CN208700990U - A kind of gasification of biomass reformate upgrading pilot system - Google Patents

A kind of gasification of biomass reformate upgrading pilot system Download PDF

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Publication number
CN208700990U
CN208700990U CN201821363495.4U CN201821363495U CN208700990U CN 208700990 U CN208700990 U CN 208700990U CN 201821363495 U CN201821363495 U CN 201821363495U CN 208700990 U CN208700990 U CN 208700990U
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China
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tar bottle
tar
biomass
bottle
gasification
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CN201821363495.4U
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Inventor
赵立欣
马腾
孟海波
姚宗路
丛宏斌
王敬茹
霍丽丽
贾吉秀
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Chinese Academy of Agricultural Engineering CAAE
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Chinese Academy of Agricultural Engineering CAAE
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Abstract

The utility model discloses a kind of gasification of biomass reformate upgrading pilot systems, including the first electrothermal furnace, steam generator, second electrothermal furnace, refrigeration machine and the gas cylinder being sequentially communicated, pyrolysis reactor, heat tracing pipe, cracking reactor, tar bottle group and airbag, the gas cylinder is provided with inert gas, the pyrolysis reactor is sealed in first electrothermal furnace, the steam generator is connected to the heat tracing pipe, the cracking reactor is sealed in second electrothermal furnace, biomass is equipped in the pyrolysis reactor, catalyst is equipped in the cracking reactor, the tar bottle group is set in the refrigeration machine.The utility model structure is simple, easy to operate, substantially increases the upgrading effect of gasification of biomass reformate.

Description

A kind of gasification of biomass reformate upgrading pilot system
Technical field
The utility model relates to gasification of biomass reforming technique fields, more particularly to a kind of gasification of biomass reformate Upgrading pilot system.
Background technique
Stalk is as a kind of typical agricultural residue in China's very abundant, and major part is using tradition such as compost, burnings Method handles it.Since stalk contains a small amount of nitrogen and a large amount of solid particle, cigarette can be generated during the burning process It is imperative to convert biomass into high-value product using various thermalization technologies such as pyrolysis, gasifications for mist.
In all biomass transformation processes, gasification is one of most promising process, the energy dose-effect of gas cations Rate is higher than the energy efficiency of burning.One main problem of gasification of biomass is to handle the tar formed in gasification.It is burnt Oil is the aggregate of hydrocarbon, is at high temperature gaseous state, account for pyrolysis gas energy has 5~15%, it is difficult to flammable gas Body is burned utilizes together, waste of energy.When temperature is at 200 DEG C or less, most of tar can condense into the sticky shape of dark brown Liquid, be easily attached on the inner wall of pipeline and relevant device, result in blockage to pipeline, hinder the normal operation of equipment, simultaneously Noxious material in tar will also result in great damage to the health of people.
Utility model content
It is above-mentioned existing to solve the purpose of the utility model is to provide a kind of gasification of biomass reformate upgrading pilot system The problem of with the presence of technology, structure is simple, easy to operate, improves the upgrading effect of gasification of biomass reformate.
To achieve the above object, the utility model provides following scheme:
The utility model provides a kind of gasification of biomass reformate upgrading pilot system, including the first electrothermal furnace, steaming Vapour generator, the second electrothermal furnace, refrigeration machine and the gas cylinder being sequentially communicated, pyrolysis reactor, heat tracing pipe, cracking reactor, coke Oil bottle group and airbag, the gas cylinder are provided with inert gas, and the pyrolysis reactor is sealed in first electrothermal furnace, The steam generator is connected to the heat tracing pipe, and the cracking reactor is sealed in second electrothermal furnace, described It is equipped with biomass in pyrolysis reactor, is equipped with catalyst in the cracking reactor, the tar bottle group is set to the refrigeration In machine.
Preferably, the pyrolysis reactor includes the first inner tube and the first outer tube that from-inner-to-outer is set gradually, and described The lower part of one inner tube is equipped with the first sieve plate, and the biomass is set on first sieve plate;The upper end of first inner tube is set There are the first blow vent and the second blow vent, first blow vent is connect with the gas cylinder, second blow vent and the first pressure The connection of power table, is equipped with switch valve and gaseous mass flowmeter, first outer tube between the gas cylinder and first blow vent Lower end be connected to the upper end of the heat tracing pipe.
