CN107474790B - A kind of waterproof color cementitious matter and preparation method thereof, waterproof roll - Google Patents
A kind of waterproof color cementitious matter and preparation method thereof, waterproof roll Download PDFInfo
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- CN107474790B CN107474790B CN201710583568.4A CN201710583568A CN107474790B CN 107474790 B CN107474790 B CN 107474790B CN 201710583568 A CN201710583568 A CN 201710583568A CN 107474790 B CN107474790 B CN 107474790B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
To overcome the problems, such as that current material adhesive property is poor, not beautiful enough, the present invention provides a kind of waterproof color cementitious matter, including furfural treatment readymade oil, hydrogenated petroleum resin, age resister, high-temperature viscosity reducer, talcum powder, inorganic pigment and selectively polyethylene, SBS, SBR for containing；Based on the waterproof color cementitious matter total weight, the content of furfural treatment readymade oil is 20~40%, the content of hydrogenated petroleum resin is 10~20%, the content that the content of SBS is 0~10%, SBR is 0~10%, and the content of age resister is 0.5~1%, the content of high-temperature viscosity reducer is 0.5~1%, the content of talcum powder is 20~40%, and the content of inorganic pigment is 4~10%, and the content of polyethylene is 0~10%.Meanwhile the present invention also provides the preparation method of above-mentioned waterproof color cementitious matter and the waterproof rolls being prepared by it.Waterproof color cementitious matter provided by the invention has excellent adhesive property, and the waterproof performance after use is excellent.And the waterproof color cementitious matter can according to actual needs deploy color, using rear more attractive.
Description
Technical field
The invention belongs to waterproof roll fields, and in particular to a kind of waterproof color cementitious matter and preparation method thereof, and adopt
The waterproof roll being prepared with the waterproof color cementitious matter.
Background technique
With the development of economy, the progress in epoch, the requirement to construction material is also higher and higher, and high-polymer modified pitch is anti-
Water coiled material is the waterproof material haveing excellent performance, and is widely used in industrial and residential construction area waterproof and dampproof.But China is anti-
The status that market for water remains high still in percolation ratio, analyze its main cause be embodied in material elongation percentage is low, resistance to ag(e)ing
Can be poor with adhesive property, it cannot realize with building and completely be stained with.Also, while present people focus on waterproof effect, to aesthetics
It also proposed certain requirement.
Summary of the invention
To overcome the problems, such as that current material adhesive property is poor, not beautiful enough, the present invention provides a kind of waterproof color cementitious matter
And preparation method thereof, and the waterproof roll being prepared using the waterproof color cementitious matter.
It is as follows that the present invention solves technical solution used by above-mentioned technical problem:
A kind of waterproof color cementitious matter, including furfural treatment readymade oil, hydrogenated petroleum resin, age resister, high temperature are provided
Thinner, talcum powder, inorganic pigment and the polyethylene selectively contained, SBS, SBR；With the waterproof color cementitious matter gross weight
Based on amount, the content of the furfural treatment readymade oil is 20~40%, and the content of hydrogenated petroleum resin is 10~20%, SBS
Content be 0~10%, SBR content be 0~10%, the content of age resister is 0.5~1%, the content of high-temperature viscosity reducer
It is 0.5~1%, the content of talcum powder is 20~40%, and the content of inorganic pigment is 4~10%, the content of polyethylene is 0~
10%.
Above-mentioned waterproof color cementitious matter provided by the invention has excellent adhesive property, and when use can firmly be bonded in
Substrate surface, to guarantee waterproof performance.It, can be according to actual use demand, to material face and due to being added with inorganic pigment
Color is deployed, and beautiful decorative effect is reached.
According to practical service environment, for example, in cold environments in use, the waterproof color glue disclosed above in the present invention
On the basis of ramming material, it is preferred that based on the waterproof color cementitious matter total weight, the content of the furfural treatment readymade oil is
30~40%, the content that the content that the content of hydrogenated petroleum resin is 10~20%, SBS is 1~5%, SBR is 5~10%, is resisted
The content of aging agent is 0.5~1%, and the content of high-temperature viscosity reducer is 0.5~1%, and the content of talcum powder is 20~40%, inorganic
The content of pigment is 4~10%, and the content of polyethylene is 0~5%.
The heat resisting temperature of the waterproof color cementitious matter is 90 DEG C or more, and low-temperature tenderness is -20 DEG C or more.Suitable for low temperature
In the higher environment of performance requirement.
On the contrary, under high temperature environment in use, on the basis of present invention waterproof color cementitious matter disclosed above, preferably
, based on the waterproof color cementitious matter total weight, the content of the furfural treatment readymade oil is 20~30%, adds hydrogen stone
The content that the content that the content of oleoresin is 15~20%, SBS is 1~5%, SBR is 5~10%, and the content of age resister is
0.5~1%, the content of high-temperature viscosity reducer is 0.5~1%, and the content of talcum powder is 20~40%, and the content of inorganic pigment is 4
~10%, the content of polyethylene is 5~10%.
The heat resisting temperature of the waterproof color cementitious matter is 115 DEG C or more, and low-temperature tenderness is -7 DEG C or more.It is particularly suited for pair
High-temperature behavior requires in higher environment.
Meanwhile the present invention provides the preparation methods of above-mentioned waterproof color cementitious matter, comprising the following steps: presses the weight
Furfural treatment readymade oil, hydrogenated petroleum resin are put into reactor tank by content, 0.5~2h are sufficiently reacted at 140~150 DEG C, so
SBS, SBR and age resister are put into reactor tank again afterwards, 10~60min is stirred at 150~160 DEG C, by colloid mill high speed
Development tank is imported after shearing, then polyethylene and high-temperature viscosity reducer are put into stirring sufficiently 1~4h of reaction in the development tank, finally
Add talcum powder and inorganic pigment to set out and educate tank stirring 0.5~2h of development, obtains the waterproof color cementitious matter.
In addition, being prepared the present invention also provides a kind of waterproof roll by foregoing waterproof color cementitious matter.
Specific embodiment
In order to which the technical problems, technical solutions and beneficial effects solved by the present invention is more clearly understood, below to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Waterproof color cementitious matter provided by the invention, including furfural treatment readymade oil, hydrogenated petroleum resin, age resister,
High-temperature viscosity reducer, talcum powder, inorganic pigment and the polyethylene selectively contained, SBS, SBR；With the waterproof color cementitious matter
Based on total weight, the content of the furfural treatment readymade oil is 20~40%, and the content of hydrogenated petroleum resin is 10~20%,
The content that the content of SBS is 0~10%, SBR is 0~10%, and the content of age resister is 0.5~1%, and high-temperature viscosity reducer contains
Amount is 0.5~1%, and the content of talcum powder is 20~40%, and the content of inorganic pigment is 4~10%, the content of polyethylene is 0~
10%.
Wherein, above-mentioned furfural treatment readymade oil is well known material.Different from furfural extract oil, furfural treatment readymade oil is
Atmospheric and vacuum distillation unit distillates product, specifically includes two wires oil, third fractional oil, four line oil etc..And furfural extract oil be made with furfural it is molten
The product of agent extracting, there are many feedstock oils extracted, such as two wires oil, third fractional oil, four line oil, catalytic slurry etc..Therefore, chaff
Aldehyde extraction oil is product of the furfural treatment readymade oil after processing.The nature difference of furfural extract oil and furfural treatment readymade oil
It is larger, for example, furfural extract oil density be greater than furfural treatment readymade oil.
In the present invention, it is found by many experiments, high-adhesion of the present invention is just able to achieve using furfural treatment readymade oil
The requirement of energy.Under preferable case, the furfural treatment readymade oil is furfural treatment two wires oil.
In more preferable situation, arene content is greater than 60% in the furfural treatment readymade oil, to preferably guarantee bonding
Performance.It is further preferred that 100 DEG C of 6~18mm of kinematic viscosity range of the furfural treatment readymade oil2/ s, at this time to raising
Adhesive property is more advantageous.The freezing point of the furfural treatment readymade oil ranges preferably from -15~0 DEG C.Using above-mentioned condition range
Interior furfural treatment readymade oil is more advantageous to raising adhesive property and waterproof performance.
The Petropols used in the present invention is hydrogenated petroleum resins.Specifically, adding hydrogen stone using C9 in the present invention
Oleoresin, the high-adhesion for realizing waterproof color cementitious matter provided by the invention are highly beneficial.
C9 hydrogenated petroleum resin refer to comprising nine carbon atoms " alkene or cycloolefin carry out polymerization or with aldehydes, aromatic hydrocarbons,
Terpene compound etc. is copolymerized " resinous material.
