CN104761211A - Cement-based cultured stone color post-repair slurry, preparation and repair construction method thereof - Google Patents
Cement-based cultured stone color post-repair slurry, preparation and repair construction method thereof Download PDFInfo
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- CN104761211A CN104761211A CN201510109302.7A CN201510109302A CN104761211A CN 104761211 A CN104761211 A CN 104761211A CN 201510109302 A CN201510109302 A CN 201510109302A CN 104761211 A CN104761211 A CN 104761211A
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Abstract
The invention provides cement-based cultured stone color post-repair slurry, a preparation method and a repair construction method thereof. By means of optimization of a cement-based nature cultured stone-imitated color post-repair formula, slurry being suitable for different spray-coating method is prepared, wherein the sequence of color forming is controlled to achieve a reverse thinking mode of product repairing. In addition, by means of spray-coating overlapping of main color slurry and auxiliary color slurry in a wet-to-wet manner, the slurry, after being dried, can form naturally merging so that the repair construction method can recover the original appearance of the product and is strong in operability. During the preparation method of the post-repair slurry, the separating-mixing operation is mainly to satisfy the difference of dispersion requirements of different components. The viscosity of the main color slurry and the auxiliary color slurry are 70-150 KU. The post-repair slurry is scientific in formula, is outstanding in performance and is low in cost. The repair construction method is strong in operability, is natural in transition and is lifelike in repairing. The invention can solve and improve production and engineering repairing and the methods are feasible.
Description
Technical field
The present invention relates to a kind of pigment slurry, after particularly relating to a kind of cement based Art Stone color, mend slurry.And preparation method thereof and constructional method.
Background technology
Natural cultural stone generally refers to the finishing material adopting lithotome engraving, and being the demand for meeting certain architectural style, with the form paving of decorative paste face brick on body of wall, giving the visual effect of recovering one's original simplicity, is a large main flow of Modern Decorative; Along with the progress of science and technology and the raising of living standards of the people, the requirement of people to material of construction also improves day by day.Be limited to the scarcity of resources of lithotome and the complexity of complete processing, create a kind of rapid emergence of cement based imitated natural cultural stone, also make the industry obtain unprecedented grand occasion; At villa, low density building, hotel, club, gardening etc., firmly in occupation of the dominant position in market.
The outstanding advantages of cement based imitation natural stone product is that fidelity is good, weather resistance is strong, the feature of environmental protection is good, be produced on a large scale, property is excellent, it is convenient etc. to construct; Especially disclose a kind of method of staining surface of imitated natural cultural stone at patent CN 101177011A after, more strengthen technician to the continuous pursuit of effect, technical renovation, domestic at present, the production of this series products adopts similar technique and operating method substantially, and the producer of simultaneously having established domestic many cement based imitated natural cultural stone is in full flourish; Natural-like stone obtained promotion and application rapidly with its simple and unsophisticated decorative effect attractive in appearance, cheap feature and the work-ing life close with stone material in nearly ten years, obtained client and highly approved.
But cement based imitated natural cultural stone is limited to the feature of material own and the particular requirement to processes simultaneously, the loose colour that simultaneous causes because of production link, grow dim, reveal the exact details, colour cast etc., the reasons such as the engineering body of wall accumulation of salt in the surface soil, crossed contamination cause the stain of the apparent effect of this series products, have a strong impact on production cost and decorative effect, serious financial loss is brought to enterprise, and this is had no way out, be also the common fault of industry; Although market have adopt acrylic paints to add water to carry out polluted product after the mode of repairing, alleviate impact to a certain extent, still there is larger gap at repair efficiency and weather resistance.
For the limitation in prior art as above in methods or Application Areas, be badly in need of a kind of processing method realizing imitated natural cultural stone color perfecting.
Summary of the invention
For solving problems of the prior art, repair slurry formulations after the invention provides a kind of color for cement based imitated natural cultural stone product and use slurry to carry out the method for repairing, described slurry comprises the preparation of main and auxiliary mill base body, repair after color being carried out to cement based Art Stone in conjunction with slurry provided by the invention, and then realize cement based and imitate the object that Art Stone has the same bandwagon effect of natural cultural stone.
For achieving the above object, slurry is repaired after providing a kind of cement based imitated natural cultural stone color in the present invention first aspect, and one or more repair slurry all from same or analogous component, count by weight, comprising:
The preparation method of slurry is repaired in second aspect of the present invention after being to provide a kind of cement based imitated natural cultural stone color, step comprises:
Step 1: by the film forming matter of liquid, properties-correcting agent, wetting agent, thickening material, film coalescence aid, the mixing of 30-40% defoamer, for subsequent use;
Step 2: after silicate cement, filler, pigment, softening agent, thixotropic agent, anti-accumulation of salt in the surface soil agent, water, the mixing of surplus defoamer, with mixed solution in step 1 carry out mixing and obtain the invention provides Art Stone color after repair slurry.
Wherein, described film forming matter, chooses one or more compounds in acrylic ester emulsion, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion, benzene emulsion, EVA emulsion, epoxy resin, polyaminoester emulsion, silicone resin etc.
Wherein, described properties-correcting agent is one or more in lithium silicate, potassium silicate, water glass, silane coupling agent, nano silicon.
Wherein, described silicate cement be white label be PO32.5, PO42.5, PO52.5, PO62.5 etc., according to specification of quality select wherein one or more.
Wherein, described filler can be water-ground limestone, talcum powder, wollastonite powder, wollastonite powder, wilkinite, mica powder, calcined kaolin any one or a few.
Wherein, the various pigment that described pigment can select the art conventional, as carbon black, ferric oxide, cobalt oxide, titanium dioxide, ultramarine, phthalocyanine blue, phthalocyanine green, chromoxide green, chrome yellow etc. that market is sold, can be wherein any one or a few.
Wherein, described fluidizer (being also called softening agent) is preferably polycarboxylic acid high-performance fluidizer, and may also be naphthalene series high-efficiency water-reducing agent, melamine water reducer, wooden calcium water reducer, can be wherein any one or a few.
Wherein, any one or a few in described wetting agent Main Anions tensio-active agent, polyalchohols surfactants, polyoxyethylene-type surfactant etc.
Wherein, described thixotropic agent can be starch ethers, smectites, swelling great soil group, attapulgite class and kaolin families and through organically-modified above-mentioned substance, can be wherein any one or a few.
Wherein, described pH adjusting agent, is selected from Monoethanolamine MEA BASF, diethanolamine, trolamine, 2-amino-2-methyl-1-propanol, N-e dimethylethanolamine, can be wherein any one or a few.
Wherein, described thickening material can be ether of cellulose and derivatives class thickening material, association type alkali swollen thickener, polyurethane thickener, can be concrete model any one or a few.
Wherein, described film coalescence aid is any one or a few in propandiol butyl ether, propandiol butyl ether acetic ester, propylene glycol, alcohol ester 12.
Wherein, described anti-accumulation of salt in the surface soil agent is at least one in cinnamic acrylic ester, phosphine and ammonia derivative, high reactivity earth silicon material.
Wherein, described defoamer is at least one in silicone oil, polyethers, higher alcohols, mineral oil, vegetables oil.
Wherein, repair in the preparation method of slurry after described a kind of cement based imitated natural cultural stone color, the described main and auxiliary viscosity when mill base body is similar and different.Can be: 1) mass-tone slurry is high viscosity monochromatic repairing slurry (some spray is major way) for having low viscosity monochrome repairing slurry (spray painting and full spray are major way) auxiliary mill base material corresponding with it; Or 2) auxiliary mill base body is high viscosity monochromatic repairing slurry (some spray is major way) for having low viscosity monochrome repairing slurry (spray painting and full spray are major way) mass-tone slurry corresponding with it.Preferably, described mass-tone slurry viscosity degree is less than auxiliary mill base body.
The range of viscosities of the above-mentioned mass-tone of the present invention, auxiliary monochromatic slurry is preferably 70 ~ 150KU, is preferably 80 ~ 120mm.
3rd aspect of the present invention is to provide a kind of reparation construction method of cement based imitated natural cultural stone, and step is as follows:
Step 1: repair slurry after preparing the one that formula described above and method provide, require according to required color or debug in advance, preparing one or more monochromatic color slurries simultaneously;
Step 2: press through journey according to repair products colour-forming layer, carries out color decomposition, determines spraying order; The instrument such as spray gun, brush is utilized to carry out wet touching wet spray or brushing;
Step 3: dry or naturally dry.
Wherein, described spraying gimmick variation, unrestricted choice according to actual needs.
Wherein, described spraying method, is mainly reflected in by adjusting tolerance and load, realizes the effects such as some spray, spray painting, office's spray, full spray; Wherein, some spray is that air output is less, shape spraying that slurry presents " particle ", and slurry is discontinuous, and pointing object is presented on product surface; Spray painting and slurry atomizing effect good, full spraying and do not hide product last layer color; Office's spray and selective spray, the spraying of different sites; Namely full spray is the color covering last layer; Basis spraying method flexible utilization with and use, particularly important to the realization of effect;
Dry or drying after spraying of the present invention completes, after carrying out rear repairing as product, need maintenance and/or post-processing step, reach the normal object used, wherein: described drying condition is: product dries more than 5h after repairing under 40 ~ 80 DEG C of conditions; Described certainly dry condition is: do not have rainwater in 24h hour, and the weather condition of more than 5 DEG C is from dry, and this mode is mainly around the drying conditions that the repairing on engineering body of wall need meet; Namely engineering is repaired and is suitable for carrying out at spring and fall.
Beneficial effect: the present invention passes through the optimization of repairing formula after cement based imitated natural cultural stone color, preparation is applicable to the slurry of different spraying method, the sequencing that control color is formed, realize the opposition thinking pattern of repair products, and by wet spraying superposition of touching wet main and auxiliary mill base body, form natural fusion after drying, recover the construction technology that product original appearance is workable.In the process of preparation rear repairing slurry, separately mixing object is mainly the difference of heterogeneity to dispersion requirement.
Component proportion science provided by the invention, superior, with low cost, technique have strong operability, transition nature, repair the features such as true to nature, to solution and improve produce and engineering repair, can be used as a kind of practical way.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Repair slurry and preparation method thereof and constructional method after the invention provides a kind of cement based imitated natural cultural stone color, the viscosity of described main and auxiliary monochromatic slurry is similar and different, but is preferably separately selected from and is prepared by composition A.
Repair slurry and preparation method thereof and constructional method after a kind of cement based imitated natural cultural stone color provided by the present invention, concrete operation step is as follows:
1) main and auxiliary monochrome repairs slurry, requires or debugs in advance, prepare one or more monochromatic color slurries simultaneously according to required color;
2), after first the film forming matter of liquid, properties-correcting agent, wetting agent, thickening material, film coalescence aid, defoamer preferentially being mixed, high speed dispersor is adopted to disperse, within controlling rate of dispersion 1200 turns/min, after being uniformly dispersed, for subsequent use.Then after silicate cement or filler, pigment, softening agent, thixotropic agent, anti-accumulation of salt in the surface soil agent, water, defoamer being closed at a high speed very much, control rate of dispersion 1200--2500 to turn/min between, secondary combination treatment is carried out with mixed solution for subsequent use after mixing, within controlling rate of dispersion 1200 turns/min, separately mixing object is mainly the difference that heterogeneity requires dispersion.The timely color debugging of this link is also the link of preparation.
3) press through journey according to repair products colour-forming layer, carry out color decomposition, determine spraying order; This link is to the accumulation outbalance of knowhow and operating experience;
4) instrument such as spray gun, brush is utilized to carry out wet touching wet spray or brushing; The variation of spraying gimmick; How the denseness that the mode of spraying decides the monochromatic slurry of major-minor look controls, and the denseness of some spray selects to reach the standard grade viscosity number, and spray painting selects to roll off the production line viscosity number, is so more conducive to the realization of control to effect.
