CN107502043A - A kind of novel environment-friendly water-based UV ink and preparation method thereof - Google Patents
A kind of novel environment-friendly water-based UV ink and preparation method thereof Download PDFInfo
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- CN107502043A CN107502043A CN201710892955.6A CN201710892955A CN107502043A CN 107502043 A CN107502043 A CN 107502043A CN 201710892955 A CN201710892955 A CN 201710892955A CN 107502043 A CN107502043 A CN 107502043A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to printing-ink technical field, specially novel environment-friendly water-based UV ink and preparation method thereof.Photosensitive resin of the present invention is compounded and formed by a certain percentage by epoxy acrylate, urethane acrylate and polyester acrylate, as resin link stuff, it is fast with curing rate, so as to reduce the energy resource consumption needed for photocuring, energy consumption during water-based UV ink settings is reduced, while the cost of water-based UV ink can be reduced；Adhesive force of the water-based UV ink to non-absorbent materials such as metal, plastics can be improved, so as to extend the printing printability scope of water-based UV ink.Using hydrogen-capture-type light initiator, because of its generation free radical that can be reacted with amine substance, so that printing process safety and environmental friendliness, nontoxic.The novel environment-friendly water-based UV ink cost of the present invention is low, energy consumption is smaller when drying, washing resistance performance and good luster.
Description
Technical field
The present invention relates to printing-ink technical field, more particularly to a kind of novel environment-friendly water-based UV ink, and this kind new
The preparation method of type ring water-retaining property UV ink.
Background technology
At present, many extraordinary effects in printing all need to use water-based UV ink, therefore water-based UV ink is widely used in
Various mode of printings, such as apply in silk-screen printing, flexo and offset printing.Water-based UV ink has the characteristic that Speediness link line is dried,
And this characteristic allows water-based UV ink to be imprinted on non-paper stock, PVC, PET, the synthetic paper of such as plastics, and because
Can be dried for it with Speediness link line to reprocess or turn-over print again all can be without waiting for, therefore can be not required to dust when drying.Separately
Outside, water-based UV ink can also have higher glossiness and rub resistance even if being imprinted on paper.The feature of environmental protection of water-based UV ink and
High-quality printing makes it extensively using food, medicine, beverage, tobacco and wine and printed etc. with the commodity packaging of human contact.
But existing water-based UV ink still suffers from following deficiency, it is necessary to further improve and optimize：The cost of water-based UV ink is high；
Gloss is poor, needs further to be improved；Washing fastness is poor；Energy resource consumption is big during water-based UV ink settings；Water-based UV ink makes
The pernicious gas that can be volatilized during with dilution, can damage to human body skin；The printing adaptability and adhesive force of water-based UV ink
Difference, need further to be improved.
The content of the invention
The present invention is high for existing water-based UV ink cost, using the pernicious gas that can be volatilized when diluting, energy consumption when drying
Greatly, and the problem of printing adaptability and poor adhesive force, there is provided a kind of cost is relatively low, energy consumption is smaller when drying, washing resistance performance
And the preferably novel environment-friendly water-based UV ink of gloss, and the preparation method of this kind of novel environment-friendly water-based UV ink.
To achieve the above object, the present invention uses following technical scheme.
A kind of novel environment-friendly water-based UV ink, include each component of following parts by weight：
Photosensitive resin 50-70 parts,
Amine substance 5-15 parts,
Light trigger 1-3 parts,
Aqueous pigment 5-15 parts,
Cosolvent 7-21 parts,
Water 7-21 parts,
Auxiliary agent 5-10 parts.
Preferably, the photosensitive resin is by epoxy acrylic resin, polyurethane acrylic resin and polyester acrylate resin
Compounding forms.
It is furthermore preferred that epoxy acrylic resin, polyurethane acrylic resin and polyester acrylic tree in the photosensitive resin
The mass ratio of fat is 35-45:15-25:35-45.
Still more preferably, epoxy acrylic resin, polyurethane acrylic resin and polyester third in the photosensitive resin
The mass ratio of olefin(e) acid resin is 40:20:40.
It is furthermore preferred that the epoxy acrylic resin is selected from SA modified epoxy acrylic ester (HL-160), the tertiary fourths of 4-
At least one of butylcyclohexyl acrylate (TBCH), bisphenol type epoxy diacrylate (SK8323).
It is furthermore preferred that the polyurethane acrylic resin is the aliphatic polyurethane acrylic resin of 3-5 degrees of functionality, viscosity
For 1000-4000mPas/25 DEG C.
It is furthermore preferred that the average functionality of the polyester acrylate resin is 3-5, viscosity 5000-12000mPas/25
℃。
The synthesis of epoxy acrylic resin：First epoxy resin is esterified to obtain epoxy acrylate (EA) using acrylic acid,
Hydrophilic radical is introduced using the hydroxyl in epoxy acrylate and anhydride reaction (such as cis-butenedioic anhydride, trimellitic anhydride), then with organic
Amine neutralizes, and obtains waterborne epoxy acrylate resin (EB).
The synthesis of polyurethane acrylic resin：Using diisocyanate as raw material, polyester or polyether Glycols are soft segment chain extension
Agent, carboxylic dihydric alcohol (such as dihydromethyl propionic acid) is hydrophilic chain extender, and crylic acid hydroxy ester is end-capping reagent, is contracted by multistep
Poly- reaction is made curable urethane acrylate, then with ammonia or organic amine and forming salt, obtains water-based UV polyurethane third
Olefin(e) acid ester (WPUA).
The synthesis of polyester acrylate resin：The part carboxylic first introduced by acrylic acid and various acrylic ester polymerizations, acrylic acid
The epoxy reaction of the hydroxyl or GMA of base and hydroxy-ethyl acrylate, so as to introduce with photoactive
Carbon-carbon double bond, then carboxyl salinization is obtained with organic amine.
Preferably, the amine substance is triethanolamine.Triethanolamine safety and environmental protection is nontoxic, can make not producing in production and appoint
What pungent smell.
Preferably, the light trigger is hydrogen-capture-type light initiator.Hydrogen-capture-type light initiator needs and the change containing active hydrogen
Compound (referred to as aided initiating, amine substance described above, triethanolamine component) be engaged, generated by hydrogen abstraction reaction free
Base.
Preferably, the light trigger is selected from benzophenone and/or aroyl phosphine oxide.
Preferably, the auxiliary agent includes each component of following parts by weight：Defoamer 1-2 parts, levelling agent 1-2 parts, wetting agent
1-2 parts, light stabilizer 2-4 parts；The auxiliary agent also contains pH stabilizers, and it is 8.0-9.5 to control the pH of auxiliary agent by pH stabilizers.
Preferably, the dosage of pH stabilizers is 1-2 parts in the auxiliary agent.
Preferably, the cosolvent is absolute ethyl alcohol.
Preferably, the aqueous pigment is aqueous alkalescence pigment.
Preferably, the water is deionized water.
The preparation method of novel environment-friendly water-based UV ink described above, comprises the following steps：
It is S1, photosensitive resin, triethanolamine, pigment, cosolvent and water is admixed together and stir；
Mixture is mixed and grinds 1.5-3h by S2 with part of auxiliary；
Preferably, mixture and part of auxiliary are added to ball milling in single tank planetary high-energy ball mill；It is furthermore preferred that ball
Consume time as 2h, ball milling speed 1000r/min.
S3 adds light trigger and remaining auxiliary agent into mixture and stirred, and then standing mixt and filters,
Mixture after must filtering；
S4 adds thickener and/or water into mixture after filtering, after regulation filtering the viscosity of mixture to required viscosity,
Environment-friendly water-based UV ink is made.
