CN107432847A

CN107432847A - Cleaning and the composition and cosmetics of refrigerant skin

Info

Publication number: CN107432847A
Application number: CN201710696745.XA
Authority: CN
Inventors: 崔黎; 陈荣志; 徐印飞; 谢茹玉; 洪国珊
Original assignee: Guangzhou Green Technology Co Ltd
Current assignee: Guangzhou Green Technology Co Ltd
Priority date: 2017-08-14
Filing date: 2017-08-14
Publication date: 2017-12-05
Anticipated expiration: 2037-08-14
Also published as: CN107432847B

Abstract

The invention discloses it is a kind of clean with the composition of refrigerant skin, include the components of following parts by weight：0.1~20 part of mud, 0.5~6 part of thickener, 2~10 parts of self foaming agents, 1~10 part of surfactant and 0.001~10 portion of freshener；Meanwhile the invention also discloses the cosmetics containing above-mentioned composition.Using having continuously from cosmetics made of the composition of effervescent cleansing and cooling effect for the present invention, can clean skin, removing aging cutin cell and absorption environmental toxin, and bring refrigerant comfortable effect, made after use skin smooth, Shui Run, it is pale, rich in gloss；The cosmetics of composition containing the present invention, tight feeling and air impermeability caused by can improving and reducing common mud film, comfortable refrigerant sense is brought, strengthen cleaning force and easy cleaning.

Description

Cleaning and the composition and cosmetics of refrigerant skin

Technical field

The present invention relates to cosmetic technical field, especially a kind of composition and cosmetics cleaned with refrigerant skin.

Background technology

There is it from ancient times with mud nursing body, the people for generation by generation living in Diarrhea lakesides, seashore and volcano side use day Right deposit comes beauty or treatment, to remove skin blemishes or loosen body.Before more than 5000 years, Egyptian will pick up from Buddhist nun sieve The soil (MUDS) of river bank is applied to treatment infection and rheumatism on body.Greek is hardened with clay (CLAY) to fix fracture Place.Famous Hippcrates obtain immense success with mud to alleviate stomach-ache and rheumatism inflammation.Evidence suggests in the Christian religion In early days, a kind of rufous clay, is called Lemnos clay, there is medical value.Abbot's Sebastian Kenai It is general to turn into 19th century famous person because clay is used.He treated Animal diseases with clay always at that time, successfully applied again later In treatment human diseases, and obtain howling success.He so describes the disease to those healings that succeeded：" with one Water, soil and certain plants ... ".Kenai general all one's life is directed to developing these " alternative medicine " for being used to treat human diseases On.Surprisingly：Although contemporary medical science and beauty culture all achieve many new breakthroughs, we have found that natural first with those Element, such as recovered on the contrary using spring, marine alga, the alternative medicine of soil.This is clearly that we re-recognize those greatly certainly The benefit of our medicative element of tool is so assigned, this is also a kind of confirmation and recurrence to nature and ancestors' wisdom.

Although nursing the with a long history of body with mud, cosmetic industry does not have the definition of the systematic science on mud. The classification of mud and title are not such as inorganic matter, humic acid according to constituent, but are distinguished according to the place of production, source, such as dead Ooze, marsh mud and sludge.

Product with mud nursing body is varied, but when they are applied when on skin, can bring tight feeling, sultry, Poor air permeability, cleaning force is weak, not easy cleaning.

The content of the invention

Based on this, provided it is an object of the invention to overcome in place of above-mentioned the deficiencies in the prior art a kind of good permeability, Cleaning capacity is effective, easy cleaned cosmetics, after it is applied to skin so that refrigerant comfortable, smooth, the water profit of skin, it is pale, Rich in gloss.

To achieve the above object, the technical scheme taken of the present invention is：A kind of composition cleaned with refrigerant skin, comprising The component of following parts by weight：0.10~20 part of mud, 0.5~6.0 part of thickener, 2.0~10 parts of self foaming agents, 1.0~10 parts of tables Face activating agent and 0.001~10 portion of freshener.The composition can clean skin, removing aging cutin cell and absorption skin Environmental toxin on skin, and bring refrigerant comfortable effect, made after skin smooth, Shui Run, it is pale, rich in gloss.

Preferably, the composition includes the component of following parts by weight：1.0~15 parts of mud, 1.0~5.0 parts of thickeners, 5.0~7.0 parts of self foaming agents, 2.0~8.0 parts of surfactants and 2.0~5.0 portions of fresheners.

