CN107476120A - 一种改性纸浆 - Google Patents

一种改性纸浆 Download PDF

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CN107476120A
CN107476120A CN201710522302.9A CN201710522302A CN107476120A CN 107476120 A CN107476120 A CN 107476120A CN 201710522302 A CN201710522302 A CN 201710522302A CN 107476120 A CN107476120 A CN 107476120A
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王君
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ANHUI ZHONGYA PAPER Co Ltd
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/10—Phosphorus-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/53—Polyethers; Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/57—Polyureas; Polyurethanes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
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Abstract

本发明公开了一种改性纸浆，按照重量份有以下原料组成：烟草浆20‑28份、烷氧基化脂肪醇2‑5份、木质纤维素18‑25份、芦粟壳20‑27份、粘合剂1‑2份、香精3‑5份、植物浆19‑22份、烷基苯酚聚氧乙烯醚2‑3份、消泡剂1‑4份、海带3‑5份、稀释剂2‑4份、破布浆17‑22份、云母占2‑7份和适量的水。本发明一种改性纸浆具有安全无毒、驱赶蚊虫、环保无污染且提高了纸制品的品质等特点。

Description

一种改性纸浆
技术领域
本发明涉及纸浆的研制生产领域，尤其涉及一种改性纸浆。
背景技术
众所周知，面巾纸是近年来国内开发起来的一个新品种，它以其卫生、方便、成本低、环保等特点越来越多地受到消费者的青睐，它不仅可以用来擦干手上的水份、油污，更可以清洁家居。随着人们生活水平的提高，面巾纸的使用必将越来越广泛。现有面巾纸大多以白色无香味为主，色彩单调，如果添加化学色素使颜色多样化，但是化学色素的加入使得面巾纸中化学物质成分增多，对人体产生伤害；市面上也存在带香味的面巾纸，大多是在生产的浆料里添加了香料，这些香料绝大多数为化工香料，对人体也有一定的伤害。随着人们的安全意识越来越强烈，面对色彩鲜艳或者香气扑鼻的面巾纸时往往会望而却步。因此，亟待研发出色彩丰富、香气怡人且安全无毒的面巾纸，以使面巾纸的市场前景更佳。
发明内容
本发明的目的是为了解决现有技术中存在的缺点，而提出的一种改性纸浆。
为了实现上述目的，本发明采用了如下技术方案：
一种改性纸浆，按照重量份有以下原料组成：烟草浆20-28份、烷氧基化脂肪醇2-5份、木质纤维素18-25份、芦粟壳20-27份、粘合剂1-2份、香精3-5份、植物浆19-22份、烷基苯酚聚氧乙烯醚2-3份、消泡剂1-4份、海带3-5份、稀释剂2-4份、破布浆17-22份、云母占2-7份和适量的水。
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料5-8份、二甲基硅油1-2.8份、磷酸三丁酯3-5份、烃化油12-15份、四丁基溴化磷3-5份和磺化蓖麻油6-9份。
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇1-3份、聚氨酯类树脂2-4份、乳化剂9-12、苍耳粉末3-5份、交联剂0.8-2份、改性聚二烷基硅氧烷3-7份和二氧化硅2-5份。
所述稀释剂，按照重量份有以下原料组成：棕榈仁油2-5份、醋酸乙酯2-3份、三水氟化铬1-3份、三氯丙烷4-5份、无水乙醇9-11份、柠檬酸三钠2-5份和聚乙烯醇2-6份。
上述一种改性纸浆，按照重量份有以下原料组成：烟草浆20-27份、烷氧基化脂肪醇2-4份、木质纤维素18-24份、芦粟壳20-26份、粘合剂1-1.9份、香精3-4.8份、植物浆19-21.5份、烷基苯酚聚氧乙烯醚2-2.9份、消泡剂1-3份、海带3-4.9份、稀释剂2-3.8份、破布浆17-21份、云母占2-6份和适量的水。
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料5-7份、二甲基硅油1-2.7份、磷酸三丁酯3-4.9份、烃化油12-14份、四丁基溴化磷3-4份和磺化蓖麻油6-8份。
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇1-2.8份、聚氨酯类树脂2-3.9份、乳化剂9-11、苍耳粉末3-4.9份、交联剂0.8-1.9份、改性聚二烷基硅氧烷3-6份和二氧化硅2-4份。
所述稀释剂，按照重量份有以下原料组成：棕榈仁油2-4份、醋酸乙酯2-2.9份、三水氟化铬1-2.8份、三氯丙烷4-4.9份、无水乙醇9-10份、柠檬酸三钠2-4份和聚乙烯醇2-5份。
