CN107474728A - A kind of dumb light transparent dust-proof finish and preparation method thereof - Google Patents

A kind of dumb light transparent dust-proof finish and preparation method thereof Download PDF

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Publication number
CN107474728A
CN107474728A CN201710582286.2A CN201710582286A CN107474728A CN 107474728 A CN107474728 A CN 107474728A CN 201710582286 A CN201710582286 A CN 201710582286A CN 107474728 A CN107474728 A CN 107474728A
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China
Prior art keywords
dumb light
light transparent
transparent dust
proof finish
mixing
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CN201710582286.2A
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CN107474728B (en
Inventor
段吉祥
谭振华
龚凯
张强国
李威
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SHANGHAI CARPOLY PAINT CO Ltd
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SHANGHAI CARPOLY PAINT CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

Dumb light transparent dust-proof finish disclosed by the invention, it is prepared by organic silicon emulsion, polyurethane thickener, hydrophobically modified aqueous slkali swollen thickener, emulsifying agent, defoamer, bactericide, pH adjusting agent, Lauryl Alcohol ester, ethylene glycol and water.The invention also discloses the preparation method of the dumb light transparent dust-proof finish.The committed step of the present invention is that Lauryl Alcohol ester and ethylene glycol are fabricated to the milkiness suspension of 10 20 μm of particle diameter using emulsifying agent, these scattered droplets can be evenly distributed among paint film during coating application, in the drying process, the droplet on close surface can gradually protrude coating surface due to surface tension effects, the evaporation rate of these droplets is slower than water, therefore numerous pit can be left in coating surface after dried, so that coating surface obtains matte effect to light diffusing reflection.

Description

A kind of dumb light transparent dust-proof finish and preparation method thereof
Technical field
The present invention relates to technical field of paint preparation, more particularly to a kind of dumb light transparent dust-proof finish and preparation method thereof
Background technology
Transparent dust-proof finish paint is a kind of widely used coating of building field, for protecting middle coating intermediate to be invaded from environment Erosion, improve the weather-proof anti-pollution characteristic of building coating.Transparent dust-proof finish paint generally has the class of matte and glossy two, due to the dust-proof face of dumb light Paint covers metope out-of-flatness defect, more fully the characteristic such as displaying middle coating intermediate color, finish application more dust-proof than light are more.
The dust-proof finish paint of traditional dumb light is coating surface is become coarse by adding glass micro mist, so as to obtain diffusing reflection Matte effect, but many defects of this method, glass micro mist can reduce the transparency of dust-proof finish paint first, influence middle level Painting color shows, and construction became uneven is also easy to cause to grow dim;Secondly, glass micro mist easily precipitates, flocculated, once occur Such case paint film may whiten, so shelf life of products is extremely short;Easily floating is sucked other glass micro mist by human body, to life Production worker has larger threat, there is certain environment harmfulness.These defects limit the popularization of product.
Although also there is the dust-proof finish paint technology of other dumb lights in recent years, the dumb light emulsion matched somebody with somebody for example with emulsion particle diameter pole, can To overcome above-mentioned most of defect, but with high costs, emulsion gloss is not sufficiently stable, and coatings enterprises formula design space is limited Deng defect is also fairly obvious.
The content of the invention
The present invention to be solved one of technical problem and be that the above-mentioned technology present in the dust-proof finish paint of existing dumb light is asked Inscribe and a kind of dumb light transparent dust-proof finish is provided.The dumb light transparent dust-proof finish need not add common glass micro mist or make With the dumb light emulsion specially matched somebody with somebody, you can obtain matte surface effect, can effectively reduce formulation cost, and improve formulation stability.
The present invention to be solved the two of the technical problem preparation method for being to provide above-mentioned dumb light transparent dust-proof finish.
As the dumb light transparent dust-proof finish of first aspect present invention, it is prepared by the raw material of following parts by weight:
In a preferred embodiment of the invention, the organic silicon emulsion is selected from Ahmedabad richness RS-996AD, sunrise TD- 661B, Bao Lijia BLJ-KD96, one kind in ten thousand magnificent Archsol8087 or both any mixing.
In a preferred embodiment of the invention, the polyurethane thickener is selected from Tao Shi RM-8W, RM-2020, Wan Hua One kind or both any mixing in U601, U505.
In a preferred embodiment of the invention, the hydrophobically modified aqueous slkali swollen thickener is selected from Tao Shi TT- 935th, one kind in ten thousand magnificent A406 or both any mixing.
In a preferred embodiment of the invention, the emulsifying agent is selected from Tao Shi BD-109, Ke Laien LCN-407, sieve One kind or both any mixing in the CO-630 of ground Asia.
In a preferred embodiment of the invention, the defoamer in Nuo Pu sections NXZ, Bi Ke LPD23159 one Kind or both any mixing.
In a preferred embodiment of the invention, the bactericide in Sol DB20, Tao Shi Rocima562 one Kind or both any mixing.
In a preferred embodiment of the invention, the pH adjusting agent in Tao Shi AMP-95, Bi Ke BS168 one Kind or both any mixing.
As the preparation method of the dumb light transparent dust-proof finish of second aspect of the present invention, comprise the following steps:
(1) a part of water, ethylene glycol, Lauryl Alcohol ester, emulsifying agent, defoamer, bactericide are mixed, and stirred with dispersion machine 10-12min is mixed, is fabricated to milkiness suspension of the size droplet diameter at 10-20 μm;
(2) organic silicon emulsion that formula ratio is added in milkiness suspension prepared by step (1) stirs;
(3) polyurethane thickener, hydrophobically-modified alkali swollen thickener, pH adjusting agent, the water for adding formula ratio adjust viscosity, 65-75KU and pH value are 7~9 acquisition dumb light transparent dust-proof finishes.
The committed step of the present invention is that Lauryl Alcohol ester and ethylene glycol are fabricated to the breast of 10-20 μm of particle diameter using emulsifying agent Turbid suspension, these scattered droplets can be evenly distributed among paint film during coating application, in the drying process, lean on For the droplet of near surface because surface tension effects can gradually protrude coating surface, the evaporation rate of these droplets is slower than water, Therefore numerous pit can be left in coating surface after dried, so that coating surface obtains dumb light effect to light diffusing reflection Fruit.Its process is as shown in Figure 1 to Figure 3.
Brief description of the drawings
Fig. 1 is view when dumb light transparent dust-proof finish of the present invention construction is completed.
Fig. 2 is the paint film view in dumb light transparent dust-proof finish drying process of the present invention.
Fig. 3 is the paint film view after dumb light transparent dust-proof finish drying process of the present invention.
Embodiment
Describe the present invention in detail with reference to specific embodiment, but it is set forth below for embodiment be only to the present invention Illustrate, do not form the limitation to the claims in the present invention protection domain.
Unless expressly stated otherwise, its raw material used is example below:Organic silicon emulsion is Ahmedabad richness RS-996AD, Polyurethane thickener is selected from Tao Shi RM-8W, and hydrophobically modified aqueous slkali swollen thickener is selected from Tao Shi TT-935, and emulsifying agent is selected from sieve Ground Asia CO-630, defoamer are selected from Bi Ke LPD23159, and bactericide is selected from Tao Shi Rocima562, and pH adjusting agent is selected from Bi Ke BS168。
Embodiment 1
The preparation method of dumb light transparent dust-proof finish, comprises the following steps:
(1) by 40 parts of water, 2 parts of ethylene glycol, 2 parts of Lauryl Alcohol esters, 0.2 part of emulsifying agent, 0.1 part of defoamer, 0.2 part of sterilization Agent mixes, and stirs 10-12min with dispersion machine, is fabricated to milkiness suspension of the size droplet diameter at 10-20 μm;
(2) 50 parts of organic silicon emulsions are added in milkiness suspension prepared by step (1) to stir;
(3) 0.5 part of polyurethane thickener, 0.5 part of hydrophobically-modified alkali swollen thickener, 0.1 part of pH adjusting agent, 4.4 are added It is 8 that part water, which adjusts viscosity to 70KU and pH value, obtains dumb light transparent dust-proof finish.
Embodiment 2
The preparation method of dumb light transparent dust-proof finish, comprises the following steps:
(1) by 40 parts of water, 1.8 parts of ethylene glycol, 2 parts of Lauryl Alcohol esters, 0.2 part of emulsifying agent, 0.1 part of defoamer, 0.2 sterilization Agent mixes, and stirs 10-12min with dispersion machine, is fabricated to milkiness suspension of the size droplet diameter at 10-20 μm;
(2) 45 parts of organic silicon emulsions are added in milkiness suspension prepared by step (1) to stir;
(3) 0.5 part of polyurethane thickener, 0.7 part of hydrophobically-modified alkali swollen thickener, 0.1 part of pH adjusting agent, 9.4 are added It is 8 that part water, which adjusts viscosity to 70KU and pH value, obtains dumb light transparent dust-proof finish.
Embodiment 3
The preparation method of dumb light transparent dust-proof finish, comprises the following steps:
(1) by 37 parts of water, 2 parts of ethylene glycol, 3 parts of Lauryl Alcohol esters, 0.25 part of emulsifying agent, 0.1 part of defoamer, 0.2 sterilization Agent mixes, and stirs 10-12min with dispersion machine, is fabricated to milkiness suspension of the size droplet diameter at 10-20 μm;
(2) 55 parts of organic silicon emulsions are added in milkiness suspension prepared by step (1) to stir;
(3) 0.45 part of polyurethane thickener, 0.4 part of hydrophobically-modified alkali swollen thickener, 0.1 part of pH adjusting agent, 1.5 are added It is 8 that part water, which adjusts viscosity to 70KU and pH value, obtains dumb light transparent dust-proof finish.

Claims (9)

1. dumb light transparent dust-proof finish, it is characterised in that be prepared by the raw material of following parts by weight:
2. dumb light transparent dust-proof finish as claimed in claim 1, it is characterised in that it is rich that the organic silicon emulsion is selected from Ahmedabad RS-996AD, sunrise TD-661B, Bao Lijia BLJ-KD96, ten thousand magnificent Archsol8087 one kind or both any mixing.
3. dumb light transparent dust-proof finish as claimed in claim 1, it is characterised in that the polyurethane thickener is selected from Tao Shi RM-8W, RM-2020, one kind in ten thousand magnificent U601, U505 or both any mixing.
4. dumb light transparent dust-proof finish as claimed in claim 1, it is characterised in that the hydrophobically modified aqueous slkali swelling increases Thick dose of one kind in Tao Shi TT-935, ten thousand magnificent A406 or both any mixing.
5. dumb light transparent dust-proof finish as claimed in claim 1, it is characterised in that the emulsifying agent is selected from Tao Shi BD- 109th, Ke Laien LCN-407, sieve ground one kind in sub- CO-630 or both any mixing.
6. dumb light transparent dust-proof finish as claimed in claim 1, it is characterised in that the defoamer be selected from Nuo Pu sections NXZ, One kind or both any mixing in Bi Ke LPD23159.
7. dumb light transparent dust-proof finish as claimed in claim 1, it is characterised in that the bactericide be selected from Sol DB20, One kind or both any mixing in Tao Shi Rocima562.
8. dumb light transparent dust-proof finish as claimed in claim 1, it is characterised in that the pH adjusting agent is selected from Tao Shi AMP- 95th, one kind in Bi Ke BS168 or both any mixing.
9. the preparation method of the dumb light transparent dust-proof finish described in any one of claim 1 to 8 claim, its feature exist In comprising the following steps:
(1) a part of water, ethylene glycol, Lauryl Alcohol ester, emulsifying agent, defoamer, bactericide are mixed, and stirred with dispersion machine 10-12min, it is fabricated to milkiness suspension of the size droplet diameter at 10-20 μm;
(2) organic silicon emulsion that formula ratio is added in milkiness suspension prepared by step (1) stirs;
(3) polyurethane thickener, hydrophobically-modified alkali swollen thickener, pH adjusting agent, the water for adding formula ratio adjust viscosity to 65 ~75 and pH value be 7~9 obtain dumb light transparent dust-proof finishes.
CN201710582286.2A 2017-07-17 2017-07-17 Matte transparent dustproof finish coat paint and preparation method thereof Active CN107474728B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110684420A (en) * 2019-11-04 2020-01-14 广州昊特建材有限公司 High-transmittance dustproof anti-fouling matte finish paint and preparation method thereof
CN114369398A (en) * 2022-03-17 2022-04-19 广东嘉宝莉科技材料有限公司 Strong-stereoscopic-sense easily-molded micro-sand textured coating and preparation method and application thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103450766A (en) * 2013-08-14 2013-12-18 青岛益群漆业集团有限公司 Development of high-grade water-based finish paint

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103450766A (en) * 2013-08-14 2013-12-18 青岛益群漆业集团有限公司 Development of high-grade water-based finish paint

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110684420A (en) * 2019-11-04 2020-01-14 广州昊特建材有限公司 High-transmittance dustproof anti-fouling matte finish paint and preparation method thereof
CN114369398A (en) * 2022-03-17 2022-04-19 广东嘉宝莉科技材料有限公司 Strong-stereoscopic-sense easily-molded micro-sand textured coating and preparation method and application thereof

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