CN107587095A - A kind of environmentally friendly copper and copper alloy plate strip surface hot-dip tinning method - Google Patents
A kind of environmentally friendly copper and copper alloy plate strip surface hot-dip tinning method Download PDFInfo
- Publication number
- CN107587095A CN107587095A CN201710952879.3A CN201710952879A CN107587095A CN 107587095 A CN107587095 A CN 107587095A CN 201710952879 A CN201710952879 A CN 201710952879A CN 107587095 A CN107587095 A CN 107587095A
- Authority
- CN
- China
- Prior art keywords
- copper
- alloy plate
- tin
- copper alloy
- plate strip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 198
- 239000010949 copper Substances 0.000 title claims abstract description 176
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 168
- 229910000881 Cu alloy Inorganic materials 0.000 title claims abstract description 121
- 238000000034 method Methods 0.000 title claims abstract description 49
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 147
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 102
- 239000011248 coating agent Substances 0.000 claims abstract description 52
- 238000000576 coating method Methods 0.000 claims abstract description 52
- 238000001035 drying Methods 0.000 claims abstract description 35
- 238000007747 plating Methods 0.000 claims abstract description 32
- 238000001816 cooling Methods 0.000 claims abstract description 26
- 239000008367 deionised water Substances 0.000 claims abstract description 21
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 21
- 230000008569 process Effects 0.000 claims abstract description 21
- 238000005554 pickling Methods 0.000 claims abstract description 18
- 238000001994 activation Methods 0.000 claims abstract description 17
- 239000013527 degreasing agent Substances 0.000 claims abstract description 14
- 229910001316 Ag alloy Inorganic materials 0.000 claims abstract description 13
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical group Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims abstract description 12
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical group [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000013043 chemical agent Chemical group 0.000 claims abstract description 7
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims abstract description 6
- 239000010410 layer Substances 0.000 claims description 101
- 238000012545 processing Methods 0.000 claims description 71
- 238000005498 polishing Methods 0.000 claims description 23
- 239000012792 core layer Substances 0.000 claims description 21
- 229910000906 Bronze Inorganic materials 0.000 claims description 20
- 239000010974 bronze Substances 0.000 claims description 20
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 20
- 238000004140 cleaning Methods 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 14
- 238000005238 degreasing Methods 0.000 claims description 12
- 229910018471 Cu6Sn5 Inorganic materials 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 7
- 239000003082 abrasive agent Substances 0.000 claims description 5
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims description 5
- 239000004745 nonwoven fabric Substances 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 229910017692 Ag3Sn Inorganic materials 0.000 claims description 3
- 229910018082 Cu3Sn Inorganic materials 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910000679 solder Inorganic materials 0.000 claims description 3
- 229910001369 Brass Inorganic materials 0.000 claims description 2
- 229910000570 Cupronickel Inorganic materials 0.000 claims description 2
- 239000010951 brass Substances 0.000 claims description 2
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 238000007494 plate polishing Methods 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 238000011049 filling Methods 0.000 abstract description 3
- 239000011135 tin Substances 0.000 description 128
- 239000003795 chemical substances by application Substances 0.000 description 23
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 5
- 229910001431 copper ion Inorganic materials 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 238000004804 winding Methods 0.000 description 5
- 238000009713 electroplating Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000005452 bending Methods 0.000 description 3
- 239000000498 cooling water Substances 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005237 degreasing agent Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- QCEUXSAXTBNJGO-UHFFFAOYSA-N [Ag].[Sn] Chemical compound [Ag].[Sn] QCEUXSAXTBNJGO-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- -1 fine copper Chemical compound 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Coating With Molten Metal (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
The invention discloses a kind of environmentally friendly copper and copper alloy plate strip surface hot-dip tinning method, comprise the following steps：Ungrease treatment is carried out to copper and copper alloy plate strip using alkaline degreaser；Use H2SO4Pickling processes are carried out to strip；Activation process is carried out to strip using the solution that ammonium bromide, hydrogen bromide and other chemical agents form；Copper and copper alloy plate strip are preheated in drying/pre-add hot-zone, preheating temperature is 50 130 DEG C；Strip is introduced into the tin liquor groove of pure tin or sn-ag alloy, progress is tin plating, and tin plating temperature is 230 290 DEG C；Strip is introduced at air knife, thickness of coating is automatically controlled according to the strip thickness of preplating and predetermined thickness of coating, air knife；Strip is introduced into air cooling zone, 120 150 DEG C are fallen within the range of using wind cooling blower；Strip is introduced into the tank for filling deionized water or pure water, its temperature is dropped to 20 60 DEG C.Strip surface hot-dip tinning method provided by the invention, its step is reasonable, and the uniformity of copper coin belt surface tin layers has been effectively ensured, and improves tin plating quality.
Description
Technical field
The present invention relates to metal plate and belt to produce and process field, more particularly to a kind of environmentally friendly copper and the hot dipping of copper alloy plate strip surface
Tin plating method.
Background technology
Tin plating copper plate/strip has a variety of good characteristics, prevent copper plate/strip be oxidized and the corruption by materials such as acidity, alkalescence
Contact resistance in erosion, reduction electrical machine element and electronic component, in generation information technology industry, advanced track traffic, energy-conservation
With being widely used and developing in new-energy automobile, electrical circuitry equipment industry, it is mainly used in large scale integrated circuit, highly dense
Spend the manufacture of lead frame, high-end electronic component, accurate plug terminal.
At present, copper plate/strip electroplating surfaces with tin is generally divided into electrotinning and hot dipped tinning.Process of tin is electroplated compared with hot dipped tinning,
Had the following disadvantages during copper plate/strip electrotinning：
（1）By then passing through the size of control electric current, the concentration of electrolyte determines the thickness of coating, causes copper coin belt surface to plate
Layer thickness profile is uneven, and generally edge thickness is more than interior thickness.
（2）In electroplating process, whisker is easily formed, causes internal stress or tin layers inside coating to be present and sticks with parent metal
Must be insecure, in turn result in the miniaturized electronic components short circuit accident using electrotinning copper plate/strip.Therefore, generally increase after plating
A step heat treatment step is added to eliminate the internal stress of coating.
（3）At present, low production efficiency during copper plate/strip electrotinning, universal velocity are 40 ~ 50m/min；
（4）Electroplating bath components are complicated, containing substantial amounts of heavy metal, are not suitable for recycling.
In addition, existing hot dipped tinning technique, generally there is the thickness of two methods control coating：
（1）Control the soak time in tin liquor.Although the method can be corresponding by the engineer testing of early stage, each thickness of coating
Process program, but it is rough be controlled, and cause thickness of coating not reach requirement or skewness；
（2）Machinery smears tin.Although the thickness of coating can be controlled by this technique, tin steel rider is being smeared using after a certain amount of,
Steel roller faces easily accumulate scruff or damage, and then cause thickness of coating skewness or coating the defects of a large amount of to be present.In addition,
Existing hot dipped tinning technique, can not meet high-speed and continuous produce, and cause hot dipped tinning copper plate/strip coil coil-diameter it is small, volume weight it is low,
Low production efficiency.
