CN107522525A - A kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs - Google Patents
A kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs Download PDFInfo
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- CN107522525A CN107522525A CN201710861915.5A CN201710861915A CN107522525A CN 107522525 A CN107522525 A CN 107522525A CN 201710861915 A CN201710861915 A CN 201710861915A CN 107522525 A CN107522525 A CN 107522525A
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- Prior art keywords
- antibiotic
- ozone
- organic fertilizer
- antibiotic bacterium
- bacterium dregs
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
Abstract
A kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs, it is related to processing method and the recycling of antibiotic bacterium dregs, it is high the invention solves existing antibiotic bacterium dregs processing cost, the problems such as environmental risk is remained after processing, antibiotic bacterium slag liquid is delivered in the ozone-oxidizing device for being provided with ozone oxidation catalyst by the present invention, catalytic ozonation processing is carried out, the bacteria residue liquid after processing, which carries out precipitation is collected by centrifugation, prepares organic fertilizer.The present invention is easy to operate, and treating capacity is big, efficiently quick, can effectively degrade and the antibiotic that is remained in harmless treatment bacteria residue, be adapted to industrialized production;Meanwhile it can also complete the sterilizing to antibiotic bacterium dregs.After being handled more than, the degradable of residual antibiotic is can reach, has no residual harmful in the effect of the different kind organism body of natural environment.
Description
Technical field
The present invention relates to the method for innocent treatment of antibiotic bacterium dregs and recycling.
Background technology
Antibiotic is heavily used in the disease treatment of humans and animals for a long time, and makes an addition to animal with big therapeutic dose
In feed, to prevent Animal diseases and promote its growth.But most antibiotic can not be absorbed by organisms completely, there are about 90%
Antibiotic be discharged into original shape or metabolite form via the excrement and urine of sick humans and animals in ecological environment, through different ways
Footpath pollutes to soil and water body.China's ferment antibiotics annual discharge capacity of its bacteria residue about 200 in process of production
Ten thousand tons, a large number of nutrients is rich in bacteria residue, but because wherein containing a small amount of antibiotic residue, to prevent antibiotic residue from triggering ring
The risk of bacterial resistance in border, antibiotic bacterium dregs must first pass around processing and remove wherein antibiotic residue, then can just be subject to
Utilize.But up to the present, China's antibiotic bacterium dregs still lack safely and effectively innoxious and recycling processing method, absolutely mostly
Number can only burning disposal, not only cause ample resources to waste, and burning disposal cost is high, the risk that secondary pollution be present.Together
When, the high cost of bacteria residue processing is severely impacted the sound development of pharmaceutical industry.
It is revised according to 2008《National Hazard waste register》, antibiotic bacterium dregs belong to chemicals production of raw medicine
During culture medium waste, must be managed by hazardous waste.Antibiotic bacterium dregs contain to be produced among residual antibiotic and metabolism
Thing etc., it is a kind of special hazardous waste, it is such as mishandling, can be potentially hazardous to ecological environment and health generation,
Its harm has the characteristics that disguise, hysteresis quality, cumulative, concertedness and related property.For antibiotic bacterium dregs yield is big, place
The realistic problems such as difficulty is big are managed,《Pharmaceuticals industry pollution prevention technique policy》It is proposed " to encourage exploitation fermentation in (exposure draft)
Reutilization technology, innoxious process for treating, comprehensive utilization technique of the bacteria residue in production technology " policy and suggestion.
Ozonation technology is a kind of high-level oxidation technology, is widely used in the processing of all kinds waste water.It is mainly
Produced after being decomposed using ozone in water in the oxidability extremely strong oxidation intermediates, with water such as antozone, hydroxyl radical free radical
The reaction of organic and inorganic pollution, so as to realize deodorization, decolouring, sterilization and the purpose of organics removal.
The content of the invention
It is high the invention solves existing antibiotic bacterium dregs processing cost, the problems such as remaining environmental risk after processing, there is provided
It is a kind of to produce the high method of the simple to operate of organic fertilizer, treatment effeciency using antibiotic bacterium dregs.
A kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs of the present invention, it is entered according to following steps
Capable:
First, antibiotic bacterium dregs are gathered, regulation solid content is that 8~10%, pH is 6~9, pending bacteria residue liquid is obtained, by antibiosis
Plain bacteria residue liquid is delivered in the ozone-oxidizing device for being provided with ozone oxidation catalyst, is carried out catalytic ozonation and is handled 2~5h;
2nd, the bacteria residue after the completion of reacting is centrifuged, by obtained bacteria residue precipitation and auxiliary material humic acid or bentonite
Mix drying to be granulated, make organic fertilizer;
The residual quantity of antibiotic in described antibiotic bacterium slag liquid is 600~700mg/L, pH=3.5~7.8;
The mol ratio of antibiotic and ozone is 1: 80~100.
The present invention operation principle be:On the one hand oxidable big point of hydroxyl radical free radical with strong oxidizing property caused by ozone
Sub- material is small-molecule substance so that antibiotic is degraded in bacteria residue;Another aspect antozone, hydroxyl radical free radical can have
Antibiotic resistant bacteria in effect inactivation bacteria residue, makes bacteria residue organic fertilizer without antibiotic resistant bacteria and does not trigger bacterium in soil
Resistance, safety in utilization improve.
The removal of antibiotic residue is different from organic matter removal in waste water in the high solid phase bacteria residue slurry of the present invention, at waste water
The target of reason is the organic matter of all kinds in water removal, and the target of bacteria residue processing is to remove antibiotic residue and retain albumen
The organic nutrient substance beneficial to plant growth such as matter, amino acid, i.e., organic matter is selective removal in bacteria residue.
The present invention has advantages below:
1. antibiotic residue can be degraded in the present invention, drug-fast bacteria is effectively inactivated in bacteria residue, and method program is simply easily grasped
Make, cost is low, fertilizer it is safe to use.
2. application prospect of the present invention is preferable, gardening, fruits and vegetables, farmland, forest or urban afforestation soil etc. can be applied to.
3. the present invention, which can be enterprise, solves the problems urgently to be resolved hurrily such as bacteria residue processing disposal, processing cost, while bacterium are reduced
The recycling of slag can be that enterprise brings potential economic benefit.
Brief description of the drawings
Fig. 1 is the removal figure of residual erythrocin in erythromycin bacterium slag processing procedure in embodiment one.
Embodiment
Embodiment one:A kind of side that organic fertilizer is produced using ozone processing antibiotic bacterium dregs of present embodiment
Method, it is characterised in that it is followed the steps below:
First, antibiotic bacterium dregs are gathered, regulation solid content is that 8~10%, pH is 6~9, obtains pending bacteria residue liquid, 1L is resisted
Raw plain bacteria residue liquid is delivered in the ozone-oxidizing device for being provided with ozone oxidation catalyst, and progress catalytic ozonation processing 2~
5h;
2nd, the bacteria residue after the completion of reacting is centrifuged, by obtained bacteria residue precipitation and auxiliary material humic acid or bentonite
Mix drying to be granulated, make organic fertilizer;
The residual quantity of antibiotic in described antibiotic bacterium slag liquid is 600~700mg/L, pH=3.5~7.8;
The mol ratio of antibiotic and ozone is 1: 80~100.
Embodiment two:Present embodiment is unlike embodiment one:Described antibiotic and ozone
Mol ratio be 1: 85~100.It is other identical with embodiment one.
Embodiment three:Present embodiment is unlike embodiment one:Described antibiotic and ozone
Mol ratio be 1: 90~100.It is other identical with embodiment one.
Embodiment four:Present embodiment is unlike embodiment one:Described antibiotic and ozone
Mol ratio be 1: 95~100.It is other identical with embodiment one.
Embodiment five:Present embodiment is unlike embodiment one:Described antibiotic and ozone
Mol ratio be 1: 80~90.It is other identical with embodiment one.
