CN106566581B - A kind of analogue experiment installation - Google Patents
A kind of analogue experiment installation Download PDFInfo
- Publication number
- CN106566581B CN106566581B CN201610954158.1A CN201610954158A CN106566581B CN 106566581 B CN106566581 B CN 106566581B CN 201610954158 A CN201610954158 A CN 201610954158A CN 106566581 B CN106566581 B CN 106566581B
- Authority
- CN
- China
- Prior art keywords
- valve
- cover
- high pressure
- liquid
- collection tank
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/44—Hydrogenation of the aromatic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/04—Pressure vessels, e.g. autoclaves
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/22—Devices for withdrawing samples in the gaseous state
- G01N1/2247—Sampling from a flowing stream of gas
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
Abstract
The present invention relates to a kind of analogue experiment installation.Its technical scheme is：High-pressure reaction pot is made up of electromagnetic stirr device, finishing reactor, cover and high pressure tank body, the high pressure tank body is arranged on heating furnace chamber, the top of high pressure tank body is provided with cover, electromagnetic stirr device, finishing reactor are installed on cover, rupture disk is arranged in the middle part of the sidepiece of the upside boss of cover, boss and is installed with electromagnetic stirr device, and the bottom of electromagnetic stirr device is installed in pressure pan body, middle and upper part is cased with finishing reactor, and the top of electromagnetic stirr device is connected to control system by control line；The beneficial effects of the invention are as follows：It is of the invention that requirement of experiment is reached by analogue experiment installation, in addition, setting the sampling equipment of gas and liquid in experimental simulation device, data are continuously acquired so as to quickly realize in experiment, experiment is realized and more fast, accurately determines.
Description
Technical field
The present invention relates to a kind of experimental provision, more particularly to a kind of analogue experiment installation.
Background technology
In recent years, petroleum heavy in poor quality problem is all suffered from China or even world wide, but with economic hair
Exhibition, light-end products requirement but increasingly increases, and this requires us that mink cell focus is more processed into light-end products, to meet warp
The need for Ji development is to lightweight high-quality oil product.At present, the main technological means of upgrading have it is conventional thermal cracking, face hydrogen and subtract
Glue cracking, hydrogen supply visbreaking and face hydrogen hydrogen supply visbreaking.The oily stability of modification that wherein conventional visbreaking is obtained, 0API
Etc. poor, and other modification technologies are subjected to the limit that hydrogen source, Hydrogen activation and hydrogen supply agent develop the problems such as preferred difficulty is big
System.
Polycyclic aromatic hydrocarbon is rich in viscous crude, some of which can be hydrogenated with the conditions of relatively relaxing, and some are under the conditions of relatively relaxing
But it is difficult to be hydrogenated with.CO hydro-thermals become the newborn hydrogen with high activity that transducing is produced, if newborn hydrogen original position can be acted on into viscous crude
In under the conditions of relatively relaxing the polycyclic aromatic hydrocarbon that can be hydrogenated with, on the one hand obtained hydrogenation products can carry out hydrogen turn inside viscous crude
Move, internal potential hydrogen supply agent effect is played, so as to play a part of hydrogenation to the viscous crude molecule for being difficult to be hydrogenated with the conditions of mitigation；
On the other hand, its own is changed into the polycyclic aromatic hydrocarbon being easily hydrogenated with again, so as to realize the effect that newborn hydrogen is efficiently transmitted into viscous crude.
The petroleum coke vaporization that raw material CO in CO hydro-thermal conversion processes can be produced by delayed coking is obtained, not only can be without to H2
Further activation and it is significantly cost-effective, can also more efficiently lift upgrading effect.Therefore, polycyclic aromatic hydrocarbon hydrogen migration
It is a problem with huge practical value to upgrading to be converted with CO hydro-thermals.
The content of the invention
There is provided a kind of analogue experiment installation, this hair aiming at the drawbacks described above that prior art is present for the purpose of the present invention
Bright utilization polycyclic aromatic hydrocarbon model compound replaces the polycyclic aromatic hydrocarbon in viscous crude under CO hydro-thermals conversion environment in experimental simulation device
Middle carry out hydrogenation reaction, and then polycyclic aromatic hydrocarbon is changed into the compound with virtue and cycloalkanes ring structure, so as to change as viscous crude
Potential hydrogen supply agent during matter, the oily viscosity of reduction generation improves the oily stability of generation, is finally reached the mesh that viscous crude is efficiently modified
's.