The content of the invention
The purpose of the present invention is to be directed to above-mentioned technical problem, there is provided a kind of environmentally friendly copper and the hot-dip of copper alloy plate strip surface
Tin method, its step is reasonable, effectively prevent the shortcomings that electroplating process of tin and existing hot dipped tinning technique, ensure that copper plate/strip table
The uniformity of face tin layers, improve production efficiency and hot dipped tinning copper plate/strip coil coil-diameter and volume weight.
Technical scheme
In order to solve the above technical problems, a kind of environmentally friendly copper provided by the invention and copper alloy plate strip surface hot-dip tinning method, tool
Body comprises the following steps：
S1, ungrease treatment is carried out to copper and copper alloy plate strip using alkaline degreaser, its concentration is 0.3-2%, temperature 30-90
℃；
In this step, using alkaline degreaser ungrease treatment, except the greasy dirt on copper plate/strip surface, ensure that tin layers are equal during hot dipped tinning
It is even, smooth.
S2, use H2SO4Pickling processes are carried out to copper and copper alloy plate strip, its concentration is 10-20%, temperature is 15-50 DEG C,
Copper ion concentration is less than 40g/l；
In this step, pickling processes remove copper plate/strip surface scale, ensure that tin layers are uniform, smooth during hot dipped tinning.
S3, the solution formed using ammonium bromide, hydrogen bromide and other chemical agents are carried out at activation to copper and copper alloy plate strip
Reason；
Before activation process, it is also necessary to carry out drying and processing to strip, it is 80 DEG C to keep drying temperature.Drying removes copper plate/strip
The moisture content of remained on surface, ensure that tin layers are uniform, smooth during hot dipped tinning.Fluxing agent is submerged or sprays in copper coin belt surface to carry out
Activation process, remove after step drying and processing in atmosphere again caused by oxide skin, while improve the leaching of tin liquor and copper strip surface
Lubricant nature, ensure that tin layers are uniform, smooth during hot dipped tinning.
S4, copper and copper alloy plate strip are preheated in drying/pre-add hot-zone, preheating temperature is 50-130 DEG C；
Preheating process preheats copper strips while drying to fluxing agent, make during copper strips hot-dip surface adhered to one layer it is dry fluxing
Agent, ensure that tin layers are uniform, smooth during hot dipped tinning.
S5, copper and copper alloy plate strip are introduced into the tin liquor groove of pure tin or sn-ag alloy, progress is tin plating, and tin plating temperature is
230-290℃；
S6, copper and copper alloy plate strip are introduced at air knife, according to the copper of preplating and copper alloy bare board tape thickness and predetermined coating
Thickness, air knife automatically control thickness of coating；
S7, copper and copper alloy plate strip are introduced into cooling zone, fall within the range of 120-150 DEG C；Copper and copper alloy plate strip are introduced
Fill pH value to be maintained in 15-50 DEG C of deionized water or the tank of pure water for 5.5-8.5, water temperature and carry out water cooling, make its temperature
Degree drops to 20-60 DEG C；
The air-cooled band to after tin plating cools down, and avoids not solidified tin layers from being scratched；Water cooling enters one to the band after tin plating
Step cooling, ensure the crystalline condition of tin layers.
S8, the copper after processing and copper alloy plate strip are introduced into thickness of coating measuring system, monitor thickness of coating automatically, and will
As a result feed back at air knife, to correct air knife parameter, thickness of coating is reached pre-provisioning request.
In this step, different experiment curvs can be selected according to the species of alloy, detects thickness of coating；Pass through plating
Layer automatic control system, ensure the thickness and surface quality situation of tin layers.
Further, the copper and copper alloy plate strip include the copper such as fine copper, high purity copper, bronze, brass and copper-nickel alloy and copper closes
Golden plate band, its thickness are 0.1-1.5mm, and width is 150-370 mm.
Further, need to carry out cold rinse and Re Chong using rinse water after copper and copper alloy plate ungrease treatment and pickling processes
Wash, cleaning water ph value is 1.5-8.5；During cold rinse, rinse water water temperature is 15-60 DEG C, and during heat flush, rinse water water temperature is 15-
90℃.Heat flush after ungrease treatment removes the degreasing agent of copper plate/strip remained on surface, ensure during hot dipped tinning tin layers uniformly, light
It is sliding；Heat flush after pickling processes is finally cleaned to copper strip surface, ensure hot dipped tinning when tin layers it is uniform, it is smooth, without convex
Rise or peeling.
Further, also needed between the cold rinse after copper and copper alloy plate pickling processes and heat flush process at polishing
Reason, the water of water polishing is deionized water or pure water, and its pH value is maintained at 5-8.5, and it is 15-60 DEG C to keep water temperature；Polishing
Polishing roll is abrasive material pin brush/nonwoven fabric brush roll, and its brush roll mesh number is 600-1000.Water polishing remove copper plate/strip surface scale and
Impurity, ensure during hot dipped tinning tin layers it is uniform, it is smooth, without raised or peeling.
Further, in step S5, tin liquor is pure tin, and its main component is：99.90% tin, remaining is impurity；Tin liquor is
Sn-ag alloy, its main component are：1.5-5.0% is silver-colored, remaining is tin.
Further, in step S6, the gases used compressed air for 100-800bar of air knife, the distance of air knife is 0.1-
50mm.Air knife system is control effectively, it is ensured that the thickness and surface quality situation of tin layers.
Further, tin-coated copper and copper alloy plate strip can include copper core layer, the signal bronze layer outside copper core layer, position
Tin layers outside signal bronze sandwich layer, the signal bronze layer composition outside copper core layer can be mutually Cu6Sn5, outside copper core layer
Signal bronze layer composition mutually can be Cu6Sn5、Cu3Sn:Sn=1:1。
Further, tin-coated copper and copper alloy plate strip include copper core layer, the copper and tin ag alloy layer outside copper core layer, are located at
Tin layers outside signal bronze sandwich layer, the copper and tin ag alloy layer composition outside copper core layer is mutually Ag3Sn and Cu6Sn5Micro- mistake of composition
Eutectic structure.
Further, in production process, the tension force of tin-coated copper and copper alloy plate strip is 5-100Mpa, tin-coated copper and copper alloy
The speed of service 5-150m/min of strip.
Disclosed herein as well is a kind of environmentally friendly copper and copper alloy plate strip surface hot-dip tinning production line, and it is an entirety
Production line, it is characterised in that in the presence of uncoiler, preceding S rollers, rear S rollers and winder, it holds automatically for copper and copper alloy plate strip
Processing step described in row claim 1.
