CN107586587A - One kind is without chlorine micro-emulsion cutting fluid - Google Patents
One kind is without chlorine micro-emulsion cutting fluid Download PDFInfo
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- CN107586587A CN107586587A CN201610538654.9A CN201610538654A CN107586587A CN 107586587 A CN107586587 A CN 107586587A CN 201610538654 A CN201610538654 A CN 201610538654A CN 107586587 A CN107586587 A CN 107586587A
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- cutting fluid
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- emulsion cutting
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Abstract
It is respectively without chlorine micro-emulsion cutting fluid, its raw material components and its parts by weight the present invention relates to one kind：Low viscosity naphthenic base oils 18-30%；Anion surfactant 10-20%；Nonionic surfactant 7-13%；Calcium soap dispersiveness assistant for emulsifying agent 3-8%；Ethylhexyl stearate 4-8%；Sulfide aliphatic acid ester 2-4%；Borate 3-7%；Metal carboxylate antirust agent 1-4%；PH value stabilizer 1-3%；MBM bactericide 0.5-1.5% alkali retention agents 5-9%；Coupling agent 0.5-1.5%；Surplus is water.The present invention is directed to existing microemulsion existing major defect in use, corresponding technical scheme is taken to seek to break through, make the product of development not only there is excellent performance and longer service life, and the not material such as chlorination-containing olefin, nitrite and phenol, meet the requirement of modern environmental regulation.
Description
Technical field
The invention belongs to cut oily field, more particularly to one kind is without chlorine micro-emulsion cutting fluid method.
Background technology
Micro-emulsion cutting fluid is a kind of novel metal processing liquid product between oil emulsion and synthetic cutting fluid, and it was both
Lubricity, rust-preventing characteristic with oil emulsion, there is excellent comprehensive such as the cleaning of synthetic cutting fluid, permeability, long-life again
Can, progressively develop into oil emulsion and the regeneration product of Synthesis liquid.It can be widely applied to metal cutting, turning, grinding, bore hole
Etc. technique.With the continuous introduction of external advanced machinery equipment and developing rapidly for domestic mechanical industry, various novel metals
The development and application of material and International Environmental Protection regulation are full to the disabling of poisonous and harmful substance in cutting fluid, the original cutting fluid in China
Foot not existing requirement, some joint ventures and big machinery processing enterprise every year need a large amount of micro-emulsion cutting fluids productions of import
Product, and import microemulsion is expensive, is the several times or so of domestic cutting fluid price.Therefore, carry out environment-friendly no chlorine extreme pressure
The development of micro emulsion cutting fluid, the level to improving China's metal working fluid, meets environmental protection and market needs, similar height outside surrogate
Performance products have important practical significance and obvious economical, societal benefits.
The content of the invention
It is an object of the invention in place of overcome the deficiencies in the prior art, there is provided a kind of green, nothing for being unlikely to deteriorate
Chlorine micro-emulsion cutting fluid.
The technical solution adopted for the present invention to solve the technical problems is：
It is a kind of to be respectively without chlorine micro-emulsion cutting fluid, its raw material components and its parts by weight：
Moreover, each raw material components and its parts by weight of the no chlorine micro-emulsion cutting fluid are respectively：
Moreover, a kind of preparation method of no chlorine micro-emulsion cutting fluid is：
(1) prepared by cutting fluid mother liquor：The low viscosity naphthenic base oils, anion surfactant, stearic acid of whole are different
Monooctyl ester, sulfide aliphatic acid ester, stirring to clear homogeneous liquid, obtain cutting fluid oil phase；
(2) prepared by microemulsion：By calcium soap dispersiveness assistant for emulsifying agent, borate, metal carboxylate antirust agent, pH value stabilizer,
Alkali retention agent, coupling agent MBM bactericide are added in excess water, stir transparent to solution, obtain cutting fluid aqueous phase；By aqueous phase plus
Enter into oil phase, stir transparent to cutting fluid, that is, obtain micro-emulsion cutting fluid.
The advantages and positive effects of the present invention are：
1st, the present invention in development process, is taking into full account its lubricity, cooling without chlorine Microemulsion as Extreme Pressure Cutting Fluid, prevented
Many characteristics such as rust property, cleaning and service life, meet the requirement of mechanical processing industry machining, its main component
There are base oil, emulsifying agent, oiliness improver, extreme pressure agent, antirust agent, water etc..It is existing main scarce in use for existing microemulsion
Fall into, take corresponding technical scheme to seek to break through, make the product of development not only there is excellent performance and longer use
Life-span, and the not material such as chlorination-containing olefin, nitrite and phenol, meet the requirement of modern environmental regulation.
2nd, the present invention allocates theoretical according to microemulsion, is evaluated by laboratory lot of experiments, filters out environment-friendly micro emulsion
The additives such as emulsifying agent, oiliness improver, extreme pressure agent, antirust agent needed for liquid, it is micro- without chlorine extreme pressure by orthogonal experimental method development
Newborn cutting fluid has excellent stability, extreme pressure property, wear resistence and rust-preventing characteristic, and indices are suitable with import like product, leads to
Production application is crossed, the extreme pressure cutting fuild microemulsion free of chlorine of development has good performance and longer service life, complete
The requirement of full up sufficient processing technology, and the not material such as chlorination-containing olefin, natrium nitrosum, phenol, environmentally friendly, alternative import
Like product, great amount of cost is saved for enterprise, thus had broad application prospects.
Embodiment
Below by specific embodiment, the invention will be further described, and following examples are descriptive, is not limit
Qualitatively, it is impossible to which protection scope of the present invention is limited with this.
Embodiment 1：
It is a kind of to be respectively without chlorine micro-emulsion cutting fluid, its raw material components and its weight：
The preparation method of above-mentioned no chlorine micro-emulsion cutting fluid is：
(1) prepared by cutting fluid mother liquor：The low viscosity naphthenic base oils, anion surfactant, stearic acid of whole are different
Monooctyl ester, sulfide aliphatic acid ester, stirring to clear homogeneous liquid, obtain cutting fluid oil phase；
(2) prepared by microemulsion：By calcium soap dispersiveness assistant for emulsifying agent, borate, metal carboxylate antirust agent, pH value stabilizer,
Alkali retention agent, coupling agent MBM bactericide are added in excess water, stir transparent to solution, obtain cutting fluid aqueous phase；By aqueous phase plus
Enter into oil phase, stir transparent to cutting fluid, that is, obtain micro-emulsion cutting fluid.
Embodiment 2：
Each raw material components and its weight of a kind of no chlorine micro-emulsion cutting fluid are respectively：
The preparation method of above-mentioned no chlorine micro-emulsion cutting fluid is：
(1) prepared by cutting fluid mother liquor：The low viscosity naphthenic base oils, anion surfactant, stearic acid of whole are different
Monooctyl ester, sulfide aliphatic acid ester, stirring to clear homogeneous liquid, obtain cutting fluid oil phase；
(2) prepared by microemulsion：By calcium soap dispersiveness assistant for emulsifying agent, borate, metal carboxylate antirust agent, pH value stabilizer,
Alkali retention agent, coupling agent MBM bactericide are added in excess water, stir transparent to solution, obtain cutting fluid aqueous phase；By aqueous phase plus
Enter into oil phase, stir transparent to cutting fluid, that is, obtain micro-emulsion cutting fluid.
Claims (8)
1. one kind is without chlorine micro-emulsion cutting fluid, it is characterised in that its raw material components and its parts by weight are respectively：
2. no chlorine micro-emulsion cutting fluid according to claim 1, it is characterised in that：The moon of the no chlorine micro-emulsion cutting fluid
Ionic surface active agent is 40%-60% petroleum sodium sulfonate.
3. according to right profit requires 1 without chlorine micro-emulsion cutting fluid, it is characterised in that：It is described non-to be from surfactant
APES or AEO.
4. according to right profit requires 1 without chlorine micro-emulsion cutting fluid, it is characterised in that：Described calcium soap dispersiveness helps emulsification
Agent is alcohol ether carboxylate amine salt.
5. according to right profit requires 1 without chlorine micro-emulsion cutting fluid, it is characterised in that：Described pH value stabilizer is carbonic acid
Sodium.
6. according to right profit requires 1 without chlorine micro-emulsion cutting fluid, it is characterised in that：Described alkali retention agent is three ethanol
Amine.
7. according to right profit requires 1 without chlorine micro-emulsion cutting fluid, it is characterised in that：Described coupling agent is glycerine.
A kind of 8. method prepared as claimed in claim 1 without chlorine micro-emulsion cutting fluid, it is characterised in that：Its step is：⑴
It is prepared by cutting fluid mother liquor：By the low viscosity naphthenic base oils of whole, anion surfactant, Ethylhexyl stearate, vulcanization
Fatty acid ester, stirring obtain cutting fluid oil phase to clear homogeneous liquid；
(2) prepared by microemulsion：Calcium soap dispersiveness assistant for emulsifying agent, borate, metal carboxylate antirust agent, pH value stabilizer, alkali are protected
Hold agent, coupling agent MBM bactericide is added in excess water, stirs transparent to solution, obtain cutting fluid aqueous phase；Aqueous phase is added to
In oil phase, stir transparent to cutting fluid, that is, obtain micro-emulsion cutting fluid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610538654.9A CN107586587A (en) | 2016-07-08 | 2016-07-08 | One kind is without chlorine micro-emulsion cutting fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610538654.9A CN107586587A (en) | 2016-07-08 | 2016-07-08 | One kind is without chlorine micro-emulsion cutting fluid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107586587A true CN107586587A (en) | 2018-01-16 |
Family
ID=61045228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610538654.9A Withdrawn CN107586587A (en) | 2016-07-08 | 2016-07-08 | One kind is without chlorine micro-emulsion cutting fluid |
Country Status (1)
| Country | Link |
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| CN (1) | CN107586587A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1730634A (en) * | 2005-08-02 | 2006-02-08 | 广州机械科学研究院 | Extreme pressure cutting fuild microemulsion free of chlorine and its preparation method and uses |
| CN102002424A (en) * | 2010-12-14 | 2011-04-06 | 上海德润宝特种润滑剂有限公司 | Micro emulsion cutting fluid composition and preparation method thereof |
| CN103031195A (en) * | 2011-10-10 | 2013-04-10 | 洛科斯润滑油（上海）有限公司 | Microemulsion cutting fluid |
| CN104073321A (en) * | 2013-03-29 | 2014-10-01 | 上海德润宝特种润滑剂有限公司 | Microemulsion cutting fluid, cutting diluent and preparation and application methods of microemulsion cutting fluid |
-
2016
- 2016-07-08 CN CN201610538654.9A patent/CN107586587A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1730634A (en) * | 2005-08-02 | 2006-02-08 | 广州机械科学研究院 | Extreme pressure cutting fuild microemulsion free of chlorine and its preparation method and uses |
| CN102002424A (en) * | 2010-12-14 | 2011-04-06 | 上海德润宝特种润滑剂有限公司 | Micro emulsion cutting fluid composition and preparation method thereof |
| CN103031195A (en) * | 2011-10-10 | 2013-04-10 | 洛科斯润滑油（上海）有限公司 | Microemulsion cutting fluid |
| CN104073321A (en) * | 2013-03-29 | 2014-10-01 | 上海德润宝特种润滑剂有限公司 | Microemulsion cutting fluid, cutting diluent and preparation and application methods of microemulsion cutting fluid |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180116 |