CN104672990A - Water-based visible ultraviolet excited ink and preparation method thereof - Google Patents
Water-based visible ultraviolet excited ink and preparation method thereof Download PDFInfo
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- CN104672990A CN104672990A CN201510100049.9A CN201510100049A CN104672990A CN 104672990 A CN104672990 A CN 104672990A CN 201510100049 A CN201510100049 A CN 201510100049A CN 104672990 A CN104672990 A CN 104672990A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to ink, in particular to water-based visible ultraviolet excited ink and a preparation method thereof. The ink is prepared from raw materials in percentage by mass as follows: 32%-37% of a pigment, 41%-45% of an emulsion vehicle, 8%-10% of an alcohol solvent, 0.4%-0.6% of a pH regulator, 3.0%-3.2% of a leveling agent, 0.1%-0.2% of a photosensitizer, 0.2%-0.4% of an antifoaming agent and 9%-13% of deionized water. The anti-forgery ink is water-based ink meeting environmental requirements for emission of VOC (volatile organic compounds), meets FDA (Food and Drug Administration) hygiene requirements, and is environment-friendly and pollution-free; the ink has good printability and fluorescent effect due to addition of the photosensitizer, can be well applied to the anti-counterfeiting printing industry, and is good in fluorescent falsification prevention effect and low in cost; and meanwhile, the ink can be further applied to adhesive sticker type labels and various printing stocks for films for printing. The preparation method of the ink is scientific, reasonable and easy to implement.
Description
Technical field
The present invention relates to ink, be specifically related to the visible burst of ultraviolel ink of a kind of water-based and compound method thereof.
Background technology
For false proof enterprise, the use of anti-forgery ink is the most extensive.Anti-forgery ink is of a great variety, fluorescent ink because of its significant antifalse effect generally approve by industry.But for the meagre profit type mode of production of false proof enterprise, the most extraordinary anti-forgery ink in market is difficult to be promoted because of the price of its costliness, and under ordinary light, the rate of utilization of visible burst of ultraviolel anti-forgery ink is especially low.At present, flexographic printing anti-forgery ink all adopts the visible ink of first printing, and ink then will be excited to carry out double exposure, and obtain the combination of visible mass colour and burst of ultraviolel mass colour, process is numerous and diverse, and cost is high.
In addition, the use of burst of ultraviolel ink also has many restricted conditions in cost and printing process, based on above consideration, needs exploitation one badly and greatly reduces printing cost, reduce process complexity, the water-based burst of ultraviolel ink that antifalse effect is good.
Summary of the invention
The object of this invention is to provide that a kind of fluorescence falsification preventing is effective, cost is low, environment-friendly water-based visible burst of ultraviolel ink; The present invention provides its preparation method simultaneously.
The visible burst of ultraviolel ink of water-based of the present invention, be made up of the raw material of following mass percent:
Wherein, preferred technical scheme is as follows:
Described pigment is the mixture of chrome yellow and fluorescein mass ratio 1:1.1 ~ 1.3, the preferred Alexa Fluor 633 of fluorescein.
Described emulsion binder is aqueous acrylic emulsion resin R-20B.
Described alcoholic solvent is the ethanol of 95wt.%.
Described pH adjusting agent is 2-amino-2-methyl-1-propanol, preferred AMP-95.
Described flow agent is 3-butoxy-1-propyl alcohol.
Described defoamer is DF-908.
Described photosensitizer is trans stilbene.
The preparation method of the visible burst of ultraviolel ink of described water-based, comprises the following steps:
(1) alcoholic solvent, emulsion binder, deionized water are added in reactor, stir, insulation;
(2) again pigment, defoamer are added in reactor, be stirred to evenly, obtain work in-process mill base;
(3) adopt beveller that work in-process mill base is ground to mill base fineness and be less than 15 μm;
(4), after adding pH adjusting agent, flow agent and photosensitizer successively in the mill base after grinding, stir, filter and obtain the visible burst of ultraviolel ink of water-based.
Wherein, step (1) heat-retaining condition is incubated 7-8h at 45-50 DEG C.In step (3), fineness is less than 15 μm namely thinner than 15 μm.
Ink of the present invention produces and excites metachromatism under 254nm ultra violet lamp condition.
The present invention is the visible burst of ultraviolel ink of a kind of water-based, is made up of hybrid pigment, emulsion binder, alcoholic solvent, deionized water, pH adjusting agent, flow agent and defoamer.Generally the ink fluorescent effect of preparation is poor like this, and in order to obtain good fluorescent effect, the present invention introduces photosensitizer breakthroughly, makes ink have good printability and fluorescent effect.
Beneficial effect of the present invention is as follows:
Anti-forgery ink of the present invention is the water color ink that a kind of VOC discharge meets environmental requirement, meets the hygienic requirements of U.S. FDA, environment friendly and pollution-free; The present invention is by adding photosensitizer, and make ink have good printability and fluorescent effect, can be advantageously applied to anti-counterfeit printing industry, fluorescence falsification preventing is effective, cost is low; Also can be used in the stock of non-setting adhesive class label and various film for printing simultaneously.The preparation method of ink of the present invention is scientific and reasonable, be easy to realize.
Embodiment
Below in conjunction with embodiment, the present invention is described further.
Embodiment 1
The visible burst of ultraviolel ink of described water-based, be made up of the raw material of following mass percent:
The preparation method of above-mentioned water-based visible burst of ultraviolel ink is as follows:
(1) alcoholic solvent, emulsion binder, deionized water are added in reactor, stir, at 45 DEG C, be incubated 8h;
(2) again pigment, defoamer are added in reactor, be stirred to evenly, obtain work in-process mill base;
(3) adopt beveller that work in-process mill base is ground to mill base fineness and be less than 15 μm;
(4), after adding pH adjusting agent, flow agent and photosensitizer successively in the mill base after grinding, stir, filter and obtain the visible burst of ultraviolel ink of water-based.
Embodiment 2
The visible burst of ultraviolel ink of described water-based, be made up of the raw material of following mass percent:
The preparation method of above-mentioned water-based visible burst of ultraviolel ink is as follows:
(1) alcoholic solvent, emulsion binder, deionized water are added in reactor, stir, at 50 DEG C, be incubated 7h;
(2) again pigment, defoamer are added in reactor, be stirred to evenly, obtain work in-process mill base;
(3) adopt beveller that work in-process mill base is ground to mill base fineness and be less than 15 μm;
(4), after adding pH adjusting agent, flow agent and photosensitizer successively in the mill base after grinding, stir, filter and obtain the visible burst of ultraviolel ink of water-based.
Embodiment 3
The visible burst of ultraviolel ink of described water-based, be made up of the raw material of following mass percent:
The preparation method of the visible burst of ultraviolel ink of embodiment 3 water-based is as embodiment 1.
Embodiment 4
The visible burst of ultraviolel ink of described water-based, be made up of the raw material of following mass percent:
The preparation method of the visible burst of ultraviolel ink of embodiment 4 water-based is as embodiment 2.
Embodiment 5
The visible burst of ultraviolel ink of described water-based, be made up of the raw material of following mass percent:
The preparation method of the visible burst of ultraviolel ink of embodiment 5 water-based is as embodiment 1.
The ink of the different ratio obtained by embodiment 1-5, carries out sample prints, controls aberration range delta E≤1.5NBS, and scrape sample and detect, relative fluorescence brightness is in S=100 ± 10% scope.After testing, the ultraviolet absorption peak of the trans stilbene of photosensitizers is about 330-360nm, and make the emission wavelength generation blue-shifted phenomenon of fluorescein pigment Alexa Fluor 633, fluorescent effect is strengthened.
Claims (10)
1. the visible burst of ultraviolel ink of water-based, is characterized in that being made up of the raw material of following mass percent:
2. the visible burst of ultraviolel ink of water-based according to claim 1, is characterized in that: pigment is the mixture of chrome yellow and fluorescein mass ratio 1:1.1 ~ 1.3.
3. the visible burst of ultraviolel ink of water-based according to claim 2, is characterized in that: fluorescein is Alexa Fluor 633.
4. the visible burst of ultraviolel ink of water-based according to claim 1, is characterized in that: emulsion binder is aqueous acrylic emulsion resin R-20B.
5. the visible burst of ultraviolel ink of water-based according to claim 1, is characterized in that: alcoholic solvent is the ethanol of 95wt.%.
6. the visible burst of ultraviolel ink of water-based according to claim 1, is characterized in that: pH adjusting agent is 2-amino-2-methyl-1-propanol.
7. the visible burst of ultraviolel ink of water-based according to claim 1, is characterized in that: flow agent is 3-butoxy-1-propyl alcohol.
8. the visible burst of ultraviolel ink of water-based according to claim 1, is characterized in that: photosensitizer is trans stilbene.
9. a preparation method for the arbitrary described visible burst of ultraviolel ink of water-based of claim 1-8, is characterized in that comprising the following steps:
(1) alcoholic solvent, emulsion binder, deionized water are added in reactor, stir, insulation;
(2) again pigment, defoamer are added in reactor, be stirred to evenly, obtain work in-process mill base;
(3) adopt beveller that work in-process mill base is ground to mill base fineness and be less than 15 μm;
(4), after adding pH adjusting agent, flow agent and photosensitizer successively in the mill base after grinding, stir, filter and obtain the visible burst of ultraviolel ink of water-based.
10. the preparation method of the visible burst of ultraviolel ink of water-based according to claim 9, is characterized in that: step (1) heat-retaining condition is incubated 7-8h at 45-50 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510100049.9A CN104672990A (en) | 2015-03-06 | 2015-03-06 | Water-based visible ultraviolet excited ink and preparation method thereof |
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| CN201510100049.9A CN104672990A (en) | 2015-03-06 | 2015-03-06 | Water-based visible ultraviolet excited ink and preparation method thereof |
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| CN104672990A true CN104672990A (en) | 2015-06-03 |
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| CN201510100049.9A Pending CN104672990A (en) | 2015-03-06 | 2015-03-06 | Water-based visible ultraviolet excited ink and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368157A (en) * | 2015-12-28 | 2016-03-02 | 李栋军 | Fluorescent printing ink |
| CN105482549A (en) * | 2016-01-20 | 2016-04-13 | 江西统百利彩印包装股份有限公司 | Environment-friendly, sun-resistant and wear-proof water-based ink and preparation method thereof |
| CN106147399A (en) * | 2016-08-24 | 2016-11-23 | 苏州中亚油墨有限公司 | Photosensitive colour-changing anti-forgery ink |
| CN114350206A (en) * | 2022-01-05 | 2022-04-15 | 江苏友威科技股份有限公司 | Ultraviolet-excited starlight film printing ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012009364A (en) * | 2010-06-28 | 2012-01-12 | Jujo Chemical Kk | Uv-curing type ink for light guide plate and light guide plate |
| CN102791811A (en) * | 2010-02-26 | 2012-11-21 | 斑马株式会社 | W/O-type emulsion ink composition for writing utensil and writing utensil |
| CN103396699A (en) * | 2013-07-30 | 2013-11-20 | 江西核工业兴中科技有限公司 | Environment-friendly fluorescent enhanced anti-counterfeiting ink and preparation method thereof |
-
2015
- 2015-03-06 CN CN201510100049.9A patent/CN104672990A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102791811A (en) * | 2010-02-26 | 2012-11-21 | 斑马株式会社 | W/O-type emulsion ink composition for writing utensil and writing utensil |
| JP2012009364A (en) * | 2010-06-28 | 2012-01-12 | Jujo Chemical Kk | Uv-curing type ink for light guide plate and light guide plate |
| CN103396699A (en) * | 2013-07-30 | 2013-11-20 | 江西核工业兴中科技有限公司 | Environment-friendly fluorescent enhanced anti-counterfeiting ink and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368157A (en) * | 2015-12-28 | 2016-03-02 | 李栋军 | Fluorescent printing ink |
| CN105482549A (en) * | 2016-01-20 | 2016-04-13 | 江西统百利彩印包装股份有限公司 | Environment-friendly, sun-resistant and wear-proof water-based ink and preparation method thereof |
| CN106147399A (en) * | 2016-08-24 | 2016-11-23 | 苏州中亚油墨有限公司 | Photosensitive colour-changing anti-forgery ink |
| CN114350206A (en) * | 2022-01-05 | 2022-04-15 | 江苏友威科技股份有限公司 | Ultraviolet-excited starlight film printing ink |
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Application publication date: 20150603 |