Compared with prior art, the beneficial effects of the invention are as follows：Photosensitive resin of the present invention passes through epoxy acrylic
Ester, urethane acrylate and polyester acrylate compound by a certain percentage to be formed, and as resin link stuff, has curing rate
It hurry up, so as to reduce the energy resource consumption needed for photocuring, reduce energy consumption during water-based UV ink settings, while water-based UV can be reduced
The cost of ink；The glossiness of water-based UV ink can be improved by urethane acrylate；Can by polyester acrylate
Reduce the viscosity of whole system, improve pliability, and price is also relatively cheap, can further reduce water-based UV ink into
This.Using photosensitive resin of the present invention, attachment of the water-based UV ink to non-absorbent materials such as metal, plastics can be improved
Power, so as to extend the printing printability scope of water-based UV ink.Using hydrogen-capture-type light initiator, because it can send out with amine substance
Raw reaction generation free radical, so that printing process safety and environmental friendliness, nontoxic.The novel environment-friendly water-based UV ink of the present invention
Cost is low, energy consumption is smaller when drying, washing resistance performance and good luster.
Embodiment
In order to more fully understand the technology contents of the present invention, with reference to specific embodiment to technical scheme
It is described further and illustrates.
In following examples, polyurethane acrylic resin be 3-5 degrees of functionality aliphatic polyurethane acrylic resin, viscosity
For 1000-4000mPas/25 DEG C；The average functionality of polyester acrylate resin is 3-5, viscosity 5000-12000mPas/
25℃；Epoxy acrylic resin is selected from SA modified epoxy acrylic ester (HL-160), 4- tert-butylcyclohexyl acrylate
(TBCH), at least one of bisphenol type epoxy diacrylate (SK8323)；Aqueous alkalescence pigment selects phthalocyanine blue b
(PB15:0)；Aroyl phosphine oxide selects (2,3,6- trimethylbenzenes from (2,3,6- front threes benzoyl)-diphenyl phosphine oxide
Acyl)-diphenyl phosphine oxide.
The auxiliary agent used in embodiment 1-11 is (parts by weight) composed of the following components：1 part of defoamer, 1 part of levelling agent, wetting
1 part of agent, 2 parts of light stabilizer；PH stabilizers are appropriate, and the pH for making auxiliary agent is 9.
Embodiment 1-11
Embodiment 1-11 provides a kind of preparation method of novel environment-friendly water-based UV ink, the novel environment-friendly water-based UV respectively
Ink each component and dosage are as shown in table 1 below.
The specific preparation process of novel environment-friendly water-based UV ink is as follows：
(1) it is photosensitive resin, triethanolamine, pigment, cosolvent and water is admixed together and stir.
(2) mixture and part of auxiliary are added to ball milling in single tank planetary high-energy ball mill；Ball milling
Time is 2h, ball milling speed 1000r/min.
(3) light trigger and remaining auxiliary agent are added into mixture and is stirred, then standing mixt and is filtered,
Mixture after must filtering.
(4) thickener and/or water are added into mixture after filtering, the viscosity of mixture is to required viscosity after regulation filtering
(viscosity (25 DEG C) of the novel environment-friendly water-based UV ink in embodiment is 9500cp), environment-friendly water-based UV ink is made.
The each component and dosage (parts by weight) of novel environment-friendly water-based UV ink are formed in the embodiment 1-11 of table 1
| Embodiment | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 |
| Epoxy acrylic resin | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 17 | 23 |
| Polyurethane acrylic resin | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 12 | 8 |
| Polyester acrylate resin | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 21 | 19 |
| Triethanolamine | 8 | 5 | 7 | 11 | 6 | 11 | 15 | 5 | 12 | 12 | 12 |
| Benzophenone | 1 | 1 | 3 | 1 | 1 | 1 | 3 | 2 | 2 | 2 | |
| Aroyl phosphine oxide | 1 | 1 | |||||||||
| Aqueous alkalescence pigment | 7 | 5 | 8 | 5 | 5 | 5 | 10 | 15 | 5 | 5 | 5 |
| Absolute ethyl alcohol | 12 | 7 | 8 | 21 | 15 | 7 | 10 | 10 | 12 | 12 | 12 |
| Deionized water | 15 | 7 | 8 | 7 | 10 | 21 | 7 | 10 | 12 | 12 | 12 |
| Auxiliary agent | 7 | 5 | 6 | 5 | 10 | 5 | 5 | 7 | 7 | 7 | 7 |
Comparative example 1-6
Comparative example 1-6 provides a kind of preparation method of water-based UV ink, the water-based UV ink each component and dosage respectively
It is as shown in table 2 below.The preparation process of the water-based UV ink is consistent with embodiment 9.
The each component and dosage (parts by weight) of water-based UV ink are formed in the comparative example 1-6 of table 2
| Comparative example | 1 | 2 | 3 | 4 | 5 | 6 |
| Epoxy acrylic resin | 32 | 16 | 16 | 16 | 19 | 25 |
| Polyurethane acrylic resin | 16 | 8 | 17 | 11 | 12 | 12 |
| Polyester acrylate resin | 32 | 16 | 17 | 23 | 19 | 13 |
| Triethanolamine | 12 | 12 | 12 | 12 | 12 | 12 |
| Benzophenone | 2 | 2 | 2 | 2 | 2 | 2 |
| Aqueous alkalescence pigment | 5 | 5 | 5 | 5 | 5 | 5 |
| Absolute ethyl alcohol | 12 | 12 | 12 | 12 | 12 | 12 |
| Deionized water | 12 | 12 | 12 | 12 | 12 | 12 |
| Auxiliary agent | 7 | 7 | 7 | 7 | 7 | 7 |
Test the performance of UV ink prepared by above-described embodiment 1-11 and comparative example 1-6 respectively, including it is curing rate, flexible
Property (being represented with ink cracking situation), the adhesive force on non-adsorbed material, glossiness and washing resistance performance (use resistance to acids and bases table
Show).Inspection method is with reference to as follows：
1. determine attachment fastness of the ink to glass according to GB/T 13217.7-2009；
2. the glossiness of ink is determined according to GB/T 13217.2-2009.
The performance test results of UV ink prepared by embodiment 1-11 and comparative example 1-6 are as shown in following table 3-5.
The performance test results of UV ink prepared by the embodiment 1-6 of table 3
The performance test results of UV ink prepared by the embodiment 7-11 of table 4
The performance test results of UV ink prepared by the comparative example 1-6 of table 5
The technology contents described above that the present invention is only further illustrated with embodiment, in order to which reader is easier to understand,
But embodiments of the present invention are not represented and are only limitted to this, any technology done according to the present invention extends or recreation, is sent out by this
Bright protection.
Claims (10)
1. a kind of novel environment-friendly water-based UV ink, it is characterised in that include each component of following parts by weight：
Photosensitive resin 50-70 parts,
Amine substance 5-15 parts,
Light trigger 1-3 parts,
Aqueous pigment 5-15 parts,
Cosolvent 7-21 parts,
Water 7-21 parts,
Auxiliary agent 5-10 parts.
2. a kind of novel environment-friendly water-based UV ink according to claim 1, it is characterised in that the photosensitive resin is by epoxy third
Olefin(e) acid resin, polyurethane acrylic resin and polyester acrylate resin compounding form.
A kind of 3. novel environment-friendly water-based UV ink according to claim 2, it is characterised in that the epoxy acrylic resin choosing
From in SA modified epoxy acrylic ester, 4- tert-butylcyclohexyls acrylate, bisphenol type epoxy diacrylate at least
It is a kind of；The polyurethane acrylic resin be degree of functionality be 3-5 aliphatic polyurethane acrylic resin, viscosity 1000-
4000mPa·s/25℃；The average functionality of the polyester acrylate resin is 3-5, viscosity 5000-12000mPas/25
℃。
A kind of 4. novel environment-friendly water-based UV ink according to claim 3, it is characterised in that epoxy third in the photosensitive resin
The mass ratio of olefin(e) acid resin, polyurethane acrylic resin and polyester acrylate resin is 35-45:15-25:35-45.