Disclosed herein as well is a kind of environmentally friendly copper and copper alloy plate strip surface hot-dip tinning production line, it includes degreasing pickling
Clean line, hot-dip solder, it is characterised in that when perform claim requires the processing step described in 1, degreasing pickling line is set
Independent uncoiler, preceding S rollers, rear S rollers and winder, hot-dip solder set independent uncoiler, preceding S rollers, rear S rollers and winding
Machine.
Beneficial effect of the present invention：
A kind of environmentally friendly copper provided by the invention and copper alloy plate strip surface hot-dip tinning method, its step is reasonable, has with following
Beneficial effect：
（1）The shortcomings that effectively prevent plating process of tin and existing hot dipped tinning technique, improve the matter of copper coin belt surface tin layers
Amount；
（2）Can continuous production, centre occurs without interruption, improves production efficiency；
（3）Hot dipped tinning copper plate/strip coil coil-diameter is up to 1600mm or higher, volume weight up to 4t or higher, strip length up to up to ten thousand
Rice is higher；
（4）Thickness and the distribution of coating can be accurately controlled by air knife system, ensure that the uniform of copper coin belt surface tin layers
Property；
（5）Copper and copper alloy plate strip surface hot-dip tinning method and device described herein, meets the requirement of environmental protection.
Brief description of the drawings
By the detailed description made in conjunction with the following drawings, above-mentioned advantage of the invention will be apparent and be easier reason
Solution, these accompanying drawings are simply schematical, are not intended to limit the present invention, wherein：
Fig. 1 is copper and copper alloy plate strip surface hot-dip tinning method flow diagram of the present invention.
Embodiment
With reference to specific embodiments and the drawings, the present invention is described in detail.
The embodiment recorded herein is specific embodiment of the invention, for illustrating the design of the present invention,
It is explanatory and exemplary, should not be construed as the limitation to embodiment of the present invention and the scope of the invention.Except what is recorded herein
Outside embodiment, those skilled in the art can also be based on the application claims and specification disclosure of that using aobvious and
The other technical schemes being clear to, these technical schemes include any obvious using making for the embodiment to recording herein
The technical scheme of substitutions and modifications.
As shown in figure 1, a kind of environmentally friendly copper provided by the invention and copper alloy plate strip surface hot-dip tinning method, are specifically included
Following steps：
S1, ungrease treatment is carried out to copper and copper alloy plate strip using alkaline degreaser, its concentration is 0.3-2%, temperature 30-90
℃；
In this step, using alkaline degreaser ungrease treatment, except the greasy dirt on copper plate/strip surface, ensure that tin layers are equal during hot dipped tinning
It is even, smooth.
S2, use H2SO4Pickling processes are carried out to copper and copper alloy plate strip, its concentration is 10-20%, temperature is 15-50 DEG C,
Copper ion concentration is less than 40g/l；
In this step, pickling processes remove copper plate/strip surface scale, ensure that tin layers are uniform, smooth during hot dipped tinning.
S3, the solution formed using ammonium bromide, hydrogen bromide and other chemical agents are carried out at activation to copper and copper alloy plate strip
Reason；
Before activation process, it is also necessary to carry out drying and processing to strip, it is 80 DEG C to keep drying temperature.Drying removes copper plate/strip
The moisture content of remained on surface, ensure that tin layers are uniform, smooth during hot dipped tinning.Fluxing agent is submerged or sprays in copper coin belt surface to carry out
Activation process, remove after step drying and processing in atmosphere again caused by oxide skin, while improve the leaching of tin liquor and copper strip surface
Lubricant nature, ensure that tin layers are uniform, smooth during hot dipped tinning.
S4, copper and copper alloy plate strip are preheated in drying/pre-add hot-zone, preheating temperature is 50-130 DEG C；
Preheating process preheats copper strips while drying to fluxing agent, make during copper strips hot-dip surface adhered to one layer it is dry fluxing
Agent, ensure that tin layers are uniform, smooth during hot dipped tinning.
S5, copper and copper alloy plate strip are introduced into the tin liquor groove of pure tin or sn-ag alloy, progress is tin plating, and tin plating temperature is
230-290℃；
S6, copper and copper alloy plate strip are introduced at air knife, according to the copper of preplating and copper alloy bare board tape thickness and predetermined coating
Thickness, air knife automatically control thickness of coating；
S7, copper and copper alloy plate strip are introduced into cooling zone, fall within the range of 120-150 DEG C；Copper and copper alloy plate strip are introduced
Fill pH value to be maintained in 15-50 DEG C of deionized water or the tank of pure water for 5.5-8.5, water temperature and carry out water cooling, make its temperature
Degree drops to 20-60 DEG C；
The air-cooled band to after tin plating cools down, and avoids not solidified tin layers from being scratched；Water cooling enters one to the band after tin plating
Step cooling, ensure the crystalline condition of tin layers.
S8, the copper after processing and copper alloy plate strip are introduced into thickness of coating measuring system, monitor thickness of coating automatically, and will
As a result feed back at air knife, to correct air knife parameter, thickness of coating is reached pre-provisioning request.
In this step, different experiment curvs can be selected according to the species of alloy, detects thickness of coating；Pass through plating
Layer automatic control system, ensure the thickness and surface quality situation of tin layers.
Illustrate specific technical process with reference to embodiment.
Embodiment one：
A kind of production technology of environmentally friendly metal tape hot dipped tinning, comprises the following steps：
（1）Uncoiling, the C70250 copper alloy belts volume that the 0.1mm of preplating is thick, 370mm is wide is placed on uncoiler and unreeled.
（2）By step（1）Before C70250 copper alloy belts volume after processing is introduced into S rollers, retainer belt volume tension force is 15Mpa.
（3）Degreasing, to step（2）C70250 copper alloy belts volume after processing is lived using silicates and non-ionic surface
Property agent composition alkaline degreaser carry out surface cleaning by degreasing, keep degreaser concentration be 1-2%, temperature be 50-80 DEG C.Pass through
Step（3）The greasy dirt of copper coin belt surface is removed, ensures that tin layers are uniform, smooth during hot dipped tinning.
（4）Cold rinse, to step（3）Copper and copper alloy plate strip after processing are carried out cold using deionized water or pure water
Rinse, holding cleaning water ph value is 7, water temperature is 40 DEG C.Pass through step（4）Cold rinse removes the degreasing agent of copper plate/strip remained on surface
And greasy dirt, ensure that tin layers are uniform, smooth during hot dipped tinning.
（5）Heat flush, to step（4）C70250 copper alloy belts volume after processing is carried out using deionized water or pure water
Heat flush, holding cleaning water ph value is 7, water temperature is 80 DEG C.Pass through step（5）Heat flush removes the degreasing of copper plate/strip remained on surface
Agent, ensure that tin layers are uniform, smooth during hot dipped tinning.
