CN107602031A - A kind of mould proof heat-insulating fireproof door component and preparation method thereof - Google Patents

A kind of mould proof heat-insulating fireproof door component and preparation method thereof Download PDF

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Publication number
CN107602031A
CN107602031A CN201710868831.4A CN201710868831A CN107602031A CN 107602031 A CN107602031 A CN 107602031A CN 201710868831 A CN201710868831 A CN 201710868831A CN 107602031 A CN107602031 A CN 107602031A
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China
Prior art keywords
parts
mould proof
door panel
resistant coating
proof heat
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Pending
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CN201710868831.4A
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Chinese (zh)
Inventor
刘敏
张二虎
谭林
巫立洪
谭三诚
孙柱齐
彭冠凡
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Huizhou Ying Ying Hui Industrial Co Ltd
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Huizhou Ying Ying Hui Industrial Co Ltd
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Priority to CN201710868831.4A priority Critical patent/CN107602031A/en
Publication of CN107602031A publication Critical patent/CN107602031A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of mould proof heat-insulating fireproof door component, including door panel, polyurethane foam board and fungus resistant coating;Door panel includes following components, as mass fraction:30 40 parts of polyvinyl alcohol, 100 120 parts of sulphate aluminium cement, 38 parts of phenolic resin, 5 10 parts of the short silk of glass fibre, 15 25 parts of the fine scrim of polypropylene, 20 30 parts of alumina cement foaming agent;Fungus resistant coating includes following components, as mass fraction:53 58 parts of acrylic emulsion, 32 38 parts of water soluble amino modified alkyd resin, 33 37 parts of modification infusorial earth, 12 17 parts of silicon dioxide powder, 69 parts of antiseptic, 46 parts of fluorine richness oligomer, 9 11 parts of polyfunctional acrylic ester, 34 parts of light trigger.The mould proof heat-insulating fireproof door has efficient heat-insulated and fire resistance, and the fungus resistant coating on the fire resistant doorsets surface has lipophobic hydrophobic energy, has antimildew function, convenient use.

Description

A kind of mould proof heat-insulating fireproof door component and preparation method thereof
Technical field
The invention belongs to one kind finishing household field, specifically, it is related to a kind of mould proof heat-insulating fireproof door component and its system Preparation Method.
Background technology
Fire resistant doorsets refer to the door that can meet fire stability, integrality and thermal insulation requirement within a certain period of time.It is to set There are the fire protection separators of certain fire resistance in fire protection interval, emergency staircase, vertical shaft etc.;Fire resistant doorsets, which remove, to be had commonly Outside the effect of door, with more the effect for preventing fire spreading and flue gas diffusion, the sprawling of the intensity of a fire can be prevented within a certain period of time, really Protect evacuating personnel.
Fire resistant doorsets ensure that the security performance of household, but existing Fireproof door structure is simple, and existing fire resistant doorsets are main It is divided into fire resistance steel door and fire-proof wooden door, after fire-proof wooden door long-time use, fire resistant doorsets easily go mouldy due to making moist, greatly The big practicality for reducing fire resistant doorsets.
The content of the invention
It is an object of the invention to provide a kind of mould proof heat-insulating fireproof door component and preparation method thereof, to solve above-mentioned background The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical scheme:
A kind of mould proof heat-insulating fireproof door component, including door panel, polyurethane foam board and fungus resistant coating;
Described door panel includes following components, as mass fraction:Polyvinyl alcohol 30-40 parts, sulphate aluminium cement 100-120 parts, phenolic resin 3-8 parts, the short silk 5-10 parts of glass fibre, the fine scrim 15-25 parts of polypropylene, alumina cement Foaming agent 20-30 parts;
Described door panel surface both sides are bonded with polyurethane foam board, described polyurethane foam plate surface by viscose glue It is painted with fungus resistant coating;
Described fungus resistant coating includes following components, as mass fraction:Acrylic emulsion 50-60 parts, water soluble amino Modified alkyd resin 30-40 parts, modification infusorial earth 30-40 parts, silicon dioxide powder 10-20 parts, antiseptic 5-10 parts, fluorine richness are low Polymers 3-8 parts, polyfunctional acrylic ester 8-12 parts, light trigger 2-5 parts.
As the further scheme of the present invention:Above-mentioned mould proof heat-insulating fireproof door component, including door panel, polyurethane foam board And fungus resistant coating;
Described door panel includes following components, as mass fraction:Polyvinyl alcohol 32-37 parts, sulphate aluminium cement 105-115 parts, phenolic resin 4-6 parts, the short silk 7-9 parts of glass fibre, the fine scrim 18-22 parts of polypropylene, alumina cement Foaming agent 22-26 parts;
Described door panel surface both sides are bonded with polyurethane foam board, described polyurethane foam plate surface by viscose glue It is painted with fungus resistant coating;
Described fungus resistant coating includes following components, as mass fraction:Acrylic emulsion 53-58 parts, water soluble amino Modified alkyd resin 32-38 parts, modification infusorial earth 33-37 parts, silicon dioxide powder 12-17 parts, antiseptic 6-9 parts, fluorine richness are low Polymers 4-6 parts, polyfunctional acrylic ester 9-11 parts, light trigger 3-4 parts.
As further scheme of the invention:Above-mentioned mould proof heat-insulating fireproof door component, including door panel, polyurethane foam Plate and fungus resistant coating;
Described door panel includes following components, as mass fraction:35 parts of polyvinyl alcohol, 110 parts of sulphate aluminium cement, 8 parts of the short silk of 5 parts of phenolic resin, glass fibre, 20 parts of the fine scrim of polypropylene, 25 parts of alumina cement foaming agent;
Described door panel surface both sides are bonded with polyurethane foam board, described polyurethane foam plate surface by viscose glue It is painted with fungus resistant coating;
Described fungus resistant coating includes following components, as mass fraction:55 parts of acrylic emulsion, water soluble amino are modified 35 parts of alkyd resin, 35 parts of modification infusorial earth, 15 parts of silicon dioxide powder, 8 parts of antiseptic, 5 parts of fluorine richness oligomer, polyfunctionality 10 parts of acrylate, 3 parts of light trigger.
As further scheme of the invention:Described polyfunctional acrylic ester is the acrylate of 3-6 degrees of functionality.
As further scheme of the invention:Described antiseptic be quaternary ammonium salt derivative, Kathon CG, surfactant and Several mixtures of synergist.
As further scheme of the invention:Described modification infusorial earth carries out acid using weak acid water-washing method and is modified.
Above-mentioned mould proof heat-insulating fireproof door component, the preparation method of described door panel, is comprised the following steps that:
S1, polyethylene alcohol and water is modulated into glue, glue is placed in high-speed shearing machine, add sulphate aluminium cement and Phenolic resin carries out high shear agitation, shear rate 6000-8000RPM;And shear time is 2-3h, mixed liquor A is prepared;
S2, the mixed liquor prepared in step S1 is placed in homogenizer and stirred, and added the fine chemical fibre of polypropylene and knit Thing and alumina cement foaming agent, high-speed stirred, mixing time 1h are carried out, and speed of agitator is 1000-1500r/min;Prepare Mixed liquid B;
S3, the short silk of glass fibre is added in mixed liquid B prepared by step S3, after stirring in discharging to mould, mould It is quiet to after curing molding in tool, take out drying door panel.
Above-mentioned mould proof heat-insulating fireproof door component, the preparation method of described fungus resistant coating, is comprised the following steps that:
W1, acrylic emulsion and water soluble amino modified alkyd resin mixed, add in homogenizer and stir, stirring Time is 1 hour, and acrylic emulsion and water soluble amino modified alkyd resin form glue;
W2, modification infusorial earth, silicon dioxide powder, antiseptic, fluorine richness oligomer are added in glue prepared by step W1 And polyfunctional acrylic ester, it is well mixed, stirring, which is stood, is made mixed liquor;
Light trigger is added in W3, the mixed liquor prepared in step W2 to be well mixed, and mixed liquor is passed through into ultraviolet light Exposure intensity is 30-40mW/cm2Irradiation environment, the ultraviolet light time is 10-20 minutes, stand prepares coating glue;
W4, by the coating glue brushing prepared in step W4 on the described surface of polyurethane foam board 2, remember mould proof heat-insulated Fire resistant doorsets component.
Compared with prior art, the beneficial effects of the invention are as follows:The mould proof heat-insulating fireproof door function is strong, has heat-insulating flame-retardant Performance, the practicality of fire resistant doorsets is substantially increased, there is efficient heat-insulated and fire resistance, and the mould proof painting on the fire resistant doorsets surface Layer has lipophobic hydrophobic energy, and the situation that effectively prevent water droplet wall built-up occurs, and has antimildew function, convenient use.
Brief description of the drawings
Fig. 1 is the structural representation of mould proof heat-insulating fireproof door.
In figure:1- door panels;2- polyurethane foam boards;3- fungus resistant coatings.
Embodiment
Technical scheme is described in more detail with reference to embodiment.
Embodiment 1
Referring to Fig. 1, a kind of mould proof heat-insulating fireproof door component, including door panel 1, polyurethane foam board 2 and fungus resistant coating 3;
Described door panel 1 includes following components, as mass fraction:30 parts of polyvinyl alcohol, sulphate aluminium cement 100 Part, 3 parts of phenolic resin, 5 parts of the short silk of glass fibre, 15 parts of the fine scrim of polypropylene, 20 parts of alumina cement foaming agent.
The preparation method of described door panel 1, is concretely comprised the following steps:
S1, polyethylene alcohol and water is modulated into glue, glue is placed in high-speed shearing machine, add sulphate aluminium cement and Phenolic resin carries out high shear agitation, shear rate 6000-8000RPM;And shear time is 2-3h, mixed liquor A is prepared;
S2, the mixed liquor prepared in step S1 is placed in homogenizer and stirred, and added the fine chemical fibre of polypropylene and knit Thing and alumina cement foaming agent, high-speed stirred, mixing time 1h are carried out, and speed of agitator is 1000-1500r/min;Prepare Mixed liquid B;
S3, the short silk of glass fibre is added in mixed liquid B prepared by step S3, after stirring in discharging to mould, mould It is quiet to after curing molding in tool, take out drying door panel 1.
The described surface both sides of door panel 1 are bonded with polyurethane foam board 2, described polyurethane foam board 2 by viscose glue External coating has fungus resistant coating 3;
Described fungus resistant coating 3 includes following components, as mass fraction:50 parts of acrylic emulsion, water soluble amino change It is 30 parts of alkyd resin of property, 30 parts of modification infusorial earth, 10 parts of silicon dioxide powder, 5 parts of antiseptic, 3 parts of fluorine richness oligomer, multifunctional Spend 8 parts of acrylate, 2 parts of light trigger.
Described polyfunctional acrylic ester is the acrylate of 3-6 degrees of functionality.
Described antiseptic is several mixtures of quaternary ammonium salt derivative, Kathon CG, surfactant and synergist.
Described modification infusorial earth carries out acid using weak acid water-washing method and is modified.
The preparation method of above-mentioned fungus resistant coating, is comprised the following steps that:
W1, acrylic emulsion and water soluble amino modified alkyd resin mixed, add in homogenizer and stir, stirring Time is 1 hour, and acrylic emulsion and water soluble amino modified alkyd resin form glue;
W2, modification infusorial earth, silicon dioxide powder, antiseptic, fluorine richness oligomer are added in glue prepared by step W1 And polyfunctional acrylic ester, it is well mixed, stirring, which is stood, is made mixed liquor;
Light trigger is added in W3, the mixed liquor prepared in step W2 to be well mixed, and mixed liquor is passed through into ultraviolet light Exposure intensity is 30-40mW/cm2Irradiation environment, the ultraviolet light time is 10-20 minutes, stand prepares coating glue;
W4, by the coating glue brushing prepared in step W4 on the described surface of polyurethane foam board 2, remember mould proof heat-insulated Fire resistant doorsets component.
