CN107500664A - Unburned quincunx tourmaline light ceramic - Google Patents
Unburned quincunx tourmaline light ceramic Download PDFInfo
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- CN107500664A CN107500664A CN201710873178.0A CN201710873178A CN107500664A CN 107500664 A CN107500664 A CN 107500664A CN 201710873178 A CN201710873178 A CN 201710873178A CN 107500664 A CN107500664 A CN 107500664A
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- Prior art keywords
- tourmaline
- light ceramic
- unburned quincunx
- unburned
- quincunx
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G24/00—Growth substrates; Culture media; Apparatus or methods therefor
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Abstract
The invention discloses a kind of unburned quincunx tourmaline light ceramic, the main points of its technical scheme are, the dispensing of unburned quincunx tourmaline light ceramic is made up of the Concave-convex clay rod after schorl, black portland cement, acidifying, powdery attapulgite foaming agent, light magnesium oxide, aluminium silicate fiber peacekeeping hollow glass micropearl, and the dispensing of unburned quincunx tourmaline light ceramic is stirred after mixing, extruder grain, steam curing, steam drying, screening and is packaged as unburned quincunx tourmaline light ceramic.Unburned quincunx tourmaline light ceramic has the characteristics of black and shinny, appearance and modeling is attractive in appearance, lightweight intensity is good, specific surface area is big, bulk density is low, permeability is superior, porosity and water absorption rate are high;Unburned quincunx tourmaline light ceramic can ensure that growth and development of plants is good, and survival rate is high and the life-span is longer, and can greatly reduce the number of moisturizing, suitable for garden landscape engineering, home gardening and prepare soilless culture substrate.
Description
Technical field
The present invention relates to haydite, and in particular to a kind of unburned quincunx tourmaline light ceramic.
Background technology
Colored haydite on the market, it is to be granulated to be made after mixing using cement, fine sand and dyestuff, proportion and heap
Product density is all very big, and water absorption rate is smaller, it is impossible to the normal growth and development of plant is ensured, also without the work(for adsorbing and purifying air
Energy.
Tested through multiple sampling:Colored haydite average bulk density >=1200kg/m3 on the market, mean water absorption rate
≤ 20%.
The content of the invention
The purpose of the present invention is to overcome weak point in the prior art, there is provided a kind of unburned quincunx tourmaline Lightweight ceramic
Grain.
The dispensing of unburned quincunx tourmaline light ceramic is by the bumps after schorl, black portland cement, acidifying
Rod stone clay, powdery attapulgite foaming agent, light magnesium oxide, alumina silicate fibre, hollow glass micropearl composition.
The production method of unburned quincunx tourmaline light ceramic:The dispensing of unburned quincunx tourmaline light ceramic is entered
Row is stirred, extruder grain, steam curing, steam drying, is packed as unburned quincunx tourmaline Lightweight ceramic after screening
Grain.
Tourmaline is the natural minerals of multielement, and tourmaline main component has more than 10 kinds of magnesium, aluminium, iron, boron etc. to have human body
The trace element of profit, because it is a kind of special polarity crystalline solid of structure, itself can produce electron ion for a long time, and forever discharge
Negative aeroion and far infrared, the peculiar smell that the adsorbable paint of tourmaline, colloid, coating are sent, moreover it is possible to smoke is absorbed for a long time,
Schorl color is different and different with composition:Tourmaline rich in Fe is in black, the present invention from schorl granularity≤
0.42 millimeter.
Black portland cement is one kind in colored portland cement, and colored portland cement quality needs to meet " JC/
The standard of T 870-2012 colored portland cements ".
Attapulgite also known as palygorskite or Palygorskite, it is the clay pit of zeopan containing Shuifu County of a kind of layer of chain structure
Thing, Concave-convex clay rod have unique layer chain structure feature, and crystal is in needle-like, threadiness or fiber collection shape.Concave convex rod
Stone clay has good colloidal nature and the higher adsorption capacities such as unique scattered, high temperature resistant, salt resistance alkali.
Concave-convex clay rod after acidifying is made in the absorption property, percent of decolourization, catalysis for increasing substantially Concave-convex clay rod
With, specific surface area, porosity while, can increase acidifying after Concave-convex clay rod colloid viscosity and adjustment acidifying after it is recessed
Convex rod stone clay pH value.
Powdery attapulgite foaming agent has that foaming capacity is strong, coefficient of foaming is high, unit volume bubble production volume is big, foam outer membrane is tough
Property it is good non-breakable, foam stability is good, can not defoam for a long time, foam is fine and smooth, the hole size that is generated in medium uniformly,
The advantages that bleeding quantity is low and good using the compatibility of medium.
Light magnesium oxide is the loose unformed powder of white lightweight, and odorless, tasteless is nontoxic, and volume shared by light magnesium oxide is about
Three times for heavy-burned magnesia or so, there is extremely fireproof heat-insulating property, reinforcing agent, adhesive, and the present invention selects light magnesium oxide
Granularity≤0.074 millimeter.
Alumina silicate fibre have that unit weight is light, thermostable heat-conductive coefficient is low, service life is long, tensile strength is big, elasticity is good and
The features such as nontoxic, the present invention select alumina silicate fibre length≤0.5 millimeter.
Hollow glass micropearl(Hollow glass microbead)It is a kind of small, hollow ball sprills, particle diameter can be as needed
Arbitrarily selected between 30-100 microns, have lightweight is big, thermal conductivity factor is low, compression strength is high, dispersiveness, flowing
Property, the advantages of stability is good, the present invention selects particle diameter≤0.1 millimeter of hollow glass micropearl.
The technical scheme is that:
1st, the dispensing of unburned quincunx tourmaline light ceramic is made up of following component by weight percentage:Schorl 15~
45%th, black portland cement 15~30%, acidifying after Concave-convex clay rod 5~20%, powdery attapulgite foaming agent 2~
15%th, light magnesium oxide 1~10%, alumina silicate fibre 1~8%, hollow glass micropearl 1~8% and water 5~40%.
2nd, the Concave-convex clay rod dispensing after being acidified is made up of following component by weight percentage:Attapulgite after acidifying
Clay semi-finished product 90~98%, quick dissolved sodium silicate 0.1~5%, polyvinyl alcohol 0.1~5%, hydroxypropyl methyl cellulose 0.01~
3% and sodium carbonate 0~3%;The production method of Concave-convex clay rod after acidifying:Concave-convex clay rod dispensing after acidifying is defeated
Enter in grinding machine and be milled, grain fineness≤0.074 millimeter, the powder after milling is the Concave-convex clay rod after acidifying;
The production method of Concave-convex clay rod semi-finished product after acidifying:(1) first the Concave-convex clay rod after weathering is inputted
In mixer through operating, then dilute sulfuric acid is slowly added to carry out acidification in the Concave-convex clay rod after weathering;⑵
By the Concave-convex clay rod after acidification, it is Concave-convex clay rod tablet to be extruded by twin rollers, Concave-convex clay rod piece
Thickness≤3 millimeter of shape thing;(3) Concave-convex clay rod tablet is transported in swinging drying oven and be calcined, roasting time 1
~3 hours, sintering temperature was controlled at 250~350 DEG C, Concave-convex clay rod tablet water content≤5% after roasting, after roasting
Concave-convex clay rod tablet for acidifying after Concave-convex clay rod semi-finished product;
The dispensing of Concave-convex clay rod tablet is made up of following component by weight percentage:Attapulgite after weathering glues
Soil 55~75% and dilute sulfuric acid 25~45%;The dispensing of dilute sulfuric acid is made up of following component by weight percentage:The ﹪'s of concentration 98
Sulfuric acid 1~5%, water 95~99%;Concave-convex clay rod raw ore is needed by two time weatherings more than winter, from big
The fine and close raw ore disintegration of block is the Concave-convex clay rod after the weathering of fine particle, picks and is evident that barren rock block, plants
Fibres and other soil impurity, Concave-convex clay rod grain fineness≤5 millimeter after weathering.
Concave-convex clay rod after acidifying is " recessed after acidifying using being applied by the present inventor on 06 01st, 2014
Convex rod stone clay ", Chinese patent Authorization Notice No. is:CN 104016366B, authorized announcement date:On December 02nd, 2015.
3rd, powdery attapulgite foaming agent dispensing is made up of following component by weight percentage:Activated attapulgite 45~
95%th, lauryl sodium sulfate 1~35%, SODIUM PERCARBONATE 1~25%, Sodium Polyacrylate 0.01~5%, sodium pyrophosphate 0.01~
5% and poly- naphthalene formaldehyde sulfonate salt 0.01~5%;The production method of powdery attapulgite foaming agent:By powdery attapulgite foaming agent
It is stirred in dispensing input mixer, inputs in grinding machine and be milled after stirring, grain fineness≤0.074 millimeter.
Powdery attapulgite foaming agent using applied by the present inventor on 05 26th, 2013 " powdery attapulgite foam
Agent ", Chinese patent Authorization Notice No. are:The B of CN 103265213, authorized announcement date:On 09 24th, 2014.