（6）Pickling, to step（5）C70250 copper alloy belts volume after processing uses H2SO4Surface acid-washing is carried out, is kept
H2SO4Concentration is 15%, temperature is 25-40 DEG C, copper ion concentration is less than 40g/l.
（7）Cold rinse, to step（6）C70250 copper alloy belts volume after processing is carried out using deionized water or pure water
Cold rinse, holding cleaning water ph value is 7, water temperature is 40 DEG C.Step（7）Cold rinse removes copper plate/strip remained on surface acid solution, prevents
Residual acid liquid corrosion copper strips causes tin plating infiltration incomplete.
（8）Polishing, to step（7）C70250 copper alloy belts volume after processing enters water-filling using deionized water or pure water
Polishing, holding polishing water ph value is 7, water temperature is 40 DEG C.Pass through step（8）Water polishing removes copper plate/strip surface scale and miscellaneous
Matter, ensure during hot dipped tinning tin layers it is uniform, it is smooth, without raised or peeling.
（9）Heat flush, to step（8）C70250 copper alloy belts volume after processing is carried out using deionized water or pure water
Heat flush, holding cleaning water ph value is 7, water temperature is 80 DEG C.In addition, polishing roll is abrasive material pin brush/nonwoven fabric brush roll, its brush roll mesh
Number is 600-1000.Step（9）Heat flush is finally cleaned to copper strip surface, ensure hot dipped tinning when tin layers it is uniform, it is smooth,
Without raised or peeling.
（10）Drying, to step（9）C70250 copper alloy belts volume after processing carries out skin drying processing, keeps drying temperature
Spend for 80 DEG C.Pass through step（10）Drying remove copper plate/strip remained on surface moisture content, ensure hot dipped tinning when tin layers uniformly, light
It is sliding.
（11）Activation process, will be to step（10）C70250 copper alloy belts volume after processing is introduced by ammonium bromide, hydrogen bromide
And in the fluxing agent groove of other chemical agent compositions, activation process is carried out to its surface.Pass through step（11）Soaked in copper coin belt surface
Not or spray fluxing agent carries out activation process, removes step（10）Afterwards in atmosphere again caused by oxide skin, while improve tin
The wellability of liquid and copper strip surface, ensure that tin layers are uniform, smooth during hot dipped tinning.
（12）Drying/preheating, by step（11）C70250 copper alloy belts volume after processing introduces drying/pre-add hot-zone,
It is preheated, it is 50 DEG C to keep pre-heating temperature.Pass through step（12）Preheating, pre-add while drying to fluxing agent
Hot copper strips, surface during copper strips hot-dip has been adhered to one layer of dry fluxing agent, ensure that tin layers are uniform, smooth during hot dipped tinning.
（13）It is tin plating, by step（12）C70250 copper alloy belts volume after processing, which is introduced into pure tin liquid bath, carries out tin plating, guarantor
Tin liquor temperature is held as 265 DEG C.
（14）Coating controls, by step（13）C70250 copper alloy belts volume after processing is introduced at air knife, thick according to copper strips
0.1mm and 1 μm desired of thickness of coating are spent, holding air pressure is 800bar, the distance of air knife is 0.6mm.Pass through step
（14）Air knife system is controlled, ensures the thickness and surface quality situation of tin layers.
（15）It is air-cooled, by step（14）C70250 copper alloy belts volume after processing introduces air cooling zone, drops its temperature
To 120-150 DEG C, it is 500-1500r/min to keep cooling air rotating speed.Pass through step（15）The air-cooled band to after tin plating enters
Row cooling, avoids not solidified tin layers from being scratched.
（16）Water cooling, by step（15）C70250 copper alloy belts volume after processing is introduced into tank, its temperature is dropped to 20-
60 DEG C, holding water cooling water ph value is 7, temperature is 40 DEG C.Pass through step（16）Water cooling further cools down to the band after tin plating, protects
Demonstrate,prove the crystalline condition of tin layers.
（17）Coating detects, by step（16）C70250 copper alloy belts volume after processing introduces thickness of coating measuring system,
Automatic monitoring thickness of coating, and result is fed back at air knife, to correct air knife parameter, thickness of coating is reached 1 μm.Pass through step
Suddenly（17）Coating automatic control system, ensure the thickness and surface quality situation of tin layers.
（18）By step（17）After C70250 copper alloy belts volume after processing is introduced into S rollers, retainer belt volume tension force is
30Mpa。
（19）Oiling, by step（18）C70250 copper alloy belts volume after processing introduces oiling station, in its surface smear
Low viscosity mineral oil.
（20）Winding, by step（19）C70250 copper alloy belts volume after processing, which is introduced on winder, to be wound, rolling speed
For 130m/min.
The C70250 copper alloy tin-plating belts produced using the present embodiment, this kind of tin coating thickness are 1 μm, including copper core layer,
Signal bronze layer outside copper core layer, the tin layers outside signal bronze sandwich layer, and the signal bronze layer composition outside copper core layer
It is mutually Cu6Sn5、Cu3Sn:Sn=1:1.The tin layers surface is uniform, it is smooth, be more than 5 μm, contact impedance without whisker, crystallite dimension
It is low, bending is excellent.
Embodiment two：
A kind of production technology of environmentally friendly metal tape hot dipped tinning, comprises the following steps：
（1）Uncoiling, the C42500 copper alloy belts volume that the 1.5mm of preplating is thick, 200mm is wide is placed on uncoiler and unreeled.
（2）By step（1）Before C42500 copper alloy belts volume after processing is introduced into S rollers, retainer belt volume tension force is 30Mpa.
（3）Degreasing, to step（2）C42500 copper alloy belts volume after processing is lived using silicates and non-ionic surface
Property agent composition alkaline degreaser carry out surface cleaning by degreasing, keep degreaser concentration be 1-2%, temperature be 50-80 DEG C.Pass through
Step（3）The greasy dirt of copper coin belt surface is removed, ensures that tin layers are uniform, smooth during hot dipped tinning.
（4）Cold rinse, to step（3）Copper and copper alloy plate strip after processing are carried out cold using deionized water or pure water
Rinse, holding cleaning water ph value is 7, water temperature is 40 DEG C.
（5）Heat flush, to step（4）C42500 copper alloy belts volume after processing is carried out using deionized water or pure water
Heat flush, holding cleaning water ph value is 7, water temperature is 80 DEG C.Pass through step（5）Heat flush removes the degreasing of copper plate/strip remained on surface
Agent, ensure that tin layers are uniform, smooth during hot dipped tinning.
（6）Pickling, to step（5）C42500 copper alloy belts volume after processing uses H2SO4Surface acid-washing is carried out, is kept
H2SO4Concentration is 15%, temperature is 25-40 DEG C, copper ion concentration is less than 40g/l.