Embodiment 2
Referring to Fig. 1, a kind of mould proof heat-insulating fireproof door component, including door panel 1, polyurethane foam board 2 and fungus resistant coating 3;
Described door panel 1 includes following components, as mass fraction:35 parts of polyvinyl alcohol, sulphate aluminium cement 110 Part, 5 parts of phenolic resin, 8 parts of the short silk of glass fibre, 20 parts of the fine scrim of polypropylene, 25 parts of alumina cement foaming agent.
The preparation method of described door panel 1, is concretely comprised the following steps:
S1, polyethylene alcohol and water is modulated into glue, glue is placed in high-speed shearing machine, add sulphate aluminium cement and Phenolic resin carries out high shear agitation, shear rate 6000-8000RPM;And shear time is 2-3h, mixed liquor A is prepared;
S2, the mixed liquor prepared in step S1 is placed in homogenizer and stirred, and added the fine chemical fibre of polypropylene and knit Thing and alumina cement foaming agent, high-speed stirred, mixing time 1h are carried out, and speed of agitator is 1000-1500r/min;Prepare Mixed liquid B;
S3, the short silk of glass fibre is added in mixed liquid B prepared by step S3, after stirring in discharging to mould, mould It is quiet to after curing molding in tool, take out drying door panel 1.
The described surface both sides of door panel 1 are bonded with polyurethane foam board 2, described polyurethane foam board 2 by viscose glue External coating has fungus resistant coating 3;
Described fungus resistant coating 3 includes following components, as mass fraction:55 parts of acrylic emulsion, water soluble amino change It is 35 parts of alkyd resin of property, 35 parts of modification infusorial earth, 15 parts of silicon dioxide powder, 8 parts of antiseptic, 5 parts of fluorine richness oligomer, multifunctional Spend 10 parts of acrylate, 3 parts of light trigger.
Described polyfunctional acrylic ester is the acrylate of 3-6 degrees of functionality.
Described antiseptic is several mixtures of quaternary ammonium salt derivative, Kathon CG, surfactant and synergist.
Described modification infusorial earth carries out acid using weak acid water-washing method and is modified.
The preparation method of above-mentioned fungus resistant coating, is comprised the following steps that:
W1, acrylic emulsion and water soluble amino modified alkyd resin mixed, add in homogenizer and stir, stirring Time is 1 hour, and acrylic emulsion and water soluble amino modified alkyd resin form glue;
W2, modification infusorial earth, silicon dioxide powder, antiseptic, fluorine richness oligomer are added in glue prepared by step W1 And polyfunctional acrylic ester, it is well mixed, stirring, which is stood, is made mixed liquor;
Light trigger is added in W3, the mixed liquor prepared in step W2 to be well mixed, and mixed liquor is passed through into ultraviolet light Exposure intensity is 30-40mW/cm2Irradiation environment, the ultraviolet light time is 10-20 minutes, stand prepares coating glue;
W4, by the coating glue brushing prepared in step W4 on the described surface of polyurethane foam board 2, remember mould proof heat-insulated Fire resistant doorsets component.
Embodiment 3
Referring to Fig. 1, a kind of mould proof heat-insulating fireproof door component, including door panel 1, polyurethane foam board 2 and fungus resistant coating 3;
Described door panel 1 includes following components, as mass fraction:40 parts of polyvinyl alcohol, sulphate aluminium cement 120 Part, 8 parts of phenolic resin, 10 parts of the short silk of glass fibre, 25 parts of the fine scrim of polypropylene, 30 parts of alumina cement foaming agent.
The preparation method of described door panel 1, is concretely comprised the following steps:
S1, polyethylene alcohol and water is modulated into glue, glue is placed in high-speed shearing machine, add sulphate aluminium cement and Phenolic resin carries out high shear agitation, shear rate 6000-8000RPM;And shear time is 2-3h, mixed liquor A is prepared;
S2, the mixed liquor prepared in step S1 is placed in homogenizer and stirred, and added the fine chemical fibre of polypropylene and knit Thing and alumina cement foaming agent, high-speed stirred, mixing time 1h are carried out, and speed of agitator is 1000-1500r/min;Prepare Mixed liquid B;
S3, the short silk of glass fibre is added in mixed liquid B prepared by step S3, after stirring in discharging to mould, mould It is quiet to after curing molding in tool, take out drying door panel 1.
The described surface both sides of door panel 1 are bonded with polyurethane foam board 2, described polyurethane foam board 2 by viscose glue External coating has fungus resistant coating 3;
Described fungus resistant coating 3 includes following components, as mass fraction:60 parts of acrylic emulsion, water soluble amino change 40 parts of alkyd resin of property, 40 parts of modification infusorial earth, 20 parts of silicon dioxide powder, 10 parts of antiseptic, 8 parts of fluorine richness oligomer, more officials 12 parts of energy degree acrylate, 5 parts of light trigger.
Described polyfunctional acrylic ester is the acrylate of 3-6 degrees of functionality.
Described antiseptic is several mixtures of quaternary ammonium salt derivative, Kathon CG, surfactant and synergist.
Described modification infusorial earth carries out acid using weak acid water-washing method and is modified.
The preparation method of above-mentioned fungus resistant coating, is comprised the following steps that:
W1, acrylic emulsion and water soluble amino modified alkyd resin mixed, add in homogenizer and stir, stirring Time is 1 hour, and acrylic emulsion and water soluble amino modified alkyd resin form glue;
W2, modification infusorial earth, silicon dioxide powder, antiseptic, fluorine richness oligomer are added in glue prepared by step W1 And polyfunctional acrylic ester, it is well mixed, stirring, which is stood, is made mixed liquor;
Light trigger is added in W3, the mixed liquor prepared in step W2 to be well mixed, and mixed liquor is passed through into ultraviolet light Exposure intensity is 30-40mW/cm2Irradiation environment, the ultraviolet light time is 10-20 minutes, stand prepares coating glue;
W4, by the coating glue brushing prepared in step W4 on the described surface of polyurethane foam board 2, remember mould proof heat-insulated Fire resistant doorsets component.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.

Claims (8)

1. a kind of mould proof heat-insulating fireproof door component, it is characterised in that including door panel, polyurethane foam board and fungus resistant coating;
Described door panel includes following components, as mass fraction:Polyvinyl alcohol 30-40 parts, sulphate aluminium cement 100-120 Part, phenolic resin 3-8 parts, the short silk 5-10 parts of glass fibre, the fine scrim 15-25 parts of polypropylene, alumina cement foaming agent 20-30 parts;
Described door panel surface both sides are bonded with polyurethane foam board, described polyurethane foam board external coating by viscose glue There is fungus resistant coating;
Described fungus resistant coating includes following components, as mass fraction:Acrylic emulsion 50-60 parts, water soluble amino are modified Alkyd resin 30-40 parts, modification infusorial earth 30-40 parts, silicon dioxide powder 10-20 parts, antiseptic 5-10 parts, fluorine richness oligomer 3-8 parts, polyfunctional acrylic ester 8-12 parts, light trigger 2-5 parts.
2. a kind of mould proof heat-insulating fireproof door component according to claim 1, it is characterised in that including door panel, polyurethane Foamed board and fungus resistant coating;
Described door panel includes following components, as mass fraction:Polyvinyl alcohol 32-37 parts, sulphate aluminium cement 105-115 Part, phenolic resin 4-6 parts, the short silk 7-9 parts of glass fibre, the fine scrim 18-22 parts of polypropylene, alumina cement foaming agent 22-26 parts;
Described door panel surface both sides are bonded with polyurethane foam board, described polyurethane foam board external coating by viscose glue There is fungus resistant coating;
Described fungus resistant coating includes following components, as mass fraction:Acrylic emulsion 53-58 parts, water soluble amino are modified Alkyd resin 32-38 parts, modification infusorial earth 33-37 parts, silicon dioxide powder 12-17 parts, antiseptic 6-9 parts, fluorine richness oligomer 4-6 parts, polyfunctional acrylic ester 9-11 parts, light trigger 3-4 parts.
3. a kind of mould proof heat-insulating fireproof door component according to claim 1, it is characterised in that including door panel, polyurethane Foamed board and fungus resistant coating;
Described door panel includes following components, as mass fraction:35 parts of polyvinyl alcohol, 110 parts of sulphate aluminium cement, phenolic aldehyde 8 parts of the short silk of 5 parts of resin, glass fibre, 20 parts of the fine scrim of polypropylene, 25 parts of alumina cement foaming agent;
Described door panel surface both sides are bonded with polyurethane foam board, described polyurethane foam board external coating by viscose glue There is fungus resistant coating;
Described fungus resistant coating includes following components, as mass fraction:55 parts of acrylic emulsion, water soluble amino acid modified alcoholic 35 parts of resin, 35 parts of modification infusorial earth, 15 parts of silicon dioxide powder, 8 parts of antiseptic, 5 parts of fluorine richness oligomer, polyfunctionality propylene 10 parts of acid esters, 3 parts of light trigger.
4. according to a kind of any described mould proof heat-insulating fireproof door components of claim 1-3, it is characterised in that described is multifunctional Spend the acrylate that acrylate is 3-6 degrees of functionality.
5. a kind of mould proof heat-insulating fireproof door component according to claim 4, it is characterised in that described antiseptic is quaternary ammonium Salt derivative, Kathon CG, several mixtures of surfactant and synergist.
6. a kind of mould proof heat-insulating fireproof door component according to claim 5, it is characterised in that described modification infusorial earth is adopted It is modified that acid is carried out with weak acid water-washing method.
A kind of a kind of 7. mould proof heat-insulating fireproof door component as described in claim 1-3 is any, it is characterised in that described door core The preparation method of plate, is comprised the following steps that:
S1, polyethylene alcohol and water is modulated into glue, glue is placed in high-speed shearing machine, add sulphate aluminium cement and phenolic aldehyde Resin carries out high shear agitation, shear rate 6000-8000RPM;And shear time is 2-3h, mixed liquor A is prepared;
S2, the mixed liquor prepared in step S1 is placed in homogenizer and stirred, and add the fine chemical & blended fabric of polypropylene and Alumina cement foaming agent, high-speed stirred, mixing time 1h are carried out, and speed of agitator is 1000-1500r/min;Prepare mixing Liquid B;
S3, the short silk of glass fibre is added in mixed liquid B prepared by step S3, after stirring in discharging to mould, in mould It is quiet to after curing molding, take out drying door panel.
8. a kind of a kind of mould proof heat-insulating fireproof door component as described in claim 1-3 is any, it is characterised in that described is mould proof The preparation method of coating, is comprised the following steps that:
W1, acrylic emulsion and water soluble amino modified alkyd resin mixed, add in homogenizer and stir, mixing time For 1 hour, acrylic emulsion and water soluble amino modified alkyd resin formed glue;
W2, modification infusorial earth, silicon dioxide powder, antiseptic, fluorine richness oligomer and more are added in glue prepared by step W1 Degree of functionality acrylate, it is well mixed, stirring, which is stood, is made mixed liquor;
Light trigger is added in W3, the mixed liquor prepared in step W2 to be well mixed, and mixed liquor is passed through into ultraviolet light Intensity is 30-40mW/cm2Irradiation environment, the ultraviolet light time is 10-20 minutes, stand prepares coating glue;
W4, by the coating glue brushing prepared in step W4 on the described surface of polyurethane foam board 2, remember mould proof heat-insulating, fire-preventing Door component.
CN201710868831.4A 2017-09-22 2017-09-22 A kind of mould proof heat-insulating fireproof door component and preparation method thereof Pending CN107602031A (en)

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Application publication date: 20180119