CN107488526A - A kind of anti-rust cleaning agent of turbocharger of motor and preparation method thereof - Google Patents
A kind of anti-rust cleaning agent of turbocharger of motor and preparation method thereof Download PDFInfo
- Publication number
- CN107488526A CN107488526A CN201710612076.3A CN201710612076A CN107488526A CN 107488526 A CN107488526 A CN 107488526A CN 201710612076 A CN201710612076 A CN 201710612076A CN 107488526 A CN107488526 A CN 107488526A
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- Prior art keywords
- turbocharger
- cleaning agent
- rust cleaning
- agent
- motor
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/82—Compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a kind of anti-rust cleaning agent of turbocharger of motor, include the following components of percentage by weight：1 20% organic silicon double-ion surfactant, 10 30% macromolecule ether amines cleaning agents, 1 10% fuel oil friction improver, 1 10% antirust agent, 10 30% organic solvents, 1 10% dispersant, 1 10% chelating agent and 30 60% deionized waters.The deposits such as the anti-rust cleaning agent of the turbocharger of motor of the present invention, the carbon distribution that can be cleaned in turbocharger, greasy dirt, recover turbocharger performance, improve fuel economy, reduce discharge；Cleaning agent of the present invention also contains antirust agent, and it can form one layer of polymer protective film in turbocharger vanes, and turbo blade can be made permanent bright as new, protection turbocharger, the blocking of ternary catalyzing unit will not be caused after cleaning.
Description
Technical field
The present invention relates to automobile engine cleaning additive field, more particularly to the turbine of a kind of gasoline and diesel car engine
The anti-rust cleaning agent of booster.
Background technology
Hyundai Motor engine technique largely uses turbocharger, for lifting engine power output, reducing oil consumption, turbine
The work of booster is to promote the impeller in opposite side inlet end using the impeller of engine exhaust discharge end, is reached more
Air is sent into each cylinder.
With the increase of VMT Vehicle-Miles of Travel number, the carbon distribution on blade in inlet end is consequently increased, so not only
Efficiency of turbocharger can be reduced, but also the balance of rotor can be destroyed, cause vibration, power and oil consumption can accordingly be influenceed.
Traditional turbocharger cleaning agent uses acid-base class aqueous cleaning agent or a large amount of solvent cleaners, and needs to adopt
Flush clean is carried out to turbocharger with special equipment, and gasoline or diesel car engine turbocharger are in the feelings do not dismantled
It under condition, can not be cleaned using big quantity of fluid, can so cause to start the hydrops of machine airway, cause the drawing of engine
Cylinder etc., damage engine.
With the increasingly precision of turbocharger of motor, turbocharger is carried out to exempt from demolition clean using the mode of tearing open is exempted from
Necessitate.Therefore exempt to tear anti-rust cleaning agent open, it is necessary to develop a kind of new safety with protection turbocharger function.
The content of the invention
Cleaning agent is permeated and spread into carbon distribution by the present invention using the ultra-low surface tension of organic silicon double-ion surfactant
Deng the inside of deposit, while using the abundant foam characteristic of organic silicon double-ion surfactant, utilize rushing for foam microburst
Wash power and thoroughly dissolve the deposits such as the carbon distribution of cleaning turbine blade surface, in addition, cleaning agent of the present invention also contains antirust agent, it can
To form one layer of polymer protective film in turbocharger vanes, turbo blade can be made permanent bright as new, protection turbine increases
Depressor, the blocking of ternary catalyzing unit will not be caused after cleaning.
It is an object of the invention to provide a kind of anti-rust cleaning agent of turbocharger of motor, and it can be used for engine whirlpool
The cleaning of booster deposit is taken turns, one layer of polymer protective film can also be formed in turbocharger vanes, protection turbine increases
Depressor.
To achieve the above object, the present invention uses following technical scheme：
A kind of anti-rust cleaning agent of turbocharger of motor, it includes the following components of percentage by weight：
Preferably, the anti-rust cleaning agent of turbocharger of motor of the invention includes the following of percentage by weight
Component：
Preferably, the structural formula for the organic silicon double-ion surfactant that the present invention uses is B (A)mB,
Wherein, m is the integer more than or equal to 2；
A is diallyl high molecular polyether, and its structural formula is：
-CH2-CH2-CH2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH2-CH2-CH2-
Wherein, x, y are the integer from 0 to 200,
R is H either C1-C3 alkyl
B is hydrophobic silicones, and its structural formula is：-Si(CH3)-[O-Si(CH3)3]2。
Organic silicon double-ion surfactant of the present invention is a kind of new surfactant, hydrocarbon compared to common
Surfactant, it has higher surface-active, has lower surface tension, excellent wetability and abundant foam
Property, while the problem of overcome common organic silicon surfactant hydrolytic stability difference again.Organic silicon double-ion surfactant by
In there is two trisiloxanes segments, and the methyl on siloxanes segment is arranged on interface, and the rotation of methyl occupies larger sky
Between, so as to add the distance between adjacent siloxane molecule, between the intermolecular forces and molecule of molecule six powers of distance into
Inverse ratio, so the force ratio hydrocarbon between siloxane molecule wants weak more, easily sprawled on interface.Organosilicon is double
The lowest surface tension of sub- surfactant can reach 20 dynes per centimeters (dyn/cm) left and right, and common hydrocarbon surface-active
The lowest surface tension of agent can only achieve 30 dynes per centimeters (dyn/cm) left and right.
Organic silicon double-ion surfactant acts on the surface of cleaned material and its interface of contact, can dirt is clear
Remove, the Fouling Cleaning mechanism of organic silicon double-ion surfactant is as shown in Figure 1.When organic silicon double-ion surfactant is with being cleaned
When thing A and dirt B interracial contact, due to surface tension is extremely low, organic silicon double-ion surfactant will can clean
Centre of the agent rapid osmotic to dirt and by clean thing, diffusion, play a part of peeling off dirt.Organosilicone gemini table simultaneously
Face activating agent has abundant and uniform microfoam, in cleaning, can thoroughly be dissolved using the flushing ability of foam microburst
Clean the carbon distribution of turbine blade surface.
Preferably, the macromolecule ether amines cleaning agent is PIBA or polyphosphazene polymer ether amines, conventional polymeric ether
Amine cleaning agent has BASF Kerocom PIBA 03, Huntsman Surfonamine B-100, Surfonamine L-100,
SurfonamineB-60, Keropur 3448N, Keropur 3458N etc..
Preferably, the fuel oil friction improver is polyether-modified animals and plants oleyl amine, and its structural formula is：
Wherein, R is C8-C18 alkyl series matter；Such as cocounut oil, cottonseed oil, linseed oil, soybean oil, sunflower
Oil, butter etc.；
Q1+q2=0-30, p1+p2=0-60, q1, q2, p1, p2 are integer, such as Lubrizol 9525A, Hitec
6457 etc..
It is that the turbocharger antirust is clear as the reason for fuel oil friction improver using polyether-modified animals and plants oleyl amine
Fuel system is entered from gas handling system after lotion cleaning, cleaning agent typically also can be by the lubricating layer of system while cleaning
Wash, be advantageous to the lubrication of fuel system, protect turbocharger and the safety of engine.
Preferably, the antirust agent is fatty acid alkanol amides, and conventional antirust agent has lauric acid amide of ethanol, cocounut oil
Sour single ethanol amide, oleic monoethanolamide, oleic acid diethyl amide, stearic acid diglycollic amide and laurate diethanol acyl
Amine.
Preferably, organic solvent of the present invention includes alcohols, such as methanol, ethanol, isopropanol etc.；Ethers, such as
Butyl glycol ether, butyl, ethylene glycol ethyl ether, propylene glycol monomethyl ether, propylene-glycol ethyl ether etc.；Petroleum aromatic class, such as
D40, D60, D80, No. 200 solvent naphthas etc..
Preferably, the dispersant is polycarboxylate salt dispersant or naphthalene sulfonic acid condensate dispersant.
The dispersant of the present invention can come the soil dispersion washed down, prevent from re-uniting, so as to enter
Gas system and fuel system, finally burn or discharged from gas extraction system in the event of high temperatures.Conventional dispersant has
Sokalan CP 5、Sokalan CP 7、Sokalan CP 9、Sokalan CP 10、Sokalan CP 10S、Sokalan
CP 12S and Sokalan CP 13S etc..
Preferably, the chelating agent is organic chelating agent, predominantly amino carboxylic acid salt, such as methylglycine diethyl
Acid, nitrilotriacetic acid, ethoxy ethylene diamin(e) triacetic acid, diethylene-triamine pentaacetic acid and ethylenediamine tetra-acetic acid.
Present invention also offers the preparation method of the anti-rust cleaning agent of turbocharger of motor, this method includes following step
Suddenly：
1) deionized water, organic solvent are added in the reactor；
2) continue to add organic silicon double-ion surfactant in the reactor, macromolecule ether amines cleaning agent, fuel oil friction change
Enter agent, antirust agent, dispersant and chelating agent, stir, you can obtain the anti-rust cleaning agent of turbocharger of motor.
