CN107517997A - Composition pesticide containing Belmark and Celastrus angulatus - Google Patents
Composition pesticide containing Belmark and Celastrus angulatus Download PDFInfo
- Publication number
- CN107517997A CN107517997A CN201710967506.3A CN201710967506A CN107517997A CN 107517997 A CN107517997 A CN 107517997A CN 201710967506 A CN201710967506 A CN 201710967506A CN 107517997 A CN107517997 A CN 107517997A
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- China
- Prior art keywords
- belmark
- celastrus angulatus
- pesticidal combination
- agent
- celastrus
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
Abstract
The invention discloses a kind of Pesticidal combination containing Belmark and Celastrus angulatus.The composition pesticide contains active component Belmark and Celastrus angulatus, and the mass fraction ratio of Belmark and Celastrus angulatus is 30:1~1:1, Belmark and Celastrus angulatus have synergistic effect to the prevention effect of aphid, diamondback moth, cabbage caterpillar in the proportion, Belmark and Celastrus angulatus can be processed into pesticidal preparations, the mass fraction ratio of Belmark and Celastrus angulatus pesticidal preparations is 0.1% 40%, remaining is insecticides adjuvant, and said composition can be used for preventing and treating brassicaceous vegetable cabbage caterpillar, diamondback moth, aphid.
Description
Technical field
The invention belongs to the synergistic composition field that botanical pesticide combines with chemical pesticide, the specific one kind that provides is containing work
The Synergistic insecticidal compositions of property composition Belmark and Celastrus angulatus.
Background technology
Belmark (fenvalerate) be SUMITOMO CHEMICAL chemical company initiative one kind efficiently, wide spectrum, low residual hazard,
The good non-cyclopropane system pyrethroid insecticides of light resistance, wide spectrum, efficient, quick pyrethroid, to tag and stomach toxicity
Based on effect, no systemic action is invalid to mite class, effective to lepidopterous larvae, Orthoptera, Semiptera, Diptera pest, is applicable
In the control of insect of cotton, fruit tree, vegetables and other crops.
Celastrus angulatus (Celastrus angulatus) belongs to the perennial liana of Celastraceae Celastrus, is distributed widely in
Chinese the Yellow River, the hills and mountain area of the Yangtze river basin.Celastrus angulatus is from the isolated active component of the plant.Celastrus angulatus pair
Beet armyworm, prodenia litura special efficacy, it is efficient to rice leaf roller, pink rice borer, striped rice borer, yellow rice borer.
The single use of agricultural chemicals can bring resistance risk, and agriculture chemical compounding is the effective way for solving resistance problem.
Develop new product bactericide is expensive, the cycle is grown, and by contrast, exploitation is efficient, less toxic, low-residual with research
Compounding have with mixture invest small, lead time it is short and by attention both domestic and external, it is numerous and confused to increase development dynamics.
The combination of Belmark and Celastrus angulatus has no report.
The content of the invention
The present invention provides a kind of composition pesticide containing Belmark and Celastrus angulatus, for preventing and treating brassicaceous vegetable
Cabbage caterpillar, diamondback moth, aphid.
The present invention is achieved through the following technical solutions：
A kind of Pesticidal combination containing Belmark and Celastrus angulatus, contains active component Belmark and bitter skin
The mass fraction ratio of rattan element, Belmark and Celastrus angulatus is 50:1~1:5, it is preferably in a proportion of 30:1~1:1, further
It is preferably in a proportion of 20:1~6:1, still more preferably ratio is 15:1 and 12:1.
The described Pesticidal combination containing Belmark and Celastrus angulatus, contains active component Belmark and hardship
Skin rattan element, also contains insecticides adjuvant, in order to be processed into insecticides adjuvant, wherein Belmark and Celastrus angulatus in the composition
Gross weight percentage composition be 0.1~40%, remaining is insecticides adjuvant.
The described Pesticidal combination containing Belmark and Celastrus angulatus, can be processed into aqueous suspension agent, aqueous emulsion,
Microemulsion.
The aqueous suspension agent formulation weight percent forms：Belmark 0.01~30%, Celastrus angulatus 0.01
~10%, active ingredient total content be not more than 40%, dispersant 0.2~19%, wetting agent 0.2~12%, thickener 0.1~
3%th, antifreezing agent 0.1~5%, deionized water carrier complement to 100%.Specifically production stage is：By active ingredient and other help
Agent is mixed, and after high speed shear is disperseed, is sanded in sand mill, high dispersive, stable suspension system, system are formed in water-medium
Obtain the aqueous suspension agent of corresponding weight percentage.
The aqueous emulsion agent weight percent forms：Belmark 0.01~30%, Celastrus angulatus 0.01~
10%th, active ingredient total content is not more than 40%, emulsifying agent 0.5-20%, solvent 0.2~25%, dispersant 0.2~7%, steady
Determine agent 0.1~1%, antifreezing agent 0.1~4%, defoamer 0.1~2%, deionized water carrier complements to 100%；Specific production step
Suddenly it is：Above-mentioned active ingredient, solvent, emulsifying agent, dispersant and stabilizer are mixed to form oil phase, antifreezing agent dissolves shape in water
Into aqueous phase, slowly oil phase is added in aqueous phase under cutter effect, and continues shearing about 40 minutes, that is, the water and milk is made
Agent.
The micro-emulsion form weight percent forms：Belmark 0.01~30%, Celastrus angulatus 0.01~
10%th, active ingredient total content is not more than 40%, solvent 0.5-20%, stabilizer 0.2~16%, emulsifying agent 0.1~4%, oozes
0.1~3%, antifreezing agent 0.1~5% is penetrated into, deionized water carrier complements to 100%；Specifically production stage is：By active ingredient
It is completely dissolved with solvent, then adds emulsifying agent, stabilizer, bleeding agent, antifreezing agent and be well mixed, be eventually adding deionization
Water, after being sufficiently stirred, you can the microemulsion is made.
Described auxiliary component is solvent, emulsifying agent, wetting agent, dispersant, stabilizer, antifreezing agent, thickener, bonding
Agent, disintegrant, defoamer, bleeding agent, macromolecule cyst material, synergist, film forming agent, preservative, warning coloration and filler etc., all
It is to commonly use in pesticidal preparations or allow the composition used, is not particularly limited, specific composition and dosage pass through according to recipe requirements
Simple experiment determines.
The described Pesticidal combination containing Belmark and Celastrus angulatus is applied to preventing and treating wild cabbage diamondback moth, dark greyish green
Worm, aphid.
Compared with prior art, the advantage of the invention is that：
1st, Belmark and Celastrus angulatus compound in the range of certain proportion has association to diamondback moth, cabbage caterpillar, aphid
Same synergistic effect.
2nd, two kinds of active ingredients of Belmark and Celastrus angulatus compounding, reduces Pesticide use amount, reduce use into
Originally, alleviate the pollution to environment, delay the drug-fast service life for producing, adding agricultural chemicals of pest and disease damage.
Embodiment
According to the abundant methods of Sun Yun, the synergy of pharmacy mix is evaluated according to co-toxicity coefficient (CTC), i.e. CTC≤80 are association
Same antagonism, 80 ＜ CTC ＜ 120 are joint action of antagonism, and CTC >=120 are synergistic function.Survey toxicity index
(ATI)=(LC of standard agent50The LC of/reagent agent50)×100；The toxicity index of theoretical toxicity index TTI=A medicaments ×
In mixture in toxicity index × mixture of the percentage composition+B medicaments of A medicaments B medicaments percentage composition；Co-toxicity coefficient (CTC)=
[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100
The table 1 of embodiment one:Belmark determines (stomach toxicity with Celastrus angulatus to the toxicity of diamondback moth (3 instar larvae)
Activity, using leaching leaf stomach toxicity method, investigate within 5 days after medicine, test method is tried with reference to NYT1154.14-2008 farm-chemical indoor determinations
Test the part of criterion insecticide the 14th：Leaf dipping method)
The data result that table 1 is recorded shows that Belmark and Celastrus angulatus mass fraction ratio are 30:1~1:1 scope
The interior stomach poison activity to diamondback moth (3 instar larvae) has synergistic effect, and co-toxicity coefficient is more than 120；Belmark and Celastrus angulatus
Plain quality parts ratio example is 20:1~6:There is synergistic effect to the stomach poison activity of diamondback moth (3 instar larvae) in the range of 1, altogether poison system
Number is more than 140；Belmark and Celastrus angulatus mass fraction ratio are 15:1 and 12:To the stomach of diamondback moth (3 instar larvae) in 1
Cytotoxic activity has more preferable synergistic effect, and co-toxicity coefficient is more than 190.
The table 2 of embodiment two:Belmark determines (stomach toxicity with Celastrus angulatus to the toxicity of cabbage caterpillar (2 instar larvae)
Activity, using leaching leaf stomach toxicity method, investigate within 5 days after medicine, test method is tried with reference to NYT1154.14-2008 farm-chemical indoor determinations
Test the part of criterion insecticide the 14th：Leaf dipping method)
The data result that table 2 is recorded shows that Belmark and Celastrus angulatus mass fraction ratio are 30:1~1:1 scope
The interior stomach poison activity to cabbage caterpillar (2 instar larvae) has synergistic effect, and co-toxicity coefficient is more than 125；Belmark and Celastrus angulatus
Plain quality parts ratio example is 20:1~6:There is synergistic effect to the stomach poison activity of cabbage caterpillar (2 instar larvae) in the range of 1, altogether poison system
Number is more than 145；Belmark and Celastrus angulatus mass fraction ratio are 15:1 and 12:To the stomach of cabbage caterpillar (2 instar larvae) in 1
Cytotoxic activity has more preferable synergistic effect, and co-toxicity coefficient is more than 180.
The table 3 of embodiment three:Belmark determines (systemic activity with Celastrus angulatus to the toxicity of aphid (radish aphid)
Test, continuous immersion method, investigate within 4 days after medicine, test method is accurate with reference to the experiment of NYT1154.4-2006 farm-chemical indoor determinations
The then part of insecticide the 4th：Systemic activity tests continuous immersion method)
The data result that table 3 is recorded shows that Belmark and Celastrus angulatus mass fraction ratio are 30:1~1:1 scope
The interior stomach poison activity to aphid (radish aphid) has synergistic effect, and co-toxicity coefficient is more than 125；Belmark and Celastrus angulatus quality
Number ratio is measured 20:1~6:There is synergistic effect to the stomach poison activity of aphid (radish aphid) in the range of 1, co-toxicity coefficient is more than
150；Belmark and Celastrus angulatus mass fraction ratio are 15:1 and 12:Have in 1 to the stomach poison activity of aphid (radish aphid)
More preferable synergistic effect, co-toxicity coefficient are more than 180.
The Belmark Celastrus angulatus suspending agent of example IV 16%
Belmark 15%, Celastrus angulatus 1%, dodecyl sodium sulfate 7%, acrylic acid-maleic acid copolymerized macromolecule
Sodium salt 6%, polyethylene glycol 5%, Arabic gum 1%, polyethers emulsion 0.1%, deionized water supplies 100%；By it is above-mentioned effectively into
Point, wetting agent, dispersant, antifreezing agent, thickener and defoamer through high speed shear is scattered, is sanded in sand mill, in water-medium
The high dispersive of middle formation, stable suspension system, you can 16% Belmark Celastrus angulatus suspending agent is made.
The Belmark Celastrus angulatus aqueous emulsion of embodiment 5 16%
Belmark 15%, Celastrus angulatus 1%, DMF 4%, cyclohexanone 12%, polyoxyethylene sorbitan fat
Sour ketone 12%, fatty acid amide N methyl taurine sodium salt 1%, pentaerythrite 1%, glycerine 1%, deionized water supplies 100%；
Above-mentioned active ingredient, solvent, emulsifying agent, dispersant and stabilizer are mixed to form oil phase, antifreezing agent dissolves in water forms water
Phase, slowly oil phase is added in aqueous phase under cutter effect, and continue shearing about 30 minutes, 16% valeric acid cyanogen ether is made
Ester Celastrus angulatus aqueous emulsion.
The Belmark Celangulins ME of embodiment 6 13%
Belmark 12%, Celastrus angulatus 1%, DMF2%, cyclohexanone 8%, disecoctylmaleate sodium sulfonate
15%th, pyrogallic acid 3%, organosilicon 2%, glycerine 2%, deionized water supplies 100%；Active ingredient solvent is complete
Fully dissolved, then add emulsifying agent, stabilizer, bleeding agent, antifreezing agent and be well mixed, be eventually adding deionized water, fully stir
After mixing, you can 13% Belmark Celangulins ME is made.
16% Belmark Celastrus angulatus aqueous emulsion of the gained of seven embodiment of embodiment five, the gained of embodiment six 13%
16% Belmark Celastrus angulatus suspending agent preventing and treating wild cabbage obtained by Belmark Celangulins ME, example IV
Diamondback moth, cabbage aphid, cabbage pieris field control effectiveness test (cauline leaf spray-on process, every mu of 30 kilograms of injection flow rate, are adjusted for 5 days after medicine
Look into)
Table 4 respectively handles chemical control wild cabbage diamondback moth, cabbage aphid (radish aphid), cabbage pieris field control effectiveness test
The result of table 4 shows that 16% Belmark Celastrus angulatus aqueous emulsion, 13% Belmark Celastrus angulatus are micro-
Emulsion, 105 grams/ha of 16% Belmark Celastrus angulatus suspending agent effective ingredient consumption to wild cabbage diamondback moth, cabbage caterpillar,
Aphid (radish aphid) is respectively provided with preferable prevention effect.
Claims (10)
- A kind of 1. Pesticidal combination containing Belmark and Celastrus angulatus, it is characterised in that：Including active component valeric acid cyanogen The mass fraction ratio of ether-ether and Celastrus angulatus, Belmark and Celastrus angulatus is 50:1~1:5.
- 2. the Pesticidal combination according to claim 1 containing Belmark and Celastrus angulatus, it is characterised in that：It is described The mass fraction ratio of Belmark and Celastrus angulatus is 30:1~1:1.
- 3. the Pesticidal combination according to claim 1 containing Belmark and Celastrus angulatus, it is characterised in that：It is described The mass fraction ratio of Belmark and Celastrus angulatus is 20:1~6:1.
- 4. the Pesticidal combination according to claim 1 containing Belmark and Celastrus angulatus, it is characterised in that：It is described The mass fraction ratio of Belmark and Celastrus angulatus is 15:1.
- 5. the Pesticidal combination according to claim 1 containing Belmark and Celastrus angulatus, it is characterised in that：It is described The mass fraction ratio of Belmark and Celastrus angulatus is 12:1.
- 6. the Pesticidal combination containing Belmark and Celastrus angulatus according to Claims 1 to 5 any one, it is special Sign is：The gross weight percentage composition of the Belmark and Celastrus angulatus in the composition is 0.1~40%, and remaining is agriculture Medicine auxiliary agent.
- 7. the Pesticidal combination according to claim 6 containing Belmark and Celastrus angulatus, it is characterised in that：It is described The gross weight percentage composition of Belmark and Celastrus angulatus in the composition is 0.1~40%, and remaining is insecticides adjuvant, desinsection The formulation of composition is aqueous suspension agent, aqueous emulsion, microemulsion.
- A kind of 8. preparation side of the Pesticidal combination aqueous suspension agent containing Belmark and Celastrus angulatus described in claim 7 Method, it is characterised in that：Belmark 15%, Celastrus angulatus 1%, dodecyl sodium sulfate 7%, acrylic acid-maleic acid copolymerization Macromolecule sodium salt 6%, polyethylene glycol 5%, Arabic gum 1%, polyethers emulsion 0.1%, deionized water supplies 100%；Will be above-mentioned Active ingredient, wetting agent, dispersant, antifreezing agent, thickener and defoamer disperse through high speed shear, are sanded in sand mill, in water It is high dispersive, the stable suspension system formed in medium, you can 16% Belmark Celastrus angulatus aqueous suspension agent is made.
- A kind of 9. preparation side of the Pesticidal combination aqueous emulsion containing Belmark and Celastrus angulatus described in claim 7 Method, it is characterised in that：Belmark 15%, Celastrus angulatus 1%, DMF 4%, cyclohexanone 12%, polyoxyethylene sorbitan Polyol fatty acid ketone 12%, fatty acid amide N methyl taurine sodium salt 1%, pentaerythrite 1%, glycerine 1%, deionized water is supplied 100%；Above-mentioned active ingredient, solvent, emulsifying agent, dispersant and stabilizer are mixed to form oil phase, antifreezing agent dissolves in water Aqueous phase is formed, slowly oil phase is added in aqueous phase under cutter effect, and continues shearing about 30 minutes, 16% valeric acid is made Cyanogen ether-ether Celastrus angulatus aqueous emulsion.
- 10. the Pesticidal combination containing Belmark and Celastrus angulatus described in claim 1 is in preventing and treating wild cabbage diamondback moth, dish Application on blue or green worm, aphid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710967506.3A CN107517997A (en) | 2017-10-17 | 2017-10-17 | Composition pesticide containing Belmark and Celastrus angulatus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710967506.3A CN107517997A (en) | 2017-10-17 | 2017-10-17 | Composition pesticide containing Belmark and Celastrus angulatus |
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| Publication Number | Publication Date |
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| CN107517997A true CN107517997A (en) | 2017-12-29 |
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ID=60684626
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710967506.3A Withdrawn CN107517997A (en) | 2017-10-17 | 2017-10-17 | Composition pesticide containing Belmark and Celastrus angulatus |
Country Status (1)
| Country | Link |
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| CN (1) | CN107517997A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108308200A (en) * | 2018-03-01 | 2018-07-24 | 金华市胤宏农业科技有限公司 | A kind of corn seedling insecticide |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106417349A (en) * | 2016-09-12 | 2017-02-22 | 广西南宁乐蕊生物科技有限责任公司 | Insecticidal composition containing bifenthrin and celangulin |
-
2017
- 2017-10-17 CN CN201710967506.3A patent/CN107517997A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106417349A (en) * | 2016-09-12 | 2017-02-22 | 广西南宁乐蕊生物科技有限责任公司 | Insecticidal composition containing bifenthrin and celangulin |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108308200A (en) * | 2018-03-01 | 2018-07-24 | 金华市胤宏农业科技有限公司 | A kind of corn seedling insecticide |
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Application publication date: 20171229 |
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