CN109609293A - One kind is exempted to tear automobile three-way catalysts cleaning agent open - Google Patents

One kind is exempted to tear automobile three-way catalysts cleaning agent open Download PDF

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Publication number
CN109609293A
CN109609293A CN201811592421.2A CN201811592421A CN109609293A CN 109609293 A CN109609293 A CN 109609293A CN 201811592421 A CN201811592421 A CN 201811592421A CN 109609293 A CN109609293 A CN 109609293A
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agent
cleaning agent
structural formula
way catalysts
exempted
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詹五洲
邱小明
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Zhongshan Feite Yongwang Automotive Products Co Ltd
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Zhongshan Feite Yongwang Automotive Products Co Ltd
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Priority to CN201811592421.2A priority Critical patent/CN109609293A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • C11D3/182Hydrocarbons branched
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • C11D3/187Hydrocarbons aromatic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/32Amides; Substituted amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723Polyamines or polyalkyleneimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43Solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/82Compounds containing silicon
    • C11D2111/20

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Abstract

Exempt to tear automobile three-way catalysts cleaning agent, including the following raw material: surfactant, macromolecule amine dispersing agent, fuel oil friction improver, antirust agent, solvent, gasoline additive open the invention discloses one kind.This product is combined by some functional polymolecular compounds and cleaning agent, auxiliary agent etc., by way of being directly added into fuel tank, the problems such as cleaning entire oil circuit, effectively dissolve obstinate carbon distribution and greasy filth on air inlet system parts, improving unsmooth exhaust, power dropping, oil consumption increase;Rate of pollution is reduced, ternary catalyzing unit is protected, prolongs the service life;Operating procedure is reduced, is settled at one go.