5) dry or naturally dry.Carry out in factory carrying out repair procedure, naturally dry and determine according to external conditions with oven dry, it is more effective usually to dry, and ensures to some extent the quality of repair layer.
The preparation that the present invention repairs slurry because of the restriction of material slightly loaded down with trivial details, but the not homogeneous phase of slurry on microcosmic under the different spraying methods of preparation, and reverse theoretical laminated relationship and wetly touch wet spray mode, and be aided with the cross-over control of different spraying method, easily realize the patch work of polluted product, get a desired effect.
Embodiment 1
Step 1, according to the demand of producing for a kind of imitated natural cultural stone---the fading of cultural brick A, the accumulation of salt in the surface soil, complete bulk article in factory and repair, need prepare a kind of mass-tone slurry and the auxiliary mill base material of one, mass-tone pulp components comprises:
The weight ratio of the auxiliary look pulp components of collocation corresponding is with it:
Product surface dust to be repaired blows off;
The auxiliary mill base body by the viscosity of preparation being the mass-tone slurry of 90KU and 120KU is for subsequent use, adopts bore to be the spray gun of 2mm, mass-tone entirely to spray, office's spray, auxiliary look based on a spray, order auxiliary after the former head;
For keeping the validity of spraying, with product distance for 20cm is advisable, injection direction and product degree in a vertical angle, Total Product in layer sprays, and keeps wet and touches wet spray;
After spraying surface drying, compare with on-gauge plate, evaluate ok and can continue to carry out remaining product; If there is difference, need finely tune;
This material contains cement composition, in spraying process, within controlling main and auxiliary mill base body 4h working lipe;
Dry 5h at 40 DEG C or naturally dry 1d, can case, before vanning, can water-resisting agent protective treatment be carried out.Wall construction can be gone up after 7 days.
Embodiment 2
Example 2, according to the demand of market and client imitated natural cultural stone---the Art Stone B for the engineering accumulation of salt in the surface soil and pollution; Subject matter be engineered cementitious slurry pollute with local the accumulation of salt in the surface soil after, color deviation; Need prepare a kind of mass-tone mortar and the auxiliary smalt slurry of one, mass-tone mortar component comprises:
Step 1, according to the demand of producing for a kind of imitated natural cultural stone---the fading of cultural brick A, the accumulation of salt in the surface soil, complete bulk article in factory and repair, need prepare a kind of mass-tone slurry and two kinds of auxiliary mill base material, mass-tone pulp components comprises:
The weight ratio of the first auxiliary look pulp components of collocation corresponding is with it:
The weight ratio of the auxiliary look pulp components of collocation the second corresponding is with it:
Carry out surface treatment to the product polluted, employing hairbrush removes accumulation of salt in the surface soil material and pollutent, and maintenance product surface layer is firm, solid, dry, smooth, clean, floating grey, the oil stains-less of nothing;
Be that to be the main and auxiliary mill base body of 100KU for subsequent use by the viscosity of preparation, adopt bore to be the spray gun of 2mm, it is main that mass-tone is sprayed entirely, auxiliary look based on office's spray, order auxiliary after the former head;
For keeping the validity of spraying, with product distance for 20cm is advisable, injection direction and product degree in a vertical angle, Total Product in layer sprays, and keeps wet and touches wet spray;
After spraying surface drying, compare with on-gauge plate, evaluate that feasible rear is sustainable carries out remaining product; If there is difference, need finely tune;
Construction temperature: more than 5 DEG C and relative humidity less than 85% construct, the severe weather such as strong wind, heavy rain should avoid construction.
Naturally dry, consider weather condition during construction, 24h does not have rainwater.
In foregoing of the present invention, described viscosity is all according to GB/T9269-1988 standard test.
Repairing case in the above embodiment of the present invention, compensate for the defect of corresponding product preferably, reduces production cost, and can mass-producing operation; Engineering repairs the flaw solving decorative effect, and the test of elapsed-time standards and external conditions, remain intact.
Be described in detail specific embodiments of the invention above, but it is just as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and substituting also all among category of the present invention.Therefore, equalization conversion done without departing from the spirit and scope of the invention and amendment, all should contain within the scope of the invention.
Claims (10)
1. repair a slurry after cement based Art Stone color, it is characterized in that, count by weight, comprising:
2. repair slurry after cement based Art Stone color according to claim 1, it is characterized in that, described film forming matter, to be selected from acrylic ester emulsion, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion, benzene emulsion, EVA emulsion, epoxy resin, polyaminoester emulsion, silicone resin any one and multiple mixture; Described film coalescence aid, be selected from propandiol butyl ether, propandiol butyl ether acetic ester, propylene glycol, alcohol ester 12 any one or a few.
3. repair slurry after cement based Art Stone color according to claim 1, it is characterized in that, described properties-correcting agent is one or more in lithium silicate, potassium silicate, water glass, silane coupling agent, nano silicon.
4. repair slurry after cement based Art Stone color according to claim 1, it is characterized in that, described filler be selected from water-ground limestone, talcum powder, wollastonite powder, wollastonite powder, wilkinite, mica powder, calcined kaolin any one or a few; Described fluidizer is selected from least one in polycarboxylic acid high-performance fluidizer, naphthalene series high-efficiency water-reducing agent, melamine water reducer, wooden calcium water reducer.
5. repair slurry after cement based Art Stone color according to claim 1, it is characterized in that, described thickening material is selected from ether of cellulose and derivatives class thickening material, association type alkali swollen thickener, polyurethane thickener; Described wetting agent be selected from anion surfactant, polyalchohols surfactants, polyoxyethylene-type surfactant any one or a few.
6. repair slurry after cement based Art Stone color according to claim 1, it is characterized in that, described thixotropic agent can be starch ethers, smectites, swelling great soil group, attapulgite class and kaolin families and any one or a few in organically-modified above-mentioned substance thereof.
7. repair slurry after cement based Art Stone color according to claim 1, it is characterized in that, described anti-accumulation of salt in the surface soil agent is at least one in cinnamic acrylic ester, phosphine and ammonia derivative, high reactivity earth silicon material; Described defoamer is at least one in silicone oil, polyethers, higher alcohols, mineral oil, vegetables oil.
8. repair slurry after cement based Art Stone color according to claim 1, it is characterized in that, the range of viscosities of main and auxiliary mill base body is 70 ~ 150KU.
9. mend a preparation method for slurry after preparing cement based Art Stone color described in claim 1, it is characterized in that, step comprises:
Step 1: by the film forming matter of liquid, properties-correcting agent, wetting agent, thickening material, film coalescence aid, the mixing of 30-40% defoamer, for subsequent use;
Step 2: after silicate cement, filler, pigment, softening agent, thixotropic agent, anti-accumulation of salt in the surface soil agent, water, the mixing of surplus defoamer, repair slurry after carrying out mixing and obtain Art Stone color described in claim 1 with mixed solution in step 1.
10. mend a constructional method for slurry after the cement based Art Stone color that prepared by method described in claim 9, it is characterized in that step comprises:
Step 1: repair slurry after preparing the one that formula described above and method provide, require according to required color or debug in advance, preparing one or more monochromatic color slurries simultaneously;
Step 2: press through journey according to repair products colour-forming layer, carries out color decomposition, determines spraying order; The instrument such as spray gun, brush is utilized to carry out wet spray or brushing;
Step 3: dry or naturally dry.
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| CN201510109302.7A CN104761211B (en) | 2015-03-12 | 2015-03-12 | Slurry and its preparation and reparation construction method are repaired after a kind of cement base Art Stone color |
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| CN201510109302.7A CN104761211B (en) | 2015-03-12 | 2015-03-12 | Slurry and its preparation and reparation construction method are repaired after a kind of cement base Art Stone color |
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