上述一种改性纸浆，按照重量份有以下原料组成：烟草浆21-27份、烷氧基化脂肪醇3-4份、木质纤维素19-24份、芦粟壳21-26份、粘合剂1.2-1.9份、香精3.6-4.8份、植物浆20-21.5份、烷基苯酚聚氧乙烯醚2.4-2.9份、消泡剂2-3份、海带3.2-4.9份、稀释剂2.5-3.8份、破布浆18-21份、云母占3-6份和适量的水。
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料5-7份、二甲基硅油1.2-2.7份、磷酸三丁酯3.2-4.9份、烃化油13-14份、四丁基溴化磷3.1-4份和磺化蓖麻油7-8份。
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇1.5-2.8份、聚氨酯类树脂2.5-3.9份、乳化剂10-11、苍耳粉末3.5-4.9份、交联剂0.9-1.9份、改性聚二烷基硅氧烷4-6份和二氧化硅3-4份。
所述稀释剂，按照重量份有以下原料组成：棕榈仁油3-4份、醋酸乙酯2.1-2.9份、三水氟化铬1.2-2.8份、三氯丙烷4.1-4.9份、无水乙醇9.1-10份、柠檬酸三钠2.3-4份和聚乙烯醇3-5份。
上述一种改性纸浆，按照重量份有以下原料组成：烟草浆24份、烷氧基化脂肪醇3.5份、木质纤维素21.5份、芦粟壳23.5份、粘合剂1.5份、香精3.5份、植物浆20.5份、烷基苯酚聚氧乙烯醚2.5份、消泡剂2.5份、海带4份、稀释剂3份、破布浆19.5份、云母占4.5份和适量的水。
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料6.5份、二甲基硅油1.9份、磷酸三丁酯4份、烃化油13.5份、四丁基溴化磷4份和磺化蓖麻油7.5份。
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇2份、聚氨酯类树脂3份、乳化剂10.5、苍耳粉末4份、交联剂1.4份、改性聚二烷基硅氧烷5份和二氧化硅3.5份。
所述稀释剂，按照重量份有以下原料组成：棕榈仁油3.5份、醋酸乙酯2.5份、三水氟化铬2份、三氯丙烷4.5份、无水乙醇10份、柠檬酸三钠3.5份和聚乙烯醇4份。
与现有技术相比，本发明的有益效果是：
本发明一种改性纸浆具有安全无毒、驱赶蚊虫、环保无污染且提高了纸制品的品质等特点。
具体实施方式
实施例1
一种改性纸浆，按照重量份有以下原料组成：烟草浆20份、烷氧基化脂肪醇2份、木质纤维素18份、芦粟壳20份、粘合剂1份、香精3份、植物浆19份、烷基苯酚聚氧乙烯醚2份、消泡剂1份、海带3份、稀释剂2份、破布浆17份、云母占2份和适量的水。
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料5份、二甲基硅油1份、磷酸三丁酯3份、烃化油12份、四丁基溴化磷3份和磺化蓖麻油6份。
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇1份、聚氨酯类树脂2份、乳化剂9、苍耳粉末3份、交联剂0.8份、改性聚二烷基硅氧烷3份和二氧化硅2份。
所述稀释剂，按照重量份有以下原料组成：棕榈仁油2份、醋酸乙酯2份、三水氟化铬1份、三氯丙烷4份、无水乙醇9份、柠檬酸三钠2份和聚乙烯醇2份。
实施例2
上述的一种改性纸浆，按照重量份有以下原料组成：烟草浆28份、烷氧基化脂肪醇5份、木质纤维素25份、芦粟壳27份、粘合剂2份、香精5份、植物浆22份、烷基苯酚聚氧乙烯醚3份、消泡剂4份、海带5份、稀释剂4份、破布浆22份、云母占7份和适量的水。
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料8份、二甲基硅油2.8份、磷酸三丁酯5份、烃化油15份、四丁基溴化磷5份和磺化蓖麻油9份。
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇3份、聚氨酯类树脂4份、乳化剂12、苍耳粉末5份、交联剂2份、改性聚二烷基硅氧烷7份和二氧化硅5份。
所述稀释剂，按照重量份有以下原料组成：棕榈仁油5份、醋酸乙酯3份、三水氟化铬3份、三氯丙烷5份、无水乙醇11份、柠檬酸三钠5份和聚乙烯醇6份。
实施例3
上述一种改性纸浆，按照重量份有以下原料组成：烟草浆24份、烷氧基化脂肪醇3.5份、木质纤维素21.5份、芦粟壳23.5份、粘合剂1.5份、香精3.5份、植物浆20.5份、烷基苯酚聚氧乙烯醚2.5份、消泡剂2.5份、海带4份、稀释剂3份、破布浆19.5份、云母占4.5份和适量的水。
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料6.5份、二甲基硅油1.9份、磷酸三丁酯4份、烃化油13.5份、四丁基溴化磷4份和磺化蓖麻油7.5份。
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇2份、聚氨酯类树脂3份、乳化剂10.5、苍耳粉末4份、交联剂1.4份、改性聚二烷基硅氧烷5份和二氧化硅3.5份。
所述稀释剂，按照重量份有以下原料组成：棕榈仁油3.5份、醋酸乙酯2.5份、三水氟化铬2份、三氯丙烷4.5份、无水乙醇10份、柠檬酸三钠3.5份和聚乙烯醇4份。
上面对本专利的较佳实施方式作了详细说明，但是本专利并不限于上述实施方式，在本领域的普通技术人员所具备的知识范围内，还可以在不脱离本专利宗旨的前提下做出各种变化。

