CN107601960A - A kind of true mineral varnish and preparation method thereof and coating, product - Google Patents
A kind of true mineral varnish and preparation method thereof and coating, product Download PDFInfo
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- CN107601960A CN107601960A CN201710867107.XA CN201710867107A CN107601960A CN 107601960 A CN107601960 A CN 107601960A CN 201710867107 A CN201710867107 A CN 201710867107A CN 107601960 A CN107601960 A CN 107601960A
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Abstract
The invention provides the preparation method of a kind of true mineral varnish and the true mineral varnish, using the coating coated by the true mineral varnish and the product comprising the coating.True mineral varnish wherein of the present invention, it is made up of aggregate and the female part of paint, the paint mother liquor includes core shell self crosslinking acrylic acid ester emulsion, ethylene-vinyl acetate copolymer emulsion, 2-ethylhexyl acrylate, ABVN, disodium hydrogen phosphate, tertiary ethylene carbonate, potassium peroxydisulfate, latex powder, bentonite and water.True mineral varnish of the present invention, its component is reasonable, and product stability is good, and perception, texture, touch sense, rough sense are approached with true stone, and do not influenceed by adverse circumstances, and good weatherability, hydrophobic is breathed freely, cracking resistance, good frost resistance, service life length.
Description
Technical field
The invention belongs to paint production field, in particular it relates to a kind of true mineral varnish, and the preparation method of the true mineral varnish and
Using the coating coated by the true mineral varnish and the product comprising the coating.
Background technology
Paint, in general, it can exactly be coated in coated article body surface face and the continuous film of firm attachment can be formed
Material, whether traditional coating products using natural materials as raw material, or in modern development to synthesize chemical products
For the coating products of raw material, organic chemical industry's macromolecular material is belonged to, the film formed belongs to high-molecular compound type, presses
The classification for the chemical products passed through according to the modern times, coating belong to fine chemical product, and modern coating is progressively turning into a kind of more
Functional engineering material, it is an important industry in chemical industry.
Outer surface of building stone decoration, it is simple and tasteful, it is loved by people, but stone decoration is limited by several aspects
System：The exploitation welding of stone material：Earth's surface stone material will level off hilltops or Wa Kuang holes because weathering is serious, crackle is not suitable for manufacture sheet material more
To exploit ratchel, sheet material is sawn into.Welding, polluted source；Stone lumber weight is costly, it is necessary to steel extension installation；Stone material
It is not good enough that steel hangs installation security：Steel has a potential safety hazard after hanging corrosion, and maintenance cost is high.
Rock, especially sandstone are copied particularly difficult due to the lines of unique and beautiful, common process.Early in 2003
When true mineral varnish rises, producer is just had begun to and has attempted to copy rock with true mineral varnish.Till now, most of producers are also
It is using true mineral varnish batch priming operation, the mode that emulsion paint retouches lines is carried out.Although this mode fidelity is made very high, to work
The construction skill and technique of people requires also very high, and construction is got up, and speed is very slow, can not large area duplication.So imitative rock of this technique
At present be relatively used for television background wall etc. finely fit up, exterior wall do and if small area.In addition, the lines paint film that emulsion paint is retouched
It is very thin, do not possess durability, be not suitable in outdoor utility.
Therefore, this area, which is still needed, provides a kind of new stone material emulation coating, existing imitative stone material visual effect, there is imitative stone again
Material sense effect.
The content of the invention
Goal of the invention：In order to overcome the above insufficient, the invention provides the preparation side of a kind of true mineral varnish and the true mineral varnish
Coating coated by method and the application true mineral varnish and product comprising the coating.
Technical scheme：In order to overcome the deficiencies in the prior art, the invention provides a kind of true mineral varnish, with weight group
Divide meter, be made up of aggregate 40-60 parts and paint mother liquor 20-30 parts, it is described to paint mother liquor by weight part, including following components：
Core shell self crosslinking acrylic acid ester emulsion 40-50 parts
Ethene-vinyl acetate copolymer emulsion 20-30 parts
2-ethylhexyl acrylate 10-20 parts
ABVN 3-8 parts
Disodium hydrogen phosphate 2-6 parts
Tertiary ethylene carbonate 1-4 parts
Potassium peroxydisulfate 2-12 parts
Latex powder 4-10 parts
Bentonite 3-8 parts
Water 10-30 parts.