C9 hydrogenated petroleum resin is also known as Aromatic Petroleum Resins, is divided into the types such as hot polymerization, cold poly-, tar, wherein cold poly- method produces
Product are of light color, high-quality, average molecular weight 2000~5000.Faint yellow to light brown sheet, granular or blocks of solid, it is transparent and
It is glossy, relative density 0.97~1.04.80~140 DEG C of softening point.81 DEG C of glass transition temperature.Refractive index 1.512.Flash-point 260
℃.Acid value 0.1~1.0.Iodine number 30~120.It is dissolved in acetone, methyl ethyl ketone, hexamethylene, dichloroethanes, ethyl acetate, toluene, vapour
Oil etc..Insoluble in second alcohol and water.With cyclic structure, containing partial double bond, cohesive force is big.Polarity or function are free of in molecular structure
Energy property group, without chemical activity.Acid and alkali-resistance, chemical resistance, water resistance are good.With phenolic resin, coumarone indene resin, terpene
Olefine resin, SBR, SIS compatibility are good.It enbrittles, tackifying, caking property and plasticity.
According to the present invention, in above-mentioned waterproof color cementitious matter, age resister can be used it is conventional various, under preferable case,
The age resister is selected from one of phenyl salicylate, ultraviolet absorbing agent, light stabilizer, sulfurous organic compound or a variety of.Tool
Body, Ultraviolet Absorber UV-P, ultraviolet absorbing agent UV-O, ultraviolet absorbing agent UV- can be selected in above-mentioned ultraviolet absorbing agent
531.Light stabilizer GW-540 can be selected in light stabilizer.
Sulfurous organic compound includes one or more of sulphur, sulfur-bearing organic peroxide.
The polyethylene used in the present invention is preferably low density linear polyethylene.
Material above-mentioned SBS known to those skilled in the art, specially s-B-S block are total
Polymers.Under preferable case, styrene-content is 30~40% in the SBS, at this time to further increasing waterproof color cementitious matter
Performance it is more advantageous.
Butadiene-styrene rubber above-mentioned SBR known to those skilled in the art.Under preferable case, the glue effective quantity of the SBR
It is 95% or more.
Routine can be selected in inorganic pigment, for example, specifically can be selected from iron oxide red, lead chromate yellow (plumbous chromate), zinc yellow (chromium
Sour zinc), cadmium yellow (cadmium sulfide), chrome oxide green, one of chrome green or a variety of.
The talcum powder is known to those skilled in the art, and under preferable case, the mesh number of the talcum powder is 400 mesh
More than.For example, being specifically as follows 400 mesh medical talc powders.
According to the present invention, particularly, the waterproof color cementitious matter further includes high-temperature viscosity reducer.Specifically, above-mentioned height
Temperature drop stick is selected from one of husky rope wax, high sticky wax or a variety of.
In waterproof color cementitious matter provided by the invention, SBR, SBS and polymerized ethylene content as modifying agent are higher, reach
To 15% or more, in general, the viscosity of waterproof color cementitious matter at high temperature is higher under this high-content, it is unfavorable for improving its property
Can, by using special high-temperature viscosity reducer in the present invention, in particular by one of husky rope wax, high sticky wax or a variety of, make
(such as 170 DEG C) viscosity keeps good to waterproof color cementitious matter at high temperature, to ensure that excellent adhesive property.
In general, existing under different use environments (such as hot environment and low temperature environment) to the actual performance of material
A small amount of difference.On the basis of above-mentioned waterproof color cementitious matter provided by the invention, the material for being applicable in varying environment can be optimized and revised out
Material, for example, it is preferable in the case of, based on the waterproof color cementitious matter total weight, the content of the furfural treatment readymade oil
It is 30~40%, the content that the content that the content of hydrogenated petroleum resin is 10~20%, SBS is 1~5%, SBR is 5~10%,
The content of age resister is 0.5~1%, and the content of high-temperature viscosity reducer is 0.5~1%, and the content of talcum powder is 20~40%, nothing
The content of machine pigment is 4~10%, and the content of polyethylene is 0~5%.
Under above-mentioned composition, the heat resisting temperature of the waterproof color cementitious matter is 90 DEG C or more, low-temperature tenderness be -20 DEG C with
On, suitable in low temperature environment.
On the other hand, according to the invention it is preferred in the case of, it is described based on the waterproof color cementitious matter total weight
The content of furfural treatment readymade oil is 20~30%, the content that the content of hydrogenated petroleum resin is 15~20%, SBS is 1~
The content of 5%, SBR are 5~10%, and the content of age resister is 0.5~1%, and the content of high-temperature viscosity reducer is 0.5~1%, sliding
The content of mountain flour is 20~40%, and the content of inorganic pigment is 4~10%, and the content of polyethylene is 5~10%.
At this point, the heat resisting temperature of the waterproof color cementitious matter with above-mentioned composition is 115 DEG C or more, low-temperature tenderness is -10
DEG C or more, it is particularly suited under hot environment.
