CN107549181A - A kind of composition containing Ningnanmycin - Google Patents
A kind of composition containing Ningnanmycin Download PDFInfo
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- CN107549181A CN107549181A CN201710914756.0A CN201710914756A CN107549181A CN 107549181 A CN107549181 A CN 107549181A CN 201710914756 A CN201710914756 A CN 201710914756A CN 107549181 A CN107549181 A CN 107549181A
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- ningnanmycin
- cyclohexylmethylene
- methyl
- indoles
- composition
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Abstract
The invention discloses a kind of composition containing Ningnanmycin.Calculate by weight percentage, the percentage by weight that Ningnanmycin accounts for complex composition is 0.05%~40%, (1S, 3S) the methyl 2 of N ' (cyclohexylmethylene) 1,3,4, the 9 tetrahydropyridines percentage by weight that simultaneously formylhydrazine of [3,4 b] indoles 3 accounts for complex composition is 0.1%~80%.Active ingredient Ningnanmycin and the tetrahydropyridine of 1 methyl of (1S, 3S) N ' (cyclohexylmethylene) 2,3,4,9 percentage by weight that simultaneously formylhydrazine of [3,4 b] indoles 3 accounts for total composition are 0.18%~88%.Said composition can be used for preventing and treating various plants virosis, such as tomato, cucumber, tobacco, celery, capsicum, potato, while to proposing the resistance ability such as crop drought resistance, high temperature resistance, and adjustable plant growth, Accelerate bloom, improve fruit yield and quality.
Description
Technical field
The present invention relates to a kind of composition pesticide, with Ningnanmycin and (1S, 3S)-N '-(cyclohexylmethylene) -1- first
Base -2,3, simultaneously [3,4-b] indoles -3- formylhydrazines are active ingredient to 4,9- tetrahydropyridines, and said composition can be used for preventing and treating fruit tree, vegetable
Dish, the Disease of field crop, can also effectively improve the resistance of crop, regulating crop growth, and rush is bloomed, improves production
Amount, improve fruit quality etc..
Background technology
Ningnanmycin belongs to Cystosine nucleocide type broad-spectrum antibiotic bactericide, has prevention, therapeutic action.Ningnanmycin
The viral incubation period can be extended, destroy virion structure, reduce virion concentration, the ability of plant resistance virus is improved and reach
To the effect of preventing and treating virosis；Fungal hyphal growth is may also suppress simultaneously, and plant can be induced to produce resistance protein, improves and plants
The immunity of object.Meet agricultural sustainable development direction, at present the country developed 2% aqua, 8% aqua, 10% can
The Ningnanmycin series of products such as WP, bitter peaceful seed coat agent, in tobacco mosaic virus disease, tomato virus disease, capsicum virus
Disease, rice seedling blight, root rot, stripe disease, alternaria leaf spot of apple, achieve in powdery mildew of cucumber and step on
Note is more in preventing and treating sclerotinia sclerotiorum, peronophythora litchi, other crop virosis, stem rot, blight dis-ease, powdery mildew etc. in addition
Also it has been widely applied in kind disease..
(1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- formyls
Hydrazine has extraordinary bioactivity to tobacco mosaic virus (TMV).The compound of class containing tetrahydro-beta-carboline is easily absorbed by plants, in environment
In it is degradable, have good Environmental compatibility.
1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- formyls
Hydrazine structural formula：
The content of the invention
Based on case above, it is an object of the invention to provide a kind of composition containing Ningnanmycin, available for preventing and treating fruit
Tree, vegetables, the virosis of field crop, and drug effect significantly improves, and can also effectively improve the resistance of crop, adjusts crop
Growth, rush bloom, improve yield, improve fruit quality etc..
To achieve these goals, the technical solution used in the present invention is as follows：
A kind of composition containing Ningnanmycin, active ingredient be Ningnanmycin and (1S, 3S)-N '-(cyclohexylmethylene)-
1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- formylhydrazines.Calculate by weight percentage, Ningnanmycin accounts for compounding group
The percentage by weight of compound is 0.05%~40%, (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydrochysenes
The percentage by weight that pyrido [3,4-b] indoles -3- formylhydrazines account for complex composition is 0.1%~80%.
A kind of described composition containing Ningnanmycin, its active ingredient account for the percentage by weight of total composition for 0.18%~
88%.
A kind of described composition containing Ningnanmycin, its formulation are aqua, soluble concentrate, solvable pulvis, suspending agent, water
Any one in dispersible granule.
Said composition can effectively prevent and treat the virosis of fruit tree, vegetables and field crop, and can improve crop anti-adversity, promote
Enter plant growth, improve yield.Compared with prior art, had the beneficial effect that caused by the present invention：Expand Ningnanmycin and
(1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- formylhydrazine single doses
Use range.Ningnanmycin and (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines are simultaneously [3,4-b]
Indoles -3- formylhydrazines compound, and can effectively improve the drug effect of single dose, and effectively delay single medicament to be asked using caused preventive effect difference etc.
Topic, while more promote the growth of crop.
Embodiment
In example of formulations, listed percentage is weight percentage.
Embodiment 1
4% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-
B] indoles -3- formylhydrazine aquas preparation
Raw material forms：3% Ningnanmycin, 1% (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydrochysenes
Pyrido [3,4-b] indoles -3- formylhydrazines, 8% surfactant sodium dodecyl base benzene sulfonic acid, deionized water are mended to 100%.It is above-mentioned
Material is well mixed in mixing in kettle according to corresponding ratio, that is, be made active constituent content for 4% Ningnanmycin (1S,
3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- formylhydrazine aquas.
Embodiment 2
22% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,
4-b] indoles -3- formylhydrazine aquas preparation
Raw material forms：20% Ningnanmycin, 2% (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetra-
Pyridinium hydroxide simultaneously [3,4-b] indoles -3- formylhydrazines, 9% surfactant sodium dodecyl base benzene sulfonic acid, 6% acetone, deionized water mend to
100%.Above-mentioned material is well mixed in kettle in mixing according to corresponding ratio, that is, it is 22% Ningnan that active constituent content, which is made,
Mycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- formylhydrazines
Aqua.
Embodiment 3
16% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,
4-b] indoles -3- formylhydrazine soluble concentrates preparation
Raw material forms：12% Ningnanmycin, 4% (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetra-
Simultaneously [3,4-b] indoles -3- formylhydrazines, 2% answer sodium nitrate, 2% ethylene glycol, 4% agriculture breast 600#, 2% cyclohexanone, acetone to pyridinium hydroxide
Mend to 100%.Above-mentioned material is well mixed in kettle in mixing according to corresponding ratio, that is, it is 16% that active constituent content, which is made,
Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- first
Hydrazides soluble concentrate.
Embodiment 4
9% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-
B] indoles -3- formylhydrazine wettable powders preparation
Raw material forms：1.8% Ningnanmycin, 7.2% (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9-
Tetrahydropyridine simultaneously [3,4-b] indoles -3- formylhydrazines, 8% lignosulfonates, 8% alkylsulfonate, 8% citrate, diatom
Soil is mended to 100%.It is well mixed again through air-flow crushing after above-mentioned mechanical mass is crushed, that is, it is 9% that active constituent content, which is made,
Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- first
Hydrazides wettable powder.
Embodiment 5
18% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,
4-b] indoles -3- formylhydrazine wettable powders preparation
Raw material forms：6% Ningnanmycin, 12% (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetra-
Pyridinium hydroxide simultaneously [3,4-b] indoles -3- formylhydrazines, 8% lignosulfonates, 7% alkylsulfonate, 10% citrate, diatom
Soil is mended to 100%.It is well mixed again through air-flow crushing after above-mentioned mechanical mass is crushed, that is, active constituent content, which is made, is
18% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -
3- formylhydrazine wettable powders.
Embodiment 6
13% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,
4-b] indoles -3- formylhydrazine suspending agents preparation
Raw material forms：2% Ningnanmycin, 11% (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetra-
Pyridinium hydroxide simultaneously [3,4-b] indoles -3- formylhydrazines, 6% sodium lignin sulfonate, 1.2% pull open powder, 1% xanthans, 1%SAG622
Organosilicon, 8% glycerine, 0.8% sodium tripolyphosphate, remaining is supplied with deionized water, and routinely the suspending agent mode of production is prepared
It is 13% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3 that active constituent content, which is made, 4,9- tetra-
Pyridinium hydroxide simultaneously [3,4-b] indoles -3- formylhydrazine suspending agents.
Embodiment 7
22% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,
4-b] indoles -3- formylhydrazine suspending agents preparation
Raw material forms：6% Ningnanmycin, 16% (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetra-
Pyridinium hydroxide simultaneously [3,4-b] indoles -3- formylhydrazines, 6% sodium lignin sulfonate, 1.2% pull open powder, 1% xanthans, 1%SAG622
Organosilicon, 8% glycerine, 0.8% sodium tripolyphosphate, remaining is supplied with deionized water, and routinely the suspending agent mode of production is prepared
It is 22% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3 that active constituent content, which is made, 4,9- tetra-
Pyridinium hydroxide simultaneously [3,4-b] indoles -3- formylhydrazine suspending agents.
Embodiment 8
50% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,
4-b] indoles -3- formylhydrazine water dispersible granules preparation
Raw material forms：30% Ningnanmycin, 20% (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetra-
Pyridinium hydroxide simultaneously [3,4-b] indoles -3- formylhydrazines, 10% lignosulfonates, 6% alkylsulfonate, 8% glucose, 4% corn
Starch, kaolin and white carbon are mended to 100%.Above-mentioned material is crushed with micro jet, through mediating, then adds stream
Change and be granulated in bed granulating and drying machine, dry, sieve, i.e., obtained active constituent content for 50% Ningnanmycin (1S, 3S)-
N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- formylhydrazine water dispersible granules.
Embodiment 9
82% Ningnanmycin (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,
4-b] indoles -3- formylhydrazine water dispersible granules preparation
Raw material forms：32% Ningnanmycin, 50% (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetra-
Pyridinium hydroxide simultaneously [3,4-b] indoles -3- formylhydrazines, 6% alkylnaphthalene sulfonate, 3% naphthalene sulfonate, 4% sucrose, 3% cornstarch,
Kaolin is mended to 100%.Above-mentioned material is crushed with micro jet, through mediating, fluidized bed prilling is then added and dries
It is granulated, dried, sieved in machine, that is, it is 82% Ningnanmycin (1S, 3S)-N '-(cyclohexyl Asia that active constituent content, which is made,
Methyl) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- formylhydrazine water dispersible granules.
In order to verify prevention effect of the present invention to virosis, respectively to tomato virus disease, cucumber virosis, celery virus
Disease carries out field efficacy checking.The result is as follows：
Field test embodiment one：Ningnanmycin and (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9-
Tetrahydropyridine simultaneously field control effectiveness test field test of [3,4-b] indoles -3- formylhydrazines composition to tomato virus disease
Different content, difference (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-
B] indoles -3- formylhydrazines and Ningnanmycin composition be re-dubbed 5 kinds of different formulations after, enter in tomato virus disease early stage
Row foliar spray, every mu is watered 15L, dilutes 500 times of liquid, 1000 times of liquid respectively, comparison medicament is 8% Ningnanmycin aqua single dose
500 times of liquid, first time spray is carried out in tomato virus disease early stage, is total to dispenser three times, every minor tick 7 days.And respectively at three
7d, 14d, 21d are investigated after secondary medicine, are classified according to related data, count disease index, are calculated preventive effect, be the results are shown in Table 1.
Grade scale is as follows：
0 grade：It is disease-free；
1 grade：Scab heap area accounts for less than the 8% of whole leaf area；
3 grades：Scab heap area accounts for below the 6%-10% of whole leaf area；
5 grades：Scab heap area accounts for below the 11%-20% of whole leaf area；
7 grades：Scab heap area accounts for below the 21%-80% of whole leaf area；
9 grades：Scab heap area accounts for more than the 80% of whole leaf area.
Drug effect computational methods are as follows：
Sick leaf rate (the %)=sick number of sheets/investigation total number of sheets × 100
Disease index=Σ (the sick numbers of sheets at different levels × relative value of series)/(investigation total number of sheets × 9) × 100
Prevention effect (%)=[1- (disease index after disease index × treatment region medicine before blank district medicine)/(blank pair
According to disease index before disease index after area's medicine × treatment region medicine)] × 100.
The reagent agent of table 1 is to tomato virus disease test of pesticide effectiveness result
Field test embodiment two：Ningnanmycin and (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9-
Tetrahydropyridine simultaneously field control effectiveness test field test of [3,4-b] indoles -3- formylhydrazines composition to cucumber virosis
Different content (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] Yin
After the composition of diindyl -3- formylhydrazines and Ningnanmycin is re-dubbed 5 kinds of different formulations, leaf is carried out in cucumber virosis early stage
Face is sprayed, and every mu is watered 15L, dilutes 500 times of liquid, 1000 times of liquid respectively, comparison medicament is 6% amino-oligosacchride aqua single dose 500
Times liquid, first time spray is carried out in cucumber virosis early stage, altogether dispenser three times, per minor tick 7 days.And respectively at medicine three times
7d, 14d, 21d are investigated afterwards, are investigated standard grading according to related data, are counted disease index, calculate preventive effect, the results are shown in Table 2.
Grade scale and drug effect computational methods are same as above.
The reagent agent of table 2 is to cucumber virosis test of pesticide effectiveness result
Field test embodiment three：Ningnanmycin and (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9-
Tetrahydropyridine simultaneously field control effectiveness test field test of [3,4-b] indoles -3- formylhydrazines composition to celery virosis
Different content (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] Yin
After the composition of diindyl -3- formylhydrazines and Ningnanmycin is re-dubbed 5 kinds of different formulations, leaf is carried out in celery virosis early stage
Face is sprayed, and every mu is watered 15L, dilutes 500 times of liquid, 1000 times of liquid respectively, comparison medicament is 6% amino-oligosacchride aqua single dose 500
Times liquid, first time spray is carried out in celery virosis early stage, altogether dispenser three times, per minor tick 7 days.And respectively at medicine three times
7d, 14d, 21d are investigated afterwards, are investigated standard grading according to related data, are counted disease index, calculate preventive effect, the results are shown in Table 3.
Grade scale and drug effect computational methods are same as above.
The reagent agent of table 3 is to celery virosis test of pesticide effectiveness result
Shown by above field experiment：Ningnanmycin and (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,
Simultaneously each mixture of [3,4-b] indoles -3- formylhydrazines is obvious high to the preventive effect of tomato, cucumber, celery virosis for 4,9- tetrahydropyridines
In Ningnanmycin single dose, and preventive effect is above 80% after 21 days after medicine.
Claims (5)
- A kind of 1. composition containing Ningnanmycin, it is characterised in that said composition active ingredient be Ningnanmycin and (1S, 3S)- N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines simultaneously [3,4-b] indoles -3- formylhydrazines.
- 2. the composition containing Ningnanmycin as claimed in claim 1, it is characterised in that calculate by weight percentage, Ningnanmycin The percentage by weight for accounting for complex composition is 0.05%~40%, (1S, 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3, The 4,9- tetrahydropyridines percentage by weight that simultaneously [3,4-b] indoles -3- formylhydrazines account for complex composition is 0.1%~80%.
- 3. the composition containing Ningnanmycin as claimed in claim 2, it is characterised in that active ingredient Ningnanmycin and (1S, Simultaneously [3,4-b] indoles -3- formylhydrazines account for total composition to 3S)-N '-(cyclohexylmethylene) -1- methyl -2,3,4,9- tetrahydropyridines Percentage by weight is 0.15%~88%.
- 4. the composition containing Ningnanmycin as claimed in claim 1, it is characterised in that said composition is in preventing and treating fruit tree, vegetables And the application in terms of the virosis of field crop.
- 5. the composition containing Ningnanmycin as claimed in claim 1, it is characterised in that said composition can be prepared into aqua, can Any one in solution, solvable pulvis, suspending agent, water dispersible granules.
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| CN201710914756.0A CN107549181A (en) | 2017-09-30 | 2017-09-30 | A kind of composition containing Ningnanmycin |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109757497A (en) * | 2018-12-28 | 2019-05-17 | 京博农化科技有限公司 | A kind of bactericidal composition |
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| CN1093869A (en) * | 1993-04-23 | 1994-10-26 | 中国科学院成都生物研究所 | A kind of new antibiotic pesticides-Ningnan Meisu |
| CN104744460A (en) * | 2013-12-30 | 2015-07-01 | 南开大学 | B-carboline, dihydro-B-carboline and tetrahydro-B-carboline alkaloid derivative as well as preparation method and application in aspects of plant virus prevention and cure, sterilization and insecticide |
-
2017
- 2017-09-30 CN CN201710914756.0A patent/CN107549181A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1093869A (en) * | 1993-04-23 | 1994-10-26 | 中国科学院成都生物研究所 | A kind of new antibiotic pesticides-Ningnan Meisu |
| CN104744460A (en) * | 2013-12-30 | 2015-07-01 | 南开大学 | B-carboline, dihydro-B-carboline and tetrahydro-B-carboline alkaloid derivative as well as preparation method and application in aspects of plant virus prevention and cure, sterilization and insecticide |
Non-Patent Citations (1)
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| 佘本水: "《高毒农药替代品应用技术指南》", 30 January 2008, 中国农业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109757497A (en) * | 2018-12-28 | 2019-05-17 | 京博农化科技有限公司 | A kind of bactericidal composition |
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