A kind of 5. novel environment-friendly water-based UV ink according to claim 4, it is characterised in that epoxy third in the photosensitive resin
The mass ratio of olefin(e) acid resin, polyurethane acrylic resin and polyester acrylate resin is 40:20:40.
6. a kind of novel environment-friendly water-based UV ink according to claim 1, it is characterised in that the amine substance is three ethanol
Amine.
7. a kind of novel environment-friendly water-based UV ink according to claim 1, it is characterised in that the light trigger is hydrogen-abstraction
Light trigger.
8. a kind of novel environment-friendly water-based UV ink according to claim 7, it is characterised in that the light trigger is selected from hexichol
Base ketone and/or aroyl phosphine oxide.
9. a kind of novel environment-friendly water-based UV ink according to claim 1, it is characterised in that the auxiliary agent includes following weight
The each component of part：Defoamer 1-2 parts, levelling agent 1-2 parts, wetting agent 1-2 parts, light stabilizer 2-4 parts；The auxiliary agent also contains pH
Stabilizer, it is 8.0-9.5 to control the pH of auxiliary agent by pH stabilizers.
10. a kind of preparation method of novel environment-friendly water-based UV ink as claimed in claim 1, it is characterised in that including following step
Suddenly：
It is S1, photosensitive resin, triethanolamine, pigment, cosolvent and water is admixed together and stir；
Mixture is mixed and grinds 1.5-3h by S2 with part of auxiliary；
S3 adds light trigger and remaining auxiliary agent into mixture and stirred, and then standing mixt and filters, obtained
Mixture after filter；
S4 adds thickener and/or water into mixture after filtering, and the viscosity of mixture is made to required viscosity after regulation filtering
Environment-friendly water-based UV ink.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329748A (en) * | 2018-02-08 | 2018-07-27 | 广东苏比化工有限公司 | Aqueous polyurethane UV environmental protection offset inks and preparation method thereof |
| CN108330731A (en) * | 2018-02-05 | 2018-07-27 | 深圳市力嘉创意文化产业发展有限公司 | Uv gloss oil and its preparation method and application |
| CN108912815A (en) * | 2018-09-10 | 2018-11-30 | 东莞市美吉高分子材料有限公司 | A kind of novel environment friendly LED-UV water transfer plastic glue ink and its production method |
| CN111518432A (en) * | 2020-06-05 | 2020-08-11 | 苏州市博来特油墨有限公司 | High-temperature-resistant UV (ultraviolet) curing printing ink |
| CN111560233A (en) * | 2020-05-18 | 2020-08-21 | 杭州华圩新材料科技有限公司 | High-performance low-toxicity medical UV adhesive and preparation method thereof |
| CN116478573A (en) * | 2023-05-26 | 2023-07-25 | 广州亦盛环保科技有限公司 | Low-residue metal middle frame protection printing ink |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108330731A (en) * | 2018-02-05 | 2018-07-27 | 深圳市力嘉创意文化产业发展有限公司 | Uv gloss oil and its preparation method and application |
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| CN108912815A (en) * | 2018-09-10 | 2018-11-30 | 东莞市美吉高分子材料有限公司 | A kind of novel environment friendly LED-UV water transfer plastic glue ink and its production method |
| CN111560233A (en) * | 2020-05-18 | 2020-08-21 | 杭州华圩新材料科技有限公司 | High-performance low-toxicity medical UV adhesive and preparation method thereof |
| CN111560233B (en) * | 2020-05-18 | 2022-03-22 | 杭州华圩新材料科技有限公司 | High-performance low-toxicity medical UV adhesive and preparation method thereof |
| CN111518432A (en) * | 2020-06-05 | 2020-08-11 | 苏州市博来特油墨有限公司 | High-temperature-resistant UV (ultraviolet) curing printing ink |
| CN116478573A (en) * | 2023-05-26 | 2023-07-25 | 广州亦盛环保科技有限公司 | Low-residue metal middle frame protection printing ink |
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Application publication date: 20171222 |