Preferably, the mud be Dead Sea mud (DEAD SEA MUD), marsh mud (MOOR MUD), sludge (FANGO MUD), Peat (PELOID), mud coal (PEAT), salt mine mud (SALT MINE MUD), ooze (MARIS LIMUS), volcanic mud (VOLCANIC SOIL), volcanic sand (VOLCANIC S), volcanic ash (VOLCANIC ASH), clay (CLAY) and mud At least one of (SILT)；The thickener is hydrophilic thickeners, source include acrylate polymer, natural polysaccharide and Its derivative and clay mineral and its modifier, specifically, the thickener be selected from acrylate polymer, natural polysaccharide and its Derivative and at least one of clay mineral and its modifier；The self foaming agent is selected from perfluoro butyl methyl ether, methyl perfluoro In isobutyl ether, ethyl perfluorobutyl ether, perfluor isobutyl ethyl ether, perfluor isohexane, Decafluoropentane and two polysiloxanes It is at least one；The surfactant is selected from anion surfactant, amphoteric surfactant and nonionic surfactant At least one of；The freshener is selected from erythrite, linalool, geraniol, laurine, menthol, menthol and derived At least one of thing and mint extract.

Preferably, the hydrophilic natural polysaccharide gum is selected from xanthans, gum arabic, bassora gum, locust bean gum, fruit Glue, carragheen, gellan gum, mosanom and guar gum at least one of；It is highly preferred that the hydrophilic natural polysaccharide gum is Xanthans.

Preferably, the clay mineral and its modifier in Magnesiumaluminumsilicate, lithium magnesium silicate and sodium magnesium silicate at least It is a kind of；It is highly preferred that the clay mineral and its modifier are selected from Magnesiumaluminumsilicate.

Preferably, the thickener is Magnesiumaluminumsilicate, xanthans and acrylate polymer combination.Through present invention People has found that the mass ratio of Magnesiumaluminumsilicate and xanthans is 4~5 in thickener through test of many times:When 1, using the combination of the present invention Mud film prepared by thing is all good in terms of skin sense, outward appearance and thickening effect；When mass ratio is 4~5:1 Magnesiumaluminumsilicate and xanthans When being compounded with acrylate polymer, thickening and foaming effect are obviously improved.

Self foaming agent uses volatility perfluoro alkane and dimethyl silicone polymer, and the vapour pressure of these organic matters is high, is opening Easily discharged between emptying.The self foaming agent used in the present invention is selected from perfluoro butyl methyl ether, methylperfluoroisobutylether, second Base perfluorobutyl ether, perfluor isobutyl ethyl ether, perfluor isohexane, Decafluoropentane and two polysiloxanes；Preferably, foaming agent is Decafluoropentane and two polysiloxanes.The latent value (ODP) of the ozone-depleting of Decafluoropentane is 0, and the latent value (GWP) of greenhouse effects is 0.25, Boiling point：55 DEG C (lit.), flash-point：>125 DEG C, for the non-ignitable organic matter of environmental protection；The heat of evaporation of two polysiloxanes is low, will not make skin Skin cools rapidly and not felt well.

When mud film prepared by composition is coated on skin, surfactant and foaming agent phase interaction in composition With because foaming agent continues outside, open space evaporation, discharges and drive surfactant to form abundant bubble.

Preferably, the anion surfactant is selected from alkyl sulfate salt, alkyl, polyether sulfate, isethionic acid ester Sodium salt, alkyl sulfosuccinates salt, alkyl, polyether sulfosuccinate ester salt, alkylamidoalkyl sulfosuccinamic acid ester salt, Alkyl phosphate salt, alkyl carboxylate, alkyl, polyether carboxylate, acyl amino hydrochlorate, acyl sarcosinates, acyl taurine salt At least one of；It is highly preferred that considering from mildness, the anion surfactant is acyl amino hydrochlorate, acyl group flesh At least one of propylhomoserin salt and acyl taurine salt.

Preferably, the amphoteric surfactant is selected from carboxylic acid beet alkali ampholytic surface active agent, sulphonic acid betaine both sexes Surfactant, sulfuric ester beet alkali ampholytic surface active agent, Amphoteric Surfactant Alkylami-dophosphobetaines amphoteric surfactant, alkyl Both sexes acetate, alkyl both sexes propionate at least one of.

Preferably, the nonionic surfactant is selected from aliphatic alcohol polyether, alkyl phenol polyether, alkylolamides, poly- second At least one of diol fatty acid ester, polyglycerol ester and alkyl glucoside；It is highly preferred that the nonionic surfactant choosing From polyglycerol ester and alkyl glucoside.

Preferably, the mud is clay or/and mud, and the clay is selected from kaolin (KAOLIN), montmorillonite And at least one of illite (ILLITE) (MONTMORILLONITE)；Preferably, mud is high according to content of organics Low to be divided into organic sludge and inorganic mud, organic sludge can be green mud and black mud from freshwater lake, and inorganic mud can be with It is extra large mud.

Clay is a kind of deposit, and its mineralogical composition comes from atmospheric disintegration of rocks decomposition.They are often by multi mineral Element forms, and a key property of clay is that its Primary particle size is less than 2 microns.It is divided into following four classes by its structure： Kaolinite race, montmorillonite race, illite race and chlorite race.Chemically from the point of view of angle, clay Main Ingredients and Appearance is hydrated aluminium silicate, In layered silicate structure.The property of clay is the structures shape by it.

