the air
Separation.
3. humidity control device according to claim 1 or 2, it is characterised in that possess：
1st processing unit, make the moisture in the hygroscopic material absorption air of hydrophilic state；
2nd processing unit, the moisture absorbed using the stimulation assigning unit and the heating part discharge hygroscopic material, is made described
Hygroscopic material is regenerated as drying regime；And
Switching part, the hygroscopic material is switched to the 1st state for being configured at the 1st processing unit and is configured at the 2nd processing
2nd state in portion；
Possess multiple moisture absorption portions,
The switching part switches the position in each moisture absorption portion, so that any one moisture absorption portion in multiple moisture absorption portions is configured at
1st processing unit, any one other moisture absorption portion are configured at the 2nd processing unit.
4. humidity control device according to claim 1 or 2, it is characterised in that possess：
1st processing unit, make the moisture in the hygroscopic material absorption air of hydrophilic state；
2nd processing unit, the moisture absorbed using the stimulation assigning unit and the heating part discharge hygroscopic material, is made described
Hygroscopic material is regenerated as drying regime；And
Switching part, the hygroscopic material is switched to the 1st state for being configured at the 1st processing unit and is configured at the 2nd processing
2nd state in portion；
The switching part changes relative position of the moisture absorption portion relative to the 1st processing unit and the 2nd processing unit, so that
The part in the moisture absorption portion is configured at the 1st processing unit, and another part is configured at the 2nd processing unit.
5. according to the humidity control device any one of Claims 1-4 item, it is characterised in that：
The outside stimulus is heat,
The stimulation assigning unit and the heating part are common heater.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015-079620 | 2015-04-08 | ||
| JP2015079620A JP6595199B2 (en) | 2015-04-08 | 2015-04-08 | Humidity control device |
| PCT/JP2016/054623 WO2016163160A1 (en) | 2015-04-08 | 2016-02-17 | Humidity control device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107614089A true CN107614089A (en) | 2018-01-19 |
Family
ID=57072045
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680013181.9A Pending CN107614089A (en) | 2015-04-08 | 2016-02-17 | Humidity Control Device |
Country Status (3)
| Country | Link |
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| JP (1) | JP6595199B2 (en) |
| CN (1) | CN107614089A (en) |
| WO (1) | WO2016163160A1 (en) |
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| CN113965672A (en) * | 2020-07-03 | 2022-01-21 | 安讯士有限公司 | Camera and method |
| CN114923230A (en) * | 2022-04-01 | 2022-08-19 | 东南大学 | Magnetic stimulation response ionic liquid dehumidification air conditioning system |
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| SE1851206A1 (en) | 2018-10-05 | 2020-04-06 | Corroventa Avfuktning Ab | Method and apparatus for dehumidification |
| WO2022244498A1 (en) * | 2021-05-20 | 2022-11-24 | シャープ株式会社 | Humidity absorbing device and tableware washing and drying machine |
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- 2016-02-17 CN CN201680013181.9A patent/CN107614089A/en active Pending
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2016198706A (en) | 2016-12-01 |
| WO2016163160A1 (en) | 2016-10-13 |
| JP6595199B2 (en) | 2019-10-23 |
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