CN107446547A - A kind of fire resistant resin base frication material - Google Patents
A kind of fire resistant resin base frication material Download PDFInfo
- Publication number
- CN107446547A CN107446547A CN201710711012.9A CN201710711012A CN107446547A CN 107446547 A CN107446547 A CN 107446547A CN 201710711012 A CN201710711012 A CN 201710711012A CN 107446547 A CN107446547 A CN 107446547A
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- Prior art keywords
- parts
- fire resistant
- resin base
- resistant resin
- modified
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- 239000000463 material Substances 0.000 title claims abstract description 24
- 229920005989 resin Polymers 0.000 title claims abstract description 20
- 239000011347 resin Substances 0.000 title claims abstract description 20
- 230000009970 fire resistant effect Effects 0.000 title claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 23
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 20
- 244000226021 Anacardium occidentale Species 0.000 claims abstract description 15
- 235000020226 cashew nut Nutrition 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000010466 nut oil Substances 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims abstract description 10
- 239000003607 modifier Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- 239000012783 reinforcing fiber Substances 0.000 claims abstract description 9
- 239000005011 phenolic resin Substances 0.000 claims abstract description 6
- 239000013078 crystal Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- -1 Delanium Chemical compound 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 229920006231 aramid fiber Polymers 0.000 claims description 5
- 239000010425 asbestos Substances 0.000 claims description 5
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims description 5
- 239000003365 glass fiber Substances 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 235000010755 mineral Nutrition 0.000 claims description 5
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 5
- 229910052895 riebeckite Inorganic materials 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 claims description 5
- 239000010455 vermiculite Substances 0.000 claims description 5
- 229910052902 vermiculite Inorganic materials 0.000 claims description 5
- 235000019354 vermiculite Nutrition 0.000 claims description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000007767 bonding agent Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 235000019198 oils Nutrition 0.000 claims description 3
- 238000002525 ultrasonication Methods 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 2
- 235000012255 calcium oxide Nutrition 0.000 claims description 2
- 239000002383 tung oil Substances 0.000 claims description 2
- 239000002783 friction material Substances 0.000 abstract description 12
- 239000011159 matrix material Substances 0.000 abstract description 5
- 229920000459 Nitrile rubber Polymers 0.000 abstract description 4
- 239000003822 epoxy resin Substances 0.000 abstract description 4
- 239000000314 lubricant Substances 0.000 abstract description 4
- 229920000647 polyepoxide Polymers 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- IKRMZAOEXULJQX-UHFFFAOYSA-N calcium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Ca+2].O1B([O-])OB2OB([O-])OB1O2 IKRMZAOEXULJQX-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1436—Composite particles, e.g. coated particles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
- F16D69/02—Composition of linings ; Methods of manufacturing
- F16D69/027—Compositions based on metals or inorganic oxides
- F16D69/028—Compositions based on metals or inorganic oxides containing fibres
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D2200/00—Materials; Production methods therefor
- F16D2200/0034—Materials; Production methods therefor non-metallic
- F16D2200/0056—Elastomers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D2200/00—Materials; Production methods therefor
- F16D2200/006—Materials; Production methods therefor containing fibres or particles
- F16D2200/0065—Inorganic, e.g. non-asbestos mineral fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Braking Arrangements (AREA)
Abstract
The invention discloses the raw material composition of a kind of fire resistant resin base frication material, including following parts by weight：6 10 parts of phenol-formaldehyde resin modified；68 parts of nitrile rubber powder；48 parts of reinforcing fiber；10 14 parts of friction modifiers；24 parts of epoxy resin lubricant；12 14 parts of filler.The present invention is modified by cashew nut oil modified dose to phenolic resin so that the performance of phenol-formaldehyde resin modified is more preferably；And it is applied to resin-matrix friction material preparation so that the anti-wear performance of the resin-matrix friction material of preparation, resistance to elevated temperatures, stable friction factor are improved；And raw material sources are extensive, it is adapted to industrialized production, there is good economic and social benefit.
Description
Technical field
The present invention relates to friction materials technology field, more particularly to a kind of fire resistant resin base frication material.
Background technology
Friction material is that one kind is applied on dynamic power machine, and the part of braking and transmission agency is performed by rubbing action
Material, is widely used in automobile, train, in aircraft and all kinds of engineering mechanical devices.Automobile using friction material mainly by bonding,
Formed after fibre reinforced materials, frictional property regulator and the mixing of the major class constituent element of filler four through compacting.As vehicle is to environmental protection, height
Speed and overload direction development, people propose higher requirement to the performance of automobile brake material, particularly in high-temperature brake
When, the stability and security of material are most important.
In the prior art, friction material can produce thermal decomposition when operating temperature is more than 250 DEG C, cause coefficient of friction bright
Aobvious to reduce, wear rate dramatically increases, and has a strong impact on people's driving safety.Therefore resin-matrix friction material how is improved in high temperature ring
The stabilization of anti-wear performance and holding coefficient of friction under border has become research topic urgently to be resolved hurrily, so as to meet actual answer
Needs.
Therefore, in order to solve above-mentioned problem, spy of the present invention provides a kind of new technical scheme.
The content of the invention
It is an object of the invention to provide a kind of fire resistant resin base frication material, prior art friction material can solve the problem that
The problems such as resistance to elevated temperatures is poor, coefficient of friction is unstable and safety coefficient is not high.
Technical scheme is used by the present invention is directed to above-mentioned technological deficiency：
A kind of fire resistant resin base frication material, include the raw material composition of following parts by weight：
Further, the raw material composition of following parts by weight is included：
Further, the raw material composition of following parts by weight is included：
Further, the phenol-formaldehyde resin modified is modified obtained by cashew nut oil modified dose.
Further, the reinforcing fiber is glass fibre, aramid fiber, the composition of non-asbestos mineral fibres.
Further, the friction modifiers are crystalline flake graphite, Delanium, molybdenum disulfide, antimonous sulfide, potassium titanate
The composition of whisker, calcium sulfate crystal whiskers.
Further, the filler is silicon ash, Frication powder, expanded vermiculite, kaolinic composition.
Further, the described cashew nut oil modified dose raw material for including following parts by weight forms：Cashew nut shell oil 10-15 parts；
Barium sulfate 10-15 parts, quick lime 0.2-0.9 parts；Tung oil 0.5-2 parts.
It is a further object of the present invention to provide a kind of method of cashew nut oil modified dose of phenol-formaldehyde resin modified is as follows：By cashew nut
Shell oil modifying agent, phenolic resin, modified bonding agent are placed in mixing channel and stirred, and it is 80-100 DEG C to control whipping temp, stirring
15-20min ultrasonication is carried out after uniformly.
The beneficial effects of the invention are as follows：
1st, the present invention is modified by cashew nut oil modified dose to phenolic resin so that the performance of phenol-formaldehyde resin modified is more
It is good；
2nd, the present invention prepares phenol-formaldehyde resin modified applied to resin-matrix friction material so that the resin base friction material of preparation
The anti-wear performance of material, resistance to elevated temperatures, stable friction factor are improved；
3rd, raw material sources of the present invention are extensive, are adapted to industrialized production, have good economic and social benefit.
Embodiment
Limited with reference to embodiment technical scheme is further, but claimed model
Enclose and be not only limited to made description.
Embodiment 1
A kind of fire resistant resin base frication material, include the raw material composition of following parts by weight：
6 parts of phenol-formaldehyde resin modified；
6 parts of nitrile rubber powder；
4 parts of reinforcing fiber,
Wherein, reinforcing fiber is glass fibre, aramid fiber, the composition of non-asbestos mineral fibres；
10 parts of friction modifiers,
Wherein, friction modifiers are crystalline flake graphite, Delanium, molybdenum disulfide, antimonous sulfide, potassium titanate crystal whisker, sulphur
The composition of sour calcium pyroborate；
2 parts of epoxy resin lubricant；
12 parts of filler,
Wherein, filler is silicon ash, Frication powder, expanded vermiculite, kaolinic composition.
Embodiment 2
A kind of fire resistant resin base frication material, include the raw material composition of following parts by weight：
8 parts of phenol-formaldehyde resin modified；
7 parts of nitrile rubber powder；
6 parts of reinforcing fiber,
Wherein, reinforcing fiber is glass fibre, aramid fiber, the composition of non-asbestos mineral fibres；
12 parts of friction modifiers,
Wherein, friction modifiers are crystalline flake graphite, Delanium, molybdenum disulfide, antimonous sulfide, potassium titanate crystal whisker, sulphur
The composition of sour calcium pyroborate；
3 parts of epoxy resin lubricant；
13 parts of filler,
Wherein, filler is silicon ash, Frication powder, expanded vermiculite, kaolinic composition.
Embodiment 3
A kind of fire resistant resin base frication material, include the raw material composition of following parts by weight：
10 parts of phenol-formaldehyde resin modified；
8 parts of nitrile rubber powder；
8 parts of reinforcing fiber,
Wherein, reinforcing fiber is glass fibre, aramid fiber, the composition of non-asbestos mineral fibres；
14 parts of friction modifiers,
Wherein, friction modifiers are crystalline flake graphite, Delanium, molybdenum disulfide, antimonous sulfide, potassium titanate crystal whisker, sulphur
The composition of sour calcium pyroborate；
4 parts of epoxy resin lubricant；
14 parts of filler,
Wherein, filler is silicon ash, Frication powder, expanded vermiculite, kaolinic composition.
Embodiment 4
A kind of method of cashew nut oil modified dose of phenol-formaldehyde resin modified is as follows：By cashew nut oil modified dose, phenolic resin, change
Property bonding agent be placed in mixing channel and stir, control whipping temp be 80-100 DEG C, carried out 15-20min after stirring
Ultrasonication.
The beneficial effects of the invention are as follows：
1st, the present invention is modified by cashew nut oil modified dose to phenolic resin so that the performance of phenol-formaldehyde resin modified is more
It is good；
2nd, the present invention prepares phenol-formaldehyde resin modified applied to resin-matrix friction material so that the resin base friction material of preparation
The anti-wear performance of material, resistance to elevated temperatures, stable friction factor are improved；
3rd, raw material sources of the present invention are extensive, are adapted to industrialized production, have good economic and social benefit.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (9)
- A kind of 1. fire resistant resin base frication material, it is characterised in that：Raw material composition including following parts by weight：
- A kind of 2. fire resistant resin base frication material according to claim 1, it is characterised in that：Including following parts by weight Raw material forms：
- A kind of 3. fire resistant resin base frication material according to claim 1, it is characterised in that：Including following parts by weight Raw material forms：
- A kind of 4. fire resistant resin base frication material according to claims 1 to 3 any one, it is characterised in that：It is described Phenol-formaldehyde resin modified is modified obtained by cashew nut oil modified dose.
- A kind of 5. fire resistant resin base frication material according to claims 1 to 3 any one, it is characterised in that：It is described Reinforcing fiber is glass fibre, aramid fiber, the composition of non-asbestos mineral fibres.
- A kind of 6. fire resistant resin base frication material according to claims 1 to 3 any one, it is characterised in that：It is described Friction modifiers are the combination of crystalline flake graphite, Delanium, molybdenum disulfide, antimonous sulfide, potassium titanate crystal whisker, calcium sulfate crystal whiskers Thing.
- A kind of 7. fire resistant resin base frication material according to claims 1 to 3 any one, it is characterised in that：It is described Filler is silicon ash, Frication powder, expanded vermiculite, kaolinic composition.
- A kind of 8. fire resistant resin base frication material according to claim 4, it is characterised in that：It is described cashew nut oil modified The raw material that agent includes following parts by weight forms：Cashew nut shell oil 10-15 parts；Barium sulfate 10-15 parts, quick lime 0.2-0.9 parts；Tung oil 0.5-2 parts.
- A kind of 9. fire resistant resin base frication material according to claim 8, it is characterised in that：It is described cashew nut oil modified The method of agent phenol-formaldehyde resin modified is as follows：Cashew nut oil modified dose, phenolic resin, modified bonding agent are placed in mixing channel and stirred Mix, it is 80-100 DEG C to control whipping temp, and 15-20min ultrasonication is carried out after stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710711012.9A CN107446547A (en) | 2017-08-18 | 2017-08-18 | A kind of fire resistant resin base frication material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710711012.9A CN107446547A (en) | 2017-08-18 | 2017-08-18 | A kind of fire resistant resin base frication material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107446547A true CN107446547A (en) | 2017-12-08 |
Family
ID=60492750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710711012.9A Withdrawn CN107446547A (en) | 2017-08-18 | 2017-08-18 | A kind of fire resistant resin base frication material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107446547A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108424608A (en) * | 2018-03-20 | 2018-08-21 | 枣阳兴亚摩擦材料有限公司 | A kind of New Type of Friction Materials without Asbestos and preparation method and application |
| CN110005736A (en) * | 2019-03-29 | 2019-07-12 | 上海壬丰新材料科技有限公司 | A kind of lightweight automotive brake pads and preparation method thereof that bottom plate is recyclable |
| CN112625458A (en) * | 2020-12-11 | 2021-04-09 | 黄山菲英汽车零部件有限公司 | High-performance automobile brake pad friction material and brake pad thereof |
| CN113321895A (en) * | 2021-06-08 | 2021-08-31 | 东营博瑞制动系统有限公司 | Friction material for improving antirust effect |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107606005A (en) * | 2017-07-12 | 2018-01-19 | 苏州翠南电子科技有限公司 | A kind of fire resistant resin base frication material |
-
2017
- 2017-08-18 CN CN201710711012.9A patent/CN107446547A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107606005A (en) * | 2017-07-12 | 2018-01-19 | 苏州翠南电子科技有限公司 | A kind of fire resistant resin base frication material |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108424608A (en) * | 2018-03-20 | 2018-08-21 | 枣阳兴亚摩擦材料有限公司 | A kind of New Type of Friction Materials without Asbestos and preparation method and application |
| CN110005736A (en) * | 2019-03-29 | 2019-07-12 | 上海壬丰新材料科技有限公司 | A kind of lightweight automotive brake pads and preparation method thereof that bottom plate is recyclable |
| CN110005736B (en) * | 2019-03-29 | 2021-04-13 | 上海壬丰新材料科技有限公司 | Light automobile brake pad with recyclable bottom plate and preparation method thereof |
| CN112625458A (en) * | 2020-12-11 | 2021-04-09 | 黄山菲英汽车零部件有限公司 | High-performance automobile brake pad friction material and brake pad thereof |
| CN112625458B (en) * | 2020-12-11 | 2022-09-09 | 黄山菲英汽车零部件有限公司 | High-performance automobile brake pad friction material and brake pad thereof |
| CN113321895A (en) * | 2021-06-08 | 2021-08-31 | 东营博瑞制动系统有限公司 | Friction material for improving antirust effect |
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| PB01 | Publication | ||
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Application publication date: 20171208 |