Temporarily find no dedicated for the special turbocharger cleaning agent of gasoline car and diesel car engine, this hair at present
Bright product beneficial effect is：The anti-rust cleaning agent of the turbocharger of motor of the present invention, can be cleaned in turbocharger
The deposits such as carbon distribution, greasy dirt, recover turbocharger performance, improve fuel economy, reduce discharge；Cleaning agent of the present invention also contains
There is antirust agent, it can form one layer of polymer protective film in turbocharger vanes, can make the permanent light of turbo blade such as
Newly, turbocharger is protected, the blocking of ternary catalyzing unit will not be caused after cleaning.
Brief description of the drawings
Fig. 1 is the Fouling Cleaning mechanism schematic diagram of organic silicon double-ion surfactant.
Embodiment
The present invention is further illustrated below by embodiment, following examples are implemented for the present invention is specific
Example, but embodiments of the present invention are not limited by following implementations.
Embodiment 1
A kind of anti-rust cleaning agent of turbocharger of motor, include the following components of percentage by weight：
The preparation method of the anti-rust cleaning agent of turbocharger of motor is：At normal temperatures, it has been added into reactor
Solvent, deionized water, other components are then added, compounding substances are stirred.
Embodiment 2
A kind of anti-rust cleaning agent of turbocharger of motor, include the following components of percentage by weight：
The preparation method phase of the preparation method of the anti-rust cleaning agent of the turbocharger of motor of the present embodiment and embodiment 1
Together.
Embodiment 3
A kind of anti-rust cleaning agent of turbocharger of motor, include the following components of percentage by weight：
The preparation method phase of the preparation method of the anti-rust cleaning agent of the turbocharger of motor of the present embodiment and embodiment 1
Together.
Embodiment 4
A kind of anti-rust cleaning agent of turbocharger of motor, include the following components of percentage by weight：
The preparation method phase of the preparation method of the anti-rust cleaning agent of the turbocharger of motor of the present embodiment and embodiment 1
Together.
Embodiment 5
A kind of anti-rust cleaning agent of turbocharger of motor, include the following components of percentage by weight：
The preparation method phase of the preparation method of the anti-rust cleaning agent of the turbocharger of motor of the present embodiment and embodiment 1
Together.
The anti-rust cleaning agent of turbocharger of motor prepared by embodiment 1-5 has excellent performance, can clean whirlpool
The deposit such as carbon distribution, greasy dirt on booster is taken turns, recovers turbocharger performance, can also be in turbocharger vanes after cleaning
One layer of polymer protective film of upper formation, turbo blade can be made permanent bright as new, protection turbocharger, will not be caused after cleaning
The blocking of ternary catalyzing unit.
The anti-rust cleaning agent of the embodiment 1-5 turbocharger of motor prepared is entered according to GB/T 19230.1-2003
The measure of row gasoline cleaning agent effect (rust-preventing characteristic result), acquired results are 0, and non-corroding phenomenon occurs, and illustrate the present invention's
The anti-rust cleaning agent of turbocharger of motor has excellent performance.Its result is as shown in the table.
Claims (10)
- A kind of 1. anti-rust cleaning agent of turbocharger of motor, it is characterised in that the following components including percentage by weight：
- 2. the anti-rust cleaning agent of turbocharger of motor according to claim 1, it is characterised in that including weight percent The following components of ratio：
- 3. the anti-rust cleaning agent of turbocharger of motor according to claim 1 or 2, it is characterised in that described organic The structural formula of silicon Gemini surface active agent is B (A)mB,Wherein, m is the integer more than or equal to 2；A is diallyl high molecular polyether, and its structural formula is：-CH2-CH2-CH2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH2-CH2-CH2-Wherein, x, y are the integer from 0 to 200,R is H either C1-C3 alkylB is hydrophobic silicones, and its structural formula is：-Si(CH3)-[O-Si(CH3)3]2。
- 4. the anti-rust cleaning agent of turbocharger of motor according to claim 1 or 2, it is characterised in that the high score Sub- ether amines cleaning agent is PIBA or polyphosphazene polymer ether amines.
- 5. the anti-rust cleaning agent of turbocharger of motor according to claim 1 or 2, it is characterised in that the fuel oil Friction improver is polyether-modified animals and plants oleyl amine, and its structural formula is：Wherein, R is C8-C18 alkyl series matter；Q1+q2=0-30, p1+p2=0-60, q1, q2, p1, p2 are integer.
- 6. the anti-rust cleaning agent of turbocharger of motor according to claim 1 or 2, it is characterised in that the antirust Agent is fatty acid alkanol amides.
- 7. the anti-rust cleaning agent of turbocharger of motor according to claim 1 or 2, it is characterised in that the solvent For alcohols, ethers or petroleum aromatic class.
- 8. the anti-rust cleaning agent of turbocharger of motor according to claim 1 or 2, it is characterised in that described scattered Agent is polycarboxylate salt dispersant or naphthalene sulfonic acid condensate dispersant.
- 9. the anti-rust cleaning agent of turbocharger of motor according to claim 1 or 2, it is characterised in that the chelating Agent is MDGA, nitrilotriacetic acid, ethoxy ethylene diamin(e) triacetic acid, diethylene-triamine pentaacetic acid or ethylenediamine Tetraacethyl.
- 10. the preparation method of the anti-rust cleaning agent of the turbocharger of motor any one of claim 1-9, its feature It is, comprises the following steps：1) deionized water, organic solvent are added in the reactor；2) continue in the reactor add organic silicon double-ion surfactant, macromolecule ether amines cleaning agent, fuel oil friction improver, Antirust agent, dispersant and chelating agent, stir, you can obtain the anti-rust cleaning agent of turbocharger of motor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710612076.3A CN107488526A (en) | 2017-07-25 | 2017-07-25 | A kind of anti-rust cleaning agent of turbocharger of motor and preparation method thereof |
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| CN201710612076.3A CN107488526A (en) | 2017-07-25 | 2017-07-25 | A kind of anti-rust cleaning agent of turbocharger of motor and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753479A (en) * | 2018-06-05 | 2018-11-06 | 深圳市艾德化学品科技有限公司 | A kind of direct fuel-injection engine gas handling system decarbonizer |
| CN109234053A (en) * | 2018-09-18 | 2019-01-18 | 金华市鸿新新材料科技有限公司 | Aqueous engine cleansing agent of a kind of environment-friendly antirust erosion and preparation method thereof |
| CN109609293A (en) * | 2018-12-21 | 2019-04-12 | 中山市非特永旺汽车用品有限公司 | One kind is exempted to tear automobile three-way catalysts cleaning agent open |
| CN110042010A (en) * | 2019-05-28 | 2019-07-23 | 马鞍山华之杰金属表面处理剂有限公司 | A kind of environment protection type multifunctional agent for carbon hydrogen detergent and preparation method thereof |
| CN110643437A (en) * | 2019-09-23 | 2020-01-03 | 广州卡士德汽车用品有限公司 | Pressurized air inlet turbine decarbonizer and preparation method thereof |
| CN114317144A (en) * | 2021-12-31 | 2022-04-12 | 上海舒尔雅日化有限公司 | Active nano silicon, water-based heavy oil dirt cleaning agent containing active nano silicon, and preparation method and application of water-based heavy oil dirt cleaning agent |
| CN114958496A (en) * | 2022-06-20 | 2022-08-30 | 江苏云瀚股份有限公司 | Antirust cleaning agent for engine turbocharger and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753479A (en) * | 2018-06-05 | 2018-11-06 | 深圳市艾德化学品科技有限公司 | A kind of direct fuel-injection engine gas handling system decarbonizer |
| CN108753479B (en) * | 2018-06-05 | 2021-03-26 | 深圳市艾德化学品科技有限公司 | Carbon remover for air intake system of direct injection engine |
| CN109234053A (en) * | 2018-09-18 | 2019-01-18 | 金华市鸿新新材料科技有限公司 | Aqueous engine cleansing agent of a kind of environment-friendly antirust erosion and preparation method thereof |
| CN109609293A (en) * | 2018-12-21 | 2019-04-12 | 中山市非特永旺汽车用品有限公司 | One kind is exempted to tear automobile three-way catalysts cleaning agent open |
| CN110042010A (en) * | 2019-05-28 | 2019-07-23 | 马鞍山华之杰金属表面处理剂有限公司 | A kind of environment protection type multifunctional agent for carbon hydrogen detergent and preparation method thereof |
| CN110643437A (en) * | 2019-09-23 | 2020-01-03 | 广州卡士德汽车用品有限公司 | Pressurized air inlet turbine decarbonizer and preparation method thereof |
| CN114317144A (en) * | 2021-12-31 | 2022-04-12 | 上海舒尔雅日化有限公司 | Active nano silicon, water-based heavy oil dirt cleaning agent containing active nano silicon, and preparation method and application of water-based heavy oil dirt cleaning agent |
| CN114958496A (en) * | 2022-06-20 | 2022-08-30 | 江苏云瀚股份有限公司 | Antirust cleaning agent for engine turbocharger and preparation method thereof |
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Application publication date: 20171219 |
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| RJ01 | Rejection of invention patent application after publication |