4th, the dispensing of unburned quincunx tourmaline light ceramic is applied to produce unburned spheroidal tourmaline light ceramic, exempted from
Burn cylindrical tourmaline light ceramic, baking-free gravel tourmaline light ceramic, unburned quincunx tourmaline lightweight through hole haydite,
Unburned spheroidal tourmaline lightweight through hole haydite and cylindrical sintering-free tourmaline lightweight through hole haydite.
5th, the production method of unburned quincunx tourmaline light ceramic:(1) matching somebody with somebody unburned quincunx tourmaline light ceramic
In the stirring mixer that material input has operated, it is stirred as the mixture of unburned quincunx tourmaline light ceramic;(2) will
The mixture of unburned quincunx tourmaline light ceramic is transported in Squeezinggranulator, and extruder grain is unburned quincunx tourmaline
Light ceramic semi-finished product;(3) unburned quincunx tourmaline light ceramic semi-finished product are transported into steam-curing chamber's progress steam to support
Protect, at 55~75 DEG C, curing time controlled at 7~15 days temperature control in steam curing room;(4) will be unburned after steam curing
Quincunx tourmaline light ceramic semi-finished product, it is transported in steam rotary dryer and processing is dried, drying temperature control exists
60~100 DEG C, drying time was controlled at 1~5 hour;(5) it is dried unburned quincunx tourmaline light ceramic semi-finished product are defeated
It is sent in vibratory sieve and is sieved, unburned quincunx tourmaline light ceramic finished product is packaged as after screening.
Tourmaline itself can produce electron ion for a long time, and forever discharge negative aeroion and far infrared, improve unburned plum
The adsorption effect of flower-shape tourmaline light ceramic.
Black portland cement can ensure that unburned quincunx tourmaline light ceramic is black and shinny, increase unburned quincunx electricity
The intensity of gas stone light ceramic.
Concave-convex clay rod after tourmaline and acidifying can increase substantially the suction of unburned quincunx tourmaline light ceramic
Echo the function of purification air.
Powdery attapulgite foaming agent be stirred for unburned quincunx tourmaline light ceramic mixture when, it will produce
A certain amount of bubble, be advantageous to increase unburned quincunx tourmaline light ceramic surface and internal porosity.
It is micro- using light magnesium oxide, aluminium silicate fiber peacekeeping hollow glass in unburned quincunx tourmaline light ceramic dispensing
Pearl, haydite surface and internal porosity can be increased, reduce the bulk density of unburned quincunx tourmaline light ceramic, raising is exempted from
Burn the specific surface area and intensity of quincunx tourmaline light ceramic.
It is mutual that unburned quincunx tourmaline light ceramic is advantageous to increase unburned quincunx tourmaline light ceramic
Voidage and the bulk density for reducing unburned quincunx tourmaline light ceramic.
Unburned quincunx tourmaline light ceramic surface and it is internal have largely interconnected micropore, be advantageous to increase unburned
Effective ratio area, intensity and the reduction bulk density of quincunx tourmaline light ceramic haydite.
Unburned quincunx tourmaline light ceramic is put into water, unburned quincunx tourmaline light ceramic can be sunk to rapidly
The bottom, while large quantity of moisture is sucked, the air in unburned quincunx tourmaline light ceramic internal capillary can be displaced
Come.
When unburned quincunx tourmaline light ceramic water absorption rate >=25%, unburned quincunx tourmaline light ceramic it is outer
Table is a kind of state of moistening, and not obvious water leaks out, and unburned quincunx tourmaline light ceramic is deposited in
Together, numerous spaces is formed between each other, will not be bonded together, and permeability is good, unburned quincunx tourmaline Lightweight ceramic
Grain does not have dust in the dry state, and disintegration will not also be produced by being immersed in all the year round in water.
Unburned quincunx tourmaline light ceramic has that black and shinny, appearance and modeling is attractive in appearance, lightweight intensity is good, specific surface area
Greatly, the characteristics of bulk density is low, permeability is superior, porosity and water absorption rate are high.
In order to ensure the normal growth and development of plant, water, the organic fertilizer of liquid or inorganic fertilizer are sprayed at unburned quincunx
In tourmaline light ceramic, or unburned quincunx tourmaline light ceramic is immersed in the solution of water, organic fertilizer or inorganic fertilizer,
Unburned quincunx tourmaline light ceramic takes out after absorbing a certain amount of water of storage or liquid fertilizer, for cultivating or planting each seedling
When wood, flowers and plants and vegetables, the root of plant will absorb the battalion of water or liquid fertilizer in unburned quincunx tourmaline light ceramic
Form point, it is ensured that growth and development of plants is good, and survival rate is high and the life-span is longer, and can greatly reduce the number of moisturizing.
Unburned quincunx tourmaline light ceramic is applied to garden landscape engineering, home gardening and prepares soilless culture base
Matter.
Brief description of the drawings
Fig. 1 is unburned quincunx tourmaline light ceramic schematic diagram, and Fig. 2 is unburned quincunx tourmaline light ceramic A-A
Section.
As shown in the figure:1 is unburned quincunx tourmaline light ceramic.
Embodiment
With reference to embodiment, the invention will be further described:
1st, the dispensing of unburned quincunx tourmaline light ceramic is made up of following component by weight percentage:Schorl 30%,
Concave-convex clay rod 12%, powdery attapulgite foaming agent 8%, light magnesium oxide after black portland cement 25%, acidifying
4%th, alumina silicate fibre 3%, hollow glass micropearl 2% and water 16%.
2nd, the production method of unburned quincunx tourmaline light ceramic:(1) matching somebody with somebody unburned quincunx tourmaline light ceramic
In the stirring mixer that material input has operated, it is stirred as the mixture of unburned quincunx tourmaline light ceramic;(2) will
The mixture of unburned quincunx tourmaline light ceramic is transported in Squeezinggranulator, and extruder grain is unburned quincunx tourmaline
Light ceramic semi-finished product;(3) the unburned quincunx semi-finished product of tourmaline light ceramic 1 are transported into steam-curing chamber's progress steam to support
Protect, at 55~75 DEG C, curing time controlled at 12 days temperature control in steam curing room;(4) by the unburned plum blossom after steam curing
The semi-finished product of shape tourmaline light ceramic 1, are transported in steam rotary dryer and processing are dried, drying temperature control 60~
100 DEG C, drying time was controlled at 2 hours;(5) the dried unburned quincunx semi-finished product of tourmaline light ceramic 1 are transported to and shaken
Sieved in dynamic sieve, the unburned quincunx finished product of tourmaline light ceramic 1 is packaged as after screening.
3rd, it is 862kg/m3 to survey unburned quincunx tourmaline light ceramic average bulk density, water absorption rate 52%.
Claims (3)
- A kind of 1. unburned quincunx tourmaline light ceramic, it is characterised in that the dispensing of unburned quincunx tourmaline light ceramic It is made up of by weight percentage following component:It is recessed after schorl 15~45%, black portland cement 15~30%, acidifying Convex rod stone clay 5~20%, powdery attapulgite foaming agent 2~15%, light magnesium oxide 1~10%, alumina silicate fibre 1~8%, Hollow glass micropearl 1~8% and water 5~40%.
- 2. unburned quincunx tourmaline light ceramic according to claim 1, it is characterised in that unburned quincunx tourmaline The dispensing of light ceramic is applied to produce unburned spheroidal tourmaline light ceramic, cylindrical sintering-free tourmaline light ceramic, exempted from Burn gravel tourmaline light ceramic, unburned quincunx tourmaline lightweight through hole haydite, unburned spheroidal tourmaline lightweight through hole Haydite and cylindrical sintering-free tourmaline lightweight through hole haydite.
- 3. unburned quincunx tourmaline light ceramic according to claim 1, it is characterised in that unburned quincunx tourmaline The production method of light ceramic:(1) the stirring mixer dispensing input of unburned quincunx tourmaline light ceramic operated In, it is stirred as the mixture of unburned quincunx tourmaline light ceramic;(2) by unburned quincunx tourmaline light ceramic Mixture is transported in Squeezinggranulator, and extruder grain is unburned quincunx tourmaline light ceramic semi-finished product;(3) by unburned plum Flower-shape tourmaline light ceramic semi-finished product are transported to steam-curing chamber and carry out steam curing, and temperature control is 55 in steam curing room ~75 DEG C, curing time was controlled at 7~15 days;(4) by the unburned quincunx tourmaline light ceramic semi-finished product after steam curing, It is transported in steam rotary dryer and processing is dried, at 60~100 DEG C, drying time is controlled 1~5 for drying temperature control Hour;(5) dried unburned quincunx tourmaline light ceramic semi-finished product are transported in vibratory sieve and sieved, after screening It is packaged as unburned quincunx tourmaline light ceramic finished product.
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CN201710873178.0A CN107500664A (en) | 2017-09-25 | 2017-09-25 | Unburned quincunx tourmaline light ceramic |
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CN201710873178.0A CN107500664A (en) | 2017-09-25 | 2017-09-25 | Unburned quincunx tourmaline light ceramic |
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Application publication date: 20171222 |