A kind of analogue experiment installation that the present invention is mentioned, including CO air accumulators（1）, high-pressure reaction pot, gas and liquid collecting system
Most of with control system four, the high-pressure reaction pot is by electromagnetic stirr device（12）, finishing reactor（13）, rupture disk（14）、
First thermocouple（17）, cover（15）With high pressure tank body（16）Constitute, the high pressure tank body（16）Installed in heating furnace（11）It is interior
Chamber, high pressure tank body（16）Top be provided with cover（15）, in cover（15）Upper installation electromagnetic stirr device（12）, finishing reactor
（13）, rupture disk（14）, the first thermocouple（17）, rupture disk（14）Installed in cover（15）Upside boss sidepiece, boss
Middle part be installed with electromagnetic stirr device（12）With the first thermocouple（17）, electromagnetic stirr device（12）Bottom be installed in high pressure tank body
（16）Interior, middle and upper part is cased with finishing reactor（13）, electromagnetic stirr device（12）Top control system is connected to by control line；
Described gas and liquid collecting system includes gas collection tank（9）And liquid collection tank（25）With the second thermocouple（23）Group
Into, wherein, gas collection tank（9）Pass through pipeline and CO air accumulators（1）After parallel connection, then pass through cover（15）It is connected to high pressure tank body
（16）, the liquid collection tank（25）Pass through pipeline, cover（15）It is connected to high pressure tank body（16）；
The control system is by temperature and rotational speed governor（27）, liquid collection tank temperature indicator（28）, high pressure tank body
Temperature indicator（29）And speed display（30）Constitute.
It is preferred that, above-mentioned high-pressure reaction pot also includes the first needle-valve（3）, the second needle-valve（20）, air inlet（4）, exhaust
Mouthful（19）, the CO air accumulators（1）Pass through pipeline and the air inlet of high-pressure reaction pot（4）It is connected, and in reaction under high pressure canister incoming gas
Mouthful（4）First needle-valve is installed（3）Air inlet aperture is controlled, the first needle-valve（3）With in the connecting pipeline of high-pressure reaction pot
Gas phase sampling system is installed.
It is preferred that, in gas collection tank（9）Top is provided with nitrogen protection valve（6）, take air valve（7）, first pressure table
（8）, bottom is equipped with the atmospheric valve of liquid（10）.
It is preferred that, in cover（15）Right-hand member be provided with second pressure table（18）, exhaust outlet（19）With the second needle-valve（20）,
Second needle-valve（20）To exhaust outlet（19）Aperture be controlled.
It is preferred that, above-mentioned gas collection tank（9）Lower end be provided with atmospheric valve（10）, upper end side is provided with and takes air valve（7）
With first pressure table（8）, upper center passes through pipeline and valve（5）It is connected to the first needle-valve（3）With cover（15）Between pipe
On line.
It is preferred that, in valve（5）Nitrogen protection valve is connected with the pipeline of downside（6）.
It is preferred that, above-mentioned liquid collection tank（25）Top is equipped with the 3rd pressure gauge（24）With the second thermocouple（23）, under
Portion is provided with liquid taking valve（26）.
It is preferred that, the first thermocouple（17）With the second thermocouple（23）With electromagnetic stirr device（12）By circuit and temperature and
Rotating speed control cabinet（27）It is connected.
It is preferred that, the finishing reactor（13）Using quickly cooling coil pipe.
A kind of application method for analogue experiment installation that the present invention is mentioned, including following operating procedure：
（1）Checkout facility device seal, using water and the anthracene of polycyclic aromatic hydrocarbon model compound is used as if seal is intact
It is dissolved in after toluene and is placed in pressure pan body with naphthalene, use CO pressurisings, reaction initial pressure is pressurized to after purging three times；
（2）Heat up heating after pressure needed for reaction is pressurized in kettle, is warming up to 100oStart stirring during C, and continue heating
Until temperature needed for reaction, and maintain at the reaction temperatures until reaching the defined reaction time；
（3）After reaching the time required to reaction, the valve that liquid phase sampling system is connected with high-pressure reaction pot, Partial Liquid Phase are opened
Enter under elevated pressure conditions in liquid-phase collection tank, liquid taking valve is opened after the temperature in liquid-phase collection tank reaches requirement with pressure and is taken
Go out liquid product, then toluene is dissolved in after wherein condensed water is distilled off and carry out chromatography, liquid-phase collection tank is clear using solvent
Wash clean, and it is used for the continuous sampling of liquid product after being purged with nitrogen；
（4）After after liquid product taking-up, the valve that gas phase sampling system is connected with high-pressure reaction pot, taking-up portion are opened immediately
Divide gas phase to enter in gas collection tank, treat pressure stability in gas collection tank, stabilization, which is down to open after room temperature, takes air valve, collects gas
Phase product carries out chromatography；The liquid phase in atmospheric valve emptying tank is opened, is cleaned using solvent and is used for gas after being purged with nitrogen
The continuous sampling of phase product；
（5）According to the gas-phase product gas chromatographic analysis result obtained under the differential responses time, show that CO hydro-thermals are converted
Kinetics, and contrasted with pure CO hydro-thermals transformationreation；Liquid product show that anthracene and naphthalene face CO through chromatography respectively
Hydro-thermal converts dynamics, and is contrasted with the dynamics under hydro condition；
（6）In using anthracene and naphthalene as viscous crude under the conditions of relatively relaxing the easy polycyclic aromatic hydrocarbon modelling of hydrogenation and difficult hydrogenation
Compound, above-mentioned experiment is carried out by anthracene and naphthalene in high pressure tank body simultaneously, by the continuous sampling to liquid-phase product and analysis draws naphthalene
Conversion ratio and with its face CO hydro-thermals conversion in conversion ratio contrasted；
（7）Finishing reactor is opened after the completion of reaction with terminating reaction.
The beneficial effects of the invention are as follows：The polycyclic aromatic hydrocarbon in viscous crude is replaced in CO hydro-thermals using polycyclic aromatic hydrocarbon model compound
Hydrogenation reaction is carried out under conversion environment in analogue means, and then polycyclic aromatic hydrocarbon is changed into the change with fragrant simultaneously cycloalkanes ring structure
Compound, so that as the potential hydrogen supply agent during upgrading, the oily viscosity of reduction generation improves the oily stability of generation, finally
Reach the purpose that viscous crude is efficiently modified；
In addition, the present invention reaches requirement of experiment by analogue experiment installation, and by setting gas-liquid sampling system can letter
Singly, rapidly realize that viscous crude faces the continuous sampling of CO hydro-thermals modification, more fast, accurately determine polycyclic aromatic hydrocarbon hydrogen migration and CO
Hydro-thermal converts the effect to upgrading.
Brief description of the drawings
Accompanying drawing 1 is the structural representation of the present invention；
In figure：CO air accumulators 1, valve 2, the first needle-valve 3, air inlet 4, valve 5, nitrogen protect valve 6, take air valve 7, first
Pressure gauge 8, gas collection tank 9, atmospheric valve 10, heating furnace 11, electromagnetic stirr device 12, finishing reactor 13, rupture disk 14, cover
15th, high pressure tank body 16, thermocouple 17, second pressure table 18, exhaust outlet 19, the second needle-valve 20, common valve 21, solvent purge valve
22nd, the second thermocouple 23, the 3rd pressure gauge 24, liquid collection tank 25, liquid taking valve 26, temperature and rotational speed governor 27, liquid are received
Collect tank temperature indicator 28, high pressure pot temperature display 29 and speed display 30, mobile base 31.
Embodiment
With reference to accompanying drawing 1, the invention will be further described：
A kind of analogue experiment installation that the present invention is mentioned, including CO air accumulators 1, high-pressure reaction pot, gas and liquid collecting system and
Control system four is most of, and the high-pressure reaction pot is by electromagnetic stirr device 12, finishing reactor 13, rupture disk 14, the first thermoelectricity
Even 17, cover 15 and high pressure tank body 16 are constituted, and the high pressure tank body 16 is arranged on the inner chamber of heating furnace 11, the top of high pressure tank body 16
Provided with cover 15, electromagnetic stirr device 12, finishing reactor 13, rupture disk 14, the first thermocouple 17, explosion are installed on cover 15
Piece 14 is arranged in the middle part of the sidepiece of the upside boss of cover 15, boss and is installed with the thermocouple 17 of electromagnetic stirr device 12 and first, electricity
The bottom of magnetic stirring device 12 is installed in high pressure tank body 16, and middle and upper part is cased with finishing reactor 13, the top of electromagnetic stirr device 12
Control system is connected to by control line；
Wherein, gas and liquid collecting system includes gas collection tank 9 and the thermocouple 23 of liquid collection tank 25 and second is constituted, its
In, gas collection tank 9 by pipeline it is in parallel with CO air accumulators 1 after, then high pressure tank body 16, the liquid be connected to by cover 15
Collecting tank 25 is connected to high pressure tank body 16 by pipeline, cover 15；
The control system is by temperature and rotational speed governor 27, liquid collection tank temperature indicator 28, high pressure pot temperature
Display 29 and speed display 30 are constituted.
In addition, above-mentioned high-pressure reaction pot also includes the first needle-valve 3, the second needle-valve 20, air inlet 4, exhaust outlet 19, it is described
CO air accumulators 1 are connected by pipeline with the air inlet 4 of high-pressure reaction pot, and install the first needle-valve 3 in high-pressure reaction pot air inlet 4
Air inlet aperture is controlled, the first needle-valve 3 in the connecting pipeline of high-pressure reaction pot with being provided with gas phase sampling system.
It is preferred that, nitrogen protection valve 6 is installed on the top of gas collection tank 9, air valve 7, first pressure table 8, bottom peace is taken
There is the atmospheric valve 10 of liquid.
It is preferred that, the right-hand member of cover 15 is provided with second pressure table 18, the needle-valve 20 of exhaust outlet 19 and second, the second needle-valve
The aperture of 20 pairs of exhaust outlets 19 is controlled.
It is preferred that, the lower end of above-mentioned gas collection tank 9 is provided with atmospheric valve 10, and upper end side is provided with and takes air valve 7 and first
Pressure gauge 8, upper center is connected on the pipeline between the first needle-valve 3 and cover 15 by pipeline and valve 5.
It is preferred that, nitrogen protection valve 6 is connected with the pipeline of the downside of valve 5, nitrogen is passed through during for needing and is protected
Shield.
It is preferred that, the above-mentioned top of liquid collection tank 25 is equipped with the 3rd pressure gauge 24 and the second thermocouple 23, and bottom is provided with
Liquid taking valve 26.
It is preferred that, the first thermocouple 17 and the second thermocouple 23 and electromagnetic stirr device 12 pass through circuit and temperature and rotating speed control
Case 27 processed is connected.In addition, finishing reactor（13）Using quickly cooling coil pipe, by coil winding in the outer of electromagnetic stirr device 12
Side, at the end of needs are reacted, by being passed through refrigerant liquid, such as cold water, can quickly realize temperature drop, and then terminate
Reaction.
In addition, high-pressure reaction pot is installed in the middle part of the inner chamber of heating furnace, specifically heating furnace 11 is tubular construction, and top is provided with
Bell, bell center is provided with circular hole, and high pressure tank body 16 is placed into the inner chamber of heating furnace 11, the top of high pressure tank body 16 through circular hole
Provided with cover 15, the cover 15 is fixedly connected with bell by multiple bolts, and boss is provided with the upside of cover 15；Rupture disk
Superpressure is prevented for the confined space or excessive vacuum occurs, plays safeguard protection effect.
A kind of application method for analogue experiment installation that the present invention is mentioned, including following operating procedure：
（1）Checkout facility device seal, using water and the anthracene of polycyclic aromatic hydrocarbon model compound is used as if seal is intact
It is dissolved in after toluene and is placed in pressure pan body with naphthalene, use CO pressurisings, 2 ~ 6MPa of reaction initial pressure is pressurized to after purging three times；
（2）Heat up heating after pressure needed for reaction is pressurized in kettle, is warming up to 100oStart stirring during C, and continue heating
Until 380 ~ 420 DEG C of temperature needed for reaction, and maintain at the reaction temperatures until reaction time 2-24h as defined in reaching；
（3）After reaching the time required to reaction, the valve that liquid phase sampling system is connected with high-pressure reaction pot, Partial Liquid Phase are opened
Enter under elevated pressure conditions in liquid-phase collection tank, liquid taking valve is opened after the temperature in liquid-phase collection tank reaches requirement with pressure and is taken
Go out liquid product, then toluene is dissolved in after wherein condensed water is distilled off and carry out chromatography, liquid-phase collection tank is clear using solvent
Wash clean, and it is used for the continuous sampling of liquid product after being purged with nitrogen；
（4）After after liquid product taking-up, the valve that gas phase sampling system is connected with high-pressure reaction pot, taking-up portion are opened immediately
Divide gas phase to enter in gas collection tank, treat pressure stability in gas collection tank, stabilization, which is down to open after room temperature, takes air valve, collects gas
Phase product carries out chromatography；The liquid phase in atmospheric valve emptying tank is opened, is cleaned using solvent and is used for gas after being purged with nitrogen
The continuous sampling of phase product；
（5）According to the gas-phase product gas chromatographic analysis result obtained under the differential responses time, show that CO hydro-thermals are converted
Kinetics, and contrasted with pure CO hydro-thermals transformationreation；Liquid product show that anthracene and naphthalene face CO through chromatography respectively
Hydro-thermal converts dynamics, and is contrasted with the dynamics under hydro condition；
（6）In using anthracene and naphthalene as viscous crude under the conditions of relatively relaxing the easy polycyclic aromatic hydrocarbon modelling of hydrogenation and difficult hydrogenation
Compound, above-mentioned experiment is carried out by anthracene and naphthalene in high pressure tank body simultaneously, by the continuous sampling to liquid-phase product and analysis draws naphthalene
Conversion ratio and with its face CO hydro-thermals conversion in conversion ratio contrasted；
（7）Finishing reactor is opened after the completion of reaction with terminating reaction.
The high pressure tank volume of above-mentioned high-pressure reaction pot is 300mL, and gas collection tank volume is 100mL, liquid collection tank
Volume is 60mL, and reaction temperature is usually 380 ~ 420 DEG C, and the molar ratio of reaction initial pressure 2 ~ 6MPa, CO and water is 1:2~
1:6, anthracene and naphthalene are 0.1-10wt% in the accounting of toluene, and electromagnetic stirr device is made of resistant material, in addition, CO can lead to
The petroleum coke vaporization for crossing delayed coking generation is obtained, not only can be without to H2Further activation and it is significantly cost-effective, also
Upgrading effect can more efficiently be lifted.
Embodiment 2, analogue experiment installation of the invention is same as Example 1, wherein, the analogue experiment installation mentioned makes
With method, wherein parameter is：The volume ratio of water and solvent toluene is 1:10, anthracene/naphthalene of addition is organic solvent mass fraction
5.0wt%, reaction time 4h, every 0,30,60,90,120min sampling.
Embodiment 3, analogue experiment installation of the invention is same as Example 1, wherein, the analogue experiment installation mentioned makes
With method, wherein parameter is：The volume ratio of water and solvent toluene is 1:10, anthracene/naphthalene of addition is organic solvent mass fraction
0.1wt%, reaction time 24h, every 0,30,60,90,120min sampling.
Embodiment 4, analogue experiment installation of the invention is different from embodiment 1, a mobile base 31 is added, by each
Test accessory and be arranged on mobile base, be easy to movement, it is convenient in laboratory operation and movement, wherein, the simulated experiment dress mentioned
The application method put, wherein parameter are：The volume ratio of water and solvent toluene is 1:10, anthracene/naphthalene of addition is organic solvent quality
The 10wt% of fraction, reaction time 2h, every 0,30,60,90,120min sampling.
It is described above, only it is the part preferred embodiment of the present invention, any those skilled in the art may profit
Equivalent technical scheme is changed or is revised as with the technical scheme of above-mentioned elaboration.Therefore, the technology according to the present invention
Any simple modification or substitute equivalents that scheme is carried out, belong to the greatest extent the scope of protection of present invention.
Claims (6)
1. a kind of analogue experiment installation, it is characterized in that：Including CO air accumulators（1）, high-pressure reaction pot, gas and liquid collecting system and control
System four is most of, and the high-pressure reaction pot is by electromagnetic stirr device（12）, finishing reactor（13）, rupture disk（14）, first heat
Galvanic couple（17）, cover（15）With high pressure tank body（16）Constitute, the high pressure tank body（16）Installed in heating furnace（11）Inner chamber, high pressure
Tank body（16）Top be provided with cover（15）, in cover（15）Upper installation electromagnetic stirr device（12）, finishing reactor（13）, explosion
Piece（14）, the first thermocouple（17）, rupture disk（14）Installed in cover（15）Upside boss sidepiece, be installed with the middle part of boss
Electromagnetic stirr device（12）With the first thermocouple（17）, electromagnetic stirr device（12）Bottom be installed in high pressure tank body（16）It is interior, on
Portion is cased with finishing reactor（13）, electromagnetic stirr device（12）Top control system is connected to by control line；
Described gas and liquid collecting system includes gas collection tank（9）And liquid collection tank（25）With the second thermocouple（23）, wherein,
Gas collection tank（9）Pass through pipeline and CO air accumulators（1）After parallel connection, then pass through cover（15）It is connected to high pressure tank body（16）, institute
State liquid collection tank（25）Pass through pipeline, cover（15）It is connected to high pressure tank body（16）；
The control system is by temperature and rotational speed governor（27）, liquid collection tank temperature indicator（28）, high pressure pot temperature
Display（29）And speed display（30）Constitute.
2. analogue experiment installation according to claim 1, it is characterized in that：In gas collection tank（9）Top is provided with nitrogen
Protect valve（6）, take air valve（7）, first pressure table（8）, bottom is equipped with the atmospheric valve of liquid（10）.
3. analogue experiment installation according to claim 1, it is characterized in that：In cover（15）Right-hand member be provided with second pressure
Table（18）, exhaust outlet（19）With the second needle-valve（20）, the second needle-valve（20）To exhaust outlet（19）Aperture be controlled.
4. analogue experiment installation according to claim 1, it is characterized in that：Described gas collection tank（9）Lower end be provided with
Atmospheric valve（10）, upper end side is provided with and takes air valve（7）With first pressure table（8）, upper center passes through pipeline and valve（5）Connection
To the first needle-valve（3）With cover（15）Between pipeline on.
5. analogue experiment installation according to claim 4, it is characterized in that：In valve（5）Nitrogen is connected with the pipeline of downside
Gas shielded valve（6）.
6. analogue experiment installation according to claim 1, it is characterized in that：Described liquid collection tank（25）Top is equipped with the
Three pressure gauges（24）With the second thermocouple（23）, bottom is provided with liquid taking valve（26）.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710741800.2A CN107537424B (en) | 2016-10-27 | 2016-10-27 | A kind of application method of imitative experimental appliance |
| CN201710743623.1A CN107446617B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
| CN201710743612.3A CN107557056B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
| CN201610954158.1A CN106566581B (en) | 2016-10-27 | 2016-10-27 | A kind of analogue experiment installation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610954158.1A CN106566581B (en) | 2016-10-27 | 2016-10-27 | A kind of analogue experiment installation |
Related Child Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710743623.1A Division CN107446617B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
| CN201710743612.3A Division CN107557056B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
| CN201710741800.2A Division CN107537424B (en) | 2016-10-27 | 2016-10-27 | A kind of application method of imitative experimental appliance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106566581A CN106566581A (en) | 2017-04-19 |
| CN106566581B true CN106566581B (en) | 2017-11-07 |
Family
ID=58535608
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610954158.1A Expired - Fee Related CN106566581B (en) | 2016-10-27 | 2016-10-27 | A kind of analogue experiment installation |
| CN201710743623.1A Expired - Fee Related CN107446617B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
| CN201710741800.2A Active CN107537424B (en) | 2016-10-27 | 2016-10-27 | A kind of application method of imitative experimental appliance |
| CN201710743612.3A Active CN107557056B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710743623.1A Expired - Fee Related CN107446617B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
| CN201710741800.2A Active CN107537424B (en) | 2016-10-27 | 2016-10-27 | A kind of application method of imitative experimental appliance |
| CN201710743612.3A Active CN107557056B (en) | 2016-10-27 | 2016-10-27 | A kind of imitative experimental appliance |
Country Status (1)
| Country | Link |
|---|---|
| CN (4) | CN106566581B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110180461A (en) * | 2019-04-04 | 2019-08-30 | 西安交通大学 | A kind of coal tar high-temperature high-voltage reaction experimental provision |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101707025A (en) * | 2009-12-11 | 2010-05-12 | 南京化工职业技术学院 | Actual training device for producing cyclohexane by hydrogenation of benzene for teaching |
| US20140051897A1 (en) * | 2010-05-07 | 2014-02-20 | Gevo, Inc. | Renewable jet fuel blendstock from isobutanol |
| CN204111689U (en) * | 2014-08-19 | 2015-01-21 | 中国石油天然气股份有限公司 | A kind of selective hydrogenation device |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5015404A (en) * | 1988-04-05 | 1991-05-14 | Nippon Oil Co., Ltd. | Oil composition containing hydrogenated oil |
| PL2516926T3 (en) * | 2009-12-22 | 2017-11-30 | Accordant Energy, Llc | Sorbent-containing engineered fuel feed stocks |
| CN102161911A (en) * | 2011-03-10 | 2011-08-24 | 何巨堂 | Hydrogenation conversion integrated method for high-nitrogen and high-aromatic hydrocarbon oil |
| CN203663799U (en) * | 2013-12-31 | 2014-06-25 | 黄石市利福达医药化工有限公司 | High-pressure reaction kettle |
| CN105567316B (en) * | 2015-12-23 | 2018-07-31 | 上海新佑能源科技有限公司 | Inferior heavy oil processing and treating method |
-
2016
- 2016-10-27 CN CN201610954158.1A patent/CN106566581B/en not_active Expired - Fee Related
- 2016-10-27 CN CN201710743623.1A patent/CN107446617B/en not_active Expired - Fee Related
- 2016-10-27 CN CN201710741800.2A patent/CN107537424B/en active Active
- 2016-10-27 CN CN201710743612.3A patent/CN107557056B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101707025A (en) * | 2009-12-11 | 2010-05-12 | 南京化工职业技术学院 | Actual training device for producing cyclohexane by hydrogenation of benzene for teaching |
| US20140051897A1 (en) * | 2010-05-07 | 2014-02-20 | Gevo, Inc. | Renewable jet fuel blendstock from isobutanol |
| CN204111689U (en) * | 2014-08-19 | 2015-01-21 | 中国石油天然气股份有限公司 | A kind of selective hydrogenation device |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107557056A (en) | 2018-01-09 |
| CN107557056B (en) | 2019-06-25 |
| CN107537424B (en) | 2019-09-24 |
| CN106566581A (en) | 2017-04-19 |
| CN107446617B (en) | 2019-08-20 |
| CN107446617A (en) | 2017-12-08 |
| CN107537424A (en) | 2018-01-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106566581B (en) | A kind of analogue experiment installation | |
| Silverwood et al. | Persistent species formed during the carbon dioxide reforming of methane over a nickel–alumina catalyst | |
| CN205761025U (en) | A kind of portable minisize High Temperature High Pressure thermal cracking of heavy oil Fast Evaluation reaction unit | |
| CN108440406B (en) | Preparation and dehydrogenation method of perhydrogenated hydrogen storage molecules | |
| DE1009602B (en) | Process for carrying out exothermic catalytic gas reactions under high pressure and at high temperature | |
| Čelič et al. | In situ generation of Ni nanoparticles from metal–organic framework precursors and their use for biomass hydrodeoxygenation | |
| Yan et al. | Liquefaction of cotton seed in sub-critical water/ethanol with modified medical stone for bio-oil | |
| Boutaieb et al. | Pine cone pyrolysis: optimization of temperature for energy recovery | |
| CN108865282A (en) | A kind of gasification of biomass reformate upgrading pilot system and its test method | |
| CN103808543B (en) | Self-heating substance heat reaction testing system | |
| CN109833910B (en) | Catalyst for synthetic ammonia reaction | |
| CN109613133A (en) | Each fraction of residual oil can extracting rate measuring method in a kind of crude oil | |
| CN114441366A (en) | Device and method for quantitatively determining surface acidity of material | |
| CN208700990U (en) | A kind of gasification of biomass reformate upgrading pilot system | |
| Musolino et al. | Aromatic alcohols as model molecules for studying hydrogenolysis reactions promoted by palladium catalysts | |
| Stephens | A Step Toward Sustainability: Mechanisms of Hydrodeoxygenation Reactions over a Metal-Metal Oxide Catalyst | |
| CN207571059U (en) | A kind of measurement device of heavy oil green coke trend | |
| CN208313684U (en) | Low-temperature sample box with attemperator | |
| JP4322006B2 (en) | Pseudo-equilibrium apparatus for fluid catalytic cracking catalyst for hydrocarbons | |
| Meiramov | Hydrogenation of model compounds in the presence of iron-containing catalysts | |
| CN206479375U (en) | Industrial steam pyrolysis furnace on-line period device | |
| CN104179482B (en) | A kind of High Temperature High Pressure oil gas sand control screen sand block experimental apparatus for capability | |
| GB605707A (en) | Improvements in or relating to the manufacture of copper catalysts and their use for hydrogenating organic substances | |
| Arifin et al. | Long-term service at high temperatures effect of KHR 35 CT Kubota reformer tube material | |
| CN204122129U (en) | A kind of device of simulating spent agent oil gas desorption under stripping conditions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171107 Termination date: 20211027 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |