CN107417474A - Urban soil dust controlling method - Google Patents
Urban soil dust controlling method Download PDFInfo
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- CN107417474A CN107417474A CN201710852670.XA CN201710852670A CN107417474A CN 107417474 A CN107417474 A CN 107417474A CN 201710852670 A CN201710852670 A CN 201710852670A CN 107417474 A CN107417474 A CN 107417474A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G22/00—Cultivation of specific crops or plants not otherwise provided for
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G24/00—Growth substrates; Culture media; Apparatus or methods therefor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
Abstract
The present invention provides a kind of urban soil dust controlling method, belongs to greening and environmental protection field of engineering technology.A kind of urban soil dust controlling method, comprises the following steps:(1) by stalk of 10 20 parts by weight after solid state fermentation, the starch grafted acrylate of 25 parts by weight, 14 parts by weight plant growth regulator, the ammonium dihydrogen phosphate of 58 parts by weight, the vegetable seeds of 20 30 parts by weight are mixed to prepare mixture;(2) obtained airborne dust liquid is diluted with water into mixture;(3) airborne dust liquid is sprayed to urban soil surface.This method uses the design of science, and extensive construction can be achieved, and can reach the effect of control urban soil airborne dust well, quick, cost is low, green.
Description
Technical field
The invention belongs to greening and environmental protection field of engineering technology, specifically, is related to a kind of urban soil dust controlling method.
Background technology
Particulate Pollution is wider to the coverage of China's urban air-quality, be most urban air pollutions it is primary because
Element, Particulate Pollution jeopardize environmental and human health impacts, it has also become the world pollutes problem, and airborne dust is to cause city Particulate Pollution
Principal element.As China's industrialization degree is deepened, dust pollution problem is serious all the more, and airborne dust problem not only causes largely to provide
Source is lost, and pollutes surrounding enviroment, influences people normally production and life.
City raised dust can be by the method for watering and lowering dust, and still, watering and lowering dust index is not effected a permanent cure, and frequently watering also can shadow
Ring traffic, also have by cover the less green net in aperture so as to reach suppress airborne dust purpose, it is done so that not only not environmentally but also
Waste of resource, cost is higher uneconomical, and the effect for suppressing airborne dust is general.
The content of the invention
For deficiency above-mentioned in the prior art, the present invention provides a kind of urban soil dust controlling method, and this method is adopted
With the design of science, extensive construction can be achieved, the effect of control urban soil airborne dust well can be reached, it is quick, into
This is low, green.
In order to achieve the above object, the solution that uses of the present invention is:
A kind of urban soil dust controlling method, comprises the following steps:(1) by 10-20 parts by weight after solid state fermentation
Stalk, the starch grafted acrylate of 2-5 parts by weight, the plant growth regulator of 1-4 parts by weight, the di(2-ethylhexyl)phosphate of 5-8 parts by weight
Hydrogen ammonium, the vegetable seeds of 20-30 parts by weight are mixed to prepare mixture;(2) obtained airborne dust liquid is diluted with water into mixture;(3)
Airborne dust liquid is sprayed to urban soil surface.
The beneficial effect of urban soil dust controlling method provided by the invention is by the stalk after solid state fermentation, to form sediment
After powder grafted propylene hydrochlorate, plant growth regulator, ammonium dihydrogen phosphate, vegetable seeds mixing plus airborne dust liquid is made in water, by airborne dust
Liquid is sprayed at the surface of urban soil, can realize that large area is sprayed, improve operability, realizes extensive construction;By solid-state
Raw material of the stalk as airborne dust liquid after fermentation, can not only twice laid, reach the effect of environmental protection, while after solid state fermentation
Stalk contains the nutrients such as abundant nitrogen, phosphorus, potassium, also containing various trace elements, nutrient can not only be provided for vegetable seeds, simultaneously
The property of soil can also be improved, improve its permeability;Starch grafted acrylate is that a kind of soaking effect absorbs water tree well
Fat, can be used as water-loss reducer, provide moisture for vegetable seeds, while starch grafted acrylate is readily biodegradable;Plant
Thing growth regulator can effectively adjust the growing process of plant;
By the stalk after solid state fermentation, starch grafted acrylate, plant growth regulator, ammonium dihydrogen phosphate, plant
Seed mixes by a certain percentage, is diluted with water obtained airborne dust liquid, and above-mentioned each raw material components play a part of coordinated simultaneously, system
Airborne dust liquid its nutrition general equilibrium, its proportioning pass through scientific design, obtained according to prepared by the raw material of proportioning preparation
Airborne dust liquid, it is possible to increase crop rooting rate.Stalk wherein after solid state fermentation can administer airborne dust, plant seed germination growth
Airborne dust can also be administered well afterwards, this method uses the design of science, and extensive construction can be achieved, can reach good control
The effect of urban soil airborne dust processed, quick, cost is low, green.
Embodiment
, below will be in the embodiment of the present invention to make the purpose, technical scheme and advantage of the embodiment of the present invention clearer
Technical scheme be clearly and completely described.Unreceipted actual conditions person, builds according to normal condition or manufacturer in embodiment
The condition of view is carried out.Agents useful for same or the unreceipted production firm person of instrument, it is the conventional production that can be obtained by commercially available purchase
Product.
Urban soil dust controlling method provided in an embodiment of the present invention is specifically described below.
A kind of urban soil dust controlling method, comprises the following steps:
(1) by stalk of the 10-20 parts by weight after solid state fermentation, the starch grafted acrylate of 2-5 parts by weight, 1-4 weights
The amount plant growth regulator of part, the ammonium dihydrogen phosphate of 5-8 parts by weight, the vegetable seeds of 20-30 parts by weight are mixed to prepare mixing
Thing;(2) obtained airborne dust liquid is diluted with water into the mixture;(3) airborne dust liquid is sprayed to urban soil surface.
Wherein, the stalk after solid state fermentation is a kind of organic material, content of organic matter very abundant, not only rich in nitrogen,
The a great number of elements such as phosphorus, potassium, micro- and various trace element in calcic, magnesium, sulphur, iron, manganese, zinc, copper, boron, molybdenum, chlorine etc. is gone back,
Stalk after solid state fermentation can decompose the mineral phosphorus in soil, and and can decomposes the mineral K in soil, discharges phosphorus, potassium etc.
Multiple nutritional components, can be persistently provide endlessly nutrient to vegetable seeds.Stalk wide material sources, cost is low, makes
By the use of stalk as raw material can twice laid, reach environmental protection effect.
Specifically, the stalk after solid state fermentation can be prepared according to following steps:(1) stalk is crushed into length is
0.5cm, in order to preferably fermentation;(2) by dry bacterium powder and water in mass ratio 1:100 are mixed to form zymotic fluid;(3) by powder
The stalk after 12 days obtained solid state fermentations of solid state fermentation, the straw after crushing are carried out after stalk, zymotic fluid, corn flour mixing after broken
The mass ratio of stalk, zymotic fluid and corn flour is 1:0.05:0.1.
Starch grafted acrylate has good water imbibition and water-retaining property, can use, can effectively press down as water-loss reducer
Moisture evaporation processed, reduce the infiltration and loss of moisture, reach the purpose of water conservation, can be that vegetable seeds carries in growth course
Supply water and divide, stimulate crop root growth and development.Starch grafted acrylate also has the purpose of degraded simultaneously, is a kind of biology
Degradable material, it is a kind of environment-friendly material.
Specifically, starch grafted acrylate is prepared according to the following steps:(1) by the starch of 5-10 parts by weight, 80-100 weights
1-1.5h is reacted in 80 DEG C of environment after the water mixing of amount part and obtains gelatinized starch, preferable starch is selected from cornstarch, cassava
At least one of starch, potato starch, wheaten starch;(2) in gelatinized starch add 20-25 parts by weight acrylates,
The initiator of 0.05-0.1 parts by weight, 0.01-0.05 parts by weight N, N '-methylene-bisacrylamide are 5-6 in pH, temperature 30
DEG C environment in react 2-3h starch grafted acrylate first product be made, it is preferred that initiator is selected from ammonium persulfate, potassium peroxydisulfate
At least one of, acrylates can be PAA, or potassium acrylate, can also be other acrylates;(3) will
Starch grafted acrylate first product dries 1-2h under 65-75 DEG C of temperature conditionss and starch grafted acrylate is made.Wherein, N,
N '-methylene-bisacrylamide uses as crosslinking agent, in order to prevents starch grafted acrylate when absorbing water
Dissolving, makes to crosslink between strand, forms cross-linking compounds.The starch grafted acrylate prepared as stated above is inhaled
Water and Water-saving effect are good.
Plant growth regulator selection is not particularly limited, in the present embodiment, preferably, plant growth regulator
Including at least one of heteroauxin, indolebutyric acid and methyl α-naphthyl acetate.Wherein, heteroauxin, indolebutyric acid and methyl α-naphthyl acetate are respectively provided with
Promote the effect of plant establishment.Wherein, heteroauxin can stimulate cambial cell to divide;Stimulate the cell elongation of branch;Promote tough
Skin zone, Xylem Cell Differentiation, improve the effect of stress resistance of plant.
Ammonium dihydrogen phosphate is a kind of composite fertilizer, and plant nitrogen, phosphorus in growth course are essential, and ammonium dihydrogen phosphate exists
Nitrogen, phosphorus are provided for plant in growing process, the growth of plant can be effectively promoted.
Vegetable seeds is selected from least one of pale reddish brown lucerne place seed, tawny daylily seed, book band grass seed, kiss-me seed, its
In, pale reddish brown lucerne place, tawny daylily, rochebrun, kiss-me are herbaceous plant, compared to other shrub plants, magaphanerophytes etc., draft
Plant is more suitable for planting in city, can not only play a part of preventing airborne dust, and plant is smaller, is advantageous to enter in various occasions
Row plantation, cultivated area is big, and with beautifying the environment and ornamental value.
Preferably, in step (2), the mass ratio of mixture and water is 1:100-120, in the ratio range, water is with mixing
Compound preferably combines, and makes the airborne dust liquid that sprays out more uniform, adds water to be sprayed, make sprinkling more convenient, avoid
Individually watering, it is time saving and energy saving, save human cost.
The feature and performance of the present invention are described in further detail with reference to embodiments.
Embodiment 1
A kind of urban soil dust controlling method, comprises the following steps:
(1) by stalk of 10 parts by weight after solid state fermentation, the starch grafted acrylate of 2 parts by weight, 1 parts by weight Yin
Diindyl butyric acid, the ammonium dihydrogen phosphate of 5 parts by weight, the pale reddish brown lucerne place seed of 20 parts by weight are mixed to prepare mixture;
(2) it is 1 according to the mass ratio of mixture and water to said mixture:100 are diluted with water to obtain airborne dust liquid;
(3) airborne dust liquid is sprayed to urban soil surface;
Wherein, starch grafted acrylate is prepared according to the following steps:(1) by the cornstarch of 5 parts by weight, 80 parts by weight
1h is reacted in 80 DEG C of environment obtain gelatinized starch after water mixing;(2) added in gelatinized starch 20 parts by weight PAA,
The ammonium persulfate of 0.05 parts by weight, 0.01 parts by weight N, N '-methylene-bisacrylamide are 5 in pH, and temperature is 30 DEG C of environment
Starch grafted acrylate first product is made in middle reaction 2h, and (3) are by starch grafted acrylate first product under 65 DEG C of temperature conditionss
Dry 1h and starch grafted acrylate is made.
Embodiment 2
A kind of urban soil dust controlling method, comprises the following steps:
(1) by stalk of 20 parts by weight after solid state fermentation, the starch grafted acrylate of 5 parts by weight, 4 parts by weight Yin
Indolylbutyric acid, the ammonium dihydrogen phosphate of 8 parts by weight, the tawny daylily seed of 30 parts by weight are mixed to prepare mixture;
(2) it is 1 according to the mass ratio of mixture and water to said mixture:120 are diluted with water to obtain airborne dust liquid;
(3) airborne dust liquid is sprayed to urban soil surface;
Wherein, starch grafted acrylate is prepared according to the following steps:(1) by the wheaten starch of 10 parts by weight, 100 parts by weight
Water mixing after in 80 DEG C of environment react 1.5h obtain gelatinized starch;(2) propylene of 25 parts by weight is added in gelatinized starch
Sour potassium, the potassium peroxydisulfate of 0.1 parts by weight, 0.05 parts by weight N, N '-methylene-bisacrylamide are 6 in pH, and temperature is 30 DEG C
3h is reacted in environment and is made starch grafted acrylate first product, (3) are by temperature strip of the starch grafted acrylate first product at 75 DEG C
2h is dried under part starch grafted acrylate is made.
Embodiment 3
A kind of urban soil dust controlling method, comprises the following steps:
(1) by stalk of 15 parts by weight after solid state fermentation, the starch grafted acrylate of 3 parts by weight, 3 parts by weight naphthalene
Acetic acid, the ammonium dihydrogen phosphate of 6 parts by weight, the book band grass seed of 25 parts by weight are mixed to prepare mixture;
(2) it is 1 according to the mass ratio of mixture and water to said mixture:110 are diluted with water to obtain airborne dust liquid;
(3) airborne dust liquid is sprayed to urban soil surface;
Wherein, starch grafted acrylate is prepared according to the following steps:(1) by the potato starch of 8 parts by weight, 90 parts by weight
1.2h is reacted in 80 DEG C of environment obtain gelatinized starch after water mixing;(2) acrylic acid of 20 parts by weight is added in gelatinized starch
Sodium, the ammonium persulfate of 0.02 parts by weight, the potassium peroxydisulfate of 0.01 parts by weight, 0.02 parts by weight N, N '-methylene-bisacrylamide
It is 5.5 in pH, temperature is to react 2.5h in 30 DEG C of environment to be made starch grafted acrylate first product, and (3) are by starch-grafted third
Olefin(e) acid salt first product dries 1.5h under 70 DEG C of temperature conditionss and starch grafted acrylate is made.
Embodiment 4
A kind of urban soil dust controlling method, comprises the following steps:
(1) by stalk of 18 parts by weight after solid state fermentation, the starch grafted acrylate of 4 parts by weight, 2 parts by weight Yin
Diindyl butyric acid, the methyl α-naphthyl acetate of 1 parts by weight, the ammonium dihydrogen phosphate of 7 parts by weight, the book band grass seed of 20 parts by weight, the tiger of 10 parts by weight
Auricled Hedyotis Herb seed is mixed to prepare mixture;
(2) it is 1 according to the mass ratio of mixture and water to said mixture:100 are diluted with water to obtain airborne dust liquid;
(3) airborne dust liquid is sprayed to urban soil surface;
Wherein, starch grafted acrylate is prepared according to the following steps:(1) by the cornstarch of 2 parts by weight, 3 parts by weight
Tapioca, the water of 80 parts by weight react 1h in 80 DEG C of environment after mixing and obtain gelatinized starch;(2) added in gelatinized starch
The ammonium persulfate of the PAA of 20 parts by weight, 0.05 parts by weight, 0.01 parts by weight N, N '-methylene-bisacrylamide are in pH
5, temperature is to react 2h in 30 DEG C of environment to be made starch grafted acrylate first product, and (3) are by starch grafted acrylate first product
1h is dried under 65 DEG C of temperature conditionss starch grafted acrylate is made.
Comparative example 1
A kind of urban soil dust controlling method, comprises the following steps:
(1) by stalk of 5 parts by weight after solid state fermentation, the starch grafted acrylates of 1 parts by weight, 0.8 parts by weight
Indolebutyric acid, the ammonium dihydrogen phosphate of 4 parts by weight, the pale reddish brown lucerne place seed of 15 parts by weight are mixed to prepare mixture;
(2) it is 1 according to the mass ratio of mixture and water to said mixture:80 are diluted with water to obtain airborne dust liquid;
(3) airborne dust liquid is sprayed to urban soil surface;
Wherein, starch grafted acrylate is prepared according to the following steps:(1) by the cornstarch of 5 parts by weight, 80 parts by weight
1h is reacted in 80 DEG C of environment obtain gelatinized starch after water mixing;(2) added in gelatinized starch 20 parts by weight PAA,
The ammonium persulfate of 0.05 parts by weight, 0.01 parts by weight N, N '-methylene-bisacrylamide are 5 in pH, and temperature is 30 DEG C of environment
Starch grafted acrylate first product is made in middle reaction 2h, and (3) are by starch grafted acrylate first product under 65 DEG C of temperature conditionss
Dry 1h and starch grafted acrylate is made.
Comparative example 2
A kind of urban soil dust controlling method, comprises the following steps:
(1) by stalk of 25 parts by weight after solid state fermentation, the starch grafted acrylate of 8 parts by weight, 6 parts by weight Yin
Diindyl butyric acid, the ammonium dihydrogen phosphate of 10 parts by weight, the pale reddish brown lucerne place seed of 35 parts by weight are mixed to prepare mixture;
(2) it is 1 according to the mass ratio of mixture and water to said mixture:150 are diluted with water to obtain airborne dust liquid;
(3) airborne dust liquid is sprayed to urban soil surface;
Wherein, starch grafted acrylate is prepared according to the following steps:(1) by the cornstarch of 5 parts by weight, 80 parts by weight
1h is reacted in 80 DEG C of environment obtain gelatinized starch after water mixing;(2) added in gelatinized starch 20 parts by weight PAA,
The ammonium persulfate of 0.05 parts by weight, 0.01 parts by weight N, N '-methylene-bisacrylamide are 5 in pH, and temperature is 30 DEG C of environment
Starch grafted acrylate first product is made in middle reaction 2h, and (3) are by starch grafted acrylate first product under 65 DEG C of temperature conditionss
Dry 1h and starch grafted acrylate is made.
Comparative example 3
A kind of urban soil dust controlling method, comprises the following steps:
(1) by the starch grafted acrylate of 2 parts by weight, the indolebutyric acid of 1 parts by weight, 5 parts by weight ammonium dihydrogen phosphate,
The pale reddish brown lucerne place seed of 20 parts by weight is mixed to prepare mixture;
(2) it is 1 according to the mass ratio of mixture and water to said mixture:100 are diluted with water to obtain airborne dust liquid;
(3) airborne dust liquid is sprayed to urban soil surface;
Wherein, starch grafted acrylate is prepared according to the following steps:(1) by the cornstarch of 5 parts by weight, 80 parts by weight
1h is reacted in 80 DEG C of environment obtain gelatinized starch after water mixing;(2) added in gelatinized starch 20 parts by weight PAA,
The ammonium persulfate of 0.05 parts by weight, 0.01 parts by weight N, N '-methylene-bisacrylamide are 5 in pH, and temperature is 30 DEG C of environment
Starch grafted acrylate first product is made in middle reaction 2h, and (3) are by starch grafted acrylate first product under 65 DEG C of temperature conditionss
Dry 1h and starch grafted acrylate is made.
By embodiment 1-4, comparative example 1-3 urban soil dust controlling method is sprayed to urban soil of the same area etc.
Airborne dust liquid (is ejected into urban soil surface, the distance of muzzle and soil is 2m, spray by the airborne dust liquid of amount using rotor spraying machine
Injection pressure is 0.13MPa, injection flow 1.5L/min), the germination percentage of seed was observed after 5 days, kind is observed after 15 days
The survival rate of son, as a result as shown in table 1.
Table 1
From the data in table 1, it can be seen that the percentage of seedgermination and survival rate of the urban soil dust controlling method using embodiment 1-4
Significantly larger than comparative example 1-3 percentage of seedgermination and survival rate.Compared to embodiment 1-4, airborne dust in comparative example 1 and comparative example 2
The proportioning of each raw material of liquid has lacked the stalk after solid state fermentation not in scope provided in an embodiment of the present invention in comparative example 3, should
As a result show, the urban soil dust controlling method that the application is protected, as a result of scientific and reasonable formula, enable to plant
Species has higher germination percentage and survival rate, can large area growth, and it is environmentally friendly, cost is low, easy to use.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (7)
- A kind of 1. urban soil dust controlling method, it is characterised in that:Comprise the following steps:(1) by 10-20 parts by weight through solid-state Stalk, the starch grafted acrylate of 2-5 parts by weight, the plant growth regulator of 1-4 parts by weight after fermentation, 5-8 parts by weight Ammonium dihydrogen phosphate, the vegetable seeds of 20-30 parts by weight be mixed to prepare mixture;(2) system is diluted with water into the mixture Obtain airborne dust liquid;(3) airborne dust liquid is sprayed to urban soil surface.
- 2. urban soil dust controlling method according to claim 1, it is characterised in that:The plant growth regulator bag Include at least one of heteroauxin, indolebutyric acid and methyl α-naphthyl acetate.
- 3. urban soil dust controlling method according to claim 1, it is characterised in that:The starch grafted acrylate Prepare according to the following steps:(1) reacted after the water of the starch of 5-10 parts by weight, 80-100 parts by weight is mixed in 80 DEG C of environment 1-1.5h obtains gelatinized starch;(2) acrylates, the 0.05-0.1 parts by weight of 20-25 parts by weight are added in the gelatinized starch Initiator, 0.01-0.05 parts by weight N, N ,-methylene-bisacrylamide is 5-6 in pH, and temperature is to be reacted in 30 DEG C of environment Starch grafted acrylate first product is made in 2-3h;(3) by temperature conditionss of the starch grafted acrylate first product at 65-75 DEG C The starch grafted acrylate is made in lower dry 1-2h.
- 4. urban soil dust controlling method according to claim 3, it is characterised in that:The initiator is selected from persulfuric acid At least one of ammonium, potassium peroxydisulfate.
- 5. urban soil dust controlling method according to claim 3, it is characterised in that:The starch forms sediment selected from corn At least one of powder, tapioca, potato starch, wheaten starch.
- 6. urban soil dust controlling method according to claim 1, it is characterised in that:In step (2), mixture and water Mass ratio be 1:100-120.
- 7. urban soil dust controlling method according to claim 1, it is characterised in that:The vegetable seeds is selected from pale reddish brown At least one of lucerne place seed, tawny daylily seed, book band grass seed, kiss-me seed.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113951031A (en) * | 2021-12-14 | 2022-01-21 | 河南工业大学 | Method for inhibiting dust generated on loose ground surface |
CN115088511A (en) * | 2022-07-05 | 2022-09-23 | 中通服咨询设计研究院有限公司 | City flower box with intelligent induction air purification device |
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WO1996001881A1 (en) * | 1994-07-11 | 1996-01-25 | Du Pont-Mitsui Fluorochemicals Co., Ltd. | Method of controlling dust |
CN1752179A (en) * | 2005-09-30 | 2006-03-29 | 武汉理工大学 | High water absorption environment protection ecologic sand control material and preparing process thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113951031A (en) * | 2021-12-14 | 2022-01-21 | 河南工业大学 | Method for inhibiting dust generated on loose ground surface |
CN115088511A (en) * | 2022-07-05 | 2022-09-23 | 中通服咨询设计研究院有限公司 | City flower box with intelligent induction air purification device |
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Application publication date: 20171201 |