CN107513219A - A kind of preparation method of easy dyeing plastic master batch - Google Patents
A kind of preparation method of easy dyeing plastic master batch Download PDFInfo
- Publication number
- CN107513219A CN107513219A CN201710849938.4A CN201710849938A CN107513219A CN 107513219 A CN107513219 A CN 107513219A CN 201710849938 A CN201710849938 A CN 201710849938A CN 107513219 A CN107513219 A CN 107513219A
- Authority
- CN
- China
- Prior art keywords
- master batch
- preparation
- parts
- plastic master
- easy dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/223—Packed additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K2003/023—Silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coloring (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The present invention discloses a kind of preparation method of easy dyeing plastic master batch, including following operating procedure：（1）After melamine cyanurate, citric acid stearoyl monoglyceride, sodium vanadate are mixed, after the 25min of ball-milling treatment 20,5 10 parts of nano silica fumes are added thereto, and after continuing the 40min of ball-milling treatment 30, master batch additive is made；（2）After acrylic resin, glass fiber yarn, coupling agent, antioxidant are mixed, continuation adds step thereto（1）Gained master batch additive, add into extruder, extrusion, be granulated, finished product after being well mixed.The preparation method of easy dyeing plastic master batch provided by the invention, it is simple to operate, cost is cheap, obtained plastic master batch, after being made into finished product, every excellent in mechanical performance, especially in its external coating coating, operation difficulty is low, and the active component in coating is big in the cohesive force of frosting, will not occur the phenomenon to fade easily.
Description
Technical field
The invention belongs to plastics preparing technical field, and in particular to a kind of preparation method of easy dyeing plastic master batch.
Background technology
Coloring plastic be modern plastics processing in an important ring, there are about according to statistics in all plastic products 80% with
On be by coloring.Plastic products coloring can be divided into intrinsic color and the class of extrinsic color two, and intrinsic color is the dispensing before plastic processing
When add colouring agent, make have uniform color and luster inside and outside product；Extrinsic color is using printing, gold stamping, plating, spraying, applique, vacuum
The methods of evaporation, colours in frosting.Wherein in extrinsic color technique, most widely used, most convenient is directly spraying side
Method, but in the prior art, due to the limitation of plastic master batch performance, cause to carry out spray colouration to plastics, dyestuff is in plastic table
The adhesive force in face is relatively low, and the phenomenon to fade easily occur in plastics.
The content of the invention
In order to solve the above-mentioned technical problem, the present invention provides a kind of preparation method of easy dyeing plastic master batch.
The present invention is achieved by the following technical solutions.
A kind of preparation method of easy dyeing plastic master batch, including following operating procedure：
（1）By weight, by 18-22 parts melamine cyanurate, 11-16 part citric acid stearoyls monoglyceride, 1-2 parts
After sodium vanadate mixing, after ball-milling treatment 20-25min, 5-10 part nano silica fumes are added thereto, continue ball-milling treatment 30-
After 40min, master batch additive is made；
（2）By weight, by 36-44 parts acrylic resin, 11-17 parts glass fiber yarn, 2-4 parts coupling agent, 1-2 part antioxygens
After agent mixing, continuation adds step thereto（1）Gained master batch additive, added after being well mixed into extruder, extrude, make
Grain, finished product.
Specifically, the purity of above-mentioned melamine cyanurate is 99.5%, and Average Particle Diameters are 50 μm.
Specifically, above-mentioned steps（1）The content of silicon is 99.9% in middle nano silica fume, Average Particle Diameters 40nm.
Specifically, above-mentioned steps（2）In, coupling agent is aluminium titanium composite coupler, and above-mentioned antioxidant is phenolic antioxidant.
Specifically, above-mentioned steps（2）In, extruder extrusion temperature is 128-135 DEG C.
Technical scheme more than, the beneficial effects of the invention are as follows：
The preparation method of easy dyeing plastic master batch provided by the invention, simple to operate, cost is cheap, obtained plastic master batch, will
After finished product is made in it, every excellent in mechanical performance, especially in its external coating coating, operation difficulty is low, the activity in coating
Composition is big in the cohesive force of frosting, will not occur the phenomenon to fade easily.Wherein, master batch additive provided by the invention,
For nano silica fume after organically-modified, its surface is linked with substantial amounts of organic group, can effectively lift the surface of masterbatch master batch
Can, lift the effect of dyeing, while melamine cyanurate can also after plastic products are made in reinforced plastics master batch, finished product it is each
Item excellent in mechanical performance, while after citric acid stearoyl monoglyceride and glass fiber yarn synergy, moreover it is possible to reduce plastics system
The cohesive force of product surface and oil contaminant, reduces the adhesion of greasy dirt, and then improves the effect of dyeing.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, following examples are carried out to the present invention
It is further described.It should be appreciated that specific embodiment party example described herein is not used to limit only to explain the present invention
The fixed present invention.
Embodiment 1
A kind of preparation method of easy dyeing plastic master batch, including following operating procedure：
（1）By weight, by 18 parts of melamine cyanurates, 11 parts of citric acid stearoyl monoglycerides, 1 part of sodium vanadate
After mixing, after ball-milling treatment 20min, 5 parts of nano silica fumes are added thereto, and after continuing ball-milling treatment 30min, master batch addition is made
Agent；
（2）By weight, after 36 parts of acrylic resins, 11 parts of glass fiber yarns, 2 parts of coupling agents, 1 part of antioxidant being mixed,
Continuation adds step thereto（1）Gained master batch additive, added after being well mixed into extruder, extrusion, be granulated, be made into
Product.
Specifically, the purity of above-mentioned melamine cyanurate is 99.5%, and Average Particle Diameters are 50 μm.
Specifically, above-mentioned steps（1）The content of silicon is 99.9% in middle nano silica fume, Average Particle Diameters 40nm.
Specifically, above-mentioned steps（2）In, coupling agent is aluminium titanium composite coupler, and above-mentioned antioxidant is phenolic antioxidant.
Specifically, above-mentioned steps（2）In, extruder extrusion temperature is 128 DEG C.
Embodiment 2
A kind of preparation method of easy dyeing plastic master batch, including following operating procedure：
（1）By weight, by 20 parts of melamine cyanurates, 13 parts of citric acid stearoyl monoglycerides, 1 part of sodium vanadate
After mixing, after ball-milling treatment 23min, 8 parts of nano silica fumes are added thereto, and after continuing ball-milling treatment 35min, master batch addition is made
Agent；
（2）By weight, after 40 parts of acrylic resins, 13 parts of glass fiber yarns, 3 parts of coupling agents, 1 part of antioxidant being mixed,
Continuation adds step thereto（1）Gained master batch additive, added after being well mixed into extruder, extrusion, be granulated, be made into
Product.
Specifically, the purity of above-mentioned melamine cyanurate is 99.5%, and Average Particle Diameters are 50 μm.
Specifically, above-mentioned steps（1）The content of silicon is 99.9% in middle nano silica fume, Average Particle Diameters 40nm.
Specifically, above-mentioned steps（2）In, coupling agent is aluminium titanium composite coupler, and above-mentioned antioxidant is phenolic antioxidant.
Specifically, above-mentioned steps（2）In, extruder extrusion temperature is 132 DEG C.
Embodiment 3
A kind of preparation method of easy dyeing plastic master batch, including following operating procedure：
（1）By weight, by 22 parts of melamine cyanurates, 16 parts of citric acid stearoyl monoglycerides, 2 parts of sodium vanadates
After mixing, after ball-milling treatment 25min, 10 parts of nano silica fumes are added thereto, after continuing ball-milling treatment 40min, obtained master batch adds
Add agent；
（2）By weight, after 44 parts of acrylic resins, 17 parts of glass fiber yarns, 4 parts of coupling agents, 2 parts of antioxidant being mixed,
Continuation adds step thereto（1）Gained master batch additive, added after being well mixed into extruder, extrusion, be granulated, be made into
Product.
Specifically, the purity of above-mentioned melamine cyanurate is 99.5%, and Average Particle Diameters are 50 μm.
Specifically, above-mentioned steps（1）The content of silicon is 99.9% in middle nano silica fume, Average Particle Diameters 40nm.
Specifically, above-mentioned steps（2）In, coupling agent is aluminium titanium composite coupler, and above-mentioned antioxidant is phenolic antioxidant.
Specifically, above-mentioned steps（2）In, extruder extrusion temperature is 135 DEG C.
Comparative example 1
Do not add step（1）In master batch additive, remaining operating procedure is identical with embodiment 1.
Plastic master batch is made with the method for each embodiment and comparative example respectively, then using identical technique by obtained modeling
Finished product is made in material master batch, is varnished with lacquer in finished surface, and after paint is dried, plastic products are placed on to 65 DEG C of hot blast environment
In, after hot blast is handled 72 hours, whether have the phenomenon that comes off, result of the test is as shown in table 1 if checking the paint of surface of plastic products：
The coating color throw of table 1
| Project | Coating color throw |
| Embodiment 1 | Without depainting situation |
| Embodiment 2 | Without depainting situation |
| Embodiment 3 | Without depainting situation |
| Comparative example | Depainting is more serious |
As shown in Table 1, plastic master batch produced by the present invention, after plastic products are made, paint colouring significant effect, it is less prone to de-
The phenomenon of paint.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Protect scope.
Claims (5)
1. a kind of preparation method of easy dyeing plastic master batch, it is characterised in that including following operating procedure：
（1）By weight, by 18-22 parts melamine cyanurate, 11-16 part citric acid stearoyls monoglyceride, 1-2 parts
After sodium vanadate mixing, after ball-milling treatment 20-25min, 5-10 part nano silica fumes are added thereto, continue ball-milling treatment 30-
After 40min, master batch additive is made；
（2）By weight, by 36-44 parts acrylic resin, 11-17 parts glass fiber yarn, 2-4 parts coupling agent, 1-2 part antioxygens
After agent mixing, continuation adds step thereto（1）Gained master batch additive, added after being well mixed into extruder, extrude, make
Grain, finished product.
2. according to a kind of preparation method of easy dyeing plastic master batch described in claim 1, it is characterised in that above-mentioned melamine
The purity of amine cyanurate is 99.5%, and Average Particle Diameters are 50 μm.
3. according to a kind of preparation method of easy dyeing plastic master batch described in claim 1, it is characterised in that above-mentioned steps
（1）The content of silicon is 99.9% in middle nano silica fume, Average Particle Diameters 40nm.
4. according to a kind of preparation method of easy dyeing plastic master batch described in claim 1, it is characterised in that above-mentioned steps
（2）In, coupling agent is aluminium titanium composite coupler, and above-mentioned antioxidant is phenolic antioxidant.
5. according to a kind of preparation method of easy dyeing plastic master batch described in claim 1, it is characterised in that above-mentioned steps
（2）In, extruder extrusion temperature is 128-135 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710849938.4A CN107513219A (en) | 2017-09-20 | 2017-09-20 | A kind of preparation method of easy dyeing plastic master batch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710849938.4A CN107513219A (en) | 2017-09-20 | 2017-09-20 | A kind of preparation method of easy dyeing plastic master batch |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107513219A true CN107513219A (en) | 2017-12-26 |
Family
ID=60725611
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710849938.4A Pending CN107513219A (en) | 2017-09-20 | 2017-09-20 | A kind of preparation method of easy dyeing plastic master batch |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107513219A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752807A (en) * | 2018-06-26 | 2018-11-06 | 全椒祥瑞塑胶有限公司 | A kind of polyvinyl chloride resin particle of easy dyeing |
| CN108930073A (en) * | 2018-08-03 | 2018-12-04 | 巢湖市渔郎渔具有限公司 | A kind of preparation method of fresh water area resistant purse seine |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717548A (en) * | 2009-11-06 | 2010-06-02 | 金发科技股份有限公司 | High-polarity polypropylene material and application thereof as inner and outer decorative parts of automobile |
| CN103590129A (en) * | 2013-10-17 | 2014-02-19 | 惠阳中核辉新化纤有限公司 | Polypropylene fiber easy to dye and preparation method thereof |
| CN105440438A (en) * | 2015-12-11 | 2016-03-30 | 合肥会通新材料有限公司 | Polypropylene composite material with high paint adhesion and preparation method thereof |
| CN105623095A (en) * | 2016-02-25 | 2016-06-01 | 浙江誉隆科技发展有限公司 | Modified polypropylene material for electric vehicle |
| CN106750951A (en) * | 2016-12-26 | 2017-05-31 | 重庆普利特新材料有限公司 | It is a kind of to exempt from sprayable PP composite material of flame treatment and preparation method thereof |
-
2017
- 2017-09-20 CN CN201710849938.4A patent/CN107513219A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717548A (en) * | 2009-11-06 | 2010-06-02 | 金发科技股份有限公司 | High-polarity polypropylene material and application thereof as inner and outer decorative parts of automobile |
| CN103590129A (en) * | 2013-10-17 | 2014-02-19 | 惠阳中核辉新化纤有限公司 | Polypropylene fiber easy to dye and preparation method thereof |
| CN105440438A (en) * | 2015-12-11 | 2016-03-30 | 合肥会通新材料有限公司 | Polypropylene composite material with high paint adhesion and preparation method thereof |
| CN105623095A (en) * | 2016-02-25 | 2016-06-01 | 浙江誉隆科技发展有限公司 | Modified polypropylene material for electric vehicle |
| CN106750951A (en) * | 2016-12-26 | 2017-05-31 | 重庆普利特新材料有限公司 | It is a kind of to exempt from sprayable PP composite material of flame treatment and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752807A (en) * | 2018-06-26 | 2018-11-06 | 全椒祥瑞塑胶有限公司 | A kind of polyvinyl chloride resin particle of easy dyeing |
| CN108930073A (en) * | 2018-08-03 | 2018-12-04 | 巢湖市渔郎渔具有限公司 | A kind of preparation method of fresh water area resistant purse seine |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101985506B (en) | White master batch for high impact polystyrene (HIPS) and preparation method thereof | |
| CN107513219A (en) | A kind of preparation method of easy dyeing plastic master batch | |
| CN112024334A (en) | Open spraying method for water-based wood paint | |
| CN104530565A (en) | Antibacterial spraying-free polypropylene composite material as well as preparation method and application thereof | |
| CN102295846A (en) | Modified titanium white and preparation method thereof as well as automobile primer paint | |
| CN104371476A (en) | Flame-retardant and moisture-proof coating for solar cells and preparation method of coating | |
| CN109468025A (en) | Electrostatic spraying UV finishing coat and preparation method thereof | |
| CN113388139A (en) | Silicon-free PET release film and processing method thereof | |
| CN111187559B (en) | Curing agent based on hydantoin resin and preparation method and application thereof | |
| CN103666214B (en) | A kind of Water soluble polyester resin varnish and preparation method thereof | |
| CN114395359A (en) | High-strength water-based polyurethane adhesive and preparation method thereof | |
| CN110341281A (en) | A kind of copolymerization dual cure decorative panel and its preparation process | |
| CN107118608B (en) | Leveling agent for preparing ultrathin coating of alkyd resin powder coating | |
| CN110791135A (en) | Attapulgite mixture and preparation method thereof | |
| CN103351802A (en) | Ultraviolet light curing colored paint | |
| CN110626046B (en) | Manufacturing process of positioning transfer paper with embossment effect | |
| CN103665966A (en) | Water-borne aluminum sol coating | |
| CN103865356A (en) | Mould pressing resin paint and preparation method thereof as well as painting method of mould pressing resin paint | |
| CN104962160A (en) | Ultraviolet-resistant paint composition for plastics | |
| CN106867303A (en) | A kind of coating process of coating paint and its injection blank | |
| CN108178954A (en) | For the high-performance coating of polypropylene cat food packaging bag | |
| CN107902916A (en) | A kind of preparation method of self-cleaning glass | |
| CN108940794B (en) | Metal surface treatment process and metal product thereof | |
| CN106609069A (en) | Glass heat insulation coating | |
| CN107602896A (en) | A kind of coating process of plastic products |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171226 |
|
| RJ01 | Rejection of invention patent application after publication |