Preferably, the cracking reactor includes the second inner tube and the second outer tube that from-inner-to-outer is set gradually, and described The lower part of two inner tubes is equipped with the second sieve plate, and the catalyst is set on second sieve plate, the upper end of second outer tube with The lower end of the heat tracing pipe is connected to.
Preferably, first inner tube, first outer tube, second inner tube, second outer tube and the heat tracing Pipe is quartz ampoule.
Preferably, the tar bottle group includes sequentially connected first tar bottle, the second tar bottle, third tar bottle and Four tar bottles, the first tar bottle are empty bottle, are equipped with bead in the second tar bottle and the third tar bottle, institute It states and is equipped with tar adsorbing medium in the 4th tar bottle.
Preferably, the first tar bottle, the second tar bottle, the third tar bottle and the 4th tar bottle are equal Equipped with entrance, first outlet and second outlet, the entrance of the first tar bottle is connected to the lower end of second outer tube, described The first outlet of first tar bottle extends to the bottom of the first tar bottle, the second outlet of the first tar bottle with it is described The entrance of second tar bottle is connected to, and the first outlet of the second tar bottle extends to the glass in the second tar bottle In pearl, the second outlet of the second tar bottle is connected to the entrance of the third tar bottle, and the first of the third tar bottle Outlet extends in the bead in the third tar bottle, the second outlet of the third tar bottle and the 4th coke The entrance of oil bottle is connected to, and the first outlet of the 4th tar bottle extends to the absorption of the tar in the 4th tar bottle and is situated between In matter, the second outlet of the 4th tar bottle is connected to the airbag.
Preferably, the outside of the heat tracing pipe is equipped with heating tape and heat-preservation cotton, first outer tube and the heat tracing pipe it Between be equipped with a temperature thermocouple, the temperature thermocouple connect with the first temperature controller, and the heat tracing pipe is equipped with vapor Entrance and air pressure mouth, the vapor entrance are connect with the steam generator, and the air pressure mouth and second pressure gauge connect It connects.
Preferably, first electrothermal furnace is equipped with second temperature controller, and second electrothermal furnace is equipped with the control of third temperature Instrument processed.
Preferably, the catalyst is charcoal or dolomite.
The utility model achieves following technical effect: gasification of biomass reformate upgrading test compared with the existing technology Pyrolysis reactor and cracking is respectively set in the first electrothermal furnace and the second electrothermal furnace by the way that electrothermal furnace is divided into two sections in system Reactor, and vapor is introduced by steam evaporator, so that biomass is successively in pyrolysis reactor and cracking reactor Pyrolytic reaction and cracking reaction are carried out respectively, are realized quick, the abundant cracking for the tar that biomass combustion generates, are substantially increased The upgrading effect of gasification of biomass reformate, while the yield of pyrolysis gas of biomass is increased, be conducive to the recycling of heat again Utilize, can also the upgrading effect to the pyrolysis gas under different condition study, be conducive to gasification of biomass reformate and mention Matter pilot system advanced optimizes.
Detailed description of the invention
In order to illustrate the embodiment of the utility model or the technical proposal in the existing technology more clearly, below will be to embodiment Needed in attached drawing be briefly described, it should be apparent that, the accompanying drawings in the following description is only the utility model Some embodiments for those of ordinary skill in the art without creative efforts, can also be according to this A little attached drawings obtain other attached drawings.
Fig. 1 is the structural schematic diagram of the utility model gasification of biomass reformate upgrading pilot system;
Fig. 2 is the partial enlarged view in Fig. 1 at I;
Fig. 3 is the partial enlarged view in Fig. 1 at II;
Wherein: 1- gas cylinder, 2- switch valve, 3- gas mass flow meter, 4- first pressure gauge, the first blow vent of 5-, 6- Two blow vents, 7- pyrolysis reactor, the first inner tube of 8-, the first electrothermal furnace of 9-, the first outer tube of 10-, 11- second temperature controller, The first temperature controller of 12-, 13- temperature thermocouple, 14- heat tracing pipe, 15- steam generator, 16- second pressure gauge, 17- heat tracing Band, 18- cracking reactor, the second inner tube of 19-, the second electrothermal furnace of 20-, 21- third temperature controller, the second outer tube of 22-, 23- First tar bottle, 24- the second tar bottle, 25- third tar bottle, the 4th tar bottle of 26-, 27- refrigeration machine, 28- airbag, 29- are raw Substance, the first sieve plate of 30-, 31- catalyst, the second sieve plate of 32-.
