CN107467063A - A kind of plant photo-catalyst Yield-increasing Hormone and its synthetic method - Google Patents
A kind of plant photo-catalyst Yield-increasing Hormone and its synthetic method Download PDFInfo
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- CN107467063A CN107467063A CN201710677806.8A CN201710677806A CN107467063A CN 107467063 A CN107467063 A CN 107467063A CN 201710677806 A CN201710677806 A CN 201710677806A CN 107467063 A CN107467063 A CN 107467063A
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- titanium
- running water
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- hydroxycarboxylate
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Inorganic Chemistry (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of plant photo-catalyst Yield-increasing Hormone and its synthetic method, and it is using volume ratio as 7 by peroxy titanium hydroxycarboxylate and peroxide multi-hydroxy carboxy acid titanium:3 mix；The peroxy titanium hydroxycarboxylate is prepared by the raw material of following parts by weight：90 100 parts of citric acid, 50 60 parts of titanium tetrachloride, 500 600 parts of running water, 100 120 parts of ammoniacal liquor；The peroxide multi-hydroxy carboxy acid titanium is prepared by the raw material of following parts by weight：40 60 parts of vitamin C, 45 parts of titanium tetrachloride, each 13 parts of magnesium sulfate, zinc sulfate, manganese sulfate, 23 parts of ferrous sulfate, 13 parts of sodium benzoate, 13 parts of neopelex, 35 parts of sodium hydroxide, 500 parts of running water.
Description
Technical field
Plant medicines field of the present invention, more particularly to a kind of plant photo-catalyst Yield-increasing Hormone and its synthetic method.
Background technology
Sulphur preparation, the copper agent of traditional chemical agriculture chemicals fungicide protective, also antibiotic agents and interior absorption class
Preparation.Bactericide is by disturbing the chitin of germ living matter, lipoid, amino acid, protein, nucleic acid and biotin, pressing down
Bacterium living matter synthesis processed, reaches and suppresses growth and sporulation and kill germ.Using process often caused by improper use pair
The harm of plant growth.Often show as：1. photosynthate is obstructed：Traditional chemical agriculture chemicals fungicide can cause crop vegetative growth phase
Photosynthesis declines, and the output of blade assimilation quotient is obstructed.2. reduce Major Nutrient material content：Many bactericide are to various crops
Physiology, growth, yield have negative effect, and increase disease propagates the absorption and possibility of nutritive value, promotion or enhancing to germ
The defence of plant is reduced, promoting or strengthen disease indirectly, wildness is propagated again.Traditional chemical agriculture chemicals fungicide can be reduced in plant body
The content of free amino acid and soluble sugar, and this two classes material is all relevant with the resistance of plant.Once both materials are reduced
Pest and disease damage can be caused repeatedly rampant.3. reduce its secondary metabolites content：Traditional chemical sterilization pesticide can directly or indirectly intervene
Target plant or the secondary metabolism of non-target plant, the disease and insect resistance of plant is reduced, such as sweet phosphine suppresses higher plant aromatic amine
The biosynthesis of base acid, reduces aromatic content, have impact on the fragrant degree of fruit.4. disturb active oxygen metabolism：Largely
After agricultural chemicals, plant normal activity oxygen metabolism is disturbed, and active oxygen yield improves, and destroys with SOD（Peroxide disproportionation
Enzyme）Based on cytoprotection system, active oxygen injury destruction system can accelerate Lipid peroxidation metabolism chain type anti-when can not dispose
Should, increase peroxidating noxious products accumulation.Cause cell membrane system destruction and the damage of macromolecular living matter.5. weaken metabolism
Enzymatic activity：In plant metabolism effect, glutathione-S-transferase and Cytochrome P450（P -450 are mainly distributed on endoplasmic reticulum
On mitochondrial inner membrane, as a kind of terminal oxygenase）Body monooxygenase plays an important role, and traditional chemical disinfectant use in agriculture can draw
Play both enzymatic activitys to decline, influence plant metabolism, so as to be had an impact to plant detoxification ability.Agricultural chemicals is given birth to the physiology of crop
Change generation to have a strong impact on, so that its resistance reduces, result is that disease, worm, crop smothering are more serious.Chemical pesticide traditional at present kills
The problem of microbial inoculum is present is anxious to be resolved.
The content of the invention
The present invention seeks to provided for above-mentioned the deficiencies in the prior art a kind of plant photo-catalyst Yield-increasing Hormone and its
Synthetic method.
The present invention realizes that above-mentioned purpose is adopted the technical scheme that：A kind of plant photo-catalyst Yield-increasing Hormone, it be by
Peroxy titanium hydroxycarboxylate is with peroxide multi-hydroxy carboxy acid titanium using volume ratio as 7:3 mix；The peroxy titanium hydroxycarboxylate
It is to be prepared by the raw material of following parts by weight：Citric acid 90-100 parts, titanium tetrachloride 50-60 parts, running water 500-600
Part, ammoniacal liquor 100-120 parts；The peroxide multi-hydroxy carboxy acid titanium is prepared by the raw material of following parts by weight：Vitamin C
40-60 parts, titanium tetrachloride 4-5 parts, each 1-3 parts of magnesium sulfate, zinc sulfate, manganese sulfate, ferrous sulfate 2-3 parts, sodium benzoate 1-3
Part, neopelex 1-3 parts, sodium hydroxide 3-5 parts, 500 parts of running water.
A kind of synthetic method of the plant photo-catalyst Yield-increasing Hormone, comprises the following steps：
1）The preparation of peroxide multi-hydroxy carboxy acid's titanium
A, the container for being loaded with 250 parts of running water is arranged in electric blender, by vitamin C running water, starts stirring
Machine, vitamin C is set all to dissolve.
B, titanium tetrachloride is added dropwise into the vitamin c solution dissolved, time for adding is 3-5 minutes；
C, after magnesium sulfate, zinc sulfate, manganese sulfate, ferrous sulfate being dissolved in 80 parts of running water, b is added under stirring
In step resulting solution；
D, sodium hydroxide is dissolved in 100 parts of running water, added under stirring in step C resulting solution, and adjust solution
PH value is 4；
E, sodium benzoate, neopelex are dissolved in 70 parts of running water, Step d is added under stirring
In resulting solution, and the stopping that constantly stirring, peroxide multi-hydroxy carboxy acid's titanium is obtained, it is standby；
2）The preparation of peroxy titanium hydroxycarboxylate
A, by running water and citric acid stirring and dissolving；
B, titanium tetrachloride is slowly added dropwise after the citric acid in step a all dissolving, time for adding is 15-20 minutes；
C. ammoniacal liquor is slowly added dropwise into step b resulting solutions, tune pH value to 4, obtains peroxy titanium hydroxycarboxylate, it is stand-by；
3）Finished product synthesizes
It is 7 by volume by the peroxy titanium hydroxycarboxylate prepared and peroxide multi-hydroxy carboxy acid titanium:3 ratio mixes equal
It is even, final products are obtained, are kept in dark place.
The present invention principle and beneficial effect be：Plant photo-catalyst Yield-increasing Hormone is sprayed by peroxide multi-hydroxy carboxy acid titanium
Plant leaf surface in the presence of UV sunlight, excite plant surface peroxide titanium caused by electronics, recur energy level transition, after
And electronics flies out, the hole (positive cave) with superpower oxidability and the electronics with superpower reducing power are formed；Hole/electronics
Pair with surface and air reclaimed water reaction after can produce active oxygen [02] and hydroxyl free radical [HO] isoreactivity material.Its reaction
Journey；
Hole/electronics is produced in the presence of light to being TiO2+ luminous energy (hv)-→ electronics (e-)+positive cave (h+)；Hole/
Electronics pair is positive cave (h with surface and air reclaimed water reaction generation living radical+)+hydrone (H20)-→ 0H+H+.Electricity
Son (e-)+oxygen (02)-→ active oxygen (02ˉ).Hole/electronics pair behind surface and the reaction of air reclaimed water with that can produce active oxygen [02
-] and hydroxyl free radical [0H] isoreactivity material.Bacterial body inner cell coacetylase is directly acted on, its single aggressiveness is gradually aggregated into
Dimer, cause bacterium dead because losing aerobic respiration ability.OH bases free radical can also be by cell DNA and cell membrane
Coup injury kills bacterium with destroying.And O2 -It is a kind of strong reductant again, its oxidation electromotive force 3V, OH oxidation electromotive force is
2.8V, HO free radical and active oxygen O- 2- these active materials are than hydrogen peroxide 1.7V and the strong bactericide of chlorine dioxide 1.57V
Strong more of oxidation reduction electro-dynamic potential, can not only Oxidative demage bacterium, the cell membrane of mould these organic matters, it is curable viral
Protein.The harmful compound that can also be discharged while sterilization on decomposing bacteria corpse.Due in this course of reaction
Photocatalysis is not involved in reacting, so that reaction can be repeated, so photochemical catalyst can enduringly work, does not damage plant
Physiological function, it can protect plant not by damage of the agricultural chemicals to cell.The plant that especially protecting field greenhouse plants often occur is not old first
Decline, the heavier performance of medication it is more serious, yield and quality is severely impacted.Plant photo-catalyst Yield-increasing Hormone effectively solves
This problem.This product is used cooperatively with insecticide pesticide, and while sterilization and disinsection, protection plant preserves from, purple in the sun
In the presence of outer light, remains of pesticide can be urged to solution.Promote plant more healthy and stronger until titanium molecule is absorbed by plants.Improve plant
Photosynthetic capacity and nutrient delivery ability reach the purpose of controlling disease and volume increase.
Embodiment
The present invention is further described below with reference to embodiment.
Embodiment 1
The plant photo-catalyst Yield-increasing Hormone of the present invention, it is with body by peroxy titanium hydroxycarboxylate and peroxide multi-hydroxy carboxy acid's titanium
Product is than being 7:3 mix；The peroxy titanium hydroxycarboxylate is prepared by the raw material of following parts by weight：Citric acid 92
Part, 53 parts of titanium tetrachloride, 515 parts of running water, 112 parts of ammoniacal liquor；The peroxide multi-hydroxy carboxy acid titanium is by following parts by weight
Raw material is prepared：41 parts of vitamin C, 4 parts of titanium tetrachloride, each 1 part of magnesium sulfate, zinc sulfate, manganese sulfate, 2 parts of ferrous sulfate,
1 part of sodium benzoate, 1 part of neopelex, 3 parts of sodium hydroxide, 500 parts of running water.
A kind of synthetic method of the plant photo-catalyst Yield-increasing Hormone, comprises the following steps：
1）The preparation of peroxide multi-hydroxy carboxy acid's titanium
A, the container for being loaded with 250 parts of running water is arranged in electric blender, by vitamin C running water, starts stirring
Machine, vitamin C is set all to dissolve.
B, titanium tetrachloride is added dropwise into the vitamin c solution dissolved, time for adding is 3-5 minutes；
C, after magnesium sulfate, zinc sulfate, manganese sulfate, ferrous sulfate being dissolved in 80 parts of running water, b is added under stirring
In step resulting solution；
D, sodium hydroxide is dissolved in 100 parts of running water, added under stirring in step C resulting solution, and adjust solution
PH value is 4；
E, sodium benzoate, neopelex are dissolved in 70 parts of running water, Step d is added under stirring
In resulting solution, and the stopping that constantly stirring, peroxide multi-hydroxy carboxy acid's titanium is obtained, it is standby；
2）The preparation of peroxy titanium hydroxycarboxylate
A, by running water and citric acid stirring and dissolving；
B, titanium tetrachloride is slowly added dropwise after the citric acid in step a all dissolving, time for adding is 15-20 minutes；
C. ammoniacal liquor is slowly added dropwise into step b resulting solutions, tune pH value to 4, obtains peroxy titanium hydroxycarboxylate, it is stand-by；
3）Finished product synthesizes
It is 7 by volume by the peroxy titanium hydroxycarboxylate prepared and peroxide multi-hydroxy carboxy acid titanium:3 ratio mixes equal
It is even, final products are obtained, are kept in dark place.
Embodiment 2
The plant photo-catalyst Yield-increasing Hormone of the present invention, it is with body by peroxy titanium hydroxycarboxylate and peroxide multi-hydroxy carboxy acid's titanium
Product is than being 7:3 mix；The peroxy titanium hydroxycarboxylate is prepared by the raw material of following parts by weight：Citric acid
955 parts, 55 parts of titanium tetrachloride, 550 parts of running water, 115 parts of ammoniacal liquor；The peroxide multi-hydroxy carboxy acid titanium is by following parts by weight
Raw material be prepared：50 parts of vitamin C, 5 parts of titanium tetrachloride, each 2 parts of magnesium sulfate, zinc sulfate, manganese sulfate, ferrous sulfate 2.5
Part, 2 parts of sodium benzoate, 2 parts of neopelex, 4 parts of sodium hydroxide, 500 parts of running water；The same embodiment of its preparation method
1。
Embodiment 3
A kind of plant photo-catalyst Yield-increasing Hormone of the present invention, it is by peroxy titanium hydroxycarboxylate and peroxide multi-hydroxy carboxy acid's titanium
Using volume ratio as 7:3 mix；The peroxy titanium hydroxycarboxylate is prepared by the raw material of following parts by weight：Lemon
100 parts of acid, 60 parts of titanium tetrachloride, 600 parts of running water, 120 parts of ammoniacal liquor；The peroxide multi-hydroxy carboxy acid titanium is by following parts by weight
Several raw materials are prepared：60 parts of vitamin C, 5 parts of titanium tetrachloride, each 3 parts of magnesium sulfate, zinc sulfate, manganese sulfate, ferrous sulfate 3
Part, 3 parts of sodium benzoate, 3 parts of neopelex, 5 parts of sodium hydroxide, 500 parts of running water, the same embodiment of its preparation method
1。
The use range and method of plant photo-catalyst Yield-increasing Hormone prepared by above example see the table below：
Claims (2)
- A kind of 1. plant photo-catalyst Yield-increasing Hormone, it is characterised in that：It is by peroxy titanium hydroxycarboxylate and peroxide polyhydroxy Carboxylic acid titanium is using volume ratio as 7:3 mix；The peroxy titanium hydroxycarboxylate be by following parts by weight raw material prepare and Into：Citric acid 90-100 parts, titanium tetrachloride 50-60 parts, running water 500-600 parts, ammoniacal liquor 100-120 parts；The peroxide polyhydroxy Yl carboxylic acid titanium is prepared by the raw material of following parts by weight：Vitamin C 40-60 parts, titanium tetrachloride 4-5 parts, magnesium sulfate, Each 1-3 parts of zinc sulfate, manganese sulfate, ferrous sulfate 2-3 parts, sodium benzoate 1-3 parts, neopelex 1-3 parts, hydrogen-oxygen Change sodium 3-5 parts, 500 parts of running water.
- A kind of 2. synthetic method of plant photo-catalyst Yield-increasing Hormone as claimed in claim 1, it is characterised in that：Methods described bag Include following steps：1）The preparation of peroxide multi-hydroxy carboxy acid's titaniumA, the container for being loaded with 250 parts of running water is arranged in electric blender, vitamin C is put in running water, starts and stirs Machine is mixed, vitamin C is all dissolved；B, titanium tetrachloride is added dropwise into the vitamin c solution dissolved, time for adding is 3-5 minutes；C, after magnesium sulfate, zinc sulfate, manganese sulfate, ferrous sulfate being dissolved in 80 parts of running water, b is added under stirring In step resulting solution；D, sodium hydroxide is dissolved in 100 parts of running water, added under stirring in step C resulting solution, and adjust solution PH value is 4；E, sodium benzoate, neopelex are dissolved in 70 parts of running water, Step d is added under stirring In resulting solution, and the stopping that constantly stirring, peroxide multi-hydroxy carboxy acid's titanium is obtained, it is standby；2）The preparation of peroxy titanium hydroxycarboxylateA, by running water and citric acid stirring and dissolving；B, titanium tetrachloride is slowly added dropwise after the citric acid in step a all dissolving, time for adding is 15-20 minutes；C. ammoniacal liquor is slowly added dropwise into step b resulting solutions, tune pH value to 4, obtains peroxy titanium hydroxycarboxylate, it is stand-by；3）Finished product synthesizesIt is 7 by volume by the peroxy titanium hydroxycarboxylate prepared and peroxide multi-hydroxy carboxy acid titanium:3 ratio mixes equal It is even, final products are obtained, are kept in dark place.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710677806.8A CN107467063A (en) | 2017-08-09 | 2017-08-09 | A kind of plant photo-catalyst Yield-increasing Hormone and its synthetic method |
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| CN201710677806.8A CN107467063A (en) | 2017-08-09 | 2017-08-09 | A kind of plant photo-catalyst Yield-increasing Hormone and its synthetic method |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049149A (en) * | 1989-08-04 | 1991-02-13 | 钱自强 | Titanium-containing plant nutrient and making method |
| CN1052302A (en) * | 1989-11-28 | 1991-06-19 | 北京有色金属研究总院 | Titanium compound for plant growing regulating agent and synthetic |
| CN1176954A (en) * | 1996-09-17 | 1998-03-25 | 裴圣镐 | Multi-element and composite tiltanium trace element fertilizer |
| CN1337384A (en) * | 2001-09-26 | 2002-02-27 | 王宝歧 | Multicomponent composite liquid fertilizer |
| CN101243800A (en) * | 2007-12-12 | 2008-08-20 | 王绪征 | Cotton defoliation ripening multicomponent preparations and preparation thereof |
| CN106431679A (en) * | 2016-10-08 | 2017-02-22 | 东莞市农立农业科技有限公司 | Preparation method of titanium citrate liquid |
-
2017
- 2017-08-09 CN CN201710677806.8A patent/CN107467063A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049149A (en) * | 1989-08-04 | 1991-02-13 | 钱自强 | Titanium-containing plant nutrient and making method |
| CN1052302A (en) * | 1989-11-28 | 1991-06-19 | 北京有色金属研究总院 | Titanium compound for plant growing regulating agent and synthetic |
| CN1176954A (en) * | 1996-09-17 | 1998-03-25 | 裴圣镐 | Multi-element and composite tiltanium trace element fertilizer |
| CN1337384A (en) * | 2001-09-26 | 2002-02-27 | 王宝歧 | Multicomponent composite liquid fertilizer |
| CN101243800A (en) * | 2007-12-12 | 2008-08-20 | 王绪征 | Cotton defoliation ripening multicomponent preparations and preparation thereof |
| CN106431679A (en) * | 2016-10-08 | 2017-02-22 | 东莞市农立农业科技有限公司 | Preparation method of titanium citrate liquid |
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