Description

One kind is exempted to tear automobile three-way catalysts cleaning agent open
Technical field
The invention belongs to automobile cleaning agent technical fields, and in particular to one kind is exempted to tear automobile three-way catalysts cleaning agent open.
Background technique
It, can be inside lambda sensor surface and ternary catalyzing unit after burning due to containing the harmful substances such as sulphur, phosphorus in fuel oil Form chemical complex.In addition, since the bad steering habit or long run of driver is in congestion road surface, engine warp It is often in imperfect combustion state, carbon deposit can be formed in lambda sensor and ternary catalyzing unit.Just because of factors, cause Lambda sensor and ternary catalyzing unit poison deactivation, ternary catalyzing unit blocking and EGR valve are deposited the failures such as object obstruction clamping stagnation, make It is abnormal at engine operation, cause oil consumption increase, the problems such as power dropping and tail gas are exceeded.Therefore, periodic cleaning ternary is urged Change device to be necessary.In addition, ternary catalyzing unit main carriers are made of precious metal, the price is very expensive, conserves ternary Catalyst converter is also the effective ways of reduction vehicle cost.Cleaning ternary catalyzing unit is the most direct, effective of reduction exhaust emissions Method.As country detects automotive emission increasingly stringent, the market of three-element catalytic cleaning agent is also increasing, quilt Numerous automobile friends receive.
Reparation cleaning product on Vehicles Collected from Market for three-element catalytic substantially has following a few classes:
1. the product of hanging bottle type cleaning
A kind of most methods currently on the market, easy to operate, convenient and efficient, corresponding is exactly to clean Not enough thoroughly, main is exactly to make ternary section unimpeded by certain methods.But after short a period of time, ternary blocked state It can gradually aggravate instead.It is palliative, it cannot fundamentally restore the activity of noble metal.And need using ancillary equipment, Cleaning operation is of long duration and artificial expensive.
2. the product of detachable cleaning
As its name suggests, entire ternary catalyzing unit is exactly removed thorough cleaning, the advantages of this method is can be more thorough Three-element catalytic surface covering is removed to bottom, three-element catalytic duct is dredged, three-element catalytic effect is substantially improved.But the disadvantage is that operation Difficulty is big, and occupancy working hour is long, and generally require just can handle for 4-6 hours finishes, and unsuitable car owner does it yourself, and needs the shop 4s Or repair shop.
With social development, vehicle increases, and rhythm of life is accelerated, and artificial and awareness of safety improves;Study a car owner DIY, safety easy to operate, effect significantly exempt to tear open ternary cleaning product and necessitate.
Summary of the invention
Exempt to tear automobile three-way catalysts cleaning agent open the purpose of the present invention is to provide one kind.
The technical solution used in the present invention is:
One kind is exempted to tear automobile three-way catalysts cleaning agent open, which is characterized in that by mass percentage, including the following raw material:
Surfactant 1~20%
Macromolecule amine dispersing agent 5~25%
Fuel oil friction improver 1~10%
Antirust agent 1~10%
Solvent 20~60%
Gasoline additive 1~15%
Including the following raw material preferably, by mass percentage:
Surfactant 5~15%
Macromolecule amine dispersing agent 8~20%
Fuel oil friction improver 2~5%
Antirust agent 2~5%
Solvent 45~55%
Gasoline additive 2~12%
Preferably, the surfactant be organosilicon composition, structural formula be B (A) mB: where m be more than or equal to 2 integer;A is diallyl high molecular polyether, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR- O-]y-CH(CH3)2-CH2, wherein x, y are the integer from 0 to 200;R is the alkyl of H or C1~C3;B is hydrophobic silicones, Its structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Preferably, the macromolecule amine dispersing agent is polyisobutylene amine or polyphosphazene polymer ether amines.
Preferably, the fuel oil friction improver is polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is the alkyl series matter of C8~C18;Q1+q2=0~30, p1+p2=0~60, q1, q2, p1, p2 are Integer.
Preferably, the antirust agent is fatty acid alkanol amides.
Preferably, the solvent is petroleum aromatic class, alcohols, ethers, ketone.
Preferably, the gasoline additive is uprising dose of organic synthesis class and octane number additive.
Surfactant of the present invention is a kind of novel surfactant, compared to common hydrocarbon surface-active Agent has higher surface-active, has lower surface tension, excellent wetability.Organic silicon surfactant is clear It is acted on the surface of washing and its interface of contact, dirt removal.When being contacted on cleaned A and A, B layers of interface, by In the extremely low reason of surface tension, by cleaning agent rapid osmotic to dirt and the centre of object can be cleaned, diffusion plays Remove the effect of dirt.
Macromolecule polarity amine dispersing agent of the present invention includes macromolecule polyisobutylene amine, polyphosphazene polymer ether amines etc., As BASF Kerocom PIBA 03, Huntsman Surfonamine B-100, Surfonamine L-100, Surfonamine B-60, Keropur 3448N, Keropur 3458N etc..The macromolecule polarity amine dispersing agent of addition can Colloid is dissolved, and passes through the absorption of polarity amine salt, one layer of unimolecule protective film is formed, prevents the formation of carbon distribution colloid.
Fuel oil friction improver of the present invention preferably uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R be C8~C18 alkyl series matter, as cocounut oil, cottonseed oil, linseed oil, soybean oil, sunflower oil, Butter etc.;Q1+q2=0~30, p1+p2=0~60, q1, q2, p1, p2 are integer, such as Lubrizol 9525A, Hitec 6457 etc..While being that cleaning agent generally cleans as the reason of fuel oil friction improver using polyether-modified animals and plants oleyl amine Also the lubricant layer of system can be washed, and the raw material, which is added, can lubricate entire fuel system and ternary catalyzing unit, avoid Damage device.
Antirust agent of the present invention be lauric acid amide of ethanol, Coconut Fatty Acid Monoethanolamide, oleic monoethanolamide, Oleic acid diethyl amide, stearic acid diglycollic amide, lauric acid diethyl amide.
Solvent of the present invention includes petroleum aromatic class, such as D40, D60, D80, No. 6, No. 120, No. 200 solvent naphthas. Alcohols, such as methanol, ethyl alcohol, isopropanol;Ethers such as butyl glycol ether, butyl, ethylene glycol ethyl ether, propylene glycol first Ether, propylene-glycol ethyl ether etc.;Ketone such as acetone, butanone, cyclohexanone etc..
Gasoline additive of the present invention is uprising dose of organic synthesis class and octane number additive, such as fatty ethers, different pungent Alkane, isopropylbenzene, alkylbenzene etc..
The preparation method of the cleaning agent for exempting from demolition clean automobile three-element catalytic of the invention is simple, at normal temperature, to reactor It is middle first to add solvent, other components are then added, compounding substances are stirred evenly, finally sealed, which saves, to be used.
The beneficial effects of the present invention are: this product passes through some functional knots such as polymolecular compound and cleaning agent, auxiliary agent It closes, by way of being directly added into fuel tank, cleans entire oil circuit, effectively dissolve obstinate carbon distribution and oil on air inlet system parts Mud improves the problems such as being vented unsmooth, power dropping, oil consumption increase;Rate of pollution is reduced, ternary catalyzing unit is protected, extension makes Use the service life;Operating procedure is reduced, is settled at one go.
Specific embodiment
The present invention is described further combined with specific embodiments below.
Embodiment 1
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 20%
Macromolecule amine dispersing agent 15%
Fuel oil friction improver 10%
Antirust agent 10%
Solvent 35%
Gasoline additive 10%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 2;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X=y=200;R is H;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is BASF Kerocom PIBA 03.
Fuel oil friction improver uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is sunflower oil;Q1+q2=30, p1+p2=60, q1=q2=15, p1=p2=30,.
Antirust agent is lauric acid amide of ethanol;Solvent is butyl;Gasoline additive is isooctane, isopropyl Benzene, alkylbenzene etc. are than mixing.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 2
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 15%
Macromolecule amine dispersing agent 25%
Fuel oil friction improver 6%
Antirust agent 5%
Solvent 34%
Gasoline additive 15%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 2;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X is 80, y 200;R is H;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Huntsman Surfonamine B-100.
Fuel oil friction improver uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is linseed oil;Q1+q2=0, p1+p2=0, q1=q2=p1=p2=0.
Antirust agent is Coconut Fatty Acid Monoethanolamide;Solvent is methanol, isopropanol, cyclohexanone etc. than mixing;Gasoline additive For isopropylbenzene.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 3
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 1%
Macromolecule amine dispersing agent 20%
Fuel oil friction improver 10%
Antirust agent 5%
Solvent 54%
Gasoline additive 10%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 200;A is diallyl High molecular polyether, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, Middle x=y=145;R is H;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Surfonamine L-100.
Fuel oil friction improver uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is cottonseed oil;Q1+q2=20, p1+p2=30, q1=5, q2=15, p1=10, p2=20.
Antirust agent is oleic monoethanolamide;Solvent is butyl, ethylene glycol ethyl ether, propylene glycol monomethyl ether etc. than mixed It closes;Gasoline additive is alkylbenzene.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 4
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 17%
Macromolecule amine dispersing agent 5%
Fuel oil friction improver 10%
Antirust agent 1%
Solvent 60%
Gasoline additive 7%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 50;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X=y=160;R is the alkyl of C3;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Surfonamine B-60.
Fuel oil friction improver uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is butter, q1+q2=30, p1+p2=60, q1=q2=15, p1=p2=30.
Antirust agent is oleic acid diethyl amide;Solvent is No. 200 solvent naphthas, isopropanol, butyl, ethylene glycol ethyl ethers Ether, propylene glycol monomethyl ether etc. are than mixing;Gasoline additive is isopropylbenzene.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 5
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 20%
Macromolecule amine dispersing agent 25%
Fuel oil friction improver 10%
Antirust agent 10%
Solvent 20%
Gasoline additive 15%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 30;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X is 0, y 200;R is H;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Keropur 3448N.
Fuel oil friction improver uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is sunflower oil, q1+q2=20, p1+p2=20, q1=q2=p1=p2=10.
Antirust agent is stearic acid diglycollic amide;Solvent is D40, D60, ethyl alcohol, acetone, butanone etc. than mixing;Gasoline adds Adding agent is isopropylbenzene, alkylbenzene etc. than mixing.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 6
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 18%
Macromolecule amine dispersing agent 12%
Fuel oil friction improver 1%
Antirust agent 10%
Solvent 52%
Gasoline additive 7%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 120;A is diallyl High molecular polyether, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, Middle x is 0, y 0;R is H;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Keropur 3458N.
Fuel oil friction improver uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is soybean oil, q1+q2=10, p1+p2=60, q1=q2=5, p1=p2=30.
Antirust agent is lauric acid diethyl amide;Solvent is the ratio such as butyl glycol ether, propylene-glycol ethyl ether, butanone, cyclohexanone Mixing;Gasoline additive is isooctane.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 7
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 20%
Macromolecule amine dispersing agent 25%
Fuel oil friction improver 8%
Antirust agent 4%
Solvent 42%
Gasoline additive 1%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 2;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X is 90, y 0;R is H;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is BASF Kerocom PIBA 03, Huntsman Surfonamine B-100 With Surfonamine L-100, three etc. is than mixing.
Fuel oil friction improver uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is linseed oil, q1+q2=10, p1+p2=40, q1=q2=5, p1=p2=20.
Antirust agent is lauric acid amide of ethanol, Coconut Fatty Acid Monoethanolamide and oleic monoethanolamide, and three etc. is than mixed It closes;Solvent is isopropanol;Gasoline additive is isooctane.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 8
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 90;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X is 16, y 39;R is H;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Keropur 3448N and Keropur 3458N, and the two respectively accounts for dispersing agent total amount 1/2.
Fuel oil friction improver uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is cottonseed oil, q1+q2=30, p1+p2=0, q1=q=15, p1=p2=0.
Antirust agent is oleic acid diethyl amide and stearic acid diglycollic amide, and the two respectively accounts for the 1/2 of antirust agent total amount;Solvent For acetone;Gasoline additive is isooctane.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 9
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 10%
Macromolecule amine dispersing agent 15%
Fuel oil friction improver 5%
Antirust agent 5%
Solvent 53%
Gasoline additive 12%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 80;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X is 40, y 80;R is the alkyl of C2;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Surfonamine L-100, Surfonamine B-60, Keropur 3448N and Keropur 3458N, four kinds of raw materials respectively account for the 1/4 of dispersing agent total amount.
Fuel oil friction improver uses polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is cocounut oil, q1+q2=0, p1+p2=60, q1=q2=0, p1=p2=30.
Antirust agent lauric acid diethyl amide;Solvent is D40;Gasoline additive is alkylbenzene.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 10
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 15%
Macromolecule amine dispersing agent 20%
Fuel oil friction improver 2%
Antirust agent 2%
Solvent 55%
Gasoline additive 6%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 57;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X is 50, y 110;R is the alkyl of C3;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is BASF Kerocom PIBA 03.
Fuel oil friction improver is Lubrizol 9525A.
Antirust agent lauric acid diethyl amide;Solvent is No. 120 solvent naphthas;Gasoline additive is alkylbenzene.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 11
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 15%
Macromolecule amine dispersing agent 20%
Fuel oil friction improver 4%
Antirust agent 4%
Solvent 55%
Gasoline additive 2%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 15;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X is 100, y 100;R is the alkyl of C1;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Keropur 3448N.
Fuel oil friction improver is the mixing of 6457 equal proportion of Lubrizol 9525A and Hitec.
Antirust agent is stearic acid diglycollic amide;Solvent is D80;Gasoline additive is alkylbenzene.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 12
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 5%
Macromolecule amine dispersing agent 20%
Fuel oil friction improver 4%
Antirust agent 4%
Solvent 55%
Gasoline additive 12%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 5;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X is 200, y 200;R is H;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Huntsman Surfonamine B-100.
Fuel oil friction improver is Hitec 6457.
Antirust agent is lauric acid amide of ethanol;Solvent is methanol;Gasoline additive is alkylbenzene.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Embodiment 13
Exempt to tear automobile three-way catalysts cleaning agent raw material open:
Surfactant 15%
Macromolecule amine dispersing agent 8%
Fuel oil friction improver 5%
Antirust agent 5%
Solvent 55%
Gasoline additive 12%
Wherein, surfactant is organosilicon composition, and structural formula is B (A) mB: where m 2;A is that diallyl is high Molecule polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein X is 15, y 200;R is H;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O-Si(CH3)3]2
Macromolecule polarity amine dispersing agent is Surfonamine B-60.
Fuel oil friction improver is Lubrizol 9525A.
Antirust agent is oleic acid diethyl amide;Solvent is butyl glycol ether;Gasoline additive is isooctane.
Preparation method: at normal temperature, solvent is first added into reactor, other raw materials are then added, are mixed evenly To obtain the final product.
Experiment test
1, discharge amount is tested
The product prepared using the embodiment of the present invention 1 and the cleaning agent (comparative example 1) of the need bought on the market dismantling are done pair Than as follows using rear test data:
As seen from the above table, after using cleaning agent of the present invention to ternary catalyzing unit cleaning, automobile engine is in low idling and height Under idling mode, the discharge amount of carbon monoxide and hydrocarbon is below limit value, and therefore, this product is by being directly added into fuel tank Mode, clean entire oil circuit, can effectively dissolve obstinate carbon distribution and greasy filth on air inlet system parts, improve exhaust it is unsmooth, The problems such as power dropping, oil consumption increase;Rate of pollution is reduced, ternary catalyzing unit is protected, prolongs the service life;Face easy to use And effect is better than that the cleaning agent used need to be disassembled.
2, oil consumption is tested
The product prepared using the embodiment of the present invention 1 cleans the ternary catalyzing unit of different automobile types, test traveling 700 The fuel consumption per hundred kilometers amount of kilometer after cleaning, tests hundred kilometric fuel consumption pers of 700 kilometers of former road returns, and test data is as follows:
By upper table data it is found that through the embodiment of the present invention 1 product cleaning after, different automobile types can reach smooth gas discharge, The effect that power restores, return oil consumption is substantially reduced.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention Range.

