CN107604704A - A kind of garment material environment-friendly long-life coloring agent and preparation method thereof - Google Patents
A kind of garment material environment-friendly long-life coloring agent and preparation method thereof Download PDFInfo
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- CN107604704A CN107604704A CN201710771747.0A CN201710771747A CN107604704A CN 107604704 A CN107604704 A CN 107604704A CN 201710771747 A CN201710771747 A CN 201710771747A CN 107604704 A CN107604704 A CN 107604704A
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Abstract
The invention discloses a kind of garment material environment-friendly long-life coloring agent and preparation method thereof, the coloring agent includes the composition of following parts by weight:Sodium pyrophosphate, butyl methacrylate, sodium carbonate, zinc stearate, glycerine, dibutyl phthalate, hydroxymethyl cellulose, pigment, calcium sulfate, initiator, surfactant, diffusant, defoamer, antioxidant, deionized water.The coloring agent raw material is easy to get, and prepares simply, and reaction is gentle, and production efficiency is high, and color tolerance is easy thereon, and not fugitive color, solid color is good, and vividness is high, high covering power, still soft, smooth after cloth dyeing, comfort level is high, will not be to human body and environmental pollution, and production cost is low, good in economic efficiency.
Description
Technical field
The invention belongs to garment material processing technology field, and in particular to a kind of garment material with environment-friendly long-life coloring agent and
Its preparation method.
Background technology
Fabric is exactly the material for making clothes.As one of clothes three elements, fabric can not only annotate clothes
Style and characteristic, and directly left and right the color of clothes, the expression effect of moulding.
In clothes big world, the fabric of clothes is multifarious, makes rapid progress.But generally, it is high-quality, high-grade
Fabric, mostly with several aspects such as wear is comfortable, sweat-absorbing breathable, pendency are well-pressed, vision is noble, tactile is soft and graceful the characteristics of.
The clothes of formal social life institute wear are produced on, preferably select pure cotton, pure wool, pure silk, pure gunny products.With these four
The clothes that pure natural quality fabric makes, mostly class are higher.Sometimes, the clothes of the pure leatherwork of wear, are also allowed.
Different fabrics has the performances such as different gas permeabilities, hygroscopicity, warmth retention property, for example bafta has well saturating
Gas and hygroscopicity, comfortable and easy to wear, warmth retention property is good, is optimal children's garment fabric.Select to confirm the ventilative of fabric during fabric
Property, heat insulating ability, hygroscopicity, the performance characteristic such as static behaviour, then the stiffness for fabric, weight sense, soft durometer and drapability come
Consider that it is adapted to which type of moulding done, which type of style etc. done.
Modern society, people are concerned about grade and the colour match of oneself clothing very much, and the clothes that can purchase on the market is big
It is riotous with colour mostly, or the dark, clothes of plain color, you could be known in the dyestuff of these clothes, it is likely that contain certain
Carcinogenic material.
Most of quick dyestuff for being used for contaminating cotton goods, all contain highly carcinogenic benzidine, a kind of dichloro connection therein
Aniline, it is easy to absorb and be led to allergic through skin.The dyestuff of most of most toxicity is all for contaminating natural fiber.
For garment material coloring agent, the current country is primarily present following patent document:
Publication No. 107059438A Chinese patent discloses a kind of weaving face fabric special stain therefor, by following parts by weight
Raw material is made:Cobaltous sulfate 5-10 parts, alum 6-12 parts, butyl methacrylate 4-10 parts, ethyl acetate 4-6 parts, camphor tree
Leaf extract 7-9 parts, aluminum sulfate 4-10 parts, glycerine 3-7 parts, hydroxypropyl methyl cellulose 3-4 parts, imidazoline 2-5 parts, denaturation
Starch 20-28 parts, trimethylolpropane 4-8 parts, mica powder 2-6 parts, butyl methacrylate 4-7 parts, di lauric dibutyl
Tin 2-4 parts, oxygen iron oxide red 3-7 parts.This present invention is easily painted by adjusting the ratio of each composition, the coloring agent for developing to obtain,
And color fastness is high, not fugitive color, and it is bright in colour, it is harmless.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of garment material environment-friendly long-life coloring agent
And preparation method thereof, the coloring agent raw material is easy to get, and prepares simply, and reaction is gentle, and production efficiency is high, and color tolerance is easy thereon, and not
Fugitive color, solid color is good, and vividness is high, high covering power, and still soft, smooth after cloth dyeing, comfort level is high, will not be to human body
And environmental pollution, production cost is low, good in economic efficiency.
To reach above-mentioned purpose, the technical scheme is that:
A kind of garment material environment-friendly long-life coloring agent, the coloring agent include the composition of following parts by weight:Sodium pyrophosphate:20~
30 parts, butyl methacrylate:15 ~ 25 parts, sodium carbonate:15 ~ 20 parts, zinc stearate:10 ~ 15 parts, glycerine:It is 5 ~ 10 parts, adjacent
Dibatyl phithalate:5 ~ 10 parts, hydroxymethyl cellulose:5 ~ 10 parts, pigment:10 ~ 15 parts, calcium sulfate:5 ~ 10 parts, initiator:1
~ 5 parts, surfactant:1 ~ 5 part, diffusant:1 ~ 5 part, defoamer:1 ~ 5 part, antioxidant:1 ~ 5 part, deionized water:50~60
Part.
Further, the coloring agent includes the composition of following parts by weight:Sodium pyrophosphate:25 ~ 30 parts, methacrylic acid fourth
Ester:15 ~ 20 parts, sodium carbonate:15 ~ 18 parts, zinc stearate:10 ~ 13 parts, glycerine:6 ~ 10 parts, dibutyl phthalate:5~7
Part, hydroxymethyl cellulose:7 ~ 10 parts, pigment:12 ~ 15 parts, calcium sulfate:8 ~ 10 parts, initiator:1 ~ 3 part, surfactant:3~5
Part, diffusant:2 ~ 5 parts, defoamer:1 ~ 4 part, antioxidant:3 ~ 5 parts, deionized water:55 ~ 60 parts.
Preferably, the coloring agent includes the composition of following parts by weight:Sodium pyrophosphate:25 parts, butyl methacrylate:20
Part, sodium carbonate:18 parts, zinc stearate:3 parts, glycerine:7 parts, dibutyl phthalate:6 parts, hydroxymethyl cellulose:8 parts,
Pigment:12 parts, calcium sulfate:8 parts, initiator:3 parts, surfactant:4 parts, diffusant:2 parts, defoamer:It is 2 parts, anti-oxidant
Agent:3 parts, deionized water:55 parts.
Preferably, the initiator elects azodiisobutyronitrile or peroxidized t-butyl perbenzoate as.
Preferably, the antioxidant is butylated hydroxy anisole.
Preferably, the surfactant is laurate polyoxyethylene ester or polyoxyethylene oleic acid ester.
Preferably, the diffusant is sodium metnylene bis-naphthalene sulfonate.
Preferably, the defoamer is polyether modified silicon oil.
Meanwhile the present invention also provides a kind of preparation method of garment material environment-friendly long-life coloring agent, the preparation method
Comprise the following steps:Mixer is taken, by sodium pyrophosphate, butyl methacrylate, sodium carbonate, zinc stearate, glycerine, adjacent benzene two
Formic acid dibutyl ester, hydroxymethyl cellulose, pigment, calcium sulfate and 50wt% deionized water order add mixer, at 30 ~ 40 DEG C
Lower stirring 1 ~ 2 hour, 500 ~ 600 revs/min of mixing speed;By initiator, surfactant, diffusant, defoamer, antioxidant
It is cold and remaining deionized water adds mixer, is warming up to 50 ~ 60 DEG C, is stirred 1 ~ 2 hour under 800 ~ 1000 revs/min of rotating speed
But to room temperature, filtering, the garment material environment-friendly long-life coloring agent is produced.
The invention has the advantages that:
The coloring agent raw material is easy to get, and prepares simply, and reaction is gentle, and production efficiency is high, and color tolerance is easy thereon, and not fugitive color, Gu
Color is good, and vividness is high, high covering power, and still soft, smooth after cloth dyeing, comfort level is high, and human body and environment will not be made
Into injury, production cost is low, good in economic efficiency.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention
Scope.
A kind of garment material environment-friendly long-life coloring agent provided by the present invention, the coloring agent include following parts by weight
Composition:Sodium pyrophosphate:20 ~ 30 parts, butyl methacrylate:15 ~ 25 parts, sodium carbonate:15 ~ 20 parts, zinc stearate:10 ~ 15 parts,
Glycerine:5 ~ 10 parts, dibutyl phthalate:5 ~ 10 parts, hydroxymethyl cellulose:5 ~ 10 parts, pigment:10 ~ 15 parts, sulfuric acid
Calcium:5 ~ 10 parts, initiator:1 ~ 5 part, surfactant:1 ~ 5 part, diffusant:1 ~ 5 part, defoamer:1 ~ 5 part, antioxidant:1~
5 parts, deionized water:50 ~ 60 parts.
Further, the coloring agent includes the composition of following parts by weight:Sodium pyrophosphate:25 ~ 30 parts, methacrylic acid fourth
Ester:15 ~ 20 parts, sodium carbonate:15 ~ 18 parts, zinc stearate:10 ~ 13 parts, glycerine:6 ~ 10 parts, dibutyl phthalate:5~7
Part, hydroxymethyl cellulose:7 ~ 10 parts, pigment:12 ~ 15 parts, calcium sulfate:8 ~ 10 parts, initiator:1 ~ 3 part, surfactant:3~5
Part, diffusant:2 ~ 5 parts, defoamer:1 ~ 4 part, antioxidant:3 ~ 5 parts, deionized water:55 ~ 60 parts.
Preferably, the coloring agent includes the composition of following parts by weight:Sodium pyrophosphate:25 parts, butyl methacrylate:20
Part, sodium carbonate:18 parts, zinc stearate:3 parts, glycerine:7 parts, dibutyl phthalate:6 parts, hydroxymethyl cellulose:8 parts,
Pigment:12 parts, calcium sulfate:8 parts, initiator:3 parts, surfactant:4 parts, diffusant:2 parts, defoamer:It is 2 parts, anti-oxidant
Agent:3 parts, deionized water:55 parts.
Preferably, the initiator elects azodiisobutyronitrile or peroxidized t-butyl perbenzoate as.
Preferably, the antioxidant is butylated hydroxy anisole.
Preferably, the surfactant is laurate polyoxyethylene ester or polyoxyethylene oleic acid ester.
Preferably, the diffusant is sodium metnylene bis-naphthalene sulfonate.
Preferably, the defoamer is polyether modified silicon oil.
Meanwhile the present invention also provides a kind of preparation method of garment material environment-friendly long-life coloring agent, the preparation method
Comprise the following steps:Mixer is taken, by sodium pyrophosphate, butyl methacrylate, sodium carbonate, zinc stearate, glycerine, adjacent benzene two
Formic acid dibutyl ester, hydroxymethyl cellulose, pigment, calcium sulfate and 50wt% deionized water order add mixer, at 30 ~ 40 DEG C
Lower stirring 1 ~ 2 hour, 500 ~ 600 revs/min of mixing speed;By initiator, surfactant, diffusant, defoamer, antioxidant
It is cold and remaining deionized water adds mixer, is warming up to 50 ~ 60 DEG C, is stirred 1 ~ 2 hour under 800 ~ 1000 revs/min of rotating speed
But to room temperature, filtering, the garment material environment-friendly long-life coloring agent is produced.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (9)
1. a kind of garment material environment-friendly long-life coloring agent, it is characterised in that the coloring agent includes the composition of following parts by weight:
Sodium pyrophosphate:20 ~ 30 parts, butyl methacrylate:15 ~ 25 parts, sodium carbonate:15 ~ 20 parts, zinc stearate:10 ~ 15 parts, the third three
Alcohol:5 ~ 10 parts, dibutyl phthalate:5 ~ 10 parts, hydroxymethyl cellulose:5 ~ 10 parts, pigment:10 ~ 15 parts, calcium sulfate:5~
10 parts, initiator:1 ~ 5 part, surfactant:1 ~ 5 part, diffusant:1 ~ 5 part, defoamer:1 ~ 5 part, antioxidant:1 ~ 5 part,
Deionized water:50 ~ 60 parts.
2. garment material according to claim 1 environment-friendly long-life coloring agent, it is characterised in that the coloring agent is included such as
The composition of lower parts by weight:Sodium pyrophosphate:25 ~ 30 parts, butyl methacrylate:15 ~ 20 parts, sodium carbonate:15 ~ 18 parts, stearic acid
Zinc:10 ~ 13 parts, glycerine:6 ~ 10 parts, dibutyl phthalate:5 ~ 7 parts, hydroxymethyl cellulose:7 ~ 10 parts, pigment:12~
15 parts, calcium sulfate:8 ~ 10 parts, initiator:1 ~ 3 part, surfactant:3 ~ 5 parts, diffusant:2 ~ 5 parts, defoamer:1 ~ 4 part, resist
Oxidant:3 ~ 5 parts, deionized water:55 ~ 60 parts.
3. garment material according to claim 1 environment-friendly long-life coloring agent, it is characterised in that the coloring agent is included such as
The composition of lower parts by weight:Sodium pyrophosphate:25 parts, butyl methacrylate:20 parts, sodium carbonate:18 parts, zinc stearate:3 parts, third
Triol:7 parts, dibutyl phthalate:6 parts, hydroxymethyl cellulose:8 parts, pigment:12 parts, calcium sulfate:8 parts, initiator:3
Part, surfactant:4 parts, diffusant:2 parts, defoamer:2 parts, antioxidant:3 parts, deionized water:55 parts.
4. garment material according to claim 1 environment-friendly long-life coloring agent, it is characterised in that the initiator elects idol as
Nitrogen bis-isobutyronitrile or peroxidized t-butyl perbenzoate.
5. garment material according to claim 1 environment-friendly long-life coloring agent, it is characterised in that the antioxidant is butyl
BHA.
6. garment material according to claim 1 environment-friendly long-life coloring agent, it is characterised in that the surfactant is
Laurate polyoxyethylene ester or polyoxyethylene oleic acid ester.
7. garment material according to claim 1 environment-friendly long-life coloring agent, it is characterised in that the diffusant is methylene
Base sodium dinaphthalenesulfonate.
8. garment material according to claim 1 environment-friendly long-life coloring agent, it is characterised in that the defoamer is polyethers
Modified silicon oil.
9. a kind of preparation method of garment material environment-friendly long-life coloring agent as any one of claim 1 ~ 8, it is special
Sign is that the preparation method comprises the following steps:Mixer is taken, by sodium pyrophosphate, butyl methacrylate, sodium carbonate, hard
Resin acid zinc, glycerine, dibutyl phthalate, hydroxymethyl cellulose, pigment, calcium sulfate and 50wt% deionized water order
Mixer is added, is stirred 1 ~ 2 hour at 30 ~ 40 DEG C, 500 ~ 600 revs/min of mixing speed;By initiator, surfactant, expansion
Powder, defoamer, antioxidant and remaining deionized water add mixer, 50 ~ 60 DEG C are warming up to, at 800 ~ 1000 revs/min
Stirred 1 ~ 2 hour under rotating speed, be cooled to room temperature, filtered, produce the garment material environment-friendly long-life coloring agent.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108330625A (en) * | 2018-02-09 | 2018-07-27 | 苏州堂贝纺织品有限公司 | A kind of garment material bleaching and dyeing process |
CN108978262A (en) * | 2018-07-26 | 2018-12-11 | 合肥远科服装设计有限公司 | A kind of clothes environment-friendly dye and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104358147A (en) * | 2014-10-20 | 2015-02-18 | 江苏金牛华尔车服饰有限公司 | Fabric coloring agent |
CN106638045A (en) * | 2016-12-09 | 2017-05-10 | 苏州陈恒织造有限公司 | Dyeing agent for nylon fabric and preparation method of dyeing agent |
CN106988132A (en) * | 2017-03-24 | 2017-07-28 | 合肥云都棉花有限公司 | A kind of weaving face fabric coloring agent |
-
2017
- 2017-08-31 CN CN201710771747.0A patent/CN107604704A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104358147A (en) * | 2014-10-20 | 2015-02-18 | 江苏金牛华尔车服饰有限公司 | Fabric coloring agent |
CN106638045A (en) * | 2016-12-09 | 2017-05-10 | 苏州陈恒织造有限公司 | Dyeing agent for nylon fabric and preparation method of dyeing agent |
CN106988132A (en) * | 2017-03-24 | 2017-07-28 | 合肥云都棉花有限公司 | A kind of weaving face fabric coloring agent |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108330625A (en) * | 2018-02-09 | 2018-07-27 | 苏州堂贝纺织品有限公司 | A kind of garment material bleaching and dyeing process |
CN108978262A (en) * | 2018-07-26 | 2018-12-11 | 合肥远科服装设计有限公司 | A kind of clothes environment-friendly dye and preparation method thereof |
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