No matter the waterproof color cementitious matter that above-mentioned low temperature environment is applicable in or hot environment is applicable, all have excellent caking property
Energy.
Meanwhile the present invention also provides the preparation methods of above-mentioned waterproof color cementitious matter, it is preferred that the following steps are included:
Furfural treatment readymade oil, hydrogenated petroleum resin are put into reactor tank by the weight content, sufficiently reacted at 140~150 DEG C
Then SBS, SBR and age resister are put into reactor tank again by 0.5~2h, 10~60min is stirred at 150~160 DEG C, are passed through
Development tank is imported after colloid mill high speed shear, then polyethylene and high-temperature viscosity reducer are put into stirring sufficiently reaction in the development tank
1~4h, finally plus talcum powder and inorganic pigment set out and educate tank stirring 0.5~2h of development, obtain the waterproof color cementitious matter.
It should be understood that such as polyethylene etc., the content according to determined by reality adds for the material selectively added
Add, when being free of the material in the composition of use, is not added in corresponding step.
In addition, being prepared the present invention also provides a kind of waterproof roll by foregoing waterproof color cementitious matter.
Specific preparation method is known in those skilled in the art, such as: use modified asphalt waterproof roll production line, polyester
It is dried after the expansion of tire base by conduction oil, then using preimpregnation oil-impregnated, extracts rear upper and lower surface and coat above-mentioned waterproof color glue
Ramming material and the thickness for controlling upper and lower level pass through cooling bay and cover upper heat shrink films or surface fine sand, shale, continues to cool down, until
When surface temperature is less than 130 DEG C, lower surface heat shrink films and overleaf water-spraying control are covered, it is ensured that heat shrink films will not become
Shape, scribing line, after cooling, clot is kept well according to 10 square meter a roll.
The present invention is further detailed by the following examples.
Embodiment 1
The present embodiment is for illustrating waterproof color cementitious matter disclosed by the invention and preparation method thereof.
The composition of waterproof color cementitious matter is as follows；
(100 DEG C of viscosity are 8mm to furfural treatment readymade oil2/ s, freezing point be -12 DEG C, arene content 68%) content
The content that content for 35%, C9 hydrogenated petroleum resin (110~130 DEG C of softening point, yellow) is 15%, SBS1301 is 5%,
The content of SBR (glue effective content is 95%) is 8%, and the content of age resister (Ultraviolet Absorber UV-P) is 1%, high temperature drop
The content of stick (Sasobit LM) is 1%, and the content of talcum powder (400 mesh medical talc powder) is 27%, inorganic pigment (oxidation
Iron oxide red) content be 5%, the content of polyethylene (PE 7042) is 3%.
According to above-mentioned composition, furfural treatment readymade oil, hydrogenated petroleum resin are put into reactor tank to by the weight content,
1h is sufficiently reacted at 140~150 DEG C, and SBS, SBR and age resister are then put into reactor tank again, stirred at 150~160 DEG C
30min is mixed, development tank is imported after colloid mill high speed shear, then polyethylene and high-temperature viscosity reducer are put into the development tank
Stirring sufficiently reaction 2h, finally plus talcum powder and inorganic pigment set out and educate tank stirring development 1h, obtain waterproof color cementitious matter.
The moulding process of color coil production are as follows:
Using modified asphalt waterproof roll production line, is dried after polyester base expansion by conduction oil, then used
Oil-impregnated is presoaked, rear upper and lower surface is extracted and coats above-mentioned waterproof color cementitious matter and control the thickness of upper and lower level, pass through cooling bay
And upper heat shrink films or surface fine sand, shale are covered, continue to cool down, until covering lower surface heat is received when surface temperature is less than 130 DEG C
Contracting film and overleaf water-spraying control, it is ensured that heat shrink films will not deform, scribing line, after cooling, clot, according to 10 square meters a roll
It keeps well.
Embodiment 2
The present embodiment is for illustrating waterproof color cementitious matter disclosed by the invention and preparation method thereof.
The composition of waterproof color cementitious matter is as follows；
(100 DEG C of viscosity are 10mm to furfural treatment readymade oil2/ s, freezing point be -8 DEG C, arene content 75%) content
The content that content for 30%, C9 hydrogenated petroleum resin (110~130 DEG C of softening point, yellow) is 20%, SBS1301 is 2%,
The content of SBR (glue effective content is 95%) is 10%, and the content of age resister (Ultraviolet Absorber UV-P) is 0.6%, high
The content of temperature drop stick (Sasobit LM) is 0.6%, and the content of talcum powder (400 mesh medical talc powder) is 27.8%, inorganic
The content of pigment (iron oxide red) is 8%, and the content of polyethylene (PE 7042) is 1%.
According to above-mentioned composition, furfural treatment readymade oil, hydrogenated petroleum resin are put into reactor tank to by the weight content,
1h is sufficiently reacted at 140~150 DEG C, and SBS, SBR and age resister are then put into reactor tank again, stirred at 150~160 DEG C
30min is mixed, development tank is imported after colloid mill high speed shear, then polyethylene and high-temperature viscosity reducer are put into the development tank
Stirring sufficiently reaction 2h, finally plus talcum powder and inorganic pigment set out and educate tank stirring development 1h, obtain waterproof color cementitious matter.
The moulding process of color coil production are as follows:
Using modified asphalt waterproof roll production line, is dried after polyester base expansion by conduction oil, then used
Oil-impregnated is presoaked, rear upper and lower surface is extracted and coats above-mentioned waterproof color cementitious matter and control the thickness of upper and lower level, pass through cooling bay
And upper heat shrink films or surface fine sand, shale are covered, continue to cool down, until covering lower surface heat is received when surface temperature is less than 130 DEG C
Contracting film and overleaf water-spraying control, it is ensured that heat shrink films will not deform, scribing line, after cooling, clot, according to 10 square meters a roll
It keeps well.
Embodiment 3
The present embodiment is for illustrating waterproof color cementitious matter disclosed by the invention and preparation method thereof.
The composition of waterproof color cementitious matter is as follows；
(100 DEG C of viscosity are 15mm to furfural treatment readymade oil2/ s, freezing point be -4 DEG C, arene content 78%) content
The content that content for 40%, C9 hydrogenated petroleum resin (110~130 DEG C of softening point, yellow) is 10%, SBS1301 is 4%,
The content of SBR (glue effective content is 95%) is 5%, and the content of age resister (Ultraviolet Absorber UV-P) is 0.8%, high temperature
The content of thinner (Sasobit LM) is 0.8%, and the content of talcum powder (400 mesh medical talc powder) is 30.4%, inorganic face
The content for expecting (iron oxide red) is 4%, and the content of polyethylene (PE 7042) is 5%.
According to above-mentioned composition, furfural treatment readymade oil, hydrogenated petroleum resin are put into reactor tank to by the weight content,
1h is sufficiently reacted at 140~150 DEG C, and SBS, SBR and age resister are then put into reactor tank again, stirred at 150~160 DEG C
30min is mixed, development tank is imported after colloid mill high speed shear, then polyethylene and high-temperature viscosity reducer are put into the development tank
Stirring sufficiently reaction 2h, finally plus talcum powder and inorganic pigment set out and educate tank stirring development 1h, obtain waterproof color cementitious matter.
The moulding process of color coil production are as follows:
Using modified asphalt waterproof roll production line, is dried after polyester base expansion by conduction oil, then used
Oil-impregnated is presoaked, rear upper and lower surface is extracted and coats above-mentioned waterproof color cementitious matter and control the thickness of upper and lower level, pass through cooling bay
And upper heat shrink films or surface fine sand, shale are covered, continue to cool down, until covering lower surface heat is received when surface temperature is less than 130 DEG C
Contracting film and overleaf water-spraying control, it is ensured that heat shrink films will not deform, scribing line, after cooling, clot, according to 10 square meters a roll
It keeps well.
Embodiment 4
The present embodiment is for illustrating waterproof color cementitious matter disclosed by the invention and preparation method thereof.
Waterproof color cementitious matter is prepared using the composition of embodiment 1, difference is, the aromatic hydrocarbons of the furfural treatment readymade oil
Content is 50%, 100 DEG C of 6~10mm of kinematic viscosity range2/ s solidifies point range -15~20 DEG C.
Embodiment 5
The present embodiment is for illustrating waterproof color cementitious matter disclosed by the invention and preparation method thereof.
The composition of waterproof color cementitious matter is as follows；
(100 DEG C of viscosity are 18mm to furfural treatment readymade oil2/ s, freezing point be 0 DEG C, arene content 82%) content be
The content that the content of 30%, C9 hydrogenated petroleum resin (110~130 DEG C of softening point, yellow) is 20%, SBS4303 is 2%, SBR
The content of (glue effective content is 95%) is 3%, and the content of age resister (Ultraviolet Absorber UV-P) is 1%, high temperature viscosity reduction
The content of agent (Sasobit LM) is 1%, and the content of talcum powder (400 mesh medical talc powder) is 30%, inorganic pigment (chromium oxide
It is green) content be 5%, the content of polyethylene (PE 7042) is 8%.
According to above-mentioned composition, furfural treatment readymade oil, hydrogenated petroleum resin are put into reactor tank to by the weight content,
1h is sufficiently reacted at 140~150 DEG C, and SBS, SBR and age resister are then put into reactor tank again, stirred at 150~160 DEG C
30min is mixed, development tank is imported after colloid mill high speed shear, then polyethylene and high-temperature viscosity reducer are put into the development tank
Stirring sufficiently reaction 2h, finally plus talcum powder and inorganic pigment set out and educate tank stirring development 1h, obtain waterproof color cementitious matter.
The moulding process of color coil production are as follows:
Using modified asphalt waterproof roll production line, is dried after polyester base expansion by conduction oil, then used
Oil-impregnated is presoaked, rear upper and lower surface is extracted and coats above-mentioned waterproof color cementitious matter and control the thickness of upper and lower level, pass through cooling bay
And upper heat shrink films or surface fine sand, shale are covered, continue to cool down, until covering lower surface heat is received when surface temperature is less than 130 DEG C
Contracting film and overleaf water-spraying control, it is ensured that heat shrink films will not deform, scribing line, after cooling, clot, according to 10 square meters a roll
It keeps well.
Embodiment 6
The present embodiment is for illustrating waterproof color cementitious matter disclosed by the invention and preparation method thereof.
The composition of waterproof color cementitious matter is as follows；
(100 DEG C of viscosity are 18mm to furfural treatment readymade oil2/ s, freezing point be 0 DEG C, arene content 82%) content be
The content that the content of 20%, C9 hydrogenated petroleum resin (110~130 DEG C of softening point, yellow) is 15%, SBS4303 is 5%, SBR
The content of (glue effective content is 95%) is 5%, and the content of age resister (Ultraviolet Absorber UV-P) is 0.6%, high temperature drop
The content of stick (Sasobit LM) is 0.6%, and the content of talcum powder (400 mesh medical talc powder) is 38.8%, inorganic pigment
The content of (chrome oxide green) is 10%, and the content of polyethylene (PE 7042) is 5%.
According to above-mentioned composition, furfural treatment readymade oil, hydrogenated petroleum resin are put into reactor tank to by the weight content,
1h is sufficiently reacted at 140~150 DEG C, and SBS, SBR and age resister are then put into reactor tank again, stirred at 150~160 DEG C
30min is mixed, development tank is imported after colloid mill high speed shear, then polyethylene and high-temperature viscosity reducer are put into the development tank
Stirring sufficiently reaction 2h, finally plus talcum powder and inorganic pigment set out and educate tank stirring development 1h, obtain waterproof color cementitious matter.
The moulding process of color coil production are as follows:
Using modified asphalt waterproof roll production line, is dried after polyester base expansion by conduction oil, then used
Oil-impregnated is presoaked, rear upper and lower surface is extracted and coats above-mentioned waterproof color cementitious matter and control the thickness of upper and lower level, pass through cooling bay
And upper heat shrink films or surface fine sand, shale are covered, continue to cool down, until covering lower surface heat is received when surface temperature is less than 130 DEG C
Contracting film and overleaf water-spraying control, it is ensured that heat shrink films will not deform, scribing line, after cooling, clot, according to 10 square meters a roll
It keeps well.
Embodiment 7
The present embodiment is for illustrating waterproof color cementitious matter disclosed by the invention and preparation method thereof.
The composition of waterproof color cementitious matter is as follows；
(100 DEG C of viscosity are 18mm to furfural treatment readymade oil2/ s, freezing point be 0 DEG C, arene content 82%) content be
The content that the content of 25%, C9 hydrogenated petroleum resin (110~130 DEG C of softening point, yellow) is 18%, SBS4303 is 1%, SBR
The content of (glue effective content is 95%) is 10%, and the content of age resister (Ultraviolet Absorber UV-P) is 0.8%, high temperature drop
The content of stick (Sasobit LM) is 0.8%, and the content of talcum powder (400 mesh medical talc powder) is 30.4%, inorganic pigment
The content of (chrome oxide green) is 4%, and the content of polyethylene (PE 7042) is 10%.
According to above-mentioned composition, furfural treatment readymade oil, hydrogenated petroleum resin are put into reactor tank to by the weight content,
1h is sufficiently reacted at 140~150 DEG C, and SBS, SBR and age resister are then put into reactor tank again, stirred at 150~160 DEG C
30min is mixed, development tank is imported after colloid mill high speed shear, then polyethylene and high-temperature viscosity reducer are put into the development tank
Stirring sufficiently reaction 2h, finally plus talcum powder and inorganic pigment set out and educate tank stirring development 1h, obtain waterproof color cementitious matter.
The moulding process of color coil production are as follows:
Using modified asphalt waterproof roll production line, is dried after polyester base expansion by conduction oil, then used
Oil-impregnated is presoaked, rear upper and lower surface is extracted and coats above-mentioned waterproof color cementitious matter and control the thickness of upper and lower level, pass through cooling bay
And upper heat shrink films or surface fine sand, shale are covered, continue to cool down, until covering lower surface heat is received when surface temperature is less than 130 DEG C
Contracting film and overleaf water-spraying control, it is ensured that heat shrink films will not deform, scribing line, after cooling, clot, according to 10 square meters a roll
It keeps well.
Embodiment 8
The present embodiment is for illustrating waterproof color cementitious matter disclosed by the invention and preparation method thereof.
Waterproof color cementitious matter is prepared using the composition of embodiment 1, difference is, the aromatic hydrocarbons of the furfural treatment readymade oil
Content is 90%, 100 DEG C of 18~25mm of kinematic viscosity range2/ s solidifies 0~20 DEG C of point range.
Comparative example 1
This comparative example is for comparative illustration waterproof color cementitious matter disclosed by the invention and preparation method thereof.
Waterproof color cementitious matter is prepared using the composition of embodiment 1, difference is, using furfural extract oil replacement furfural essence
Readymade oil processed.
Comparative example 2
This comparative example is for comparative illustration waterproof color cementitious matter disclosed by the invention and preparation method thereof.
Waterproof color cementitious matter is prepared using the composition of embodiment 5, difference is, is free of high-temperature viscosity reducer.Performance test
The waterproof roll that embodiment 1-4 and comparative example 1 are prepared is tested according to GB18243-2008 standard.?
The test result arrived is as shown in table 1.
Table 1
The waterproof roll that embodiment 5-8 and comparative example 2 are prepared is tested according to GB18243-2008.
Obtained test result is as shown in table 2.
Table 2
It can be seen that waterproof color cementitious matter provided by the invention with excellent bonding from the test data of Tables 1 and 2
Performance, and heat resistance and low temperature flexibility are excellent, and there is no permeable problems.Also, due to being added to inorganic pigment, more
Attractive, decorative effect.
Especially in the furfural treatment readymade oil of use, arene content be greater than 60%, 100 DEG C of kinematic viscosity ranges 6~
18mm2/ s, it is more advantageous to raising adhesive property and waterproof performance when solidifying point range -15~0 DEG C.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (10)
1. a kind of waterproof color cementitious matter, which is characterized in that including furfural treatment readymade oil, C9 hydrogenated petroleum resin, anti-aging
Agent, high-temperature viscosity reducer, talcum powder, inorganic pigment and the polyethylene selectively contained, SBS, SBR；
Based on the waterproof color cementitious matter total weight, the content of the furfural treatment readymade oil is that 20~40%, C9 adds
The content that the content that the content of hydrogen Petropols is 10~20%, SBS is 0~10%, SBR is 0~10%, and age resister contains
Amount is 0.5~1%, and the content of high-temperature viscosity reducer is 0.5~1%, and the content of talcum powder is 20~40%, the content of inorganic pigment
It is 4~10%, the content of polyethylene is 0~10%.
2. waterproof color cementitious matter according to claim 1, which is characterized in that with the waterproof color cementitious matter total weight
Based on, the content of the furfural treatment readymade oil is that the content of 30~40%, C9 hydrogenated petroleum resin is 10~20%, SBS
Content be 1~5%, SBR content be 5~10%, the content of age resister is 0.5~1%, and the content of high-temperature viscosity reducer is
0.5~1%, the content of talcum powder is 20~40%, and the content of inorganic pigment is 4~10%, and the content of polyethylene is 0~5%.
3. waterproof color cementitious matter according to claim 2, which is characterized in that the heat-resisting temperature of the waterproof color cementitious matter
Degree is 90 DEG C or more, and low-temperature tenderness is -20 DEG C or more.
4. waterproof color cementitious matter according to claim 1, which is characterized in that with the waterproof color cementitious matter total weight
Based on, the content of the furfural treatment readymade oil is that the content of 20~30%, C9 hydrogenated petroleum resin is 15~20%, SBS
Content be 1~5%, SBR content be 5~10%, the content of age resister is 0.5~1%, and the content of high-temperature viscosity reducer is
0.5~1%, the content of talcum powder is 20~40%, and the content of inorganic pigment is 4~10%, the content of polyethylene is 5~
10%.
5. waterproof color cementitious matter according to claim 4, which is characterized in that the heat-resisting temperature of the waterproof color cementitious matter
Degree is 115 DEG C or more, and low-temperature tenderness is -10 DEG C or more.
6. waterproof color cementitious matter described in any one of -5 according to claim 1, which is characterized in that the furfural treatment subtracts
Line oil is furfural treatment two wires oil, wherein arene content is greater than 60%, 100 DEG C of 6~18mm of kinematic viscosity range2/ s, freezing point
Range -15~0 DEG C.
7. waterproof color cementitious matter described in any one of -5 according to claim 1, which is characterized in that the age resister choosing
From one of phenyl salicylate, ultraviolet absorbing agent, light stabilizer, sulfurous organic compound or a variety of；
The talcum powder mesh number is 400 mesh or more；
The inorganic pigment is selected from one of iron oxide red, lead chromate yellow, zinc yellow, cadmium yellow, chrome oxide green, chrome green or more
Kind.
8. waterproof color cementitious matter described in any one of -5 according to claim 1, which is characterized in that the high-temperature viscosity reducer
Selected from one of husky rope wax, high sticky wax or a variety of.
9. the preparation method of the waterproof color cementitious matter as described in any one of claim 1-8, which is characterized in that including with
Lower step: furfural treatment readymade oil, C9 hydrogenated petroleum resin are put into reactor tank by the weight content, at 140~150 DEG C
Sufficiently 0.5~2h of reaction, then puts into reactor tank for SBS, SBR and age resister again, stir 10 at 150~160 DEG C~
60min imports development tank after colloid mill high speed shear, then polyethylene and high-temperature viscosity reducer is put into the development tank and stirred
Sufficiently 1~4h of reaction is mixed, finally plus talcum powder and inorganic pigment set out and educate tank stirring 0.5~2h of development, obtain the anti-watercolor
Coloring agent ramming material.
10. a kind of waterproof roll, which is characterized in that cementing by the waterproof color as described in any one of claim 1-8
Material is prepared.
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| CN111286206A (en) * | 2020-02-01 | 2020-06-16 | 湖北楚天卓越工程技术有限公司 | Cementing material for road color asphalt concrete and preparation method thereof |
| CN111647363A (en) * | 2020-06-19 | 2020-09-11 | 定州市庆丰易防水材料有限公司 | Environment-friendly elastomer modified asphalt waterproof coiled material |
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| CN1097014A (en) * | 1993-07-02 | 1995-01-04 | 中国石油化工总公司抚顺石油化工研究院 | Colored road surface agglutinate and preparation method thereof |
| CN1478955A (en) * | 2003-07-14 | 2004-03-03 | 汪成夫 | Coloured cementing material for paving road surface and its preparation method |
| CN1760276A (en) * | 2005-11-02 | 2006-04-19 | 克拉玛依市金山石油化工有限公司 | Multicolor asphalt |
| CN103881402A (en) * | 2014-03-11 | 2014-06-25 | 吉林省嘉瑞沥青科技有限公司 | Colored asphalt and preparation method thereof |
| CN105255097A (en) * | 2015-10-28 | 2016-01-20 | 重庆特铺路面工程技术有限公司 | Light-colored asphalt cement and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT403052B (en) * | 1993-12-30 | 1997-11-25 | Krems Chemie Ag | BITUMEN-FREE BINDING AGENT, BUILDING MATERIAL AND AQUEOUS BINDING AGENT EMULSION |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1097014A (en) * | 1993-07-02 | 1995-01-04 | 中国石油化工总公司抚顺石油化工研究院 | Colored road surface agglutinate and preparation method thereof |
| CN1478955A (en) * | 2003-07-14 | 2004-03-03 | 汪成夫 | Coloured cementing material for paving road surface and its preparation method |
| CN1760276A (en) * | 2005-11-02 | 2006-04-19 | 克拉玛依市金山石油化工有限公司 | Multicolor asphalt |
| CN103881402A (en) * | 2014-03-11 | 2014-06-25 | 吉林省嘉瑞沥青科技有限公司 | Colored asphalt and preparation method thereof |
| CN105255097A (en) * | 2015-10-28 | 2016-01-20 | 重庆特铺路面工程技术有限公司 | Light-colored asphalt cement and preparation method thereof |
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