Embodiment six:Present embodiment is unlike embodiment one:It is 8~9% to adjust solid content,
PH is 6~7.It is other identical with embodiment one.
Embodiment seven:Present embodiment is unlike embodiment one:Adjust solid content be 9~
10%, pH are 7~8.It is other identical with embodiment one.
Embodiment eight:Present embodiment is unlike embodiment one:It is 8~9% to adjust solid content,
PH is 8~9.It is other identical with embodiment one.
Embodiment nine:Present embodiment is unlike embodiment one:Described antibiotic bacterium slag liquid
In the residual quantity of antibiotic be 640~700mg/L, pH=4.0~7.8.It is other identical with embodiment one.
Embodiment ten:Present embodiment is unlike embodiment one:Described antibiotic bacterium slag liquid
In the residual quantity of antibiotic be 640~680mg/L, pH=3.5~7.8.It is other identical with embodiment one.
Embodiment 11:Present embodiment is unlike embodiment one:Described antibiotic is big
Cyclic lactone class, Fourth Ring class or aminoglycoside antibiotics.It is other identical with embodiment one.
Embodiment 12:Present embodiment is unlike embodiment one:Macrolide antibiotics
For erythromycin, lincomycin, medecamycin or kitasamycin.It is other identical with embodiment one.
Embodiment 13:Present embodiment is unlike embodiment one:Tetracycline antibiotics is soil
Mycin, tetracycline or aureomycin.It is other identical with embodiment one.
Embodiment 14:Present embodiment is unlike embodiment one:Aminoglycoside antibiotics
For gentamicin, kanamycins, neomycin, spectinomycin or TOB.It is other identical with embodiment one.
Present invention is not limited only to the content of the respective embodiments described above, the group of one of them or several embodiments
Contract sample can also realize the purpose of invention.
Beneficial effect of the present invention is verified using following examples and contrast test:
Embodiment one
A kind of method that organic fertilizer is produced using ozone processing erythromycin bacterium slag of the present embodiment is carried out according to the following steps:
1. 1L erythromycin bacterium slags sample (residual quantity of erythromycin is 640mg/L, pH=5.93) is placed in ozone oxidation dress
In putting, regulation pH is 8, (mol ratio=1 of erythromycin and ozone: 100), carries out catalytic ozonation processing 3h.
2. through the bacteria residue that step 1 obtains under conditions of rotating speed 3000r/min, 20min is centrifuged, is precipitated and supernatant
Liquid;Bacteria residue precipitation is collected, and is added in slurry-spraying pelletizing machine and carries out drying granulation, makes organic fertilizer product, completes bacteria residue
Harmless treatment.
Bacteria residue used is the fresh bacteria residue of biological pharmaceutical factory's workshop in the present embodiment, and bacteria residue solid content is 9%, mesh
The clearance for marking erythromycin is 100%, and bacteria residue centrifugation gained precipitation is added in slurry-spraying pelletizing machine and carries out drying granulation, is made
Organic fertilizer product, complete the harmless treatment of bacteria residue.The soil of bacteria residue organic fertilizer and application fertilizer (dose 1%) after 1~30 day
The testing result of erythromycin-resistant bacterium drug resistant gene is negative in earth.
Embodiment two
A kind of method that organic fertilizer is produced using ozone processing lincomycin fungi residues of the present embodiment is carried out according to the following steps:
1. 1L lincomycin fungi residues sample (residual quantity of lincomycin is 640mg/L, pH=5.93) is placed in ozone oxygen
During makeup is put, regulation pH is 8, (mol ratio=1 of lincomycin and ozone: 80), carries out catalytic ozonation processing 2h.
2. through the bacteria residue that step 1 obtains under conditions of rotating speed 3000r/min, 20min is centrifuged, is precipitated and supernatant
Liquid;Bacteria residue precipitation is collected, and is added in slurry-spraying pelletizing machine and carries out drying granulation, makes organic fertilizer product, completes bacteria residue
Harmless treatment.
Bacteria residue used is the fresh bacteria residue of biological pharmaceutical factory's workshop in the present embodiment, and bacteria residue solid content is 8.5%,
The clearance of target lincomycin is 100%, and bacteria residue centrifugation gained precipitation is added in slurry-spraying pelletizing machine and carries out drying granulation,
Organic fertilizer product is made, completes the harmless treatment of bacteria residue.Bacteria residue organic fertilizer and application fertilizer (dose 1%) are after 1~30 day
Soil in the testing result of lincomycin drug-fast bacteria drug resistant gene be negative.
Embodiment three
A kind of method that organic fertilizer is produced using ozone processing terramycin bacteria residue of the present embodiment is carried out according to the following steps:
1. 1L terramycin strain slag specimens product (residual quantity of terramycin is 600mg/L, pH=4.2) are placed in ozone-oxidizing device
In, regulation pH is 7.5, (mol ratio=1 of terramycin and ozone: 85), carries out catalytic ozonation processing 2h.
2. through the bacteria residue that step 1 obtains under conditions of rotating speed 3000r/min, 20min is centrifuged, is precipitated and supernatant
Liquid;Bacteria residue precipitation is collected, and is added in slurry-spraying pelletizing machine and carries out drying granulation, makes organic fertilizer product, completes bacteria residue
Harmless treatment.
Bacteria residue used is the fresh bacteria residue of biological pharmaceutical factory's workshop in the present embodiment, and bacteria residue solid content is 8.5%,
The clearance of target terramycin is 99%, and bacteria residue centrifugation gained precipitation is added in slurry-spraying pelletizing machine and carries out drying granulation, is made
Make organic fertilizer product, complete the harmless treatment of bacteria residue.Bacteria residue organic fertilizer and application fertilizer (dose 1%) are after 1~30 day
The testing result of terramycin drug-fast bacteria drug resistant gene is negative in soil.
Example IV
A kind of method that organic fertilizer is produced using ozone processing gentamicin bacteria residue of the present embodiment is carried out according to the following steps:
1. 1L gentamicin bacteria residues sample (residual quantity of gentamicin is 670mg/L, pH=6.0) is placed in ozone oxidation
In device, regulation pH is 8, (mol ratio=1 of gentamicin and ozone: 85), carries out catalytic ozonation processing 2h.
2. through the bacteria residue that step 1 obtains under conditions of rotating speed 3000r/min, 20min is centrifuged, is precipitated and supernatant
Liquid;Bacteria residue precipitation is collected, and is added in slurry-spraying pelletizing machine and carries out drying granulation, makes organic fertilizer product, completes bacteria residue
Harmless treatment.
Bacteria residue used is the fresh bacteria residue of biological pharmaceutical factory's workshop in the present embodiment, and bacteria residue solid content is 8.5%,
The clearance of target gentamicin is 99.5%, and bacteria residue centrifugation gained precipitation is added in slurry-spraying pelletizing machine and carries out drying and makes
Grain, organic fertilizer product is made, completes the harmless treatment of bacteria residue.Bacteria residue organic fertilizer and apply fertilizer (dose 1%) 1~30 day
The testing result of gentamicin drug-fast bacteria drug resistant gene is negative in soil afterwards.
Claims (10)
- A kind of 1. method for producing organic fertilizer using ozone processing antibiotic bacterium dregs, it is characterised in that it is entered according to following steps Capable:First, antibiotic bacterium dregs are gathered, regulation solid content is that 8~10%, pH is 6~9, pending bacteria residue liquid is obtained, by antibiotic bacterium Slag liquid is delivered in the ozone-oxidizing device for being provided with ozone oxidation catalyst, is carried out catalytic ozonation and is handled 2~5h;2nd, the bacteria residue after the completion of reacting is centrifuged, and obtained bacteria residue is precipitated and mixed with auxiliary material humic acid or bentonite Stirring and drying is granulated, and makes organic fertilizer;The residual quantity of antibiotic in described antibiotic bacterium slag liquid is 600~700mg/L, pH=3.5~7.8;The mol ratio of antibiotic and ozone is 1: 80~100.
- 2. a kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs according to claim 1, its feature exist In the mol ratio of antibiotic and ozone be 1: 85~100.
- 3. a kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs according to claim 2, its feature exist In the mol ratio of antibiotic and ozone be 1: 90~100.
- 4. a kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs according to claim 3, its feature exist In the mol ratio of antibiotic and ozone be 1: 95~100.
- 5. a kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs according to claim 4, its feature exist In the mol ratio of antibiotic and ozone be 1: 80~90.
- 6. a kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs according to claim 1, its feature exist It is that 8~9%, pH is 6~7 in adjusting solid content.
- 7. a kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs according to claim 6, its feature exist It is that 8~10%, pH is 7~8 in adjusting solid content.
- 8. a kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs according to claim 1, its feature exist The residual quantity of antibiotic in antibiotic bacterium slag liquid is 640~700mg/L, pH=3.5~7.8.
- 9. a kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs according to claim 1, its feature exist The residual quantity of antibiotic in antibiotic bacterium slag liquid is 640~680mg/L, pH=3.5~7.8.
- 10. a kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs according to claim 1, its feature exist In described antibiotic be macrolides, Fourth Ring class or aminoglycoside antibiotics.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR970042314A (en) * | 1995-12-15 | 1997-07-24 | 백운화 | Treatment of antibiotic wastewater with ozone |
EP1686095A1 (en) * | 2005-01-31 | 2006-08-02 | Universidad Católica de la Santisima Concepción | Photocatalytic reactor with a modular configuration and advanced oxidation process for purifying and disinfecting wastewater from aquaculture |
CN103214281A (en) * | 2013-05-06 | 2013-07-24 | 四川千业环保产业发展有限公司 | Method for performing chemical innocent treatment on erythromycin waste residues and using erythromycin waste residues for producing organic fertilizer |
CN103332831A (en) * | 2013-07-18 | 2013-10-02 | 山东太平洋环保有限公司 | Comprehensive erythromycin thiocyanate mushroom dreg waste water disposal system and method |
CN103553805A (en) * | 2013-10-31 | 2014-02-05 | 宁夏启元药业有限公司 | Method for producing organic fertilizer by using erythromycin waste residue and tetracycline urea double salt mother liquor |
CN105478454A (en) * | 2016-01-12 | 2016-04-13 | 宁夏大学 | Method for removing residual high-concentration tetracycline in pharmacy mushroom residues |
-
2017
- 2017-09-21 CN CN201710861915.5A patent/CN107522525A/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR970042314A (en) * | 1995-12-15 | 1997-07-24 | 백운화 | Treatment of antibiotic wastewater with ozone |
EP1686095A1 (en) * | 2005-01-31 | 2006-08-02 | Universidad Católica de la Santisima Concepción | Photocatalytic reactor with a modular configuration and advanced oxidation process for purifying and disinfecting wastewater from aquaculture |
CN103214281A (en) * | 2013-05-06 | 2013-07-24 | 四川千业环保产业发展有限公司 | Method for performing chemical innocent treatment on erythromycin waste residues and using erythromycin waste residues for producing organic fertilizer |
CN103332831A (en) * | 2013-07-18 | 2013-10-02 | 山东太平洋环保有限公司 | Comprehensive erythromycin thiocyanate mushroom dreg waste water disposal system and method |
CN103553805A (en) * | 2013-10-31 | 2014-02-05 | 宁夏启元药业有限公司 | Method for producing organic fertilizer by using erythromycin waste residue and tetracycline urea double salt mother liquor |
CN105478454A (en) * | 2016-01-12 | 2016-04-13 | 宁夏大学 | Method for removing residual high-concentration tetracycline in pharmacy mushroom residues |
Non-Patent Citations (1)
Title |
---|
徐武军等: "臭氧氧化技术处理含抗生素废水", 《化学进展》 * |
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Application publication date: 20171229 |