Claims (8)

1. one kind is exempted to tear automobile three-way catalysts cleaning agent open, which is characterized in that by mass percentage, including the following raw material:
Surfactant 1~20%
Macromolecule amine dispersing agent 5~25%
Fuel oil friction improver 1~10%
Antirust agent 1~10%
Solvent 20~60%
Gasoline additive 1~15%.
2. one kind according to claim 1 is exempted to tear automobile three-way catalysts cleaning agent open, which is characterized in that by weight percent Meter, including the following raw material:
Surfactant 5~15%
Macromolecule amine dispersing agent 8~20%
Fuel oil friction improver 2~5%
Antirust agent 2~5%
Solvent 45~55%
Gasoline additive 2~12%.
3. one kind according to claim 1 or 2 is exempted to tear automobile three-way catalysts cleaning agent open, which is characterized in that the surface Activating agent is organosilicon composition, and structural formula is B (A) mB: where m is the integer more than or equal to 2;A is diallyl high score Sub- polyethers, structural formula are as follows:-CH2-CH(CH3)2-O-[CH2-CH2O]x-[CH2-CHR-O-]y-CH(CH3)2-CH2, wherein x, Y is the integer from 0 to 200;R is the alkyl of H or C1~C3;B is hydrophobic silicones, structural formula are as follows:-Si (CH3)-[O- Si(CH3)3]2
4. one kind according to claim 1 or 2 is exempted to tear automobile three-way catalysts cleaning agent open, which is characterized in that the height Molecule amine dispersing agent is polyisobutylene amine or polyphosphazene polymer ether amines.
5. one kind according to claim 1 or 2 is exempted to tear automobile three-way catalysts cleaning agent open, which is characterized in that the combustion Oil drag modifier is polyether-modified animals and plants oleyl amine, structural formula are as follows:
Wherein, R is the alkyl series matter of C8~C18;Q1+q2=0~30, p1+p2=0~60, q1, q2, p1, p2 are whole Number.
6. one kind according to claim 1 or 2 is exempted to tear automobile three-way catalysts cleaning agent open, which is characterized in that described is anti- Rust agent is fatty acid alkanol amides.
7. one kind according to claim 1 or 2 is exempted to tear automobile three-way catalysts cleaning agent open, which is characterized in that described is molten Agent is petroleum aromatic class, alcohols, ethers, ketone.
8. one kind according to claim 1 or 2 is exempted to tear automobile three-way catalysts cleaning agent open, which is characterized in that the vapour Oil additive is uprising dose of organic synthesis class and octane number additive.
CN201811592421.2A 2018-12-21 2018-12-21 One kind is exempted to tear automobile three-way catalysts cleaning agent open Pending CN109609293A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111117741A (en) * 2019-12-24 2020-05-08 江苏创新石化有限公司 Gasoline and diesel direct injection engine cleaning lubricant and preparation method thereof
CN111117777A (en) * 2019-12-31 2020-05-08 深圳市朗迅实业有限公司 Preparation method of diesel vehicle water-based carbon removal agent
CN112322398A (en) * 2020-09-15 2021-02-05 英德市东顺精细化工实业有限公司 Foam type air intake system disassembly-free cleaning agent
CN114958496A (en) * 2022-06-20 2022-08-30 江苏云瀚股份有限公司 Antirust cleaning agent for engine turbocharger and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN104531239A (en) * 2014-12-09 2015-04-22 中山市非特永旺汽车用品有限公司 High polymer fuel oil water removal emulsifier
CN107488526A (en) * 2017-07-25 2017-12-19 中山市非特永旺汽车用品有限公司 A kind of anti-rust cleaning agent of turbocharger of motor and preparation method thereof
CN108753479A (en) * 2018-06-05 2018-11-06 深圳市艾德化学品科技有限公司 A kind of direct fuel-injection engine gas handling system decarbonizer

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104531239A (en) * 2014-12-09 2015-04-22 中山市非特永旺汽车用品有限公司 High polymer fuel oil water removal emulsifier
CN107488526A (en) * 2017-07-25 2017-12-19 中山市非特永旺汽车用品有限公司 A kind of anti-rust cleaning agent of turbocharger of motor and preparation method thereof
CN108753479A (en) * 2018-06-05 2018-11-06 深圳市艾德化学品科技有限公司 A kind of direct fuel-injection engine gas handling system decarbonizer

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111117741A (en) * 2019-12-24 2020-05-08 江苏创新石化有限公司 Gasoline and diesel direct injection engine cleaning lubricant and preparation method thereof
CN111117777A (en) * 2019-12-31 2020-05-08 深圳市朗迅实业有限公司 Preparation method of diesel vehicle water-based carbon removal agent
CN112322398A (en) * 2020-09-15 2021-02-05 英德市东顺精细化工实业有限公司 Foam type air intake system disassembly-free cleaning agent
CN114958496A (en) * 2022-06-20 2022-08-30 江苏云瀚股份有限公司 Antirust cleaning agent for engine turbocharger and preparation method thereof

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Application publication date: 20190412