True mineral varnish of the present invention, its component is reasonable, and product stability is good, perception, texture, touch sense, it is rough sense with
True stone is approached, and is not influenceed by adverse circumstances, and good weatherability, hydrophobic is breathed freely, cracking resistance, good frost resistance, service life length.
Further, above-mentioned true mineral varnish, by weight part, it is made up of aggregate 45-55 parts and paint mother liquor 22-28 parts,
It is described to paint mother liquor by weight part, including following components：
Core shell self crosslinking acrylic acid ester emulsion 35-45 parts
Ethene-vinyl acetate copolymer emulsion 22-28 parts
2-ethylhexyl acrylate 12-16 parts
ABVN 4-6 parts
Disodium hydrogen phosphate 3-5 parts
Tertiary ethylene carbonate 2-3 parts
Potassium peroxydisulfate 4-10 parts
Latex powder 6-8 parts
Bentonite 5-7 parts
Water 15-25 parts.
One kind as the present invention preferably, above-mentioned true mineral varnish, by weight part, by 50 parts of aggregate and paints 25 parts of mother liquor
Composition, it is described to paint mother liquor by weight part, including following components：
40 parts of core shell self crosslinking acrylic acid ester emulsion
26 parts of ethene-vinyl acetate copolymer emulsion
14 parts of 2-ethylhexyl acrylate
5 parts of ABVN
4 parts of disodium hydrogen phosphate
2 parts of tertiary ethylene carbonate
6 parts of potassium peroxydisulfate
7 parts of latex powder
6 parts of bentonite
20 parts of water.
One kind as the present invention is preferred, best results under said components.
Further, above-mentioned true mineral varnish, the aggregate is natural colour sand, natural stone-powder, colored sliver, dicalcium powder, broken
One or more in stone, quartz sand.Aggregate can be selected according to different effect demands, to realize construction effect, be applicable
Property is good, has a wide range of application.
Further, above-mentioned true mineral varnish, the aggregate are sieved by 80-120 molecules of interest.True mineral varnish quality is fine and smooth, hand
Sense is soft smooth, and it is good that effect is presented.
Invention additionally discloses a kind of preparation method of true mineral varnish, comprise the following steps：
（1）Disodium hydrogen phosphate, potassium peroxydisulfate, latex powder and bentonite are put into 20-30min is stirred in water；
（2）Core shell self crosslinking acrylic acid ester emulsion, ethene-vinyl acetate copolymer emulsion, acrylic acid-2-ethyl are put into successively
Ester, ABVN and tertiary ethylene carbonate, continue to stir 30-50min；
（3）Adjust pH7.2-8.5；
（4）Aggregate is added to continue to obtain the true mineral varnish after stirring.
The preparation method of true mineral varnish of the present invention, simple for process, production efficiency is high, and application cost is low, operation
Simply, it is easily achieved.After aggregate fully wherein is ground into sieving first, take and add material by several times, finally mixed again with aggregate
Make mixing evenly, and make product quality stable, there is higher application value.
Further, the preparation method of above-mentioned true mineral varnish, mixing speed 100-300RPM.Mild condition, it is easy to real
It is existing.
Further, the preparation method of above-mentioned true mineral varnish, pH is adjusted using hydrochloric acid and/or ammoniacal liquor.Using convenience, and into
This is low.
Beneficial effect：Compared with prior art, the present invention has advantages below：True mineral varnish of the present invention, its component
Rationally, product component is reasonable, and product stability is good, and perception, texture, touch sense, rough sense approach with true stone, and effect is good, and not
Influenceed by adverse circumstances, good weatherability, hydrophobic is breathed freely, cracking resistance, good frost resistance, service life length.It is of the present invention true
The preparation method of mineral varnish, simple for process, production efficiency is high, and application cost is low, simple to operate, be easily achieved, the production of production
Quality is stable, and using conveniently, compatibility is good, has higher application value.
Invention additionally discloses a kind of coating, the coating is formed by above-mentioned true mineral varnish coating.Metope can be sprayed into each
Color plane or ridge design, the third dimension for showing rock, the effect of lithotome is presented.Dosage is：4-8kg/m2, spraying,
Roller coating or Pi Gua 1-3 roads, it is very convenient.
Invention additionally discloses a kind of product, the product includes above-mentioned coating.
True mineral varnish of the present invention has above-mentioned technique effect, and coating and product comprising the true mineral varnish should also have
Identical technique effect.
Embodiment
Below will be by several specific embodiments, the present invention is furture elucidated, these embodiments simply to illustrate that problem,
It is not a kind of limitation.
Embodiment 1
A kind of true mineral varnish, by weight part, it is made up of 40 parts of aggregate and 20 parts of mother liquor of paint, wherein, the aggregate is colored rock
Piece, also, the aggregate is sieved by 80 molecules of interest.
In addition, the paint mother liquor is by weight part, including following components：
40 parts of core shell self crosslinking acrylic acid ester emulsion
20 parts of ethene-vinyl acetate copolymer emulsion
10 parts of 2-ethylhexyl acrylate
3 parts of ABVN
2 parts of disodium hydrogen phosphate
1 part of tertiary ethylene carbonate
2 parts of potassium peroxydisulfate
4 parts of latex powder
3 parts of bentonite
10 parts of water.
The preparation method of upper true mineral varnish, comprises the following steps：
（1）Disodium hydrogen phosphate, potassium peroxydisulfate, latex powder and bentonite are put into water, 20min is stirred under 100RPM speed；
（2）Core shell self crosslinking acrylic acid ester emulsion, ethene-vinyl acetate copolymer emulsion, acrylic acid-2-ethyl are put into successively
Ester, ABVN and tertiary ethylene carbonate, continue under 100RPM speed to stir 30min；
（3）Use hydrochloric acid and/or ammoniacal liquor regulation pH7.2；
（4）Aggregate is added to continue to obtain the true mineral varnish after stirring.
During the true mineral varnish application of above-mentioned preparation, spraying 1,4kg/m2。
Embodiment 2
A kind of true mineral varnish, by weight part, it is made up of 60 parts of aggregate and 30 parts of mother liquor of paint, wherein, the aggregate is natural color
Sand, colored sliver, the mixture of dicalcium powder and quartz sand.Also, the aggregate is sieved by 120 molecules of interest.
In addition, the paint mother liquor is by weight part, including following components：
50 parts of core shell self crosslinking acrylic acid ester emulsion
30 parts of ethene-vinyl acetate copolymer emulsion
20 parts of 2-ethylhexyl acrylate
8 parts of ABVN
6 parts of disodium hydrogen phosphate
4 parts of tertiary ethylene carbonate
12 parts of potassium peroxydisulfate
10 parts of latex powder
8 parts of bentonite
30 parts of water.
The preparation method of upper true mineral varnish, comprises the following steps：
（1）Disodium hydrogen phosphate, potassium peroxydisulfate, latex powder and bentonite are put into water, 30min is stirred under 300RPM speed；
（2）Core shell self crosslinking acrylic acid ester emulsion, ethene-vinyl acetate copolymer emulsion, acrylic acid-2-ethyl are put into successively
Ester, ABVN and tertiary ethylene carbonate, continue under 300RPM speed to stir 50min；
（3）Use hydrochloric acid and/or ammoniacal liquor regulation pH 8.5；
（4）Aggregate is added to continue to obtain the true mineral varnish after stirring.
During the true mineral varnish application of above-mentioned preparation, criticize and scrape 3,8kg/m2。
Embodiment 3
A kind of true mineral varnish, by weight part, it is made up of 50 parts of aggregate and 25 parts of mother liquor of paint, wherein, the aggregate is natural stone
Powder, also, the aggregate is sieved by 100 molecules of interest.
In addition, the paint mother liquor is by weight part, including following components：
40 parts of core shell self crosslinking acrylic acid ester emulsion
26 parts of ethene-vinyl acetate copolymer emulsion
14 parts of 2-ethylhexyl acrylate
5 parts of ABVN
4 parts of disodium hydrogen phosphate
2 parts of tertiary ethylene carbonate
6 parts of potassium peroxydisulfate
7 parts of latex powder
6 parts of bentonite
20 parts of water.
The preparation method of upper true mineral varnish, comprises the following steps：
（1）Disodium hydrogen phosphate, potassium peroxydisulfate, latex powder and bentonite are put into water, 25min is stirred under 200RPM speed；
（2）Core shell self crosslinking acrylic acid ester emulsion, ethene-vinyl acetate copolymer emulsion, acrylic acid-2-ethyl are put into successively
Ester, ABVN and tertiary ethylene carbonate, continue under 200RPM speed to stir 45min；
（3）Use hydrochloric acid and/or ammoniacal liquor regulation pH7.5；
（4）Aggregate is added to continue to obtain the true mineral varnish after stirring.
During the true mineral varnish application of above-mentioned preparation, roller coating 2,5kg/m2。
Embodiment 4
A kind of true mineral varnish, by weight part, it is made up of 45 parts of aggregate and 22 parts of mother liquor of paint, wherein, the aggregate is natural color
The mixture of sand and natural stone-powder, also, the aggregate is sieved by 90 molecules of interest.
In addition, the paint mother liquor is by weight part, including following components：
35 parts of core shell self crosslinking acrylic acid ester emulsion
22 parts of ethene-vinyl acetate copolymer emulsion
12 parts of 2-ethylhexyl acrylate
4 parts of ABVN
3 parts of disodium hydrogen phosphate
2 parts of tertiary ethylene carbonate
4 parts of potassium peroxydisulfate
6 parts of latex powder
5 parts of bentonite
15 parts of water.
The preparation method of upper true mineral varnish, comprises the following steps：
（1）Disodium hydrogen phosphate, potassium peroxydisulfate, latex powder and bentonite are put into water, 30min is stirred under 150RPM speed；
（2）Core shell self crosslinking acrylic acid ester emulsion, ethene-vinyl acetate copolymer emulsion, acrylic acid-2-ethyl are put into successively
Ester, ABVN and tertiary ethylene carbonate, continue under 250RPM speed to stir 40min；
（3）Use hydrochloric acid and/or ammoniacal liquor regulation pH8；
（4）Aggregate is added to continue to obtain the true mineral varnish after stirring.
During the true mineral varnish application of above-mentioned preparation, criticize and scrape 3,5kg/m2。
Embodiment 5
A kind of true mineral varnish, by weight part, it is made up of 55 parts of aggregate and 28 parts of mother liquor of paint, wherein, the aggregate is natural stone
Powder, colored sliver, the mixture of dicalcium powder and rubble, also, the aggregate is sieved by 110 molecules of interest.
In addition, the paint mother liquor is by weight part, including following components：
45 parts of core shell self crosslinking acrylic acid ester emulsion
28 parts of ethene-vinyl acetate copolymer emulsion
16 parts of 2-ethylhexyl acrylate
6 parts of ABVN
5 parts of disodium hydrogen phosphate
3 parts of tertiary ethylene carbonate
10 parts of potassium peroxydisulfate
8 parts of latex powder
7 parts of bentonite
25 parts of water.
The preparation method of upper true mineral varnish, comprises the following steps：
（1）Disodium hydrogen phosphate, potassium peroxydisulfate, latex powder and bentonite are put into water, 20min is stirred under 200RPM speed；
（2）Core shell self crosslinking acrylic acid ester emulsion, ethene-vinyl acetate copolymer emulsion, acrylic acid-2-ethyl are put into successively
Ester, ABVN and tertiary ethylene carbonate, continue under 100RPM speed to stir 50min；
（3）Use hydrochloric acid and/or ammoniacal liquor regulation pH8.5；
（4）Aggregate is added to continue to obtain the true mineral varnish after stirring.
During the true mineral varnish application of above-mentioned preparation, spraying 2,4kg/m2。
Described above is only several embodiments of invention, it is noted that for those skilled in the art
For, on the premise of inventive principle is not departed from, some improvement can also be made, these improvement also should be regarded as the protection of the present invention
Scope.
Claims (10)
- A kind of 1. true mineral varnish, it is characterised in that：By weight part, it is made up of aggregate 40-60 parts and paint mother liquor 20-30 parts, institute State paint mother liquor by weight part, including following components：Core shell self crosslinking acrylic acid ester emulsion 40-50 partsEthene-vinyl acetate copolymer emulsion 20-30 parts2-ethylhexyl acrylate 10-20 partsABVN 3-8 partsDisodium hydrogen phosphate 2-6 partsTertiary ethylene carbonate 1-4 partsPotassium peroxydisulfate 2-12 partsLatex powder 4-10 partsBentonite 3-8 partsWater 10-30 parts.
- 2. true mineral varnish according to claim 1, it is characterised in that：By weight part, by aggregate 45-55 parts and paint mother liquor 22-28 parts form, described to paint mother liquor by weight part, including following components：Core shell self crosslinking acrylic acid ester emulsion 35-45 partsEthene-vinyl acetate copolymer emulsion 22-28 parts2-ethylhexyl acrylate 12-16 partsABVN 4-6 partsDisodium hydrogen phosphate 3-5 partsTertiary ethylene carbonate 2-3 partsPotassium peroxydisulfate 4-10 partsLatex powder 6-8 partsBentonite 5-7 partsWater 15-25 parts.
- 3. true mineral varnish according to claim 1, it is characterised in that：By weight part, by 50 parts of aggregate and paint mother liquor 25 Part composition, it is described to paint mother liquor by weight part, including following components：40 parts of core shell self crosslinking acrylic acid ester emulsion26 parts of ethene-vinyl acetate copolymer emulsion14 parts of 2-ethylhexyl acrylate5 parts of ABVN4 parts of disodium hydrogen phosphate2 parts of tertiary ethylene carbonate6 parts of potassium peroxydisulfate7 parts of latex powder6 parts of bentonite20 parts of water.
- 4. according to the true mineral varnish described in claim any one of 1-3, it is characterised in that：The aggregate is natural colour sand, natural stone One or more in powder, colored sliver, dicalcium powder, rubble, quartz sand.
- 5. true mineral varnish according to claim 4, it is characterised in that：The aggregate is sieved by 80-120 molecules of interest.
- 6. the preparation method of the true mineral varnish according to claim any one of 1-5, it is characterised in that：Comprise the following steps：（1）Disodium hydrogen phosphate, potassium peroxydisulfate, latex powder and bentonite are put into 20-30min is stirred in water；（2）Core shell self crosslinking acrylic acid ester emulsion, ethene-vinyl acetate copolymer emulsion, acrylic acid-2-ethyl are put into successively Ester, ABVN and tertiary ethylene carbonate, continue to stir 30-50min；（3）Adjust pH7.2-8.5；（4）Aggregate is added to continue to obtain the true mineral varnish after stirring.
- 7. the preparation method of true mineral varnish according to claim 6, it is characterised in that：Mixing speed is 100-300RPM.
- 8. the preparation method of true mineral varnish according to claim 6, it is characterised in that：Use hydrochloric acid and/or ammoniacal liquor regulation pH.
- A kind of 9. coating, it is characterised in that：The coating is formed as the true mineral varnish coating described in claim any one of 1-8.
- A kind of 10. product, it is characterised in that：The product includes the coating described in claim 9.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710867107.XA CN107601960A (en) | 2017-09-22 | 2017-09-22 | A kind of true mineral varnish and preparation method thereof and coating, product |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710867107.XA CN107601960A (en) | 2017-09-22 | 2017-09-22 | A kind of true mineral varnish and preparation method thereof and coating, product |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108164635A (en) * | 2017-12-30 | 2018-06-15 | 上海巴德富实业有限公司 | A kind of cracking resistance flexibility uncle the third lacquer lotion and preparation method thereof |
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| JPH06271789A (en) * | 1993-03-18 | 1994-09-27 | Atom Chem Paint Co Ltd | Water-base composition for road marking |
| CN101481568A (en) * | 2008-01-08 | 2009-07-15 | 徐军 | Environment friendly antifreezing stone-like paint and preparation thereof |
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