CN107468888A - A kind of preparation method of relieving restlessness that clears away heart-fire, antibacterial expelling parasite sachet - Google Patents
A kind of preparation method of relieving restlessness that clears away heart-fire, antibacterial expelling parasite sachet Download PDFInfo
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- CN107468888A CN107468888A CN201710711338.1A CN201710711338A CN107468888A CN 107468888 A CN107468888 A CN 107468888A CN 201710711338 A CN201710711338 A CN 201710711338A CN 107468888 A CN107468888 A CN 107468888A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/88—Liliopsida (monocotyledons)
- A61K36/896—Liliaceae (Lily family), e.g. daylily, plantain lily, Hyacinth or narcissus
- A61K36/8967—Lilium, e.g. tiger lily or Easter lily
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C25/00—Miscellaneous fancy ware for personal wear, e.g. pendants, crosses, crucifixes, charms
- A44C25/007—Charms or amulets
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/28—Asteraceae or Compositae (Aster or Sunflower family), e.g. chamomile, feverfew, yarrow or echinacea
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/36—Caryophyllaceae (Pink family), e.g. babysbreath or soapwort
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/53—Lamiaceae or Labiatae (Mint family), e.g. thyme, rosemary or lavender
- A61K36/532—Agastache, e.g. giant hyssop
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K36/00—Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
- A61K36/18—Magnoliophyta (angiosperms)
- A61K36/185—Magnoliopsida (dicotyledons)
- A61K36/53—Lamiaceae or Labiatae (Mint family), e.g. thyme, rosemary or lavender
- A61K36/534—Mentha (mint)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/0002—Galenical forms characterised by the drug release technique; Application systems commanded by energy
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/0087—Galenical forms not covered by A61K9/02 - A61K9/7023
- A61K9/009—Sachets, pouches characterised by the material or function of the envelope
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/48—Preparations in capsules, e.g. of gelatin, of chocolate
- A61K9/50—Microcapsules having a gas, liquid or semi-solid filling; Solid microparticles or pellets surrounded by a distinct coating layer, e.g. coated microspheres, coated drug crystals
- A61K9/5005—Wall or coating material
- A61K9/5021—Organic macromolecular compounds
- A61K9/5031—Organic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polyethylene glycol, poly(lactide-co-glycolide)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/48—Preparations in capsules, e.g. of gelatin, of chocolate
- A61K9/50—Microcapsules having a gas, liquid or semi-solid filling; Solid microparticles or pellets surrounded by a distinct coating layer, e.g. coated microspheres, coated drug crystals
- A61K9/5005—Wall or coating material
- A61K9/5021—Organic macromolecular compounds
- A61K9/5036—Polysaccharides, e.g. gums, alginate; Cyclodextrin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/48—Preparations in capsules, e.g. of gelatin, of chocolate
- A61K9/50—Microcapsules having a gas, liquid or semi-solid filling; Solid microparticles or pellets surrounded by a distinct coating layer, e.g. coated microspheres, coated drug crystals
- A61K9/5005—Wall or coating material
- A61K9/5021—Organic macromolecular compounds
- A61K9/5036—Polysaccharides, e.g. gums, alginate; Cyclodextrin
- A61K9/5042—Cellulose; Cellulose derivatives, e.g. phthalate or acetate succinate esters of hydroxypropyl methylcellulose
- A61K9/5047—Cellulose ethers containing no ester groups, e.g. hydroxypropyl methylcellulose
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Abstract
The invention discloses a kind of relieving restlessness that clears away heart-fire, the preparation method of antibacterial expelling parasite sachet, obtain mixing face powder after lily, eupatorium, ageratum, China pink, heroubill and peppermint are crushed, taking polyethylene glycol and mixing face powder, it is added to the water after mixing well, adds sodium alginate soln, then draws calcium chloride solution dropwise addition and wherein carry out gel, carboxymethyl cellulose is added into gel solution, obtain being wrapped in the microcapsules of spices, finally fill microcapsules in bag body, and tightened with rope and the sachet is made.Sachet produced by the present invention can be such that people carry in daily life and slowly release drug effect, and because the microcapsules of formation wrap fragrance material, drug effect is slowly discharged, and fragrance remaining time is up to 15 ~ 16 months, reach long-acting slow-release effect, people's pneumostatic with fixed attention can be aided in, there is the effect of relieving restlessness that clears away heart-fire, but also there is the effect of antibacterial, antiviral and expelling parasite.
Description
Technical field
The invention belongs to sachet technical field, and in particular to a kind of relieving restlessness that clears away heart-fire, the preparation method of antibacterial expelling parasite sachet.
Background technology
Sachet is a kind of ornament of people's body-worn, and when wearing sachet, sachet can give out fragrance.Since ancient times
People just have the custom of wearing.With the raising of people's quality of the life, this function is single to be merely able to give out fragrance
Sachet can not meet demand of the present people to sachet, and as usage time is elongated, the taste of sachet also can it is thin out even
Disappear.
With the development of society, the quickening of rhythm of life, many people produce due to being chronically under nervous and pressure
The problems such as insomnia, depression and anxiety obstacle, tension headache, and it is often accompanied by that mood is worried, easily enrages, sleep-disorder, flesh
The problems such as meat tonicity pain.Usual people treat these problems using Western medicine, but again can not during using Western medicine
What is avoided brings some side effects because Western medicine is taken, as the medicine of assisting sleep be possible to produce tolerance, habituation and into
Addiction.As long use unexpected drug withdrawal, can occur withrawal symptom such as have a sleepless night, excitement, anxiety, even convulsions symptom of trembling.
For these reasons, invent a kind of lasting fragrance and have the sachet of relieving restlessness that clears away heart-fire will be by consumers in general's
Welcome.
The content of the invention
It is an object of the invention in view of the shortcomings of the prior art, providing the preparation of a kind of relieving restlessness that clears away heart-fire, antibacterial expelling parasite sachet
Method.Sachet produced by the present invention can be such that people carry in daily life and slowly release drug effect, and due to being formed
Microcapsules fragrance material is wrapped so that drug effect can slowly discharge, and fragrance remaining time be up to 15 ~ 16 months, reach long
Slow release effect is imitated, people's pneumostatic with fixed attention can be aided in, there is the effect of relieving restlessness that clears away heart-fire, but also there is antibacterial, antiviral and expelling parasite
The effect of.
To achieve the above object, the present invention adopts the following technical scheme that:
The preparation method of a kind of relieving restlessness that clears away heart-fire, antibacterial expelling parasite sachet, specifically includes following steps:
(1)Count in parts by weight, by 20 ~ 25 parts of lily, 15 ~ 20 parts of eupatorium, 15 ~ 20 parts of ageratum, 10 ~ 15 parts of China pink, heroubill
10 ~ 15 parts and 6 ~ 8 parts of crushing of peppermint and 80 mesh sieves excessively, obtain potpourri powder;
(2)Taking polyethylene glycol and step(1)Obtained potpourri powder is added to the water mix well after, add sodium alginate soln,
Stir;
(3)Calcium chloride solution, which is drawn, with dropper is added drop-wise to step(2)Mixed liquor in carry out gel, gel time 3 ~ 5 hours, obtain
To gel solution;
(4)In the state of being kept stirring for, toward step(3)Carboxymethyl cellulose is added in obtained gel solution, is wrapped up
The microcapsules of spices;
(5)By step(4)The microcapsules that gained is wrapped in spices are filled in bag body, and are tightened with rope and the sachet is made.
The mass ratio of the polyethylene glycol, sodium alginate and carboxymethyl cellulose is 3:7:50.
Described to be wrapped in the microcapsules of spices, the quality accounting of spices is 50 ~ 70wt%.
The concentration of the calcium chloride solution is 4 ~ 10wt%.
4 ~ the 8wt% of sodium alginate soln.
It is as follows the effect of each component in spices of the present invention:
Eupatorium:With removing dampness by means of aromatics, the effect of appetizing of being amusing, its volatile oil infected by influenza contained, which has, directly to be suppressed and anti-inflammatory
Effect.
Ageratum:Slightly warm in nature, acrid flavour, return lung, stomach, the spleen channel, eliminate dampness with aromatics, the preventing or arresting vomiting that whets the appetite, deliver relieving summer-heat, have
The effect of antibacterial, antiviral and analgesic.
Lily:Contain pectin and phospholipid material in lily;Its essential oil has sterilization, anti-inflammatory, healing, deodorization, calmness, expelling parasite
Effect.
Peppermint:It is pungent with diverging, it is cool with heat-clearing, it is clear it is light it is cool dissipate, its is pungent to dissipate that this property is stronger, and being most can surname dissipate in cold-pungent and diaphoretic drugs
Table is evil, and has certain perspiration, the product commonly used for dispelling wind and heat from the body.
China pink:Herb is mainly eugenol, benzyl carbinol, Ergol, benzyl salicylate in oily containing saponin, volatile oil
And gaultherolin, the effect of tool reducing fever and causing diuresis, blood-breaking are stimulated the menstrual flow, there is the effect of absorbing the toxic gases such as chlorine, sulfur dioxide.
Heroubill:With a variety of viruses and antibiotic effect is suppressed, to shigella flexneri, Escherichia coli, golden yellow grape
Coccus, Pseudomonas aeruginosa have inhibitory action.
In the present invention, sodium alginate is a kind of Natural linear polysaccharide, is by beta-D-mannuronic acid (M units) and α-L-
Guluronic acid (G units) is by Isosorbide-5-Nitrae-glucosides key connection, and the nothing being made up of different GG, GM or MM fragments with certain proportion
Regulation block copolymer.Easily with easily with multiple oxygen atoms on alginic acid guluronic acid chelation occurs for divalent calcium ions,
So that alginic acid interchain is combined closely, synergy enhancing, the interaction of chain interchain ultimately results in three-dimensional net structure, is formed
Gel.Polyethylene glycol has extensive intermiscibility, moisture retention and dispersiveness, as spices covering material.When sodium alginate is with gathering
After ethylene glycol forms gel solution, carboxymethyl cellulose is added, because the hydrophily of carboxymethyl cellulose is much larger than sodium alginate,
Strong hydration occurs in it so that the moisture in virgin rubber body gradually shifts to carboxymethyl cellulose, the colloid quilt being originally defined
Destruction is disintegrated so that sodium alginate and polyethylene glycol are changed into solid phase from liquid phase, in inner core(Potpourri)Coagulate on corpuscle surface
Film is polymerized to, forms microcapsules.
The beneficial effects of the present invention are:Sachet produced by the present invention can be such that people carry in daily life simultaneously slowly
Drug effect is discharged, and because the microcapsules of formation wrap fragrance material so that drug effect can slowly discharge, and during lasting
Between be up to 15 ~ 16 months, reach long-acting slow-release effect.People's pneumostatic with fixed attention can be aided in, there is the effect of relieving restlessness that clears away heart-fire, but also
The effect of with antibacterial, antiviral and expelling parasite.In addition, microcapsules one in sachet it is rubbed will occur it is a number of broken
Split so that fragrance drug effect is strengthened, and is a kind of preferably human body auxiliary sachet.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1
The preparation method of a kind of relieving restlessness that clears away heart-fire, antibacterial expelling parasite sachet, specifically includes following steps:
(1)Count in parts by weight, by 6 parts of 20 parts of lily, 15 parts of eupatorium, 15 parts of ageratum, 10 parts of China pink, 10 parts of heroubill and peppermint
Crush and cross 80 mesh sieves, obtain potpourri powder;
(2)Taking polyethylene glycol and step(1)Obtained potpourri powder is added to the water mix well after, add 4wt% sodium alginate
Solution, stir;
(3)The calcium chloride solution that 4wt% is drawn with dropper is added drop-wise to step(2)Mixed liquor in carry out gel, gel time 3 is small
When, obtain gel solution;
(4)In the state of being kept stirring for, toward step(3)Carboxymethyl cellulose is added in obtained gel solution, is wrapped up
The microcapsules of spices, the wherein quality accounting of spices is 50wt%,
(5)By step(4)The microcapsules that gained is wrapped in spices are filled in bag body, and are tightened with rope and the sachet is made.
The mass ratio of the polyethylene glycol, sodium alginate and carboxymethyl cellulose is 3:7:50.
Embodiment 2
The preparation method of a kind of relieving restlessness that clears away heart-fire, antibacterial expelling parasite sachet, specifically includes following steps:
(1)Count in parts by weight, by 8 parts of 25 parts of lily, 20 parts of eupatorium, 20 parts of ageratum, 15 parts of China pink, 15 parts of heroubill and peppermint
Crush and cross 80 mesh sieves, obtain potpourri powder;
(2)Taking polyethylene glycol and step(1)Obtained potpourri powder is added to the water mix well after, add 8wt% sodium alginate
Solution, stir;
(3)The calcium chloride solution that 10wt% is drawn with dropper is added drop-wise to step(2)Mixed liquor in carry out gel, gel time 5 is small
When, obtain gel solution;
(4)In the state of being kept stirring for, toward step(3)Carboxymethyl cellulose is added in obtained gel solution, is wrapped up
The microcapsules of spices, the quality accounting of spices is 70wt%;
(5)By step(4)The microcapsules that gained is wrapped in spices are filled in bag body, and are tightened with rope and the sachet is made.
The mass ratio of the polyethylene glycol, sodium alginate and carboxymethyl cellulose is 3:7:50.
Embodiment 3
The preparation method of a kind of relieving restlessness that clears away heart-fire, antibacterial expelling parasite sachet, specifically includes following steps:
(1)Count in parts by weight, by 7 parts of 22 parts of lily, 18 parts of eupatorium, 18 parts of ageratum, 12 parts of China pink, 12 parts of heroubill and peppermint
Crush and cross 80 mesh sieves, obtain potpourri powder;
(2)Taking polyethylene glycol and step(1)Obtained potpourri powder is added to the water mix well after, add 6wt% sodium alginate
Solution, stir;
(3)The calcium chloride solution that 7wt% is drawn with dropper is added drop-wise to step(2)Mixed liquor in carry out gel, gel time 4 is small
When, obtain gel solution;
(4)In the state of being kept stirring for, toward step(3)Carboxymethyl cellulose is added in obtained gel solution, is wrapped up
The microcapsules of spices, the quality accounting of spices is 60wt%;
(5)By step(4)The microcapsules that gained is wrapped in spices are filled in bag body, and are tightened with rope and the sachet is made.
The mass ratio of the polyethylene glycol, sodium alginate and carboxymethyl cellulose is 3:7:50.
Comparative example
It will count in parts by weight, by 7 parts of 22 parts of lily, 18 parts of eupatorium, 18 parts of ageratum, 12 parts of China pink, 12 parts of heroubill and peppermint
Crush and cross 80 mesh sieves, filled after obtaining potpourri powder in bag body, and tightened with rope and sachet is made.
The physico-chemical property and sachet fragrance remaining time of the microcapsules of parcel spices obtained by the present invention are as shown in table 1.
Table 1
Application Example 1
Zhang Wenxing, people from Suzhou City, usually feel that life is constrained, and suffer from regular headache, and easily enraged by little nothings of life.From
From 3 months after the sachet for wearing the present invention, headache slows down and often feels happy, even-tempered and good-humoured, and is not easy to be given birth to
Trival matters living enrage.
Application Example 2
Li Wengui, people from Hangzhou, insomnia throughout the year, the daily effective sleep time, frequent 3,4 points of midnight could fall asleep less than 5 hours.
From after wearing sachet of the invention 3 months, and the sachet is put in pillow, the effective sleep time is up to 8 hours.
The foregoing is only presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with
Modification, it should all belong to the covering scope of the present invention.
Claims (5)
- A kind of 1. preparation method of relieving restlessness that clears away heart-fire, antibacterial expelling parasite sachet, it is characterised in that:Specifically include following steps:(1)Count in parts by weight, by 20 ~ 25 parts of lily, 15 ~ 20 parts of eupatorium, 15 ~ 20 parts of ageratum, 10 ~ 15 parts of China pink, heroubill 10 ~ 15 parts and 6 ~ 8 parts of crushing of peppermint and 80 mesh sieves excessively, obtain potpourri powder;(2)Taking polyethylene glycol and step(1)Obtained potpourri powder is added to the water mix well after, add sodium alginate soln, Stir;(3)Calcium chloride solution, which is drawn, with dropper is added drop-wise to step(2)Mixed liquor in carry out gel, gel time 3 ~ 5 hours, obtain To gel solution;(4)In the state of being kept stirring for, toward step(3)Carboxymethyl cellulose is added in obtained gel solution, is wrapped up The microcapsules of spices;(5)By step(4)The microcapsules that gained is wrapped in spices are filled in bag body, and are tightened with rope and the sachet is made.
- 2. the preparation method of relieving restlessness that clears away heart-fire according to claim 1, antibacterial expelling parasite sachet, it is characterised in that:The poly- second The mass ratio of glycol, sodium alginate and carboxymethyl cellulose is 3:7:50.
- 3. the preparation method of relieving restlessness that clears away heart-fire according to claim 1, antibacterial expelling parasite sachet, it is characterised in that:The parcel In the microcapsules of spices, the quality accounting of spices is 50 ~ 70wt%.
- 4. the preparation method of relieving restlessness that clears away heart-fire according to claim 1, antibacterial expelling parasite sachet, it is characterised in that:The chlorination The concentration of calcium solution is 4 ~ 10wt%.
- 5. the preparation method of relieving restlessness that clears away heart-fire according to claim 1, antibacterial expelling parasite sachet, it is characterised in that:The marine alga 4 ~ 8wt% of acid sodium solution.
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Cited By (1)
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CN109914109A (en) * | 2019-03-21 | 2019-06-21 | 江苏炫智新材料科技有限公司 | A kind of preparation method of the military durability anti-mosquito fabric of environmental protection |
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CN105477054A (en) * | 2015-12-11 | 2016-04-13 | 潞城市舒心养生枕有限公司 | Headache preventive traditional Chinese medicine pillow |
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