Claims (4)

1.一种改性纸浆，其特征在于，按照重量份有以下原料组成：烟草浆20-28份、烷氧基化脂肪醇2-5份、木质纤维素18-25份、芦粟壳20-27份、粘合剂1-2份、香精3-5份、植物浆19-22份、烷基苯酚聚氧乙烯醚2-3份、消泡剂1-4份、海带3-5份、稀释剂2-4份、破布浆17-22份、云母占2-7份和适量的水；
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料5-8份、二甲基硅油1-2.8份、磷酸三丁酯3-5份、烃化油12-15份、四丁基溴化磷3-5份和磺化蓖麻油6-9份；
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇1-3份、聚氨酯类树脂2-4份、乳化剂9-12、苍耳粉末3-5份、交联剂0.8-2份、改性聚二烷基硅氧烷3-7份和二氧化硅2-5份；
所述稀释剂，按照重量份有以下原料组成：棕榈仁油2-5份、醋酸乙酯2-3份、三水氟化铬1-3份、三氯丙烷4-5份、无水乙醇9-11份、柠檬酸三钠2-5份和聚乙烯醇2-6份。
2.根据权利要求1所述一种改性纸浆，其特征在于，按照重量份有以下原料组成：烟草浆20-27份、烷氧基化脂肪醇2-4份、木质纤维素18-24份、芦粟壳20-26份、粘合剂1-1.9份、香精3-4.8份、植物浆19-21.5份、烷基苯酚聚氧乙烯醚2-2.9份、消泡剂1-3份、海带3-4.9份、稀释剂2-3.8份、破布浆17-21份、云母占2-6份和适量的水；
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料5-7份、二甲基硅油1-2.7份、磷酸三丁酯3-4.9份、烃化油12-14份、四丁基溴化磷3-4份和磺化蓖麻油6-8份；
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇1-2.8份、聚氨酯类树脂2-3.9份、乳化剂9-11、苍耳粉末3-4.9份、交联剂0.8-1.9份、改性聚二烷基硅氧烷3-6份和二氧化硅2-4份；
所述稀释剂，按照重量份有以下原料组成：棕榈仁油2-4份、醋酸乙酯2-2.9份、三水氟化铬1-2.8份、三氯丙烷4-4.9份、无水乙醇9-10份、柠檬酸三钠2-4份和聚乙烯醇2-5份。
3.根据权利要求1所述一种改性纸浆，其特征在于，按照重量份有以下原料组成：烟草浆21-27份、烷氧基化脂肪醇3-4份、木质纤维素19-24份、芦粟壳21-26份、粘合剂1.2-1.9份、香精3.6-4.8份、植物浆20-21.5份、烷基苯酚聚氧乙烯醚2.4-2.9份、消泡剂2-3份、海带3.2-4.9份、稀释剂2.5-3.8份、破布浆18-21份、云母占3-6份和适量的水；
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料5-7份、二甲基硅油1.2-2.7份、磷酸三丁酯3.2-4.9份、烃化油13-14份、四丁基溴化磷3.1-4份和磺化蓖麻油7-8份；
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇1.5-2.8份、聚氨酯类树脂2.5-3.9份、乳化剂10-11、苍耳粉末3.5-4.9份、交联剂0.9-1.9份、改性聚二烷基硅氧烷4-6份和二氧化硅3-4份；
所述稀释剂，按照重量份有以下原料组成：棕榈仁油3-4份、醋酸乙酯2.1-2.9份、三水氟化铬1.2-2.8份、三氯丙烷4.1-4.9份、无水乙醇9.1-10份、柠檬酸三钠2.3-4份和聚乙烯醇3-5份。
4.根据权利要求1所述一种改性纸浆，其特征在于，按照重量份有以下原料组成：烟草浆24份、烷氧基化脂肪醇3.5份、木质纤维素21.5份、芦粟壳23.5份、粘合剂1.5份、香精3.5份、植物浆20.5份、烷基苯酚聚氧乙烯醚2.5份、消泡剂2.5份、海带4份、稀释剂3份、破布浆19.5份、云母占4.5份和适量的水；
所述消泡剂，按照重量份有以下原料组成：包括水泥熟料6.5份、二甲基硅油1.9份、磷酸三丁酯4份、烃化油13.5份、四丁基溴化磷4份和磺化蓖麻油7.5份；
所述粘合剂，按照重量份有以下原料组成：聚乙烯醇2份、聚氨酯类树脂3份、乳化剂10.5、苍耳粉末4份、交联剂1.4份、改性聚二烷基硅氧烷5份和二氧化硅3.5份；
所述稀释剂，按照重量份有以下原料组成：棕榈仁油3.5份、醋酸乙酯2.5份、三水氟化铬2份、三氯丙烷4.5份、无水乙醇10份、柠檬酸三钠3.5份和聚乙烯醇4份。
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