CN107435185A - A kind of preparation method of wool felt - Google Patents

A kind of preparation method of wool felt Download PDF

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Publication number
CN107435185A
CN107435185A CN201710504463.5A CN201710504463A CN107435185A CN 107435185 A CN107435185 A CN 107435185A CN 201710504463 A CN201710504463 A CN 201710504463A CN 107435185 A CN107435185 A CN 107435185A
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wool
yarn
preparation
parts
fur
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任新庄
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B21/02Pile fabrics or articles having similar surface features
    • D04B21/04Pile fabrics or articles having similar surface features characterised by thread material
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B35/00Details of, or auxiliary devices incorporated in, knitting machines, not otherwise provided for
    • D04B35/34Devices for cutting knitted fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613Polyethers without nitrogen
    • D06P1/6131Addition products of hydroxyl groups-containing compounds with oxiranes
    • D06P1/6133Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/6426Heterocyclic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/14Wool
    • D06P3/16Wool using acid dyes
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00Domestic or personal
    • D10B2503/06Bed linen

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides a kind of preparation method of wool felt, comprise the following steps:(1) wool skin is screened and impurity elimination;(2) it is pretreated fur is clean through aerosol hydro-peening, then through vacuum drying;(3) after the compound alkali lye of the fur cleaned up addition is handled 24 hours at 60 80 DEG C, regulation PH is 7, filters while hot, obtains wool, then will be washed, dried;(4) by wool textile;(5) dyed wool yarn again;(6) raschel machine is used, wool yarn makees suede yarn, and polyester filament makees bottom silk, and double-deck pillar stitch's fabric is woven into using 3 pin inlaid thread;(7) double-deck pillar stitch's fabric is cut into one side fabric from the middle of fine hair, then through washing, shaping, bristle, hot light, cropping, severing, bound edge obtain wool blanket.Wool felt bright prepared by the present invention, color is homogeneous, soft, smooth, scalds through high temperature and does not fade.

Description

A kind of preparation method of wool felt
Technical field
The invention belongs to the preparing technical field of wool felt, and in particular to a kind of preparation method of wool felt.
Background technology
As the wool fiber of important textile raw material, there are many advantages:Excellent elasticity, spreadability and thermal insulation, favorably The thermal with human body is kept in fabric shape;Soft gloss and good moisture adsorption and releasing energy, can obtain comfortable fabric Style;Unique felting property is advantageous to fabric forming and densification;It is good that distinctive spiral macromolecular and cross-linked structure assign fiber Good elasticity recovery and setting mechanism.
For usual people to the acquisition pattern of wool from periodically shearing, this mode typically results on sheepskin residual wool not It can be fully used, and the cultured output of China flock of sheep is limited, wool limited source, therefore be efficiently sheep using existing resource A great problem in woollen blanket process technology.
The content of the invention
The invention provides a kind of preparation method of wool felt, technique is simple, and production efficiency is high, can quickly remove Animal Skin Lipoid material in leather, is rapidly separated fur, makes full use of existing wool resource, and even dyeing, and color stability is high, Meet the high quality requirement of consumer.
The technical proposal for solving the technical problem of the invention is:
A kind of preparation method of wool felt, comprises the following steps:
(1) pre-process:Wool skin is subjected to screening and obtains the close fur of quality with impurity elimination, so as to ensure made same batch sheep Hair yarn quality is identical.
(2) aerosol hydro-peening:The fur that will be pre-processed through step (1) is clean through aerosol hydro-peening, then is dried through 40-60 DEG C of vacuum It is dry;
(3) alkali cleaning:The fur cleaned up obtained by step (2) is added into compound alkali lye 2-4 hours are handled at 60-80 DEG C Afterwards, it is 7 to adjust PH, filters while hot, obtains wool, then will be washed, dried.Will be dynamic by the special compound alkali lye of the present invention Leather component in thing fur is decomposed so that fur is rapidly separated, and good separating effect, then filtered obtains wool.
(4) wool is added into shredding in mixing willow to mix, then cleaned through scutcher shredding, carding machine cards, spinned simultaneously Twist fineness is 15-20 μm of wool raw yarn;
(5) dye:Wool raw yarn is added in dyeing cylinder, then dye solution is added toward dyeing in cylinder, is heated to 50-70 DEG C, after insulation dyeing 3-5 hours, tryptophan and color fixing agent are added, continues isothermal holding after 30 minutes, regulation PH is 7, is taken out Wool raw yarn, after 90-100 DEG C is dried in vacuo 30 minutes, room temperature is cooled to, then through washing 3-5 times, then at 40-60 DEG C of vacuum Drying dyes the high wool yarn of firmness needed for obtaining.
(6) raschel machine is used, wool yarn makees suede yarn, and polyester filament makees bottom silk, is woven into using 3 pin inlaid thread Double-deck pillar stitch's fabric;
(7) double-deck pillar stitch's fabric is cut into one side fabric from the middle of fine hair, then through washing, shaping, bristle, scald Light, cropping, severing, bound edge obtain wool blanket.
Preferably, the compound alkali lye described in step (3) is made up of following parts by weight component:20-30 part bicarbonates Sodium, 5-10 parts ethylenediamine, 3-5 parts sodium metasilicate, 1-3 parts aminophylline, 1-3 parts alum and 30-40 part water.Compound alkali lye is using a variety of Weak base compounding forms, and alkaline matter can be dissolved in the material of water with the fat in animal's leather and albumen qualitative response generation, so that Obtain animal's leather to decompose so that fur quick separating.According to highly basic processing, then wool can be caused to degrade, influence its smoothness. Sodium metasilicate in compound alkali lye can form layer protecting film in wool surfaces, further reduce alkali lye and it is damaged, and alum can be with Increase the compliance and glossiness of wool.
Preferably, the mass ratio of the fur and compound alkali lye described in step (3) is 1:10-15.
Preferably, the dye solution described in step (4) is made up of following parts by weight component:20-30 parts are acid cloudy Ion pigment, 30-40 parts water and 1-3 part cosolvents.
It is further preferred that described acidic anionic pigment be selected from acid red, acid black, acid blue, acid ash, acid golden yellow and At least one of acid brown.
It is further preferred that described cosolvent is sodium cetanesulfonate, polyoxyethylene sorbitan monooleate or dehydration Sorbitan fatty acid ester.
Preferably, the color fixing agent described in step (4) is cetylpyridinium chloride or brocide.Acid Property anionic pigment be one of the dyestuff commonly used in animal skin, but its shortcoming is that dyeing is uneven, and dyeing firmness needs to be carried It is high.Tryptophan in alkalescent, can be reacted with acidic anionic pigment as a kind of alkaloid, at the same can and wool surfaces Protein crosslink reaction so that dyeing firmness be improved.From cetylpyridinium chloride or cetyl Yl pyridines make color fixing agent, can be reacted with acidic anionic pigment, further function as the effect of fixation.
It is further preferred that the mass ratio of the wool raw yarn, dye solution, tryptophan and color fixing agent described in step (4) is 1:10- 20:0.03-0.05:0.05-0.08.
Beneficial effects of the present invention are:
1st, compound base extraction wool skin is formed using a variety of weak base compounding, so that animal's leather decomposes so that fur Quick separating, while wool is not caused to damage again, influence the quality of wool yarn.
2nd, the wool felt bright prepared by the present invention, even dyeing, dyeing firmness are high.
3rd, wool yarn processing method provided by the present invention, can be effectively using the wool near sheepskin, and wool yield is more Height, reduce production cost.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments to the present invention It is further elaborated.
Embodiment 1
(1) pre-process:Wool skin is subjected to screening and obtains the close fur of quality with impurity elimination;
(2) aerosol hydro-peening:The fur that will be pre-processed through step (1) is clean through aerosol hydro-peening, then through 40 DEG C of vacuum dryings;
(3) alkali cleaning:After the compound alkali lye of the fur cleaned up addition obtained by step (2) is handled 4 hours at 60 DEG C, adjust It is 7 to save PH, filters while hot, obtains wool, then will be washed, dried.The compound alkali lye is by following parts by weight component group Into:20 parts of sodium acid carbonates, 8 parts of ethylenediamines, 4 parts of sodium metasilicate, 1 part of aminophylline, 2 parts of alum and 35 parts of water, described animal fur Mass ratio with compound alkali lye is 1:10.
(4) wool is added into shredding in mixing willow to mix, then cleaned through scutcher shredding, carding machine cards, spinned simultaneously Twist to obtain wool raw yarn;
(5) dye:100g wools raw yarn is added in dyeing cylinder, then dye solution is added toward dyeing in cylinder, is heated to 50 DEG C, after insulation dyeing 5 hours, add 3g tryptophans and with 6g cetylpyridinium chlorides, continue isothermal holding after 30 minutes, It is 7 to adjust PH, takes out wool raw yarn, after 100 DEG C are dried in vacuo 30 minutes, is cooled to room temperature, then through washing 3-5 times, then at 60 DEG C of vacuum dryings;Described dye solution is made up of following parts by weight component:20 parts of acid reds, 35 parts of water and 3 parts Sodium cetanesulfonate.
(6) raschel machine is used, wool yarn makees suede yarn, and polyester filament makees bottom silk, is woven into using 3 pin inlaid thread Double-deck pillar stitch's fabric;
(7) double-deck pillar stitch's fabric is cut into one side fabric from the middle of fine hair, then through washing, shaping, bristle, scald Light, cropping, severing, bound edge obtain wool blanket.
Made wool felt bright, color is homogeneous, soft, smooth, scalds through high temperature and does not fade, in SEM Electronic Speculum Lower observation, wool yarn surface fracture are less.
Embodiment 2
(1) pre-process:Wool skin is subjected to screening and obtains the close fur of quality with impurity elimination;
(2) aerosol hydro-peening:The fur that will be pre-processed through step (1) is clean through aerosol hydro-peening, then through 50 DEG C of vacuum dryings;
(3) alkali cleaning:After the compound alkali lye of the fur cleaned up addition obtained by step (2) is handled 2 hours at 80 DEG C, adjust It is 7 to save PH, filters while hot, obtains wool, then will be washed, dried;The compound alkali lye is by following parts by weight component group Into:25 parts of sodium acid carbonates, 10 parts of ethylenediamines, 3 parts of sodium metasilicate, 3 parts of aminophyllines, 3 parts of alum and 30 parts of water, described fur and multiple The mass ratio for closing alkali lye is 1:12.
(4) wool is added into shredding in mixing willow to mix, then cleaned through scutcher shredding, carding machine cards, spinned simultaneously Twist to obtain wool raw yarn;
(5) dye:100g wools raw yarn is added in dyeing cylinder, then toward addition 1000g dye solutions in dyeing cylinder, added Heat to 60 DEG C, insulation dyeing 4 hours after, add 5g tryptophans and with 8g cetylpyridinium chlorides, continue isothermal holding 30 After minute, regulation PH is 7, takes out wool raw yarn, after 90 DEG C are dried in vacuo 30 minutes, is cooled to room temperature, then through washing 3-5 It is secondary, then at 60 DEG C of vacuum dryings;Described dye solution is made up of following parts by weight component:30 parts of acid golden yellows, 30 Part water and 1 part of polyoxyethylene sorbitan monooleate.
(6) raschel machine is used, wool yarn makees suede yarn, and polyester filament makees bottom silk, is woven into using 3 pin inlaid thread Double-deck pillar stitch's fabric;
(7) double-deck pillar stitch's fabric is cut into one side fabric from the middle of fine hair, then through washing, shaping, bristle, scald Light, cropping, severing, bound edge obtain wool blanket.
Made wool felt bright, color is homogeneous, soft, smooth, scalds through high temperature and does not fade, in SEM Electronic Speculum Lower observation, wool yarn surface fracture are less.
Embodiment 3
(1) pre-process:Wool skin is subjected to screening and obtains the close fur of quality with impurity elimination;
(2) aerosol hydro-peening:The fur that will be pre-processed through step (1) is clean through aerosol hydro-peening, then through 60 DEG C of vacuum dryings;
(3) alkali cleaning:After the compound alkali lye of the fur cleaned up addition obtained by step (2) is handled 3 hours at 70 DEG C, adjust It is 7 to save PH, filters while hot, obtains wool, then will be washed, dried;The compound alkali lye is by following parts by weight component group Into:30 parts of sodium acid carbonates, 5 parts of ethylenediamines, 5 parts of sodium metasilicate, 2 parts of aminophyllines, 1 part of alum and 40 parts of water, described animal fur Mass ratio with compound alkali lye is 1:15.
(4) wool is added into shredding in mixing willow to mix, then cleaned through scutcher shredding, carding machine cards, spinned simultaneously Twist to obtain wool raw yarn;
(5) dye:100g wools raw yarn is added in dyeing cylinder, then toward addition 2000g dye solutions in dyeing cylinder, added Heat to 70 DEG C, insulation dyeing 3 hours after, add 4g tryptophans and with 5g cetylpyridinium chlorides, continue isothermal holding 30 After minute, regulation PH is 7, takes out wool raw yarn, after 95 DEG C are dried in vacuo 30 minutes, is cooled to room temperature, then through washing 3-5 It is secondary, then at 60 DEG C of vacuum dryings;Described dye solution is made up of following parts by weight component:25 parts of acid blues, 35 parts Water and 3 parts of sorbitan fatty esters.
(6) raschel machine is used, wool yarn makees suede yarn, and polyester filament makees bottom silk, is woven into using 3 pin inlaid thread Double-deck pillar stitch's fabric;
(7) double-deck pillar stitch's fabric is cut into one side fabric from the middle of fine hair, then through washing, shaping, bristle, scald Light, cropping, severing, bound edge obtain wool blanket.
Made wool felt bright, color is homogeneous, soft, smooth, scalds through high temperature and does not fade, in SEM Electronic Speculum Lower observation, wool yarn surface fracture are less.
Comparative example 1
Operated with embodiment 1 it is identical, unlike use in step (3) mass concentration for 30% sodium hydrate aqueous solution replacement Compound alkali lye, made wool felt color and luster is dark, and color is homogeneous, and feel is partially puckery, scalds through high temperature and does not fade.
Comparative example 2
Operated with embodiment 1 it is identical, unlike do not add tryptophan in step (4), made wool felt color and luster is dark, and color is equal One, it is soft, smooth, scald and fade through high temperature.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.

Claims (8)

1. a kind of preparation method of wool felt, it is characterised in that the processing method comprises the following steps:
(1) pre-process:Wool skin is subjected to screening and obtains the close fur of quality with impurity elimination;
(2) aerosol hydro-peening:The fur that will be pre-processed through step (1) is clean through aerosol hydro-peening, then through 40-60 DEG C of vacuum drying;
(3) alkali cleaning:The fur cleaned up obtained by step (2) is added into compound alkali lye 2-4 hours are handled at 60-80 DEG C Afterwards, it is 7 to adjust PH, filters while hot, obtains wool, then will be washed, dried;
(4) wool is added into shredding in mixing willow to mix, then cleaned through scutcher shredding, carding machine cards, spinned and twist Obtain the wool raw yarn that fineness is 15-20 μm;
(5) dye:Wool raw yarn is added in dyeing cylinder, then dye solution is added toward dyeing in cylinder, is heated to 50-70 DEG C, after insulation dyeing 3-5 hours, tryptophan and color fixing agent are added, continues isothermal holding after 30 minutes, regulation PH is 7, is taken out Wool raw yarn, after 90-100 DEG C is dried in vacuo 30 minutes, room temperature is cooled to, then through washing 3-5 times, then at 40-60 DEG C of vacuum Drying obtains wool yarn;
(6) raschel machine is used, wool yarn makees suede yarn, and polyester filament makees bottom silk, and bilayer is woven into using 3 pin inlaid thread Pillar stitch's fabric;
(7) double-deck pillar stitch's fabric is cut into one side fabric from the middle of fine hair, then through washing, shaping, bristle, scald Light, cropping, severing, bound edge obtain wool blanket.
2. the preparation method of wool felt as claimed in claim 1, it is characterised in that compound alkali lye described in step (3) by Following parts by weight component composition:20-30 parts sodium acid carbonate, 5-10 parts ethylenediamine, 3-5 parts sodium metasilicate, 1-3 parts aminophylline, 1-3 Part alum and 30-40 part water.
3. the preparation method of wool felt as claimed in claim 1, it is characterised in that fur described in step (3) and compound The mass ratio of alkali lye is 1:10-15.
4. the preparation method of wool felt as claimed in claim 1, it is characterised in that dye solution described in step (4) by Following parts by weight component composition:20-30 part acidic anionics pigment, 30-40 parts water and 1-3 part cosolvents.
5. the preparation method of wool felt as claimed in claim 4, it is characterised in that described acidic anionic pigment is selected from acid Property red, acid black, acid blue, at least one of acid ash, acid golden yellow and acid brown.
6. the preparation method of wool felt as claimed in claim 4, it is characterised in that described cosolvent is cetyl sulfonic acid Sodium, polyoxyethylene sorbitan monooleate or sorbitan fatty ester.
7. the preparation method of wool felt as claimed in claim 1, it is characterised in that the color fixing agent described in step (4) is chlorine Change cetyl pyridinium or brocide.
8. the preparation method of the wool felt as described in claim 1 or 7, it is characterised in that the wool described in step (4) is former Yarn, dye solution, the mass ratio of tryptophan and color fixing agent are 1:10-20:0.03-0.05:0.05-0.08.
CN201710504463.5A 2017-06-28 2017-06-28 A kind of preparation method of wool felt Pending CN107435185A (en)

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CN108078273A (en) * 2018-01-22 2018-05-29 孙旭锋 A kind of horse tail hair sping mattress
CN108823707A (en) * 2018-06-04 2018-11-16 河北伟晨绒毛制品有限公司 A kind of anti-drilling wool fiber and anti-drilling wool comforter
CN108842462A (en) * 2018-06-04 2018-11-20 河北伟晨绒毛制品有限公司 A kind of washable wool fiber and washable wool comforter
CN108978172A (en) * 2018-06-04 2018-12-11 河北伟晨绒毛制品有限公司 A kind of free from extraneous odour wool fiber and free from extraneous odour wool comforter
CN111139572A (en) * 2020-03-07 2020-05-12 虞晓洁 Production process of diversified elastic single-sided velvet
CN114987000A (en) * 2022-06-30 2022-09-02 威海毛纺织集团有限公司 Washable Meilinuoraschel blanket and production method thereof
CN115110309A (en) * 2022-07-27 2022-09-27 李飞 Negative oxygen ion woolen blanket and preparation method thereof

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108078273A (en) * 2018-01-22 2018-05-29 孙旭锋 A kind of horse tail hair sping mattress
CN108078273B (en) * 2018-01-22 2024-04-02 孙旭锋 Horsetail Mao Danhuang mattress
CN108823707A (en) * 2018-06-04 2018-11-16 河北伟晨绒毛制品有限公司 A kind of anti-drilling wool fiber and anti-drilling wool comforter
CN108842462A (en) * 2018-06-04 2018-11-20 河北伟晨绒毛制品有限公司 A kind of washable wool fiber and washable wool comforter
CN108978172A (en) * 2018-06-04 2018-12-11 河北伟晨绒毛制品有限公司 A kind of free from extraneous odour wool fiber and free from extraneous odour wool comforter
CN111139572A (en) * 2020-03-07 2020-05-12 虞晓洁 Production process of diversified elastic single-sided velvet
CN114987000A (en) * 2022-06-30 2022-09-02 威海毛纺织集团有限公司 Washable Meilinuoraschel blanket and production method thereof
CN115110309A (en) * 2022-07-27 2022-09-27 李飞 Negative oxygen ion woolen blanket and preparation method thereof

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Application publication date: 20171205