（7）Cold rinse, to step（6）C42500 copper alloy belts volume after processing is carried out using deionized water or pure water
Cold rinse, holding cleaning water ph value is 7, water temperature is 40 DEG C.
（8）Polishing, to step（7）C42500 copper alloy belts volume after processing enters water-filling using deionized water or pure water
Polishing, holding polishing water ph value is 7, water temperature is 40 DEG C.Pass through step（8）Water polishing removes copper plate/strip surface scale and miscellaneous
Matter, ensure during hot dipped tinning tin layers it is uniform, it is smooth, without raised or peeling.
（9）Heat flush, to step（8）C42500 copper alloy belts volume after processing is carried out using deionized water or pure water
Heat flush, holding cleaning water ph value is 7, water temperature is 80 DEG C.In addition, polishing roll is abrasive material pin brush/nonwoven fabric brush roll, its brush roll mesh
Number is 600-1000.Step（9）Heat flush is finally cleaned to copper strip surface, ensure hot dipped tinning when tin layers it is uniform, it is smooth,
Without raised or peeling.
（10）Drying, to step（9）C42500 copper alloy belts volume after processing carries out skin drying processing, keeps drying temperature
Spend for 80 DEG C.Pass through step（10）Drying remove copper plate/strip remained on surface moisture content, ensure hot dipped tinning when tin layers uniformly, light
It is sliding.
（11）Activation process, will be to step（10）C42500 copper alloy belts volume after processing is introduced by ammonium bromide, hydrogen bromide
And in the fluxing agent groove of other chemical agent compositions, activation process is carried out to its surface.Pass through step（11）Soaked in copper coin belt surface
Not or spray fluxing agent carries out activation process, removes step（10）Afterwards in atmosphere again caused by oxide skin, while improve tin
The wellability of liquid and copper strip surface, ensure that tin layers are uniform, smooth during hot dipped tinning.
（12）Drying/preheating, by step（11）C42500 copper alloy belts volume after processing introduces drying/pre-add hot-zone,
It is preheated, it is 130 DEG C to keep pre-heating temperature.Pass through step（12）Preheating, it is pre- while drying to fluxing agent
Heated Copper band, surface during copper strips hot-dip has been adhered to one layer of dry fluxing agent, ensure that tin layers are uniform, smooth during hot dipped tinning.
（13）It is tin plating, by step（12）C42500 copper alloy belts volume after processing, which is introduced into pure tin liquid bath, carries out tin plating, guarantor
Tin liquor temperature is held as 245 DEG C.
（14）Coating controls, by step（13）C42500 copper alloy belts volume after processing is introduced at air knife, according to C51900
（QSn6-0.05）Bronze tape thickness 1.5mm and require 15 μm of thickness of coating, holdings air pressure be 100bar, air knife away from
From for 25mm.Pass through step（14）Air knife system is controlled, ensures the thickness and surface quality situation of tin layers.
（15）It is air-cooled, by step（14）C42500 copper alloy belts volume after processing introduces air cooling zone, drops its temperature
To 120-150 DEG C, it is 500-1500r/min to keep cooling air rotating speed.Pass through step（15）The air-cooled band to after tin plating enters
Row cooling, avoids not solidified tin layers from being scratched.
（16）Water cooling, by step（15）C42500 copper alloy belts volume after processing is introduced into tank, its temperature is dropped to 20-
60 DEG C, holding water cooling water ph value is 7, temperature is 40 DEG C.Pass through step（16）Water cooling further cools down to the band after tin plating, protects
Demonstrate,prove the crystalline condition of tin layers.
（17）Coating detects, by step（16）C42500 copper alloy belts volume after processing introduces thickness of coating measuring system,
Automatic monitoring thickness of coating, and result is fed back at air knife, to correct air knife parameter, thickness of coating is reached 15 μm.Pass through
Step（17）Coating automatic control system, ensure the thickness and surface quality situation of tin layers.
（18）By step（17）After C42500 copper alloy belts volume after processing is introduced into S rollers, retainer belt volume tension force is
100Mpa。
（19）Oiling, by step（18）C42500 copper alloy belts volume after processing introduces oiling station, in its surface smear
Low viscosity mineral oil.
（20）Winding, by step（19）C42500 copper alloy belts volume after processing, which is introduced on winder, to be wound, rolling speed
For 25m/min.
Rolled up using the C42500 copper alloy belts of the present embodiment production, this kind of tin coating thickness is 15 μm, including copper core layer, position
In the signal bronze layer outside copper core layer, the tin layers outside signal bronze sandwich layer, and the signal bronze layer group outside copper core layer
Cheng Xiangwei Cu6Sn5.The tin layers surface is uniform, it is smooth, without whisker, crystallite dimension are more than 5 μm, contact impedance is low, bending is excellent
It is good.
Embodiment three：
A kind of production technology of environmentally friendly metal tape hot dipped tinning, comprises the following steps：
（1）Uncoiling, by the C10100 that the 1.2mm of preplating is thick, 370mm is wide（TU00）Copper strip roll is placed on uncoiler and put
Volume.
（2）By step（1）C10100 after processing（TU00）Before copper strip roll is introduced into S rollers, retainer belt volume tension force is
20Mpa。
（3）Degreasing, to step（2）C10100 after processing（TU00）Copper strip roll uses silicates and non-ionic surface
The alkaline degreaser of activating agent composition carries out surface cleaning by degreasing, and holding degreaser concentration is 1-2%, temperature is 50-80 DEG C.It is logical
Cross step（3）The greasy dirt of copper coin belt surface is removed, ensures that tin layers are uniform, smooth during hot dipped tinning.
（4）Cold rinse, to step（3）Copper and copper alloy plate strip after processing are carried out cold using deionized water or pure water
Rinse, holding cleaning water ph value is 7, water temperature is 40 DEG C.
（5）Heat flush, to step（4）C10100 after processing（TU00）Copper strip roll is entered using deionized water or pure water
Row heat flush, holding cleaning water ph value is 7, water temperature is 80 DEG C.
（6）Pickling, to step（5）C10100 after processing（TU00）Copper strip roll uses H2SO4Surface acid-washing is carried out, is kept
H2SO4Concentration is 15%, temperature is 15-40 DEG C, copper ion concentration is less than 40g/l.
（7）Cold rinse, to step（6）C10100 after processing（TU00）Copper strip roll is entered using deionized water or pure water
Row cold rinse, holding cleaning water ph value is 7, water temperature is 40 DEG C.
（8）Polishing, to step（7）C10100 after processing（TU00）Copper strip roll is carried out using deionized water or pure water
Water polishing, holding polishing water ph value is 7, water temperature is 40 DEG C.Pass through step（8）Water polishing removes copper plate/strip surface scale and miscellaneous
Matter, ensure during hot dipped tinning tin layers it is uniform, it is smooth, without raised or peeling.
（9）Heat flush, to step（8）C10100 after processing（TU00）Copper strip roll is entered using deionized water or pure water
Row heat flush, holding cleaning water ph value is 7, water temperature is 80 DEG C.In addition, polishing roll is abrasive material pin brush/nonwoven fabric brush roll, its brush roll
Mesh number is 600-1000.Step（9）Heat flush is finally cleaned to copper strip surface, ensure hot dipped tinning when tin layers uniformly, light
Slide, without raised or peeling.
（10）Drying, to step（9）C10100 after processing（TU00）Copper strip roll carries out skin drying processing, keeps drying
Temperature is 80 DEG C.Pass through step（10）Drying remove copper plate/strip remained on surface moisture content, ensure hot dipped tinning when tin layers uniformly, light
It is sliding.
（11）Activation process, will be to step（10）C10100 after processing（TU00）Copper strip roll is introduced by ammonium bromide, bromination
In the fluxing agent groove of hydrogen and other chemical agents composition, activation process is carried out to its surface.Pass through step（11）In copper coin belt surface
Submergence or spray fluxing agent carry out activation process, remove step（10）Afterwards in atmosphere again caused by oxide skin, improve simultaneously
The wellability of tin liquor and copper strip surface, ensure that tin layers are uniform, smooth during hot dipped tinning.
（12）Drying/preheating, by step（11）C10100 after processing（TU00）Copper strip roll introduces drying/preheating
Area, it is preheated, it is 90 DEG C to keep pre-heating temperature.Pass through step（12）Preheating, while drying to fluxing agent
Copper strips is preheated, surface during copper strips hot-dip has been adhered to one layer of dry fluxing agent, ensures that tin layers are uniform, smooth during hot dipped tinning.
（13）It is tin plating, by step（12）C10100 after processing（TU00）Copper strip roll is introduced into sn-ag alloy liquid bath and plated
Tin, it is 275 DEG C to keep tin liquor temperature.
（14）Coating controls, by step（13）C10100 after processing（TU00）Copper strip roll is introduced at air knife, foundation
C10100（TU00）Copper strips thickness 1.2mm and 6 μm desired of thickness of coating, holding air pressure are 400bar, the distance of air knife
For 15mm.Pass through step（14）Air knife system is controlled, ensures the thickness and surface quality situation of tin layers.
（15）It is air-cooled, by step（14）C10100 after processing（TU00）Copper strip roll introduces air cooling zone, makes its temperature
120-150 DEG C is dropped to, it is 500-1500r/min to keep cooling air rotating speed.Pass through step（15）The air-cooled band to after tin plating
Cooled down, avoid not solidified tin layers from being scratched.
（16）Water cooling, by step（15）C10100 after processing（TU00）Copper strip roll is introduced into tank, drops to its temperature
20-60 DEG C, holding water cooling water ph value is 7, temperature is 40 DEG C.Pass through step（16）Water cooling is further cold to the band after tin plating
But, the crystalline condition of tin layers is ensured.
（17）Coating detects, by step（16）C10100 after processing（TU00）Copper strip roll introduces thickness of coating measurement system
System, monitors thickness of coating automatically, and result is fed back at air knife, to correct air knife parameter, thickness of coating is reached 6 μm.It is logical
Cross step（17）Coating automatic control system, ensure the thickness and surface quality situation of tin layers.
（18）By step（17）C10100 after processing（TU00）After copper strip roll is introduced into S rollers, retainer belt volume tension force is
60Mpa。
（19）Oiling, by step（18）C10100 after processing（TU00）Copper strip roll introduces oiling station, is applied on its surface
Smear low viscosity mineral oil.
（20）Winding, by step（19）C10100 after processing（TU00）Copper strip roll is introduced on winder and wound, winding speed
Spend for 70m/min.
The C10100 produced using the present embodiment（TU00）Copper strip roll, this kind of tin coating thickness are 6 μm, including copper core layer,
Copper and tin ag alloy layer outside copper core layer, the tin layers outside signal bronze sandwich layer, the copper and tin silver alloy outside copper core layer
Micro- hypereutectic structure that layer composition mutually forms for Ag3Sn and Cu6Sn5.The tin layers surface is uniform, it is smooth, without whisker, crystal grain chi
It is very little be more than 5 μm, contact impedance is low, bending is excellent.
The shortcomings that compared to prior art and deficiency, copper and copper alloy plate strip surface hot-dip tinning side provided by the invention
Method, its step is reasonable, and the uniformity of copper coin belt surface tin layers has been effectively ensured, the defects of avoiding electrotinning.
The present invention is not limited to the above-described embodiments, and anyone can draw other various forms under the enlightenment of the present invention
Product, it is every that there is technical side identical or similar to the present application however, make any change in its shape or structure
Case, it is within the scope of the present invention.
Claims (11)
1. a kind of environmentally friendly copper and copper alloy plate strip surface hot-dip tinning method, it is characterised in that comprise the following steps：
S1, ungrease treatment is carried out to copper and copper alloy plate strip using alkaline degreaser, its concentration is 0.3-2%, temperature 30-90
℃；
S2, use H2SO4Pickling processes are carried out to copper and copper alloy plate strip, its concentration is 10-20%, temperature is 15-50 DEG C, copper from
Sub- concentration is less than 40g/l；
S3, activation process is carried out to copper and copper alloy plate strip using the solution that ammonium bromide, hydrogen bromide and other chemical agents form；
S4, copper and copper alloy plate strip are preheated in drying/pre-add hot-zone, preheating temperature is 50-130 DEG C；
S5, copper and copper alloy plate strip are introduced into the tin liquor groove of pure tin or sn-ag alloy, progress is tin plating, and tin plating temperature is 230-
290℃；
S6, copper and copper alloy plate strip are introduced at air knife, according to the copper of preplating and copper alloy bare board tape thickness and predetermined coating
Thickness, air knife automatically control thickness of coating；
S7, copper and copper alloy plate strip are introduced into cooling zone, fall within the range of 120-150 DEG C；Copper and copper alloy plate strip are introduced
Fill pH value to be maintained in 15-50 DEG C of deionized water or the tank of pure water for 5.5-8.5, water temperature and carry out water cooling, make its temperature
Degree drops to 20-60 DEG C；
S8, the copper after processing and copper alloy plate strip are introduced into thickness of coating measuring system, monitor thickness of coating automatically, and by result
Feed back at air knife, to correct air knife parameter, thickness of coating is reached pre-provisioning request.
2. copper and copper alloy plate strip surface hot-dip tinning method according to claim 1, it is characterised in that the copper and copper close
Golden plate band includes copper and the copper alloy plate strip such as fine copper, high purity copper, bronze, brass and copper-nickel alloy, and its thickness is 0.1-1.5mm, width
For 150-370 mm.
3. copper and copper alloy plate strip surface hot-dip tinning method according to claim 1, it is characterised in that copper and copper alloy plate
It is 1.5-8.5 to need to carry out cold rinse and heat flush, cleaning water ph value using rinse water after ungrease treatment and pickling processes；Cold rinse
When, rinse water water temperature is 15-60 DEG C, and during heat flush, rinse water water temperature is 15-90 DEG C.
4. copper and copper alloy plate strip surface hot-dip tinning method according to claim 1, it is characterised in that copper and copper alloy plate
Polishing is also needed between cold rinse and heat flush process after pickling processes, the water of water polishing is deionized water or pure
Water, its pH value are maintained at 5-8.5, and it is 15-60 DEG C to keep water temperature；The polishing roll of polishing is abrasive material pin brush/nonwoven fabric brush roll, and it is brushed
Roller mesh number is 600-1000.
5. copper and copper alloy plate strip surface hot-dip tinning method according to claim 4, it is characterised in that in step S5, tin
Liquid is pure tin, and its main component is：99.90% tin, remaining is impurity；Tin liquor is sn-ag alloy, and its main component is：1.5-
5.0% silver medal, remaining be tin.
6. copper and copper alloy plate strip surface hot-dip tinning method according to claim 1, it is characterised in that in step S6, wind
The gases used compressed air for 100-800bar of knife, the distance of air knife is 0.1-50mm.
7. copper and copper alloy plate strip surface hot-dip tinning method according to claim 1, it is characterised in that tin-coated copper and copper close
Golden plate band can include copper core layer, the signal bronze layer outside copper core layer, the tin layers outside signal bronze sandwich layer, positioned at copper
Signal bronze layer composition outside sandwich layer can be mutually Cu6Sn5, the signal bronze layer outside copper core layer, which forms, can be mutually
Cu6Sn5、Cu3Sn:Sn=1:1。
8. copper and copper alloy plate strip surface hot-dip tinning method according to claim 1, it is characterised in that tin-coated copper and copper close
Golden plate band includes copper core layer, the copper and tin ag alloy layer outside copper core layer, the tin layers outside signal bronze sandwich layer, positioned at copper core
Micro- hypereutectic structure that copper and tin ag alloy layer composition outside layer mutually forms for Ag3Sn and Cu6Sn5.
9. copper and copper alloy plate strip surface hot-dip tinning method according to claim 1, it is characterised in that in production process,
The tension force of tin-coated copper and copper alloy plate strip is 5-100Mpa, tin-coated copper and copper alloy plate strip speed of service 5-150m/min.
10. a kind of environmentally friendly copper and copper alloy plate strip surface hot-dip tinning production line, it is the production line of an entirety, and its feature exists
In copper and copper alloy plate strip are in the presence of uncoiler, preceding S rollers, rear S rollers and winder, described in its automatic perform claim requirement 1
Processing step.
11. a kind of environmentally friendly copper and copper alloy plate strip surface hot-dip tinning production line, it includes degreasing pickling line, hot dipped tinning
Line, it is characterised in that during processing step described in perform claim requirement 1, degreasing pickling line sets independent uncoiler, preceding
S rollers, rear S rollers and winder, hot-dip solder set independent uncoiler, preceding S rollers, rear S rollers and winder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710952879.3A CN107587095B (en) | 2017-10-13 | 2017-10-13 | A kind of environmental protection copper and copper alloy plate strip surface hot-dip tinning method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710952879.3A CN107587095B (en) | 2017-10-13 | 2017-10-13 | A kind of environmental protection copper and copper alloy plate strip surface hot-dip tinning method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107587095A true CN107587095A (en) | 2018-01-16 |
| CN107587095B CN107587095B (en) | 2019-07-09 |
Family
ID=61053113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710952879.3A Active CN107587095B (en) | 2017-10-13 | 2017-10-13 | A kind of environmental protection copper and copper alloy plate strip surface hot-dip tinning method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107587095B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108251777A (en) * | 2018-01-18 | 2018-07-06 | 河南科技大学 | A kind of copper alloy plate strip surface hot-dip tinning technique |
| CN108385049A (en) * | 2018-01-18 | 2018-08-10 | 河南科技大学 | A kind of copper and copper alloy plate strip surface hot-dip tinning technique |
| CN109628870A (en) * | 2019-01-22 | 2019-04-16 | 陶乐敏 | A kind of environment-friendly type lead-free alloy material and its processing technology |
| CN110592515A (en) * | 2019-09-30 | 2019-12-20 | 凯美龙精密铜板带（河南）有限公司 | Hot-dip tinned copper material and manufacturing method thereof |
| CN110819926A (en) * | 2019-11-15 | 2020-02-21 | 姚超 | Tin immersion treatment process for producing and processing multi-strand copper core of automobile wire harness |
| CN111261317A (en) * | 2020-04-09 | 2020-06-09 | 江东合金技术有限公司 | High-performance antioxidant copper conductor material for special cable and preparation method thereof |
| CN113061827A (en) * | 2021-02-25 | 2021-07-02 | 宁波博威合金板带有限公司 | Hot-dip tinned silver alloy coating and preparation method and application thereof |
| CN113161092A (en) * | 2021-04-01 | 2021-07-23 | 肇庆市鼎湖正科集志电子有限公司 | Method for manufacturing strontium titanate annular piezoresistor copper-tin electrode |
| CN114395746A (en) * | 2021-12-24 | 2022-04-26 | 安徽鑫科铜业有限公司 | High-quality surface treatment method for hot-dipped tin copper strip and hot-dipped tin copper strip |
| CN114790550A (en) * | 2022-05-07 | 2022-07-26 | 云南驰宏资源综合利用有限公司 | Method for manufacturing anode beam |
| CN115044801A (en) * | 2022-08-16 | 2022-09-13 | 凯美龙精密铜板带（河南）有限公司 | Copper-nickel-silicon alloy strip and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2533048A (en) * | 1947-07-30 | 1950-12-05 | Tennessee Coal Iron And Railro | Process of hot dip tinning |
| JPH0499161A (en) * | 1990-08-06 | 1992-03-31 | Kobe Steel Ltd | Continuous hot-dip plating method |
| CN1510158A (en) * | 2002-12-23 | 2004-07-07 | 天津市宏远电子有限公司 | Lead-free alloy tin-plating copper wire |
| CN102115862A (en) * | 2010-12-31 | 2011-07-06 | 周开勇 | Circulating tin plating process and device |
| CN102154605A (en) * | 2010-02-11 | 2011-08-17 | 上海胜佰太阳能科技有限公司 | Production process of tin-coated alloy band for solar cell |
| CN102383084A (en) * | 2011-11-03 | 2012-03-21 | 江苏太阳光伏科技有限公司 | Production system and production method of extremely-soft tin-coated welding strip |
| CN206069983U (en) * | 2016-08-29 | 2017-04-05 | 江苏优轧机械有限公司 | A kind of open high speed applies stannum machine |
-
2017
- 2017-10-13 CN CN201710952879.3A patent/CN107587095B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2533048A (en) * | 1947-07-30 | 1950-12-05 | Tennessee Coal Iron And Railro | Process of hot dip tinning |
| JPH0499161A (en) * | 1990-08-06 | 1992-03-31 | Kobe Steel Ltd | Continuous hot-dip plating method |
| CN1510158A (en) * | 2002-12-23 | 2004-07-07 | 天津市宏远电子有限公司 | Lead-free alloy tin-plating copper wire |
| CN102154605A (en) * | 2010-02-11 | 2011-08-17 | 上海胜佰太阳能科技有限公司 | Production process of tin-coated alloy band for solar cell |
| CN102115862A (en) * | 2010-12-31 | 2011-07-06 | 周开勇 | Circulating tin plating process and device |
| CN102383084A (en) * | 2011-11-03 | 2012-03-21 | 江苏太阳光伏科技有限公司 | Production system and production method of extremely-soft tin-coated welding strip |
| CN206069983U (en) * | 2016-08-29 | 2017-04-05 | 江苏优轧机械有限公司 | A kind of open high speed applies stannum machine |
Non-Patent Citations (1)
| Title |
|---|
| 王章忠等: "《机械工程材料 第2版》", 30 June 2011, 机械工业出版社 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108385049A (en) * | 2018-01-18 | 2018-08-10 | 河南科技大学 | A kind of copper and copper alloy plate strip surface hot-dip tinning technique |
| CN108251777A (en) * | 2018-01-18 | 2018-07-06 | 河南科技大学 | A kind of copper alloy plate strip surface hot-dip tinning technique |
| CN109628870A (en) * | 2019-01-22 | 2019-04-16 | 陶乐敏 | A kind of environment-friendly type lead-free alloy material and its processing technology |
| CN110592515A (en) * | 2019-09-30 | 2019-12-20 | 凯美龙精密铜板带（河南）有限公司 | Hot-dip tinned copper material and manufacturing method thereof |
| CN110819926A (en) * | 2019-11-15 | 2020-02-21 | 姚超 | Tin immersion treatment process for producing and processing multi-strand copper core of automobile wire harness |
| CN111261317B (en) * | 2020-04-09 | 2021-08-31 | 江东合金技术有限公司 | Preparation method of high-performance antioxidant copper conductor material for special cable |
| CN111261317A (en) * | 2020-04-09 | 2020-06-09 | 江东合金技术有限公司 | High-performance antioxidant copper conductor material for special cable and preparation method thereof |
| CN113061827A (en) * | 2021-02-25 | 2021-07-02 | 宁波博威合金板带有限公司 | Hot-dip tinned silver alloy coating and preparation method and application thereof |
| CN113161092A (en) * | 2021-04-01 | 2021-07-23 | 肇庆市鼎湖正科集志电子有限公司 | Method for manufacturing strontium titanate annular piezoresistor copper-tin electrode |
| CN114395746A (en) * | 2021-12-24 | 2022-04-26 | 安徽鑫科铜业有限公司 | High-quality surface treatment method for hot-dipped tin copper strip and hot-dipped tin copper strip |
| CN114790550A (en) * | 2022-05-07 | 2022-07-26 | 云南驰宏资源综合利用有限公司 | Method for manufacturing anode beam |
| CN114790550B (en) * | 2022-05-07 | 2024-08-02 | 云南驰宏资源综合利用有限公司 | Manufacturing method of anode beam |
| CN115044801A (en) * | 2022-08-16 | 2022-09-13 | 凯美龙精密铜板带（河南）有限公司 | Copper-nickel-silicon alloy strip and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107587095B (en) | 2019-07-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107587095A (en) | A kind of environmentally friendly copper and copper alloy plate strip surface hot-dip tinning method | |
| CN115198215B (en) | Hot dip plating device and method for precise copper-phosphorus brazing filler metal | |
| US2274963A (en) | Process for plating tin and tin alloys | |
| JP4603394B2 (en) | Copper or copper alloy strip for press working | |
| KR101696796B1 (en) | A method for plating copper alloy with tin | |
| CN112176371B (en) | Electroplating process for plating gold on beryllium copper surface | |
| JPH04293757A (en) | Production of flat square coated wire | |
| JP2009293091A (en) | Method for producing copper alloy for electrical or electronic parts | |
| JPS6056418B2 (en) | Manufacturing method of hot-dip galvanized steel sheet | |
| JP5337760B2 (en) | Metal surface treatment aqueous solution and method for preventing discoloration of metal surface | |
| JPH0121240B2 (en) | ||
| CN114395746A (en) | High-quality surface treatment method for hot-dipped tin copper strip and hot-dipped tin copper strip | |
| JPH10330900A (en) | Hot dip plating method for hot rolled steel sheet | |
| JPH02185958A (en) | Production of wire plated with metal by hot dipping | |
| KR102204664B1 (en) | Nano passivation treatment method of reel-to-reel metal plate and processed products, and metal plate and processed products manufactured accordingly | |
| JP4231936B2 (en) | Method for producing Sn-coated copper | |
| JPS5810973B2 (en) | Manufacturing method of plated steel wire | |
| KR100436597B1 (en) | Method for plating with molten aluminum | |
| CN112496598B (en) | Heavy metal-free environment-friendly welding wire and production process thereof | |
| JPH0649614A (en) | Production of hot dip tin coated copper alloy material having excellent corrosion resistance and solderability | |
| JP5930136B1 (en) | Method for producing hot-dip galvanized steel | |
| CN115948705B (en) | Anti-sticking manufacturing method of titanium copper and titanium copper | |
| JP6753712B2 (en) | Manufacturing method of granular tin-plated steel sheet | |
| JPH10152792A (en) | Production of electrogalvanized steel sheet excellent in appearance | |
| JP2006183147A (en) | Equipment for manufacturing hot-dip galvannealed steel sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An environmentally friendly hot dip tin plating method on the surface of copper and copper alloy plates and strips Effective date of registration: 20231121 Granted publication date: 20190709 Pledgee: China Construction Bank Corporation Xinxiang Branch Pledgor: KMD PRECISE COPPER STRIP HENAN LTD. Registration number: Y2023980066437 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20190709 Pledgee: China Construction Bank Corporation Xinxiang Branch Pledgor: KMD PRECISE COPPER STRIP HENAN LTD. Registration number: Y2023980066437 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An environmentally friendly hot dip tin plating method on the surface of copper and copper alloy plates and strips Granted publication date: 20190709 Pledgee: China Construction Bank Corporation Xinxiang Branch Pledgor: KMD PRECISE COPPER STRIP HENAN LTD. Registration number: Y2024980023116 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |