CN107446617A - A kind of analogue experiment installation - Google Patents
A kind of analogue experiment installation Download PDFInfo
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- CN107446617A CN107446617A CN201710743623.1A CN201710743623A CN107446617A CN 107446617 A CN107446617 A CN 107446617A CN 201710743623 A CN201710743623 A CN 201710743623A CN 107446617 A CN107446617 A CN 107446617A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/44—Hydrogenation of the aromatic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/04—Pressure vessels, e.g. autoclaves
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/22—Devices for withdrawing samples in the gaseous state
- G01N1/2247—Sampling from a flowing stream of gas
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
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- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Biomedical Technology (AREA)
- Molecular Biology (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Sampling And Sample Adjustment (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The present invention relates to a kind of analogue experiment installation.Its technical scheme is：High-pressure reaction pot is made up of electromagnetic stirr device, finishing reactor, cover and high pressure tank body, the high pressure tank body is arranged on heating furnace chamber, the top of high pressure tank body is provided with cover, electromagnetic stirr device, finishing reactor are installed on cover, rupture disk is arranged on the sidepiece of the upside boss of cover, is installed with electromagnetic stirr device in the middle part of boss, the bottom of electromagnetic stirr device is installed in pressure pan body, middle and upper part is cased with finishing reactor, and the top of electromagnetic stirr device is connected to control system by control line；The beneficial effects of the invention are as follows：The present invention reaches requirement of experiment by analogue experiment installation, in addition, setting the sampling equipment of gas and liquid in experimental simulation device, data are continuously acquired so as to quickly realize in experiment, experiment is realized more quick, accurate measure.
Description
Technical field
The present invention relates to a kind of experimental provision, more particularly to a kind of analogue experiment installation.
Background technology
In recent years, petroleum heavy in poor quality problem is all suffered from China or even world wide, but with the hair of economy
Exhibition, light-end products requirement but increasingly increase, and this requires us that mink cell focus is more processed into light-end products, to meet to pass through
Needs of the Ji development to the high-quality oil product of lightweight.At present, the main technological means of upgrading have it is conventional thermal cracking, face hydrogen and subtract
Glue cracking, hydrogen supply visbreaking and face hydrogen hydrogen supply visbreaking.Modification oil stability that wherein conventional visbreaking obtains, 0API
Etc. poor, and other modification technologies are subjected to the limit that hydrogen source, Hydrogen activation and hydrogen supply agent develop the problems such as preferred difficulty is big
System.
Polycyclic aromatic hydrocarbon is rich in viscous crude, some of which can be hydrogenated with the conditions of relatively relaxing, and some are under the conditions of relatively relaxing
But it is difficult to be hydrogenated with.CO hydro-thermals become the newborn hydrogen caused by transducing with high activity, if newborn hydrogen original position can be acted on into viscous crude
In under the conditions of relatively relaxing the polycyclic aromatic hydrocarbon that can be hydrogenated with, obtained hydrogenation products on the one hand can carry out hydrogen turn inside viscous crude
Move, internal potential hydrogen supply agent effect is played, so as to play a part of hydrogenation to the viscous crude molecule for being difficult to be hydrogenated with the conditions of mitigation；
On the other hand, its own is changed into the polycyclic aromatic hydrocarbon being easily hydrogenated with again, so as to realize effect that newborn hydrogen efficiently transmits into viscous crude.
Raw material CO in CO hydro-thermal conversion processes can be obtained by petroleum coke vaporization caused by delayed coking, can not only not had to H2
Further activation and it is significantly cost-effective, can also more efficiently lift upgrading effect.Therefore, polycyclic aromatic hydrocarbon hydrogen migration
It is a problem with huge practical value to upgrading with the conversion of CO hydro-thermals.
The content of the invention
The purpose of the present invention is aiming at drawbacks described above existing for prior art, there is provided a kind of analogue experiment installation, this hair
It is bright to replace the polycyclic aromatic hydrocarbon in viscous crude in the case where CO hydro-thermals convert environment in experimental simulation device using polycyclic aromatic hydrocarbon model compound
Middle carry out hydrogenation reaction, and then polycyclic aromatic hydrocarbon is changed into the compound with virtue and cycloalkanes ring structure, so as to change as viscous crude
Potential hydrogen supply agent during matter, reduce and generate oily viscosity, improve and generate oily stability, be finally reached the mesh that viscous crude efficiently modifies
's.
A kind of analogue experiment installation that the present invention mentions, including CO air accumulators（1）, high-pressure reaction pot, gas and liquid collecting system
Most of with control system four, the high-pressure reaction pot is by electromagnetic stirr device（12）, finishing reactor（13）, rupture disk（14）、
First thermocouple（17）, cover（15）With high pressure tank body（16）Form, the high pressure tank body（16）Installed in heating furnace（11）It is interior
Chamber, high pressure tank body（16）Top be provided with cover（15）, in cover（15）Upper installation electromagnetic stirr device（12）, finishing reactor
（13）, rupture disk（14）, the first thermocouple（17）, rupture disk（14）Installed in cover（15）Upside boss sidepiece, boss
Middle part be installed with electromagnetic stirr device（12）With the first thermocouple（17）, electromagnetic stirr device（12）Bottom be installed in high pressure tank body
（16）Interior, middle and upper part is cased with finishing reactor（13）, electromagnetic stirr device（12）Top control system is connected to by control line；
Described gas and liquid collecting system includes gas collection tank（9）And liquid collection tank（25）With the second thermocouple（23）Composition,
Wherein, gas collection tank（9）Pass through pipeline and CO air accumulators（1）After parallel connection, then pass through cover（15）It is connected to high pressure tank body
（16）, the liquid collection tank（25）Pass through pipeline, cover（15）It is connected to high pressure tank body（16）；
The control system is by temperature and rotational speed governor（27）, liquid collection tank temperature indicator（28）, high pressure pot temperature
Display（29）And speed display（30）Form.
Preferably, above-mentioned high-pressure reaction pot also includes the first needle-valve（3）, the second needle-valve（20）, air inlet（4）, exhaust
Mouthful（19）, the CO air accumulators（1）Pass through pipeline and the air inlet of high-pressure reaction pot（4）It is connected, and in reaction under high pressure canister incoming gas
Mouthful（4）First needle-valve is installed（3）Air inlet aperture is controlled, the first needle-valve（3）With in the connecting pipeline of high-pressure reaction pot
Gas phase sampling system is installed.
Preferably, in gas collection tank（9）Top is provided with nitrogen protection valve（6）, take air valve（7）, first pressure table
（8）, bottom is equipped with the atmospheric valve of liquid（10）.
Preferably, in cover（15）Right-hand member be provided with second pressure gauge（18）, exhaust outlet（19）With the second needle-valve（20）,
Second needle-valve（20）To exhaust outlet（19）Aperture be controlled.
Preferably, above-mentioned gas collection tank（9）Lower end be provided with atmospheric valve（10）, upper end side is provided with and takes air valve（7）
With first pressure table（8）, upper center passes through pipeline and valve（5）It is connected to the first needle-valve（3）With cover（15）Between pipe
On line.
Preferably, in valve（5）Nitrogen protection valve is connected with the pipeline of downside（6）.
Preferably, above-mentioned liquid collection tank（25）Top is equipped with the 3rd pressure gauge（24）With the second thermocouple（23）, under
Portion is provided with liquid taking valve（26）.
Preferably, the first thermocouple（17）With the second thermocouple（23）With electromagnetic stirr device（12）By circuit and temperature and
Rotating speed control cabinet（27）It is connected.
Preferably, the finishing reactor（13）Using quickly cooling coil pipe.
A kind of application method for analogue experiment installation that the present invention mentions, including following operating procedure：
（1）Checkout facility device seal, using water and the anthracene and naphthalene as polycyclic aromatic hydrocarbon model compound if seal is intact
It is placed in after being dissolved in toluene in pressure pan body, with CO pressurisings, purging is pressurized to reaction initial pressure afterwards three times；
（2）Heating is heated after pressure needed for reaction is pressurized in kettle, is warming up to 100oStart to stir during C, and continue heating until
Temperature needed for reaction, and maintain at the reaction temperatures until reaching the defined reaction time；
（3）After reaching the time required to reaction, the valve that liquid phase sampling system is connected with high-pressure reaction pot is opened, Partial Liquid Phase is in height
Enter under the conditions of pressure in liquid-phase collection tank, open liquid taking valve after the temperature in liquid-phase collection tank reaches requirement with pressure and take out liquid
Phase product, then be dissolved in toluene after wherein condensed water is distilled off and carry out chromatography, liquid-phase collection tank is dry using solvent cleaning
Only, the continuous sampling of liquid product is used for after and being purged with nitrogen；
（4）After liquid product taking-up, the valve that gas phase sampling system is connected with high-pressure reaction pot is opened immediately, takes out part gas
Mutually enter in gas collection tank, treat pressure stability in gas collection tank, it is stable be down to after room temperature to open take air valve, collect gas phase production
Thing carries out chromatography；The liquid phase in atmospheric valve emptying tank is opened, is cleaned using solvent and is used for gas phase after being purged with nitrogen and produced
The continuous sampling of thing；
（5）According to the gas-phase product gas chromatographic analysis result obtained under the differential responses time, CO hydro-thermal transformationreations are drawn
Dynamics, and contrasted with pure CO hydro-thermals transformationreation；Liquid product show that anthracene and naphthalene face CO hydro-thermals through chromatography respectively
Dynamics is converted, and is contrasted with the dynamics under hydro condition；
（6）It is hydrogenated with and the difficult polycyclic aromatic hydrocarbon model chemical combination being hydrogenated with as easy under the conditions of relatively mitigation in viscous crude using anthracene and naphthalene
Thing, anthracene and naphthalene are subjected to above-mentioned experiment in high pressure tank body simultaneously, naphthalene is drawn by the continuous sampling to liquid-phase product and analysis
Conversion ratio is simultaneously contrasted with its conversion ratio in the conversion of CO hydro-thermals is faced；
（7）Finishing reactor is opened after the completion of reaction with terminating reaction.
The beneficial effects of the invention are as follows：The polycyclic aromatic hydrocarbon in viscous crude is replaced in CO hydro-thermals using polycyclic aromatic hydrocarbon model compound
Hydrogenation reaction is carried out under conversion environment in analogue means, and then polycyclic aromatic hydrocarbon is changed into the change with virtue and cycloalkanes ring structure
Compound, so as to as the potential hydrogen supply agent during upgrading, reduce and generate oily viscosity, improve and generate oily stability, finally
Reach the purpose that viscous crude efficiently modifies；
In addition, the present invention reaches requirement of experiment by analogue experiment installation, and by setting gas-liquid sampling system can simply, soon
Realize that viscous crude faces the continuous sampling of CO hydro-thermals modification fastly, more fast, accurately determine polycyclic aromatic hydrocarbon hydrogen migration and CO hydro-thermals
Convert the effect to upgrading.
Brief description of the drawings
Accompanying drawing 1 is the structural representation of the present invention；
In upper figure：CO air accumulators 1, valve 2, the first needle-valve 3, air inlet 4, valve 5, nitrogen protect valve 6, take air valve 7, first to press
Power table 8, gas collection tank 9, atmospheric valve 10, heating furnace 11, electromagnetic stirr device 12, finishing reactor 13, rupture disk 14, cover
15th, high pressure tank body 16, thermocouple 17, second pressure gauge 18, exhaust outlet 19, the second needle-valve 20, common valve 21, solvent purge valve
22nd, the second thermocouple 23, the 3rd pressure gauge 24, liquid collection tank 25, liquid taking valve 26, temperature and rotational speed governor 27, liquid are received
Collect tank temperature indicator 28, high pressure pot temperature display 29 and speed display 30, mobile base 31.
Embodiment
With reference to accompanying drawing 1, the invention will be further described：
A kind of analogue experiment installation that the present invention mentions, including CO air accumulators 1, high-pressure reaction pot, gas and liquid collecting system and control
System four is most of, the high-pressure reaction pot by electromagnetic stirr device 12, finishing reactor 13, rupture disk 14, the first thermocouple 17,
Cover 15 and high pressure tank body 16 are formed, and the high pressure tank body 16 is arranged on the inner chamber of heating furnace 11, and the top of high pressure tank body 16 is provided with
Cover 15, electromagnetic stirr device 12, finishing reactor 13, rupture disk 14, the first thermocouple 17, rupture disk 14 are installed on cover 15
Installed in the sidepiece of the upside boss of cover 15, the thermocouple 17 of electromagnetic stirr device 12 and first is installed with the middle part of boss, electromagnetism stirs
The bottom of dynamic device 12 is installed in high pressure tank body 16, and middle and upper part is cased with finishing reactor 13, and the top of electromagnetic stirr device 12 passes through
Control line is connected to control system；
Wherein, gas and liquid collecting system includes gas collection tank 9 and the thermocouple 23 of liquid collection tank 25 and second forms, wherein, gas
Body collecting tank 9 by pipeline it is in parallel with CO air accumulators 1 after, then high pressure tank body 16 is connected to by cover 15, the liquid is collected
Tank 25 is connected to high pressure tank body 16 by pipeline, cover 15；
The control system is shown by temperature and rotational speed governor 27, liquid collection tank temperature indicator 28, high pressure pot temperature
Device 29 and speed display 30 are formed.
In addition, above-mentioned high-pressure reaction pot also includes the first needle-valve 3, the second needle-valve 20, air inlet 4, exhaust outlet 19, it is described
CO air accumulators 1 are connected by pipeline with the air inlet 4 of high-pressure reaction pot, and install the first needle-valve 3 in high-pressure reaction pot air inlet 4
Air inlet aperture is controlled, the first needle-valve 3 in the connecting pipeline of high-pressure reaction pot with being provided with gas phase sampling system.
Preferably, nitrogen protection valve 6 is installed on the top of gas collection tank 9, takes air valve 7, first pressure table 8, bottom peace
There is the atmospheric valve 10 of liquid.
Preferably, the right-hand member of cover 15 is provided with second pressure gauge 18, the needle-valve 20 of exhaust outlet 19 and second, the second needle-valve
The aperture of 20 pairs of exhaust outlets 19 is controlled.
Preferably, the lower end of above-mentioned gas collection tank 9 is provided with atmospheric valve 10, and upper end side is provided with and takes air valve 7 and first
Pressure gauge 8, upper center are connected on the pipeline between the first needle-valve 3 and cover 15 by pipeline and valve 5.
Preferably, nitrogen protection valve 6 is connected with the pipeline of the downside of valve 5, being passed through nitrogen during for needing is protected
Shield.
Preferably, the above-mentioned top of liquid collection tank 25 is provided with equipped with the 3rd pressure gauge 24 and the second thermocouple 23, bottom
Liquid taking valve 26.
Preferably, the first thermocouple 17 and the second thermocouple 23 and electromagnetic stirr device 12 pass through circuit and temperature and rotating speed control
Case 27 processed is connected.In addition, finishing reactor（13）Using quickly cooling coil pipe, by coil winding in the outer of electromagnetic stirr device 12
Side, at the end of needs are reacted, by being passed through refrigerant liquid, such as cold water, it can quickly realize that temperature declines, and then terminate
Reaction.
In addition, in the middle part of the inner chamber of high-pressure reaction pot installation heating furnace, specifically heating furnace 11 is tubular construction, and top is provided with
Bell, bell center are provided with circular hole, and high pressure tank body 16 is placed into the inner chamber of heating furnace 11, the top of high pressure tank body 16 through circular hole
Provided with cover 15, the cover 15 is fixedly connected with bell by multiple bolts, and boss is provided with the upside of cover 15；Rupture disk
Superpressure is prevented for the confined space or excessive vacuum occurs, plays safeguard protection effect.
A kind of application method for analogue experiment installation that the present invention mentions, including following operating procedure：
（1）Checkout facility device seal, using water and the anthracene and naphthalene as polycyclic aromatic hydrocarbon model compound if seal is intact
It is placed in after being dissolved in toluene in pressure pan body, with CO pressurisings, purging is pressurized to 2 ~ 6MPa of reaction initial pressure afterwards three times；
（2）Heating is heated after pressure needed for reaction is pressurized in kettle, is warming up to 100oStart to stir during C, and continue heating until
380 ~ 420 DEG C of temperature needed for reaction, and maintain at the reaction temperatures until reaction time 2-24h as defined in reaching；
（3）After reaching the time required to reaction, the valve that liquid phase sampling system is connected with high-pressure reaction pot is opened, Partial Liquid Phase is in height
Enter under the conditions of pressure in liquid-phase collection tank, open liquid taking valve after the temperature in liquid-phase collection tank reaches requirement with pressure and take out liquid
Phase product, then be dissolved in toluene after wherein condensed water is distilled off and carry out chromatography, liquid-phase collection tank is dry using solvent cleaning
Only, the continuous sampling of liquid product is used for after and being purged with nitrogen；
（4）After liquid product taking-up, the valve that gas phase sampling system is connected with high-pressure reaction pot is opened immediately, takes out part gas
Mutually enter in gas collection tank, treat pressure stability in gas collection tank, it is stable be down to after room temperature to open take air valve, collect gas phase production
Thing carries out chromatography；The liquid phase in atmospheric valve emptying tank is opened, is cleaned using solvent and is used for gas phase after being purged with nitrogen and produced
The continuous sampling of thing；
（5）According to the gas-phase product gas chromatographic analysis result obtained under the differential responses time, CO hydro-thermal transformationreations are drawn
Dynamics, and contrasted with pure CO hydro-thermals transformationreation；Liquid product show that anthracene and naphthalene face CO hydro-thermals through chromatography respectively
Dynamics is converted, and is contrasted with the dynamics under hydro condition；
（6）It is hydrogenated with and the difficult polycyclic aromatic hydrocarbon model chemical combination being hydrogenated with as easy under the conditions of relatively mitigation in viscous crude using anthracene and naphthalene
Thing, anthracene and naphthalene are subjected to above-mentioned experiment in high pressure tank body simultaneously, naphthalene is drawn by the continuous sampling to liquid-phase product and analysis
Conversion ratio is simultaneously contrasted with its conversion ratio in the conversion of CO hydro-thermals is faced；
（7）Finishing reactor is opened after the completion of reaction with terminating reaction.
The high pressure tank volume of above-mentioned high-pressure reaction pot is 300mL, and gas collection tank volume is 100mL, liquid collection tank
Volume is 60mL, and reaction temperature is usually 380 ~ 420 DEG C, and the molar ratio for reacting initial pressure 2 ~ 6MPa, CO and water is 1:2~
1:6, anthracene and naphthalene are 0.1-10wt% in the accounting of toluene, and electromagnetic stirr device is made of resistant material, in addition, CO can lead to
Cross petroleum coke vaporization caused by delayed coking to obtain, can not only not have to H2Further activation and it is significantly cost-effective, also
Upgrading effect can more efficiently be lifted.
Embodiment 2, analogue experiment installation of the invention is same as Example 1, wherein, the analogue experiment installation mentioned makes
With method, wherein parameter is：The volume ratio of water and solvent toluene is 1:10, anthracene/naphthalene of addition is organic solvent mass fraction
5.0wt%, reaction time 4h, every 0,30,60,90,120min sampling.
Embodiment 3, analogue experiment installation of the invention is same as Example 1, wherein, the analogue experiment installation mentioned makes
With method, wherein parameter is：The volume ratio of water and solvent toluene is 1:10, anthracene/naphthalene of addition is organic solvent mass fraction
0.1wt%, reaction time 24h, every 0,30,60,90,120min sampling.
Embodiment 4, analogue experiment installation of the invention is different from embodiment 1, adds a mobile base 31, will be each
Experiment accessory is arranged on mobile base, easy to remove, convenient in laboratory operation and movement, wherein, the simulated experiment dress mentioned
The application method put, wherein parameter are：The volume ratio of water and solvent toluene is 1:10, anthracene/naphthalene of addition is organic solvent quality
The 10wt% of fraction, reaction time 2h, every 0,30,60,90,120min sampling.
It is described above, only it is the part preferred embodiment of the present invention, any those skilled in the art may profit
Equivalent technical scheme is changed or is revised as with the technical scheme of above-mentioned elaboration.Therefore, the technology according to the present invention
Any simple modification or substitute equivalents that scheme is carried out, belong to the greatest extent the scope of protection of present invention.
Claims (4)
1. a kind of analogue experiment installation, it is characterized in that：Including CO air accumulators（1）, high-pressure reaction pot, gas and liquid collecting system and control
System four is most of, and the high-pressure reaction pot is by electromagnetic stirr device（12）, finishing reactor（13）, rupture disk（14）, first heat
Galvanic couple（17）, cover（15）With high pressure tank body（16）Form, the high pressure tank body（16）Installed in heating furnace（11）Inner chamber, high pressure
Tank body（16）Top be provided with cover（15）, in cover（15）Upper installation electromagnetic stirr device（12）, finishing reactor（13）, explosion
Piece（14）, the first thermocouple（17）, rupture disk（14）Installed in cover（15）Upside boss sidepiece, be installed with the middle part of boss
Electromagnetic stirr device（12）With the first thermocouple（17）, electromagnetic stirr device（12）Bottom be installed in high pressure tank body（16）It is interior, on
Portion is cased with finishing reactor（13）, electromagnetic stirr device（12）Top control system is connected to by control line；
Described gas and liquid collecting system includes gas collection tank（9）And liquid collection tank（25）With the second thermocouple（23）, wherein,
Gas collection tank（9）Pass through pipeline and CO air accumulators（1）After parallel connection, then pass through cover（15）It is connected to high pressure tank body（16）, institute
State liquid collection tank（25）Pass through pipeline, cover（15）It is connected to high pressure tank body（16）；
The control system is by temperature and rotational speed governor（27）, liquid collection tank temperature indicator（28）, high pressure pot temperature
Display（29）And speed display（30）Form；
Described high-pressure reaction pot also includes the first needle-valve（3）, the second needle-valve（20）, air inlet（4）, exhaust outlet（19）, it is described
CO air accumulators（1）Pass through pipeline and the air inlet of high-pressure reaction pot（4）It is connected, and in high-pressure reaction pot air inlet（4）Installation the
One needle-valve（3）Air inlet aperture is controlled, the first needle-valve（3）Taken with being provided with gas phase in the connecting pipeline of high-pressure reaction pot
Sample system.
2. analogue experiment installation according to claim 1, it is characterized in that：In gas collection tank（9）Top is provided with nitrogen
Protect valve（6）, take air valve（7）, first pressure table（8）, bottom is equipped with the atmospheric valve of liquid（10）.
3. analogue experiment installation according to claim 1, it is characterized in that：In cover（15）Right-hand member be provided with second pressure
Table（18）, exhaust outlet（19）With the second needle-valve（20）, the second needle-valve（20）To exhaust outlet（19）Aperture be controlled.
4. analogue experiment installation according to claim 1, it is characterized in that：Described gas collection tank（9）Lower end be provided with
Atmospheric valve（10）, upper end side is provided with and takes air valve（7）With first pressure table（8）, upper center passes through pipeline and valve（5）Connection
To the first needle-valve（3）With cover（15）Between pipeline on.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710743623.1A CN107446617B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610954158.1A CN106566581B (en) | 2016-10-27 | 2016-10-27 | A kind of analogue experiment installation |
| CN201710743623.1A CN107446617B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
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| CN201610954158.1A Division CN106566581B (en) | 2016-10-27 | 2016-10-27 | A kind of analogue experiment installation |
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| Publication Number | Publication Date |
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| CN107446617A true CN107446617A (en) | 2017-12-08 |
| CN107446617B CN107446617B (en) | 2019-08-20 |
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| CN201710743612.3A Active CN107557056B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
| CN201710743623.1A Expired - Fee Related CN107446617B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
| CN201610954158.1A Expired - Fee Related CN106566581B (en) | 2016-10-27 | 2016-10-27 | A kind of analogue experiment installation |
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| US20110099890A1 (en) * | 2009-12-22 | 2011-05-05 | Bohlig James W | Sorbent containing engineered fuel feed stock |
| CN203663799U (en) * | 2013-12-31 | 2014-06-25 | 黄石市利福达医药化工有限公司 | High-pressure reaction kettle |
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| EP2566830B1 (en) * | 2010-05-07 | 2017-03-22 | GEVO, Inc. | Renewable jet fuel blendstock from isobutanol |
| CN102161911A (en) * | 2011-03-10 | 2011-08-24 | 何巨堂 | Hydrogenation conversion integrated method for high-nitrogen and high-aromatic hydrocarbon oil |
| CN204111689U (en) * | 2014-08-19 | 2015-01-21 | 中国石油天然气股份有限公司 | A kind of selective hydrogenation device |
| CN105567316B (en) * | 2015-12-23 | 2018-07-31 | 上海新佑能源科技有限公司 | Inferior heavy oil processing and treating method |
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| US20110099890A1 (en) * | 2009-12-22 | 2011-05-05 | Bohlig James W | Sorbent containing engineered fuel feed stock |
| CN203663799U (en) * | 2013-12-31 | 2014-06-25 | 黄石市利福达医药化工有限公司 | High-pressure reaction kettle |
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| CN107557056A (en) | 2018-01-09 |
| CN107446617B (en) | 2019-08-20 |
| CN107557056B (en) | 2019-06-25 |
| CN106566581A (en) | 2017-04-19 |
| CN107537424A (en) | 2018-01-05 |
| CN107537424B (en) | 2019-09-24 |
| CN106566581B (en) | 2017-11-07 |
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