CN107546282A - A kind of graphene solar cell - Google Patents

A kind of graphene solar cell Download PDF

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Publication number
CN107546282A
CN107546282A CN201610481286.9A CN201610481286A CN107546282A CN 107546282 A CN107546282 A CN 107546282A CN 201610481286 A CN201610481286 A CN 201610481286A CN 107546282 A CN107546282 A CN 107546282A
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China
Prior art keywords
electrode layer
layer
solar cell
upper electrode
photoelectric conversion
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Pending
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CN201610481286.9A
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Chinese (zh)
Inventor
林前锋
李丽萍
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Hunan Guosheng Graphite Technology Co Ltd
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Hunan Guosheng Graphite Technology Co Ltd
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Priority to CN201610481286.9A priority Critical patent/CN107546282A/en
Publication of CN107546282A publication Critical patent/CN107546282A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells

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Abstract

The invention discloses a kind of graphene solar cell, include photoelectric conversion layer, upper electrode layer and lower electrode layer, the photoelectric conversion layer has opposing sides, wherein one side of the upper electrode layer located at the photoelectric conversion layer, the lower electrode layer is located at the other one side of the photoelectric conversion layer, the upper electrode layer is square, cross groove is provided with the top of the upper electrode layer, the cross groove extends to four vertical end faces of the upper electrode layer, the lower electrode layer is square, it is raised that the lower electrode layer bottom is provided with cross, the cross projection extends to four vertical end faces of the lower electrode layer, the cross groove and the cross projection match.Graphene solar cell provided by the invention, manufacturing cost is low, electricity conversion is high.

Description

A kind of graphene solar cell
Technical field
The present invention relates to technical field of graphene, is to be related to a kind of graphene solar cell more specifically.
Background technology
In recent years, solar cell is just playing increasingly as a kind of new green power in the sustainable development of the mankind Important effect.Wherein, the share of silica-based solar cell, particularly crystal silicon solar energy battery occuping market about 90%. But compared with conventional power generation usage, solar cell power generation cost is still higher, limits large-area applications.Solar cell power generation into One of the reason for this is higher is that battery manufacture cost is higher, and another main cause is that its electricity conversion is relatively low.
Since grapheme material is after 2004 are prepared by stabilization first, increasing research finds graphene Material has excellent electricity, optical property, such as high carrier mobility, the Young's modulus that high printing opacity is new, high.These Unique property makes graphene be possible to be widely used in field of photovoltaic power generation.At present, existing researcher using graphene with And the hetero-junctions that silicon materials are formed makes solar cell, measures highest transformation efficiency 8.6%.This efficiency and current crystalline silicon are too Positive electricity pond monocrystalline silicon main flow is into production efficiency 18.5%~19.0% compared to also low.In addition to crystalline silicon, graphene in other types too Application on positive energy battery also has research, such as organic solar batteries, compound solar cell, but obtained efficiency is not It is high.
As it was previously stated, do not obtain can also be with current solar energy for application study of the grapheme material in terms of solar cell The progress that battery industry technology is mutually equal to, it is desirable to realize the application of graphene in solar cells, play its unique thing Characteristic is managed, also many technology development works will be done.
At present, producer configures the Top electrode of solar cell and bottom electrode upward, then the conduction material with enough width Material is electrically connected in the Top electrode and bottom electrode of solar cell, with multiple solar cells of connecting, is improved voltage, is avoided electricity The loss of energy, however, although such a mode is avoided that upset solar cell, but must expend a large amount of conductive materials, cause Solar cell has to be covered compared with many areas by conductive material, and reduces the efficiency that solar cell converts light energy into electric energy. Moreover, conductive material has to more accurately align relative to solar cell, can avoid being electrically connected with bad situation Occur, and then increase the degree of difficulty in manufacture.
The content of the invention
In view of this, it is an object of the invention to propose a kind of manufacturing cost is low, electricity conversion is high graphene too Positive energy battery.
To achieve these goals, technical scheme is as follows:
A kind of graphene solar cell, including photoelectric conversion layer, upper electrode layer and lower electrode layer, the photoelectric conversion layer With opposing sides, the upper electrode layer is located at the light located at wherein one side, the lower electrode layer of the photoelectric conversion layer The other one side of electric conversion layer, the upper electrode layer are square, are provided with cross groove at the top of the upper electrode layer, described ten Font groove extends to four vertical end faces of the upper electrode layer, and the lower electrode layer is square, the lower electrode layer bottom Raised provided with cross, the cross projection extends to four vertical end faces of the lower electrode layer, the cross groove and The cross projection is matched, and the photoelectric conversion layer and the upper electrode layer are brought into close contact, the photoelectric conversion layer and institute State lower electrode layer to be brought into close contact, the photoelectric conversion layer is graphene layer, and the upper electrode layer surface is provided with multiple be uniformly distributed Upper through hole, the lower electrode layer surface is provided with multiple equally distributed lower through-holes.
As a kind of preferred embodiment of the present invention, a diameter of 0.1~0.2mm of the upper through hole.
As a kind of preferred embodiment of the present invention, a diameter of 0.1~0.2mm of the lower through-hole.
As a kind of preferred embodiment of the present invention, the upper surface of the graphene layer is alveolate texture.
As a kind of preferred embodiment of the present invention, the lower surface of the graphene layer is alveolate texture.
As a kind of preferred embodiment of the present invention, four angles of the upper electrode layer are oblique angle or fillet.
As a kind of preferred embodiment of the present invention, four angles of the lower electrode layer are oblique angle or fillet.
Compared with prior art, beneficial effects of the present invention are as follows:Graphene solar cell provided by the invention, manufacture Cost is low, electricity conversion is high.
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment Accompanying drawing be briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present invention, for this For the those of ordinary skill of field, on the premise of not paying creative work, it can also be obtained according to these accompanying drawings other Accompanying drawing.
Fig. 1 is the structural representation of upper electrode layer in the present invention;
Fig. 2 is Fig. 1 A-A schematic cross-sectional views;
Fig. 3 is arrangement schematic diagram when multiple upper electrode layers use in the present invention.
Reference:1st, upper electrode layer, 2, cross groove.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made Embodiment, belong to the scope of protection of the invention.
As shown in Figures 1 to 3, a kind of graphene solar cell, including photoelectric conversion layer, upper electrode layer 1 and lower electrode layer, The photoelectric conversion layer has opposing sides, and the upper electrode layer 1 is located at the wherein one side of the photoelectric conversion layer, the lower electricity Pole layer is located at the other one side of the photoelectric conversion layer, and the upper electrode layer 1 is square, and the top of upper electrode layer 1 is provided with Cross groove 2, the cross groove 2 extend to four vertical end faces of the upper electrode layer 1, and upper electrode layer 1 views from above it Four length of sides are L, and the wide D of cross groove 2, high h size can be adjusted according to actual conditions, and the lower electrode layer is just Cube, the lower electrode layer bottom are provided with that cross is raised, and the cross projection extend to the lower electrode layer four are vertical End face, the cross groove 2 and the cross projection match, and the photoelectric conversion layer and the upper electrode layer 1 are close Fitting, the photoelectric conversion layer and the lower electrode layer be brought into close contact, and the photoelectric conversion layer is graphene layer, the Top electrode 1 surface of layer is provided with multiple equally distributed upper through holes, and the lower electrode layer surface is provided with multiple equally distributed lower through-holes.
In the present embodiment, on upper electrode layer 1 and there is cross groove 2, lower electrode layer is provided with cross projection, cross Groove 2 can be raised identical with cross, in use, can accurately align, does not have and is electrically connected with bad situation generation, greatly It is big to reduce manufacturing cost, and through hole and lower through-hole are respectively equipped with upper electrode layer 1 and lower electrode layer, light can be greatly increased Irradiated area, so as to improve photoelectric transformation efficiency, wherein, a diameter of 0.1~0.2mm of the upper through hole, the lower through-hole A diameter of 0.1~0.2mm.
In the present embodiment, the upper surface of the graphene layer is alveolate texture, can greatly increase the receiving area of light, Further improve photoelectric transformation efficiency.
In the present embodiment, the lower surface of the graphene layer is alveolate texture, can greatly increase the receiving area of light, Further improve photoelectric transformation efficiency.
In the present embodiment, four angles of the upper electrode layer are oblique angle or fillet, to reduce the possibility for damage of colliding with.
In the present embodiment, four angles of the lower electrode layer are oblique angle or fillet, to reduce the possibility for damage of colliding with.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification for being made, equivalent substitution etc., it should be included in the scope of the protection.

Claims (7)

1. a kind of graphene solar cell, it is characterised in that described including photoelectric conversion layer, upper electrode layer and lower electrode layer Photoelectric conversion layer has opposing sides, and the upper electrode layer is located at the wherein one side of the photoelectric conversion layer, the lower electrode layer Located at the other one side of the photoelectric conversion layer, the upper electrode layer is square, and cross is provided with the top of the upper electrode layer Groove, the cross groove extend to four vertical end faces of the upper electrode layer, and the lower electrode layer is square, under described It is raised that electrode layer bottom is provided with cross, and the cross projection extends to four vertical end faces of the lower electrode layer, and described ten Font groove and the cross projection are matched, and the photoelectric conversion layer and the upper electrode layer are brought into close contact, the photoelectricity Conversion layer and the lower electrode layer are brought into close contact, and the photoelectric conversion layer is graphene layer, and the upper electrode layer surface is provided with more Individual equally distributed upper through hole, the lower electrode layer surface are provided with multiple equally distributed lower through-holes.
2. graphene solar cell as claimed in claim 1, it is characterised in that a diameter of the 0.1 of the upper through hole~ 0.2mm。
3. graphene solar cell as claimed in claim 1, it is characterised in that a diameter of the 0.1 of the lower through-hole~ 0.2mm。
4. graphene solar cell as claimed in claim 1, it is characterised in that the upper surface of the graphene layer is honeycomb Shape structure.
5. graphene solar cell as claimed in claim 1, it is characterised in that the lower surface of the graphene layer is honeycomb Shape structure.
6. graphene solar cell as claimed in claim 1, it is characterised in that four angles of the upper electrode layer are oblique angle Or fillet.
7. graphene solar cell as claimed in claim 1, it is characterised in that four angles of the lower electrode layer are oblique angle Or fillet.
CN201610481286.9A 2016-06-28 2016-06-28 A kind of graphene solar cell Pending CN107546282A (en)

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CN201610481286.9A CN107546282A (en) 2016-06-28 2016-06-28 A kind of graphene solar cell

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Application Number Priority Date Filing Date Title
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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102956728A (en) * 2011-08-24 2013-03-06 神讯电脑(昆山)有限公司 Solar device and use method thereof
CN103477448A (en) * 2011-03-29 2013-12-25 加州理工学院 Graphene-based multi-junctions flexible solar cell
TW201417312A (en) * 2012-10-17 2014-05-01 Tsec Corp Solar cell having damascened backside electrode and manufacturing method thereof
CN203607056U (en) * 2013-10-25 2014-05-21 黑龙江省康格尔科技有限公司 Electrical equipment convenient to assemble
CN203761326U (en) * 2014-03-27 2014-08-06 李蓬勃 Solar cell module
CN104091840A (en) * 2014-07-28 2014-10-08 六安市大宇高分子材料有限公司 Selective emitter solar cell
CN204481052U (en) * 2015-03-16 2015-07-15 林前锋 A kind of graphene battery
CN204792820U (en) * 2015-06-27 2015-11-18 莆田市威特电子有限公司 Amorphous silicon thin film solar cell
CN204857757U (en) * 2015-08-10 2015-12-09 苏州阿特斯阳光电力科技有限公司 Many main grids solar module

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103477448A (en) * 2011-03-29 2013-12-25 加州理工学院 Graphene-based multi-junctions flexible solar cell
CN102956728A (en) * 2011-08-24 2013-03-06 神讯电脑(昆山)有限公司 Solar device and use method thereof
TW201417312A (en) * 2012-10-17 2014-05-01 Tsec Corp Solar cell having damascened backside electrode and manufacturing method thereof
CN203607056U (en) * 2013-10-25 2014-05-21 黑龙江省康格尔科技有限公司 Electrical equipment convenient to assemble
CN203761326U (en) * 2014-03-27 2014-08-06 李蓬勃 Solar cell module
CN104091840A (en) * 2014-07-28 2014-10-08 六安市大宇高分子材料有限公司 Selective emitter solar cell
CN204481052U (en) * 2015-03-16 2015-07-15 林前锋 A kind of graphene battery
CN204792820U (en) * 2015-06-27 2015-11-18 莆田市威特电子有限公司 Amorphous silicon thin film solar cell
CN204857757U (en) * 2015-08-10 2015-12-09 苏州阿特斯阳光电力科技有限公司 Many main grids solar module

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Application publication date: 20180105