It can be absorbed by the skin containing all mineral matters needed for skin, some of which element in clay.Silicon is for tissue Rebuild, prevent that the improvement of of flaccid muscles and muscle tone is significant, it is the basis of collage synthesis, and its shortage can cause skin There is disconnected line in skin, tissue follows the string, wrinkle and aging.Sodium is extremely important for regulation cell growth and equilibrium osmotic pressure.Magnesium Be control skin metabolism enzyme necessary to；Meanwhile magnesium also has the effect of anti-inflammatory.Calcium is for bone, nail and skin Metabolism be essential.Potassium assigns tissue elasticity and flexibility；In the cell under appropriate concentration, potassium can help Improve resistivity.Iron influences melanin and formed, and helps blood to transport oxygen.Zinc is used for skin tissue regeneration, helps rubber polymer Former albumen and elastin laminin, improve the toughness and elasticity of skin；Zinc is critically important for maintaining cell normally to increase, and zinc-deficiency can cause Alopecia, dermatitis and healing problems.

As carrier, the effect of clay is more than permeating.It discharges various active components, mineral matter and trace element, Maintain the normal metabolism of skin and natural equilibrium.

Clay has various benefits for body, refreshes oneself, stimulation cycle, releives, help cytothesis, toxin expelling, subtract Fat, anti-inflammatory, mineral matter, exfoliating are provided for skin, skin toner, purification, antibiotic and sterilizing, supply oxygen, compact and mitigate hyperemia etc..

The exfoliating effect of clay can remove the horn cell, toxin and dirt of aging, recover skin normal texture, skin Skin aerobic respiration strengthens, and contributes to cell to breed, and the skin after exfoliating is more easy to absorb the cosmetics then used.

Clay catharsis can remove toxin and purifying skin in skin.Its high absorption capacity helps to absorb skin The excessive grease of skin.When treating acne with clay, it can be found that it has obvious antibacterial effect and convergence effect.Clay can be with Deep layer purifying skin makes it recover natural gloss and health, while skin water loss and drying can be avoided coarse.

Clay has the ability of nourishes rough skin.There are the mineral salt and micro member that our skins need in the chemical composition of clay Element.These compositions can activate metabolic function, enliven bioprocess, improve skin appearance, reinforcing group after being absorbed by the skin Knit and desalinate wrinkle.

Clay also has psychosomatic treatment effect.Clay is used in beauty salon or hydrotherapy shop, personalized services, be quiet Environment or the music releived, sufficiently rest, warm atmosphere, autopsychic reinforcing, etc., collective effect to nurse Reach optimal effect.Now guest can reach a kind of state loosened.This state thus has analgesic effect, mitigates It is tired caused by pressure.The healthy appearance of skin can be very good to illustrate this healthy sensation.

Mud deposits in hydrostatic or slow flowing water environment, being formed through physical chemistry and biological chemistry action, not Weak particulate or the superfine particle soil of consolidation, belong to modern recent deposit thing.The mud content of organic matter is reduced with depth.

The biomass of green mud comes from algae, plant pollen, water plant and planktonic organism, rich in sterols, chlorophyll and Carotenoid.Green mud has very strong anti-oxidant and more new effects, can promote skin regeneration, releive, repairs skin, potent But gentle cleaning and toxin expelling effect, enhance metabolism, accelerate cell turnover speed, special recommendation be used for normal, dryness and Sensitiveness skin.

Under the conditions of oxygen excess, organic matter changes into black mud by depth biochemical degradation.Black mud contains humic acid, fat Fat acid, hormone analogues triterpene, rosin and organic-mineral complex, there is strength but gentle cleaning and detoxification ability, promote Enter metabolism and cytothesis, adjust peripheral nerve and immune system, be particularly suitable for oily skin and problem skin.

The basic structure of extra large mud is chlorite, but increasingly complex on this basis, and this is due to that seawater additionally provides All extra ions, containing 70 kinds of compositions are had more than, the almost rare earth element including that can be found in all oceans.Extra large mud has Multiple body care effect.Extra large mud is a kind of powerful ion-exchanger.When being applied on skin, negatively charged ocean The positively charged impurity of adsorption by clay, skin and can be cleaned and detoxified to skin.Impurity is being removed (in such as grease and pore Dirt) after, extra large mud can also help to reduce pore, make skin smooth as porcelain.Extra large mud also utilizes its penetrating power, Take the moisture of inner deep tissue to top layer and carry out Glycerin.Skin will not be made to dehydrate when cleaning skin.Extra large mud The pH value that can also maintain skin to balance, and possesses powerful buffer capacity, helps to strengthen the barrier action of skin to keep it strong Kang Meili.

Preferably, the freshener is erythrite.There are the receptor for experiencing thermal stimulus, i.e. thermoreceptor on skin, The temperature change of skin and external environment is passed to heat-regulating centers by it, the TRPM8 albumen expressed in sensory neuron, It can be reduced by temperature or menthol, ice element (icilin) and eucalyptol etc. cooling agent activate, it is instantaneous using heat sensitivity The action principle of acceptor, two distinct types of freshener can be used in cosmetics；From the aspect of smell and excitant, Preferably erythrite；Erythrite is four carbon polyol class compounds of white crystals, and chemical name is Erythritol, is Small molecule wetting agent, one kind of natural sugar alcohol, its heat of solution is -97.4J/g, because heat of solution is larger, can be absorbed when being dissolved in water More energy, there is very strong refrigeration；Experiment shows, 10g antierythrites are dissolved in 90g water, and temperature declines about 4.8 DEG C, erythrite is used in cosmetics, and for performance of keeping humidity better than trehalose, glycine betaine, glycerine and sorbierite etc., skin sense is more preferable, can band Carry out salubrious, pure and fresh, refrigerant skin sense.

As another aspect of the present invention, the present invention also provides application of the above-mentioned composition in mud film.Using above-mentioned group Mud film made of compound, after being applied to skin, spontaneously, bubble is continuously generated, abundant closely knit bubble makes mud film become soft It is ventilative, heat is taken away while bubble soft shock massage skin, makes skin refrigerant comfortable, and assigns mud film effectively gentle clear Clean ability, mud film readily washes off after having applied, and it is applied to the ring on clean skin, removing aging cutin cell and absorption skin Border toxin, and bring refrigerant comfortable effect, made after skin smooth, Shui Run, it is pale, rich in gloss.

As another aspect of the present invention, present invention also offers a kind of cosmetics, above-mentioned composition and auxiliary material are included.Its In, auxiliary material refers to can be according to prior art and cosmetic currently used for the customary adjuvant in cosmetics, those skilled in the art Formulation and purposes of product etc. select the auxiliary material of Optimum Contents, as long as selected auxiliary material is not desired for fear of the present composition Function is just；Cosmetic can be《Cosmetic material Names Catalogue is used》In find.

Preferably, the auxiliary material be preservative, it is chelating agent, essence, grease, NMF, emulsifying agent, colouring agent, anti-oxidant At least one of agent, penetration-assisting agent and skin sense conditioning agent.

Preferably, the preservative be selected from formaldehyde releaser, nipagin esters, halogen contained compound, quaternary ammonium salt, organic acid and At least one of alcohol, the NMF be glycerine, propane diols, butanediol, 1,2- pentanediols, 1,2- hexylene glycols, dipropylene glycol, At least one of pyrrolidone sodium carboxylate, 2-pyrrolidone-5-carboxylic acid's potassium, Sodium Hyaluronate, sugar and polyethylene glycol, it is described anti-oxidant Agent is at least one of tocopherol (vitamin E), tocopherol acetate, Butylated Hydroxytoluene and parahydroxyacet-ophenone；It is highly preferred that The preservative is organic acid preservative or alcohols preservative；The penetration-assisting agent be Laurocapram, ethoxydiglycol, Two acid esters of carbon of the acid esters of 20 carbon of Natrulon H-10 two/14/glycerine (Neosolue^TMAt least one of-AquaS)；Preservative, NMF, antioxidant and penetration-assisting agent include but is not limited to the preferable compound.

Preferably, the formulation of the cosmetics is emulsion agent or cream agent；It is highly preferred that the cosmetics are elution type Cosmetic.

In summary, beneficial effects of the present invention are：

(1) present invention's has continuously from effervescent cleansing and the composition of cooling effect, can clean skin, removing aging Horn cell and absorption environmental toxin, and bring refrigerant comfortable effect, and skin smooth, Shui Run, pale, rich is made after use It is glossy；

(2) cosmetics of the composition containing the present invention, tight feeling caused by can improving and reducing common mud film and not Gas permeability, comfortable refrigerant sense is brought, strengthen cleaning force and easy cleaning.

Brief description of the drawings

Fig. 1 is that 1 st volunteer the back of the hand portion is imitated using the foaming of the mud film of embodiment 8 in embodiment 11 (applying test case 2) Fruit is schemed；

Fig. 2 is that 2 st volunteer the back of the hand portions are imitated using the foaming of the mud film of embodiment 8 in embodiment 11 (applying test case 2) Fruit is schemed.

Embodiment

Signified mud can be used for the raw material of the soil sources in cosmetics in the present invention, including Dead Sea mud, marsh mud, Sludge, peat, mud coal, salt mine mud, ooze, volcanic mud, volcanic sand, volcanic ash, clay and mud.In the present invention clay according to Its structure is divided into kaolin, montmorillonite and illite；Mud is divided into organic sludge and inorganic according to content of organics height Mud.Green mud and black mud of the organic sludge such as from freshwater lake, for example extra large mud of inorganic mud.

To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with the drawings and specific embodiments pair The present invention is described further.

The screening of the thickener of embodiment 1

It is as shown in table 1 below on the basic components of thickener screening.

The basic components of the thickener of table 1 screening

It is as shown in table 2 below on the selection result of clay mineral and its modifier as thickener.

The selection result of the clay mineral of table 2 and its modifier as thickener

Thickener	Thickening property	Skin sense	Conclusion
				Magnesiumaluminumsilicate	It is good	It is good	It is good
Lithium magnesium silicate	It is bad	It is bad	It is bad
				Sodium magnesium silicate	It is bad	It is good	It is bad

" good " of thickening property in table 2 refers to the wired sexual intercourse of dosage of dispensing viscosity and thickener, otherwise calls it " no It is good "；" good " of skin sense refers to that formula tends to smear out, on the contrary then call its " bad "；" good " of conclusion refers to thickening property and skin sense all Otherwise it is " bad " for " good ".

Clay mineral and its modifier as the concentration that thickener screens be followed successively by mass fraction 1%, 2%, 3%, 4% and 5%, the results showed that, the thickening property of Magnesiumaluminumsilicate and skin sense are good.

The selection result on Magnesiumaluminumsilicate and the optimal proportion of xanthans is as shown in table 3 below.

The selection result of the optimal proportion of the Magnesiumaluminumsilicate of table 3 and xanthans

Ratio

1:1

2:1

3:1

4:1

5:1

6:1

1:6

1:5

1:4

1:3

1:2

Skin sense

It is bad

It is good

It is bad

Outward appearance

It is bad

It is good

It is bad

Thickening

It is good

Conclusion

It is bad

It is good

It is bad

" good " of skin sense in table 3 refers to that formula tends to smear out, on the contrary then call its " bad "；" good " of outward appearance refers to be formulated It is smooth in appearance, continuous, otherwise it is " bad "；" good " of thickening property refers to the linear pass of dosage of dispensing viscosity and thickener System, otherwise calls its " bad "；" good " of conclusion refers to that skin sense, outward appearance, thickening property are all " good ", is otherwise " bad ".

The Magnesiumaluminumsilicate and the gross mass of xanthans that the screening test of the optimal proportion of Magnesiumaluminumsilicate and xanthans uses point Number is 4%, the results showed that, the optimal proportion 4~5 of Magnesiumaluminumsilicate and xanthans:1.

The selection result on Magnesiumaluminumsilicate and xanthans compounding acrylate polymer is as shown in table 4 below.

The selection result of the Magnesiumaluminumsilicate of table 4 and xanthans compounding acrylate polymer

Thickener	Thickening property	Foaminess	Conclusion
				Compounding	It is good	It is good	It is good
Do not compound	It is bad	It is bad	It is bad

" good " of thickening property in table 4 refers to the wired sexual intercourse of dosage of dispensing viscosity and thickener, otherwise calls it " no It is good "；" good " of foaminess refers to that the foam of formula is intensive with lasting, otherwise calls its " bad "；" good " of conclusion refers to skin sense, outer Sight, thickening property are all " good ", are otherwise " bad ".

Magnesiumaluminumsilicate and the Magnesiumaluminumsilicate mass fraction used in the screening test of xanthans compounding acrylate polymer For 3.2%, the mass fraction of xanthans is 0.8%, and both mass ratios are 4:1, acrylate polymer (actives basis) Mass ratio be respectively 0%, 0.3% and 0.6%, the results showed that, Magnesiumaluminumsilicate and xanthans compounding acrylate polymer Thickening property and foaminess it is good.

Embodiment 2

Cleaning and a kind of embodiment of the composition of refrigerant skin, include following components in parts by weight in the present invention：Mud 0.1 The green mud of part, 0.5 part of acrylate polymer (actives basis), 1 part of Plantacare 818,1 part of perfluoro butyl methyl ether and 1 part of perfluor Butyl ether, 0.001 part of menthol, 0.5 part of triethanolamine, add water to 100 parts.

Above-mentioned composition preparation method is：It is uniformly rear to add Plantacare 818 with water elder generation dispersion acrylic ester polymer, stir Mix heating, 80 DEG C of insulated and stirreds 15 minutes, cool；65 DEG C of addition triethanolamines；40 DEG C add green mud, menthol, perfluor Butyl methyl ether and perfluoro butyl ether, stir as the composition from effervescent cleansing and cooling effect.

Embodiment 3

It is used to clean a kind of embodiment with the composition of refrigerant skin in the present invention, includes following components in parts by weight：

(mass ratio of kaolin and green mud is 10 to 11 parts of mud:1), 6 parts of thickeners { 4.4 parts of Magnesiumaluminumsilicates, 1.1 parts of xanthan Glue and 0.5 part of acrylate polymer (actives basis) }, 2.5 parts of surfactant { 1.0 parts of Plantacare 818s (actives basis) With 1.5 parts of Cocoamidopropyl betaines (actives basis) }, 6 part of two polysiloxanes, 2 parts of erythrites and 0.5 part of triethanolamine, Add water to 100 parts.

The preparation method of above-mentioned composition is：With water elder generation homogenous disperse Magnesiumaluminumsilicate, add xanthans and continue to stir, Kaolin is added after even and reserves the pre-dispersed acrylate polymer of 10 parts of water, agitating and heating, 80~85 DEG C of insulated and stirreds 15 Minute, green mud, Plantacare 818 and Cocoamidopropyl betaine are added, is cooled；65 DEG C of addition triethanolamines；40 DEG C add Enter erythrite and two polysiloxanes, stir as the composition from effervescent cleansing and cooling effect.

Embodiment 4

(wherein black mud and kaolinic mass ratio are 1 to 15 parts of mud:2), 3.9 parts of thickeners { Magnesiumaluminumsilicate, xanthans and third The mass ratio of olefine acid ester polymer (actives basis) is 10:2:1 }, 2 parts of surfactant { 1.0 parts of Plantacare 818 (active matters Meter) and 1 part of Cocoamidopropyl betaine (actives basis), 7.0 part of two polysiloxanes, 5 parts of erythrites and 0.3 part of three ethanol Amine, add water to 100 parts.

The preparation method of above-mentioned composition is：With water elder generation homogenous disperse Magnesiumaluminumsilicate, add xanthans and continue to stir, Kaolin is added after even and reserves the pre-dispersed acrylate polymer of 10 parts of water, agitating and heating, 80~85 DEG C of insulated and stirreds 15 Minute, black mud, Plantacare 818 and Cocoamidopropyl betaine are added, is cooled；65 DEG C of addition triethanolamines；40 DEG C add Enter erythrite and two polysiloxanes, stir as the composition from effervescent cleansing and cooling effect.

Embodiment 5

Cleaning and a kind of embodiment of the composition of refrigerant skin, include following components in parts by weight in the present invention：

(wherein volcanic mud and kaolinic mass ratio are 1 to 20 parts of mud:1), 5 parts of thickeners { 3.6 parts of Magnesiumaluminumsilicate, xanthan 0.5 part of 0.9 part of glue and acrylate polymer (with actives basis) }, 8 parts of surfactant { 2 parts of Plantacare 818s and 6 parts of last of the ten Heavenly stems Amido propyl betaine (with actives basis) }, 5 parts of Decafluoropentanes, 0.1 part of freshener (0.01 part of menthyl lactate and 0.09 part Erythrite) and 0.5 part of triethanolamine, add water to 100 parts.

The preparation method of above-mentioned composition is：With water elder generation homogenous disperse Magnesiumaluminumsilicate, add xanthans and continue to stir, Volcanic mud, kaolin are added after even and reserves the pre-dispersed acrylate polymer of 10 parts of water, agitating and heating, 80~85 DEG C of insulations Stirring 15 minutes, Plantacare 818 and Cocoamidopropyl betaine are added, is cooled；65 DEG C of addition triethanolamines；40℃ Menthyl lactate, erythrite and Decafluoropentane are added, is stirred as the composition from effervescent cleansing and cooling effect.

Embodiment 6

(wherein green mud and kaolinic mass ratio are 1 to 15 parts of mud:2), 4.4 parts of thickeners { Magnesiumaluminumsilicate, xanthans and third The mass ratio of olefine acid ester polymer (actives basis) is 8:2:1 }, 2.5 parts of surfactant { 1 part of Plantacare 818 (active matters Meter) and 1.5 parts of Cocoamidopropyl betaines (actives basis), 10 parts of methylperfluoroisobutylethers, 2 parts of erythrites and 0.4 part Triethanolamine, add water to 100 parts.

The preparation method of above-mentioned composition is：With water elder generation homogenous disperse Magnesiumaluminumsilicate, add xanthans and continue to stir, Kaolin is added after even and reserves the pre-dispersed acrylate polymer of 10 parts of water, agitating and heating, 80~85 DEG C of insulated and stirreds 15 Minute, green mud, Plantacare 818 and Cocoamidopropyl betaine are added, is cooled；65 DEG C of addition triethanolamines；40 DEG C add Enter erythrite and methylperfluoroisobutylether, stir as the composition from effervescent cleansing and cooling effect.

Embodiment 7

1 part of black mud, 1 part of thickener (acrylate polymer), 10 parts of surfactant { Cocoamidopropyl betaines (actives basis) }, 3 parts of methylperfluoroisobutylethers, 10 parts of erythrites and 1 part of triethanolamine add water to 100 parts.

The preparation method of above-mentioned composition is：With water elder generation homogenous disperse acrylate polymer, black mud is added afterwards, and stirring adds Heat, 80~85 DEG C of insulated and stirreds 15 minutes, Cocoamidopropyl betaine is added, is cooled；65 DEG C of addition triethanolamines；40 DEG C erythrite and methylperfluoroisobutylether are added, stirred as the composition from effervescent cleansing and cooling effect.

The moisturizing of embodiment 8 cleaning foaming mud film and its preparation technology

A kind of embodiment of the cosmetics of the present invention, the cosmetics are moisturizing cleaning foaming mud film, and it contains embodiment 3 Described composition.The composition of moisturizing cleaning mud film is as shown in table 5 described in the present embodiment.

The composition of the moisturizing of table 5 cleaning foaming mud film

The preparation technology of the moisturizing cleaning foaming mud film of the present embodiment is as follows：

1) No. 1 raw material being sprinkled into No. 2 raw materials in table 1 in stirring, 1500rpm are stirred 30 minutes, and this is 1. phase；

2) No. 3 raw materials are added, continue stirring 10 minutes, this is 2. phase；

3) No. 5 raw materials are sprinkled into No. 4 raw materials, are disperseed 10 minutes, and this is 3. phase；

4) 2. phase is 3. added to, obtains 4. phase；

5) raw material No. 6~No. 12 is added into 4. phase, agitating and heating, 80~85 DEG C of insulated and stirreds 15 minutes, 2800rpm homogeneous 5 minutes, obtain 5. phase；

6) by raw material No. 13, No. 14 and No. 15 be added to 5. phase, this is 6. phase；

7) cool, No. 16 raw materials are added to 6. phase by 65 DEG C, obtain 7. phase；

8) No. 17~No. 20 raw materials of 40 DEG C of additions, stir, filtering and discharging, obtain 8. phase, as moisturizing cleaning foaming Mud film.

The oil-control of embodiment 9 convergence foaming mud film and its preparation technology

A kind of embodiment of cosmetics of the present invention, cosmetics described in the present embodiment are oil-control convergence foaming mud film, and it contains Composition described in embodiment 4.The composition of oil-control convergence foaming mud film is as shown in table 6 described in the present embodiment.

The oil-control of table 6 convergence foaming mud film

The preparation technology of the oil-control convergence foaming mud film of the present embodiment is as follows：

4) 2. phase is 3. added to, obtains 4. phase；

5) raw material No. 6~No. 12 is added into 4. phase, agitating and heating, 80 DEG C~85 DEG C insulated and stirreds 15 minutes, 2800rpm is equal Matter 5 minutes, obtains 5. phase；

8) No. 17~No. 19 raw materials of 40 DEG C of additions, stir, filtering and discharging, obtain 8. phase, as oil-control convergence foaming Mud film.

Embodiment 10 is releived refrigerant foaming mud film and its preparation technology

A kind of embodiment of cosmetics of the present invention, cosmetics described in the present embodiment are refrigerant foaming mud film of releiving, and it contains Composition described in embodiment 6.Releived described in the present embodiment it is refrigerant foaming mud film composition it is as shown in table 7.

Table 7 releive it is refrigerant foaming mud film composition

1) No. 2 raw materials in table 1 are added to No. 1 raw material in stirring, 1500rpm is stirred 10 minutes, and this is 1. phase；

2) No. 4 raw materials are sprinkled into No. 3 raw materials, are disperseed 10 minutes, and this is 2. phase；

4) 1. phase is 2. added to, obtains 3. phase；

5) raw material No. 5~No. 12 is added into 3. phase, agitating and heating, 80 DEG C~85 DEG C insulated and stirreds 15 minutes, 2800rpm is equal Matter 5 minutes, obtains 4. phase；

6) by raw material No. 13, No. 14 and No. 15 be added to 4. phase, this is 5. phase；

7) cool, No. 16 raw materials are added to 5. phase by 65 DEG C, obtain 6. phase；

8) No. 16~No. 19 raw materials of 40 DEG C of additions, stir, filtering and discharging obtains 7. phase, refrigerant foaming of as releiving Mud film.

The measure of merit of cosmetics in the present invention of embodiment 11

(1) test case 1 is applied

Method：50 skin health female volunteers, age from 20 years old to 50 years old, average age 30 years old, use the present invention The mud film of embodiment 8~10, application after face cleaning, apply 10 minutes and wash away.Then survey is carried out to volunteer, before comparing use Assessment item situation of change afterwards, 0 point is not improved as, is improved as 1

Divide, calculate the arithmetic mean of instantaneous value of each project.Statistical result is as shown in table 8.

The moisturizing of table 8 cleaning foaming mud film application evaluation table

Moisturizing cleaning foaming mud film of the volunteer using the embodiment of the present invention 8 is can be seen that from the statistical result of table 8, respectively The mud film that individual assessment item compares embodiment 9 and 10 is all preferably approved, is scored at 0.79~0.92, shows that application is implemented After the moisturizing of example 8 cleaning foaming mud film, skin moisturizing, it is smooth it is pale have it is glossy, soft flexible.

(2) test case 2 is applied

Method：The moisturizing cleaning foaming mud film of the embodiment of the present invention 8 is smeared in single the back of the hand of two female volunteers, respectively Taken pictures in t=0 minutes, when t=5 minutes and t=8 minutes, record mud film foaming situation.As a result as depicted in figs. 1 and 2.

The moisturizing cleaning foaming mud film of the embodiment of the present invention 8 is can be seen that from Fig. 1 and Fig. 2 can continue to produce bubble, shape Into fine and close abundant foam.

(3) test case 3 is applied

35 self-assessments are the healthy volunteer of Oily, and male volunteers 30, women 5, the age was from 20 years old By 35 years old, successively using the combination of the oil-control convergence foaming mud film of the embodiment of the present invention 9, embodiment 1, embodiment 5 and embodiment 7 Mud film (preparation technology of preparation method reference implementation example 9) and the mud film of embodiment 8 and the mud film of embodiment 10 prepared by thing, Application after face cleaning, apply 10 minutes and wash away.Then survey is carried out to volunteer, compares assessment item change feelings before and after use Condition, 0 point is not improved as, is improved as 1 point, calculate the arithmetic mean of instantaneous value of each project.Statistical result is as shown in table 9.

The oil-control of table 9 convergence foaming mud film application evaluation table

Oil-control convergence foaming mud film of the volunteer using the embodiment of the present invention 9, table are can be seen that from the statistical result of table 9 After surface oil-control restrains foaming mud film, skin is glossy to reduce (score 0.95), pore receipts thin (score 0.80), skin cleanliness factor 4 projects such as (score 0.85) and skin elasticity (score 0.80) obtain higher rating with respect to other mud films organized.

(4) test case 4 is applied

20 healthy volunteers, male volunteers 8, women 12, age from 20 years old to 40 years old, successively use the present invention It is prepared by releive refrigerant foaming mud film, the mud film of embodiment 9, the mud film of embodiment 8, the composition of embodiment 2 of embodiment 10 Mud film (preparation technology of preparation method reference implementation example 10) prepared by mud film and the composition of embodiment 7, application after face cleaning, is applied Wash away within 10 minutes, survey then carried out to volunteer, compares assessment item situation of change before and after use, is not recognized as 0 point, 1 point is recognized as, calculates the arithmetic mean of instantaneous value of each project.Statistical result is as shown in table 10.

Table 10 releive it is refrigerant foaming mud film application evaluation table

Releive refrigerant foaming mud film of the volunteer using the embodiment of the present invention 10 is can be seen that from the statistical result of table 10 Afterwards, volunteer has refrigerant sense (score 1.0), and refrigerant sense persistence, skin improve and application comfortableness is also relatively other The mud film of group has higher evaluation, and score is followed successively by 0.80,0.85 and 0.80.

Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, one of ordinary skill in the art should Understand, technical scheme can be modified or equivalent substitution, without departing from the essence of technical solution of the present invention And scope.

Claims

1. a kind of composition cleaned with refrigerant skin, it is characterised in that include the component of following parts by weight：0.1~20 part of mud, 0.5~6 part of thickener, 2~10 parts of self foaming agents, 1~10 part of surfactant and 0.001~10 portion of freshener.

2. composition as claimed in claim 1, it is characterised in that include the component of following parts by weight：1~15 part of mud, 1~5 Part thickener, 5~7 parts of self foaming agents, 2~8 parts of surfactants and 2~5 portions of fresheners.

3. composition as claimed in claim 1 or 2, it is characterised in that the mud be Dead Sea mud, marsh mud, sludge, peat, Mud coal, salt mine mud, ooze, volcanic mud, volcanic sand, volcanic ash, clay and mud at least one of；The thickener is selected from Acrylate polymer, natural polysaccharide and its derivative and at least one of clay mineral and its modifier；It is described to foam certainly Agent is selected from perfluoro butyl methyl ether, methylperfluoroisobutylether, ethyl perfluorobutyl ether, perfluor isobutyl ethyl ether, perfluor dissident At least one of alkane, Decafluoropentane and two polysiloxanes；The surfactant is selected from anion surfactant, both sexes table At least one of face activating agent and nonionic surfactant；The freshener is selected from erythrite, linalool, geraniol, hydroxyl At least one of base citronellal, menthol, menthol derivative and mint extract.

4. composition as claimed in claim 3, it is characterised in that the mud is clay or/and mud, and the clay is selected from height At least one of ridge soil, montmorillonite and illite.

5. composition as claimed in claim 3, it is characterised in that the thickener is Magnesiumaluminumsilicate, xanthans and acrylic acid Ester polymer composition, the mass ratio of the Magnesiumaluminumsilicate and xanthans is 4~5:1.

6. composition as claimed in claim 2, it is characterised in that the freshener is erythrite.

7. application of the composition in mud film as described in any one of claim 1~6.

8. a kind of cosmetics, it is characterised in that include the composition and auxiliary material as described in any one of claim 1~6.

9. cosmetics as claimed in claim 8, it is characterised in that the auxiliary material is preservative, chelating agent, essence, grease, guarantor At least one of humectant, emulsifying agent, colouring agent, antioxidant, penetration-assisting agent and skin sense conditioning agent.

10. cosmetics as claimed in claim 9, it is characterised in that the preservative be selected from formaldehyde releaser, nipagin esters, At least one of halogen contained compound, quaternary ammonium salt, organic acid and alcohol, the NMF be glycerine, propane diols, butanediol, 1, 2- pentanediols, 1,2- hexylene glycols, dipropylene glycol, pyrrolidone sodium carboxylate, 2-pyrrolidone-5-carboxylic acid's potassium, Sodium Hyaluronate, sugar and poly- At least one of ethylene glycol, the antioxidant are in tocopherol, tocopherol acetate, Butylated Hydroxytoluene and parahydroxyacet-ophenone At least one.