Specific embodiment
The following will be combined with the drawings in the embodiments of the present invention, carries out the technical scheme in the embodiment of the utility model Clearly and completely describe, it is clear that the described embodiments are only a part of the embodiments of the utility model, rather than whole Embodiment.Based on the embodiments of the present invention, those of ordinary skill in the art are in the premise not made the creative labor Under every other embodiment obtained, fall within the protection scope of the utility model.
In the description of the utility model it is to be appreciated that term " on ", "lower", " left side " and " right side " instruction orientation or Positional relationship is orientation and positional relationship based on the figure, it is only for facilitate the structurally and operationally mode of description, and It is not to indicate or imply that signified part must have a particular orientation, with the operation of specific orientation, thus should not be understood as Limitations of the present invention.
The purpose of the utility model is to provide a kind of gasification of biomass reformate upgrading pilot systems, to solve existing skill Art there are the problem of, structure is simple, easy to operate, improves the upgrading effect of gasification of biomass reformate.
To keep the above objects, features, and advantages of the utility model more obvious and easy to understand, with reference to the accompanying drawing and have Body embodiment is described in further detail the utility model.
Embodiment one
It is as shown in Figure 1-Figure 3: to present embodiments provide a kind of gasification of biomass reformate upgrading pilot system, including One electrothermal furnace 9, steam generator 15, the second electrothermal furnace 20, refrigeration machine 27 and the gas cylinder 1 being sequentially communicated, pyrolysis reactor 7, Heat tracing pipe 14, cracking reactor 18, tar bottle group and airbag 28.Gas cylinder 1 is provided with inert gas, and inert gas is preferably nitrogen Gas.Pyrolysis reactor 7 is sealed in the first electrothermal furnace 9, and steam generator 15 is connected to heat tracing pipe 14, cracking reactor 18 It is sealed in the second electrothermal furnace 20, vapor is introduced into heat tracing pipe 14 by steam generator 15, urged in realization tar While changing cracking, the yield of pyrolysis gas of biomass is increased.Biomass 29 is equipped in pyrolysis reactor 7, biomass 29 is preferred For corn stover.Catalyst is equipped in cracking reactor 18, catalyst is preferably charcoal.Tar bottle group is set to refrigeration machine 27 It is interior.The pyrolysis temperature of pyrolysis reactor 7 is preferably 500-600 DEG C, and the catalytic pyrolysis temperature of cracking reactor 18 is preferably 750- 850 DEG C, the temperature of vapor is preferably 300-350 DEG C in the heating tape 17 and heat tracing pipe 14 that temperature thermocouple 13 measures, inertia The flow that is passed through of gas is preferably 90-110ml/min, and the value of the S/C of vapor is preferably 4 in steam generator 15.
Specifically, pyrolysis reactor 7 includes the first inner tube 8 and the first outer tube 10 that from-inner-to-outer is set gradually.In first The lower part of pipe 8 is equipped with the first sieve plate 30, and the first sieve plate 30 plays the role of filtered tar, and biomass 29 is set to the first sieve plate 30 On.The upper end of first inner tube 8 is equipped with the first blow vent 5 and the second blow vent 6, and the first blow vent 5 is connect with gas cylinder 1, and second is logical Port 6 is connect with first pressure gauge 4, and switch valve 2 and gaseous mass flowmeter 3 are equipped between gas cylinder 1 and the first blow vent 5, the The lower end of one outer tube 10 is connected to the upper end of heat tracing pipe 14.
Cracking reactor 18 includes the second inner tube 19 and the second outer tube 22 that from-inner-to-outer is set gradually.Second inner tube 19 Lower part is equipped with the second sieve plate 32, and the second sieve plate 32 also functions to the effect of filtered tar, and catalyst 31 is set on the second sieve plate 32. The upper end of second outer tube 22 is connected to the lower end of heat tracing pipe 14.First inner tube 8, the first outer tube 10, the second inner tube 19, the second outer tube 22 and heat tracing pipe 14 be quartz ampoule.
The outside from-inner-to-outer of heat tracing pipe 14 is successively wound with heating tape 17 and heat-preservation cotton, the first outer tube 10 and heat tracing pipe 14 Between be equipped with a temperature thermocouple 13, temperature thermocouple 13 connect with the first temperature controller 12.Heat tracing pipe 14 is steamed equipped with water Gas blowout entrance and air pressure mouth, vapor entrance are connect with steam generator 15, and air pressure mouth is connect with second pressure gauge 16.First Electrothermal furnace 9 is equipped with second temperature controller 11, and the second electrothermal furnace 20 is equipped with third temperature controller 21.The survey of temperature thermocouple 13 Amount temperature is controlled by the first temperature controller 12, and the temperature of the first electrothermal furnace 9 is controlled by second temperature controller 11, the second electric heating The temperature of furnace 20 is controlled by third temperature controller 21.
Tar bottle group includes that sequentially connected first tar bottle 23, the second tar bottle 24, third tar bottle 25 and the 4th are burnt Oil bottle 26.First tar bottle 23, the second tar bottle 24, third tar bottle 25 and the 4th tar bottle 26 are arranged at refrigeration machine 27 It is interior, so that most of tar condenses into dark brown viscous liquid, it is burnt convenient for the first tar bottle 23, the second tar bottle 24, third The collection of oil bottle 25 and the 4th 26 pairs of tar of tar bottle.Wherein, the first tar bottle 23 is empty bottle, is mainly used for collecting tar.The It is equipped with bead in two tar bottles 24 and third tar bottle 25, expands reaction contact area.Coke is equipped in 4th tar bottle 26 Oily adsorbing medium, tar adsorbing medium are preferably silica gel, play the role of tar adsorption.First tar bottle 23, the second tar bottle 24, third tar bottle 25 and the 4th tar bottle 26 are equipped with entrance, first outlet and second outlet, the entrance of the first tar bottle 23 It is connected to the lower end of the second outer tube 22, the first outlet of the first tar bottle 23 extends to the bottom of the first tar bottle 23, and first is burnt The second outlet of oil bottle 23 is connected to the entrance of the second tar bottle 24, and the first outlet of the second tar bottle 24 extends to the second tar In bead in bottle 24, the second outlet of the second tar bottle 24 is connected to the entrance of third tar bottle 25, third tar bottle 25 First outlet extend in the bead in third tar bottle 25, the second outlet of third tar bottle 25 and the 4th tar bottle 26 Entrance connection, the first outlet of the 4th tar bottle 26 extends in the tar adsorbing medium in the 4th tar bottle 26, and the 4th is burnt The second outlet of oil bottle 26 is connected to airbag 28, is collected to the gas after abundant reaction, is realized that the recycling of pyrolysis gas is sharp again With.
The test process of gasification of biomass reformate upgrading pilot system in the present embodiment is as follows: refrigeration machine 27 is opened Dynamic 2h, cryogenic temperature condition, the temperature of refrigeration machine 27 needed for reaching experiment are set as -8 DEG C, take proper catalyst 31 to be added to and split In the second inner tube 19 for solving reactor 18, cracking reactor 18 is put into the second electrothermal furnace 20, is twined in the outside of heat tracing pipe 14 Temperature thermocouple 13 is set between heating tape 17 and heat-preservation cotton, heating tape 17 and the first outer tube 10, sets temperature thermocouple 13 The temperature of vapor is preferably 300-350 DEG C in the heating tape 17 and heat tracing pipe 14 of measurement, and the pyrolysis temperature of the first electrothermal furnace 9 is excellent It is selected as 500-600 DEG C, the catalytic pyrolysis temperature of the second electrothermal furnace 20 is preferably 750-850 DEG C, to the first electrothermal furnace 9 and the second electricity After the furnace temperature of hot stove 20 rises to set temperature, N is passed through by the first blow vent 5 of 7 upper end of pyrolysis reactor2, N2To be passed through flow excellent It is selected as 300ml/min, the first tar bottle 23, the second tar bottle 24, third tar bottle 25 and the 4th tar bottle 26 are put into system In cold 27 and pipeline is connected, bead is put into the second tar bottle 24 and third tar bottle 25, in the 4th tar bottle 26 It is inside put into silica gel, continues to be passed through N210min takes appropriate biomass 29 that the first sieve plate of the first inner tube 8 of pyrolysis reactor 7 is added On 30, the pyrolysis reactor 7 with biomass 29 is put into the first electrothermal furnace 9, starts gas and gas is taken to sample, pyrolysis reactor The superheated vapour that the pyrolysis gas that 7 endogenous substances 29 generate is sprayed into steam generator 15 first is mixed, superheated vapour S/C be 4, occur steam reforming reaction, reactive chemistry formula be CnHx+nH2O→H2+ nCO, mixed gas is by cracking Reactor 18, the catalyst 31 in tar and the second inner tube 19 in mixed gas occur cracking reaction, further focus Oil is cut down, and the gas after abatement is successively passed through the first tar bottle 23, the second tar bottle 24, third tar in refrigeration machine 27 In bottle 25 and the 4th tar bottle 26, the remaining tar in gas is adsorbed, last gas enters airbag 28 and recycled again It utilizes.
The present embodiment takes 10g corn stover to be put into gasification reformer, by the first blow vent of 7 upper end of pyrolysis reactor 5 are passed through N2, it is passed through N2Flow be 100ml/min, using charcoal as catalyst 31, vapor S/C be 4, pyrolysis temperature 550 DEG C, catalytic pyrolysis temperature is 800 DEG C, and the temperature of vapor is in the heating tape 17 and heat tracing pipe 14 that temperature thermocouple 13 measures 320 DEG C, catalytic pyrolysis is carried out to tar, taking the gas time is 70min, and tar conversion is raised to 96% by 72%, gas yield from 35.5% is raised to 60.2%.
The present embodiment is respectively set in the first electrothermal furnace 9 and the second electrothermal furnace 20 by the way that electrothermal furnace is divided into two sections Pyrolysis reactor 7 and cracking reactor 18, and vapor is introduced by steam evaporator 15, so that biomass 29 is successively in heat Pyrolytic reaction and cracking reaction are carried out in solution reactor 7 and cracking reactor 18 respectively, realizes the coke that the burning of biomass 29 generates Quick, the abundant cracking of oil, substantially increases the upgrading effect of gasification of biomass reformate, while increasing 29 heat of biomass The yield vented one's spleen is conducive to the recycling and reusing of heat, can also the upgrading effect to the pyrolysis gas under different condition grind Study carefully, is conducive to advanced optimizing for gasification of biomass reformate upgrading pilot system.
Embodiment two
It takes 10g corn stover to be put into gasification reformer, N is passed through by the first blow vent 5 of 7 upper end of pyrolysis reactor2, It is passed through N2Flow flow be 100ml/min, using dolomite as catalyst 31, vapor S/C be 4, pyrolysis temperature be 550 DEG C, Catalytic pyrolysis temperature is 800 DEG C, and the temperature of vapor is 320 in the heating tape 17 and heat tracing pipe 14 that temperature thermocouple 13 measures DEG C, catalytic pyrolysis is carried out to tar, taking the gas time is 70min, and tar conversion is raised to 92% by 63%, gas yield from 27.3% is raised to 49.8%.
The technical effect of the present embodiment is referring to embodiment one.
It applies specific case in this specification to be expounded the principles of the present invention and embodiment, the above reality The explanation for applying example is merely used to help understand the method and its core concept of the utility model;Meanwhile for the general of this field Technical staff, based on the idea of the present invention, there will be changes in the specific implementation manner and application range.To sum up institute It states, the content of the present specification should not be construed as a limitation of the present invention.

Claims (9)

1. a kind of gasification of biomass reformate upgrading pilot system, it is characterised in that: including the first electrothermal furnace, steam generation Device, the second electrothermal furnace, refrigeration machine and the gas cylinder being sequentially communicated, pyrolysis reactor, heat tracing pipe, cracking reactor, tar bottle group And airbag, the gas cylinder are provided with inert gas, the pyrolysis reactor is sealed in first electrothermal furnace, the steaming Vapour generator is connected to the heat tracing pipe, and the cracking reactor is sealed in second electrothermal furnace, and the pyrolysis is anti- It answers and is equipped with biomass in device, be equipped with catalyst in the cracking reactor, the tar bottle group is set in the refrigeration machine.
2. gasification of biomass reformate upgrading pilot system according to claim 1, it is characterised in that: the pyrolysis is anti- Answering device includes the first inner tube and the first outer tube that from-inner-to-outer is set gradually, and the lower part of first inner tube is equipped with the first sieve plate, The biomass is set on first sieve plate;The upper end of first inner tube is equipped with the first blow vent and the second blow vent, First blow vent is connect with the gas cylinder, and second blow vent is connect with first pressure gauge, the gas cylinder and described the Switch valve and gaseous mass flowmeter are equipped between one blow vent, the lower end of first outer tube and the upper end of the heat tracing pipe connect It is logical.
3. gasification of biomass reformate upgrading pilot system according to claim 2, it is characterised in that: the cracking is anti- Answering device includes the second inner tube and the second outer tube that from-inner-to-outer is set gradually, and the lower part of second inner tube is equipped with the second sieve plate, The catalyst is set on second sieve plate, and the upper end of second outer tube is connected to the lower end of the heat tracing pipe.
4. gasification of biomass reformate upgrading pilot system according to claim 3, it is characterised in that: in described first Pipe, first outer tube, second inner tube, second outer tube and the heat tracing pipe are quartz ampoule.
5. gasification of biomass reformate upgrading pilot system according to claim 3, it is characterised in that: the tar bottle Group includes sequentially connected first tar bottle, the second tar bottle, third tar bottle and the 4th tar bottle, and the first tar bottle is It is equipped with bead in empty bottle, the second tar bottle and the third tar bottle, is equipped with tar in the 4th tar bottle and inhales Attached medium.
6. gasification of biomass reformate upgrading pilot system according to claim 5, it is characterised in that: described first is burnt Oil bottle, the second tar bottle, the third tar bottle and the 4th tar bottle is equipped with entrance, first outlet and second goes out Mouthful, the entrance of the first tar bottle is connected to the lower end of second outer tube, and the first outlet of the first tar bottle extends To the bottom of the first tar bottle, the second outlet of the first tar bottle is connected to the entrance of the second tar bottle, institute The first outlet for stating the second tar bottle extends in the bead in the second tar bottle, and the of the second tar bottle Two outlets are connected to the entrance of the third tar bottle, and the first outlet of the third tar bottle extends to the third tar bottle In the interior bead, the second outlet of the third tar bottle is connected to the entrance of the 4th tar bottle, and the described 4th The first outlet of tar bottle extends in the tar adsorbing medium in the 4th tar bottle, and the of the 4th tar bottle Two outlets are connected to the airbag.
7. gasification of biomass reformate upgrading pilot system according to claim 3, it is characterised in that: the heat tracing pipe Outside be equipped with heating tape and heat-preservation cotton, between first outer tube and the heat tracing pipe be equipped with a temperature thermocouple, the survey Warm galvanic couple is connect with the first temperature controller, and the heat tracing pipe is equipped with vapor entrance and air pressure mouth, the vapor Entrance is connect with the steam generator, and the air pressure mouth is connect with second pressure gauge.
8. gasification of biomass reformate upgrading pilot system according to claim 1, it is characterised in that: first electricity Hot stove is equipped with second temperature controller, and second electrothermal furnace is equipped with third temperature controller.
9. gasification of biomass reformate upgrading pilot system according to claim 1, it is characterised in that: the catalyst For charcoal or dolomite.
CN201821363495.4U 2018-08-23 2018-08-23 A kind of gasification of biomass reformate upgrading pilot system Expired - Fee Related CN208700990U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108865282A (en) * 2018-08-23 2018-11-23 农业部规划设计研究院 A kind of gasification of biomass reformate upgrading pilot system and its test method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108865282A (en) * 2018-08-23 2018-11-23 农业部规划设计研究院 A kind of gasification of biomass reformate upgrading pilot system and its test method

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Granted publication date: 20190405