CN107474735B - Ultraviolet-cured wood wax oil - Google Patents
Ultraviolet-cured wood wax oil Download PDFInfo
- Publication number
- CN107474735B CN107474735B CN201710789328.XA CN201710789328A CN107474735B CN 107474735 B CN107474735 B CN 107474735B CN 201710789328 A CN201710789328 A CN 201710789328A CN 107474735 B CN107474735 B CN 107474735B
- Authority
- CN
- China
- Prior art keywords
- parts
- oil
- wax
- wood wax
- vegetable oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/005—Drying oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses ultraviolet curing wood wax oil which comprises, by mass, 60-80 parts of polyurethane modified vegetable oil, 5-10 parts of wax slurry, 5-10 parts of orange oil, 1-5 parts of nano-additives, 1-5 parts of photoinitiators and 1-5 parts of auxiliary additives. The wood wax oil is an environment-friendly product, is quick to dry, non-toxic, tasteless, mildew-proof, high in hardness and good in chemical resistance, can embody the simplicity and natural texture of wood when being used on furniture and floors, has strong protection, is suitable for automatic water-flowing industry of factories, and greatly improves the production efficiency of the factories.
Description
Technical Field
The invention relates to the field of coatings, in particular to ultraviolet light curing wood wax oil and a manufacturing method thereof.
Background
Wood wax oil is a modern coating, and occupies certain market segments, and is a kind of environment-friendly furniture coating, which is more and more popular, and the wood wax oil is refined by natural vegetable oil and natural wax through modern chemical technology, and has the environment-friendly requirement of meeting sustainable development, and does not contain benzene, formaldehyde, heavy metal and the like. Oil in the wax oil can penetrate into the wood to provide deep moistening and maintenance for the wood; the wax can be tightly combined with wood fibers, so that the surface hardness is enhanced, and the wood fiber is waterproof, antifouling, wear-resistant and scratch-resistant. The wood wax oil is simple and convenient to construct, simple in process and more suitable for the demands of the public on DIY, but the wood wax oil has the following problems in the application process:
1) the drying time of the wood wax oil is too long, 4-8 hours of drying time is needed after the wood wax oil is coated on the woodware, and particularly, the drying time of some wood wax oil is as long as 12 hours in the environment with lower air temperature, and the drying time of the wood wax oil is longer, thus seriously influencing the production efficiency of furniture and floor industrialized flow operation.
2) The wood wax oil has poor performance, although the existing wood wax oil in the market, the surface of the coated furniture and other woodware can show the texture of the simplicity of wood and has exquisite hand feeling, the performance of the surface of the woodware is poor, and although the wax in the wood wax oil can play a certain role in water resistance and chemical resistance, the wood wax oil is still not satisfactory and has no comparability with paint.
3) The wood wax oil is extracted from vegetable oil, and has partial residual smell when being dried in the using process, although no toxicity and harm to human bodies are found at present, the wood wax oil is uncomfortable to people.
4) Most of the existing UV paints in the market are added with active monomers in the formula, the active monomers are irritant and allergic to human bodies, the UV paints can generate large pungent smell and are harmful to the human bodies due to the excessive use of cheap photoinitiators, and furniture floors coated with the UV paints cannot reflect the original natural and plain aesthetic feeling of wood due to the thick paint film.
When the UV paint is dried, the UV paint must be irradiated by ultraviolet rays in a state of a coating film, and is reacted and dried by an initiator, if the UV paint is not coated, the UV paint cannot be completely dried due to the action of oxygen inhibition, the energy of an ultraviolet lamp required by the UV paint generally needs 600-800 mj/cm2, even 1000mj/cm2, and the energy consumption and the cost of factory operation are greatly increased.
In conclusion, it is important to research a safe and high-quality ultraviolet light-cured wood wax oil.
Disclosure of Invention
According to the technical background, the invention provides the ultraviolet-cured wood wax oil which has multiple functions of environmental protection, health, good durability and the like, and overcomes the defects of the prior art.
In order to solve the problems, the technical scheme adopted by the invention is as follows:
the ultraviolet light cured wood wax oil comprises the following components in parts by weight:
60-80 parts of modified vegetable oil
5-10 parts of wax slurry
5-10 parts of sweet orange oil
1 to 5 parts of auxiliary agent
1-5 parts of nano assistant
1-5 parts of a photoinitiator.
Further, the wood wax oil comprises the following components in parts by weight:
78 parts of modified vegetable oil, namely modified vegetable oil,
wax slurry 8 parts
Sweet orange oil 5.3 parts
5.5 parts of nano assistant
3.2 parts of a photoinitiator.
Further, the wood wax oil comprises the following components in parts by weight:
67 portions of modified vegetable oil
Wax slurry 8 parts
Sweet orange oil 8 parts
5.5 parts of nano assistant
2.8 parts of photoinitiator
And 2 parts of auxiliary additive.
Further, the modified vegetable oil is obtained by modifying vegetable oil with polyurethane, wherein the vegetable oil comprises but is not limited to tung oil, linseed oil, soybean oil, castor oil and cashew nut oil, and the synthesized modified vegetable oil has two-functionality groups to multi-functionality groups and is the main performance vegetable oil.
Further, the wax slurry includes, but is not limited to, carnauba wax, beeswax, silicone wax, polyethylene wax, and polytetrafluoroethylene wax.
Further, the auxiliary agent includes, but is not limited to, a nano aluminum solution, a nano silver ion solution, and a nano zinc solution.
Further, the photoinitiator includes, but is not limited to, a radical photoinitiator, and a cationic photoinitiator.
Further, the auxiliary agent includes a dispersant, a defoamer, and a leveling agent, but is not limited to the above auxiliary agents.
By adopting the technical scheme, the invention has the following beneficial effects:
specifically, the wood wax oil comprises the following raw materials in percentage by weight:
modified vegetable oil: the vegetable oil is modified by polyurethane, the vegetable oil comprises tung oil, linseed oil, soybean oil, castor oil, cashew oil and the like, the synthesized modified vegetable oil has two-functionality-degree group to multi-functionality-degree group and is the main body performance vegetable oil, under the action of a photoinitiator and ultraviolet irradiation, the groups of the main body vegetable oil are triggered to react and dry quickly, and the modified vegetable oil is used as a main body agent and plays a role in beautifying and protecting wood.
Wax slurry: wax slurries include, but are not limited to, carnauba wax, beeswax, silicone wax, polyethylene wax, and polytetrafluoroethylene wax, among others, which serve to provide hydrophobic and hand feel, as well as protection.
Nano-additive: the auxiliary agents comprise but are not limited to nano aluminum solution, nano silver ion solution and nano zinc solution, and the auxiliary agents are environment-friendly products certified by European Union regulations, and have the effects of resisting wear, hardening, preventing mildew, sterilizing and enhancing weather resistance.
Photoinitiator (2): including but not limited to free radical photoinitiators, and cationic photoinitiators, all in compliance with the european union regulations, as initiators for drying of vegetable oils.
Sweet orange oil: from natural oranges or orange squeezes, the food and raw materials act to dilute the viscosity of the vegetable oil and add a pleasant flavor to the vegetable oil.
The auxiliary agent comprises a dispersant, a defoaming agent, a leveling agent and the like, and plays a role in balancing the wood wax oil formula.
By adopting the raw materials, compared with the existing wood wax oil on the market, the wood wax oil disclosed by the invention has the following advantages:
1. and (3) drying quickly: the existing wood wax oil in the market is dried slowly, generally needs to be dried for 4-6 hours at normal temperature, even reaches 12 hours in a low-temperature environment, but can be dried for only a few seconds under the irradiation of ultraviolet rays through the initiation of a photoinitiator, so that the production efficiency of operation is greatly improved.
2. The odor is low: the wood wax oil in the market is dried by reaction through oxygen in the air, so the residual smell is large, although no toxic or harmful effect is found to human bodies, people feel uncomfortable, the wood wax oil changes the drying mechanism of the original vegetable oil, mainly depends on ultraviolet irradiation for drying and auxiliary oxidation for drying, so the residual smell is small, and the wood wax oil can be called odorless wood wax oil.
3. The protective performance is better: the existing wood wax oil in the market is based on vegetable oil oxidation drying, and the compactness of a paint film is poor, so that the protection performance is poor, and the performances of water resistance and chemical resistance are limited. The wood wax oil has the advantages that the hardness of a paint film reaches 2-3h of pencil hardness, the protection performance is good, the water resistance, the alcohol resistance and the chemical resistance are far away from those of the existing wood wax oil in a supermarket, and the wood wax oil plays a great role in protecting woodware and floors and has durability.
4. The wood wax oil disclosed by the invention is added with the nano auxiliary agent, so that the hardness and scratch resistance of the wood wax oil on the floor are greatly improved, and the wood wax oil has obvious effects of mildew prevention and sterilization and far exceeds the protection effect and durability of the existing wood wax oil on the wood wax oil in the market on the wood.
5. Compared with the existing UV paint in the market, the wood wax oil disclosed by the invention breaks through the problem of oxygen inhibition of the UV paint during thin coating, has no paint film during construction on woodware, can be dried at low energy, and mostly adds reactive diluent (UV monomer) in the existing UV paint in the market, so that the UV paint has contact anaphylactic reaction to human bodies during construction and has irritation. The wood wax oil does not contain an active diluent, so the wood wax oil is nonirritating, nontoxic and harmless, the used photoinitiator is an environment-friendly odor-free initiator which accords with European Union instructions, and the existing UV paint in the market can be cured and dried only by the energy of 600-800 mj/cm 2.
6. The wood wax oil disclosed by the invention is simple in construction process and easy to operate, and common workers only need simple training. The construction can be finished just by wiping the base oil twice and finishing the surface oil once.
In conclusion, the ultraviolet curing wood wax oil has the advantages of short drying time, high production efficiency, environmental protection, safety and low VOC content, and meets the national requirements for environment-friendly coatings
Detailed Description
The present invention will be further analyzed with reference to the following specific examples.
The invention discloses ultraviolet-cured wood wax oil which is characterized by comprising the following components in parts by weight: 60-80 parts of modified vegetable oil, 5-10 parts of wax slurry, 5-10 parts of sweet orange oil, 1-5 parts of an auxiliary agent, 1-5 parts of a nano-additive and 1-5 parts of a photoinitiator.
In order to further realize the technical scheme of the invention, the wood wax oil comprises the following components in parts by weight: 78 parts of modified vegetable oil, 8 parts of wax slurry, 5.3 parts of sweet orange oil, 5.5 parts of nano-additive and 3.2 parts of initiator.
In order to further realize the technical scheme of the invention, the wood wax oil comprises the following components in parts by weight: 67 parts of modified vegetable oil, 8 parts of wax slurry, 8 parts of sweet orange oil, 5.5 parts of nano-additive, 2.8 parts of photoinitiator and 2 parts of auxiliary additive.
In order to further realize the technical scheme of the invention, the modified vegetable oil is obtained by modifying vegetable oil with polyurethane, the vegetable oil comprises but is not limited to tung oil, linseed oil, soybean oil, castor oil and cashew nut oil, and the synthesized modified vegetable oil has two-functional groups to multi-functional groups and is the main performance vegetable oil.
To further implement the solution of the present invention, the wax slurry includes but is not limited to carnauba wax, beeswax, silicon wax, polyethylene wax and polytetrafluoroethylene wax.
In order to further realize the technical scheme of the invention, the auxiliary agent comprises but is not limited to a nano aluminum solution, a nano silver ion solution and a nano zinc solution.
To further achieve the solution of the present invention, the photoinitiator includes, but is not limited to, a radical photoinitiator, and a cationic photoinitiator.
In order to further realize the technical scheme of the invention, the auxiliary agent comprises a dispersing agent, a defoaming agent and a leveling agent, but is not limited to the above auxiliary agents.
The following description will be given by taking specific experimental cases as examples, and it should be understood that the specific examples described herein are only for illustrating the present invention and are not intended to limit the present invention.
Example 1:
the ultraviolet light cured wood wax oil comprises the following components in parts by weight: 78 parts of modified vegetable oil, 8 parts of wax slurry, 5.3 parts of sweet orange oil, 5.5 parts of nano-additive and 3.2 parts of initiator.
Example 2:
the ultraviolet light cured wood wax oil comprises the following components in parts by weight: 67 parts of modified vegetable oil, 8 parts of wax slurry, 8 parts of sweet orange oil, 5.5 parts of nano-additive, 2.8 parts of photoinitiator and 2 parts of auxiliary additive.
The working process is as follows: the preparation method of the invention by adopting any one of the formulas comprises the following steps: mixing the raw materials, adding, stirring, and filtering.
When the wood wax oil is used specifically, the wood wax oil is uniformly coated on a woodenware or a floor, the wood wax oil is left for a little two minutes to permeate into wood, then, the excess oil is wiped off by using dry cotton cloth, and the wood wax oil passes through a UV curing machine at the speed of 400mj/cm2Can be dried quickly under the energy of the energy.
The present invention is not limited to the above preferred embodiments, and any structural changes made under the teaching of the present invention shall be understood to fall within the scope of the present invention, and all technical solutions identical or similar to the present invention shall be covered thereby.
Claims (8)
1. The ultraviolet light cured wood wax oil is characterized by comprising the following components in parts by weight:
60-80 parts of modified vegetable oil
5-10 parts of wax slurry
5-10 parts of sweet orange oil
1-5 parts of auxiliary additive
1-5 parts of nano assistant
1-5 parts of a photoinitiator;
the modified vegetable oil is obtained by modifying vegetable oil with polyurethane.
2. The ultraviolet light-cured wood wax oil according to claim 1, wherein the wood wax oil comprises the following components in parts by weight:
78 parts of modified vegetable oil
Wax slurry 8 parts
Sweet orange oil 5.3 parts
5.5 parts of nano assistant
3.2 parts of a photoinitiator.
3. The ultraviolet light-cured wood wax oil according to claim 1, wherein the wood wax oil comprises the following components in parts by weight:
67 portions of modified vegetable oil
Wax slurry 8 parts
Sweet orange oil 8 parts
5.5 parts of nano assistant
2.8 parts of photoinitiator
And 2 parts of auxiliary additive.
4. The UV-curable wood wax oil according to any one of claims 1 to 3, wherein the modified vegetable oil is obtained by modifying vegetable oil with polyurethane, the vegetable oil includes but is not limited to tung oil, linseed oil, soybean oil, castor oil, cashew nut oil, and the synthesized modified vegetable oil has two to multiple functional groups and is a main performance vegetable oil.
5. The UV-curable wood wax oil according to any one of claims 1 to 3, wherein the wax slurry comprises but is not limited to carnauba wax, beeswax, silicone wax, polyethylene wax, and polytetrafluoroethylene wax.
6. The UV-curable wood wax oil according to any one of claims 1 to 3, wherein the nano additive comprises but is not limited to a nano aluminum solution, a nano silver ion solution, and a nano zinc solution.
7. The UV-curable wood wax oil according to any one of claims 1 to 3, wherein the photoinitiator comprises but is not limited to a radical photoinitiator and a cationic photoinitiator.
8. The UV-curable wood wax oil according to any one of claims 1 to 3, wherein the auxiliary additives comprise a dispersant, a defoamer, and a leveling agent, but not limited thereto.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710789328.XA CN107474735B (en) | 2017-09-05 | 2017-09-05 | Ultraviolet-cured wood wax oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710789328.XA CN107474735B (en) | 2017-09-05 | 2017-09-05 | Ultraviolet-cured wood wax oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107474735A CN107474735A (en) | 2017-12-15 |
| CN107474735B true CN107474735B (en) | 2020-04-14 |
Family
ID=60603731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710789328.XA Active CN107474735B (en) | 2017-09-05 | 2017-09-05 | Ultraviolet-cured wood wax oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107474735B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109517525B (en) * | 2018-09-30 | 2020-12-08 | 佛山阳光逸采涂料科技有限公司 | UV LED water-based ultraviolet-curing ecological vegetable oil and preparation method thereof |
| CN110079198A (en) * | 2019-05-24 | 2019-08-02 | 临沂优彩新能源环保科技有限公司 | A kind of UV wood wax oil and preparation method thereof |
| CN111040629B (en) * | 2019-12-18 | 2022-07-08 | 广西大学 | Wooden furniture coating and preparation method thereof |
| CN111978870A (en) * | 2020-09-03 | 2020-11-24 | 宿州洛通木业有限公司 | Cerate for redwood furniture and preparation method thereof |
| CN114574101A (en) * | 2020-12-01 | 2022-06-03 | 东北林业大学 | Ultraviolet-curing wood wax oil |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4142009A (en) * | 1974-08-13 | 1979-02-27 | Fosroc International Limited | Method of treating timber with composition having a colloidal pigment |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408828B (en) * | 2011-09-29 | 2013-10-30 | 刘光君 | Nano silicon dioxide modified hard wood wax oil and preparation method thereof |
| CN102352173B (en) * | 2011-10-25 | 2013-01-30 | 北京展辰化工有限公司 | Odorless ultraviolet-curing wood lacquer and preparation method thereof |
| CN104109475A (en) * | 2014-05-09 | 2014-10-22 | 北京鑫楚之园环保科技有限责任公司 | Wood oil |
-
2017
- 2017-09-05 CN CN201710789328.XA patent/CN107474735B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4142009A (en) * | 1974-08-13 | 1979-02-27 | Fosroc International Limited | Method of treating timber with composition having a colloidal pigment |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107474735A (en) | 2017-12-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107474735B (en) | Ultraviolet-cured wood wax oil | |
| CN105199515B (en) | A kind of imitation porcelain coating and its spraying method | |
| CN101429319B (en) | Watersoluble acrylic acid modified saturated polyester, method and watersoluble baking aluminum paint | |
| CN107446393A (en) | A kind of environmentally friendly radiation proof interiro wall latex paint | |
| KR101225437B1 (en) | UV curable paint composition | |
| CN105238267A (en) | Stain-removing and furniture-servicing film plating oil and preparation method therefor | |
| CN109054638A (en) | environment-friendly wood wax oil and preparation method thereof | |
| CN105440946A (en) | Nano water-based wood wax oil and preparation method thereof | |
| CN102085678B (en) | Wood protective paint as well as preparation method and application thereof | |
| CN104212331A (en) | Energy-saving environment-friendly type aqueous UV woodenware paint | |
| CN106700689B (en) | Special aqueous wooden ware white paint of a kind of children furniture and preparation method thereof | |
| CN103289562A (en) | UV (Ultraviolet)-water-based spray coating matte finish | |
| CN108178979A (en) | A kind of quick self-drying type spraying UV paints | |
| CN104497845A (en) | Open type aqueous UV shower-coating clear primer | |
| CN101701121A (en) | Water-based baking varnish and preparation method thereof | |
| CN109468066B (en) | Water-based UV wood lacquer with overexposure protection and preparation method thereof | |
| CN110256945A (en) | A kind of open air high-weatherability wood wax oil and preparation method thereof | |
| JP2008297413A (en) | Water-based coating | |
| CN110724453B (en) | Water-based plant-based wood maintenance agent | |
| CN109082221A (en) | White light top coat top coat of the aqueous UV of resistant and preparation method thereof | |
| CN114085608A (en) | Water-based ultraviolet light-cured antiviral coating and preparation method and application thereof | |
| CN106634088A (en) | Environmental protection aromatic paint | |
| CN105440947A (en) | Water-based paint | |
| CN108359295A (en) | A kind of anticracking environment protecting paint for wooden articles | |
| CN106675243A (en) | Environment-friendly and healthy white bamboo charcoal functional coating for interior walls |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |