CN107413300A - 一种可降低花生油黄曲霉素含量的脱色剂 - Google Patents
一种可降低花生油黄曲霉素含量的脱色剂 Download PDFInfo
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- CN107413300A CN107413300A CN201710229477.0A CN201710229477A CN107413300A CN 107413300 A CN107413300 A CN 107413300A CN 201710229477 A CN201710229477 A CN 201710229477A CN 107413300 A CN107413300 A CN 107413300A
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- decolorising agent
- aflatoxins
- oil
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 37
- 229930195730 Aflatoxin Natural products 0.000 title claims abstract description 28
- 239000005409 aflatoxin Substances 0.000 title claims abstract description 28
- 235000019483 Peanut oil Nutrition 0.000 title claims abstract description 11
- 239000000312 peanut oil Substances 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 238000002525 ultrasonication Methods 0.000 claims abstract description 7
- 238000010306 acid treatment Methods 0.000 claims abstract description 6
- 238000005469 granulation Methods 0.000 claims abstract description 5
- 230000003179 granulation Effects 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 229910021536 Zeolite Inorganic materials 0.000 claims description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 239000010457 zeolite Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- 230000010355 oscillation Effects 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 238000005245 sintering Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 229910021532 Calcite Inorganic materials 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 239000004113 Sepiolite Substances 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 238000010298 pulverizing process Methods 0.000 claims description 4
- 229910052624 sepiolite Inorganic materials 0.000 claims description 4
- 235000019355 sepiolite Nutrition 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 239000004005 microsphere Substances 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- 239000003921 oil Substances 0.000 description 27
- 235000019198 oils Nutrition 0.000 description 27
- 239000000047 product Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 238000004042 decolorization Methods 0.000 description 6
- XWIYFDMXXLINPU-UHFFFAOYSA-N Aflatoxin G Chemical compound O=C1OCCC2=C1C(=O)OC1=C2C(OC)=CC2=C1C1C=COC1O2 XWIYFDMXXLINPU-UHFFFAOYSA-N 0.000 description 5
- 241000700605 Viruses Species 0.000 description 4
- 230000008030 elimination Effects 0.000 description 4
- 238000003379 elimination reaction Methods 0.000 description 4
- 238000002835 absorbance Methods 0.000 description 3
- 239000008157 edible vegetable oil Substances 0.000 description 3
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- 238000005516 engineering process Methods 0.000 description 3
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- 238000012545 processing Methods 0.000 description 3
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- 239000003463 adsorbent Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
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- 230000007547 defect Effects 0.000 description 2
- 230000035614 depigmentation Effects 0.000 description 2
- 238000001784 detoxification Methods 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 241000228197 Aspergillus flavus Species 0.000 description 1
- 241000228230 Aspergillus parasiticus Species 0.000 description 1
- 238000002965 ELISA Methods 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 206010067125 Liver injury Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 231100000570 acute poisoning Toxicity 0.000 description 1
- 239000002115 aflatoxin B1 Substances 0.000 description 1
- OQIQSTLJSLGHID-WNWIJWBNSA-N aflatoxin B1 Chemical compound C=1([C@@H]2C=CO[C@@H]2OC=1C=C(C1=2)OC)C=2OC(=O)C2=C1CCC2=O OQIQSTLJSLGHID-WNWIJWBNSA-N 0.000 description 1
- 229930020125 aflatoxin-B1 Natural products 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 231100000739 chronic poisoning Toxicity 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000003394 haemopoietic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910001411 inorganic cation Inorganic materials 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
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- 239000011806 microball Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
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- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 210000004126 nerve fiber Anatomy 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
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- 239000002994 raw material Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229930000044 secondary metabolite Natural products 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3408—Regenerating or reactivating of aluminosilicate molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/10—Refining fats or fatty oils by adsorption
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Microbiology (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Fats And Perfumes (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Description
组别 | 活性白土 | 活性炭 | 沸石 | 实施例1 |
黄曲霉素浓度μg/L | 100 | 100 | 100 | 100 |
脱色率% | 95.3 | 92.9 | 91.7 | 99.1 |
脱毒率% | 64.5 | 77.1 | 79.6 | 97.4 |
组别 | 活性白土 | 活性炭 | 沸石 | 实施例1 |
黄曲霉素浓度μg/L | 200 | 200 | 200 | 200 |
脱色率% | 94.7 | 91.6 | 91.2 | 98.8 |
脱毒率% | 60.9 | 72.8 | 75.4 | 95.3 |
Claims (6)
Priority Applications (1)
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CN201710229477.0A CN107413300B (zh) | 2017-04-10 | 2017-04-10 | 一种可降低花生油黄曲霉素含量的脱色剂 |
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CN201710229477.0A CN107413300B (zh) | 2017-04-10 | 2017-04-10 | 一种可降低花生油黄曲霉素含量的脱色剂 |
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CN107413300A true CN107413300A (zh) | 2017-12-01 |
CN107413300B CN107413300B (zh) | 2019-12-03 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109022127A (zh) * | 2018-07-26 | 2018-12-18 | 望江县振兴植物油厂(普通合伙) | 一种美容养颜芝麻油的制备方法 |
CN112694946A (zh) * | 2021-01-19 | 2021-04-23 | 南昌大学 | 一种去除油脂中黄曲霉素的方法 |
CN114405459A (zh) * | 2022-03-01 | 2022-04-29 | 河南工业大学 | 一种用于脱除植物油中黄曲霉毒素的助滤剂及制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US20020107367A1 (en) * | 2000-12-08 | 2002-08-08 | Victor Chiou | Process for isolation and purification of yolk antibodies from avian egg yolk and uses of yolk antibodies obtained thereby |
CN103521181A (zh) * | 2013-10-10 | 2014-01-22 | 浙江丰虹新材料股份有限公司 | 一种复合型霉菌毒素吸附剂及其制备方法 |
CN103849349A (zh) * | 2014-03-14 | 2014-06-11 | 江南大学 | 一种水性胶粘剂及其制备方法 |
CN105597130A (zh) * | 2016-01-01 | 2016-05-25 | 山东玉皇粮油食品有限公司 | 一种油气脱臭环保工艺 |
-
2017
- 2017-04-10 CN CN201710229477.0A patent/CN107413300B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020107367A1 (en) * | 2000-12-08 | 2002-08-08 | Victor Chiou | Process for isolation and purification of yolk antibodies from avian egg yolk and uses of yolk antibodies obtained thereby |
CN103521181A (zh) * | 2013-10-10 | 2014-01-22 | 浙江丰虹新材料股份有限公司 | 一种复合型霉菌毒素吸附剂及其制备方法 |
CN103849349A (zh) * | 2014-03-14 | 2014-06-11 | 江南大学 | 一种水性胶粘剂及其制备方法 |
CN105597130A (zh) * | 2016-01-01 | 2016-05-25 | 山东玉皇粮油食品有限公司 | 一种油气脱臭环保工艺 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109022127A (zh) * | 2018-07-26 | 2018-12-18 | 望江县振兴植物油厂(普通合伙) | 一种美容养颜芝麻油的制备方法 |
CN112694946A (zh) * | 2021-01-19 | 2021-04-23 | 南昌大学 | 一种去除油脂中黄曲霉素的方法 |
CN114405459A (zh) * | 2022-03-01 | 2022-04-29 | 河南工业大学 | 一种用于脱除植物油中黄曲霉毒素的助滤剂及制备方法 |
CN114405459B (zh) * | 2022-03-01 | 2023-12-12 | 河南工业大学 | 一种用于脱除植物油中黄曲霉毒素的助滤剂及制备方法 |
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Denomination of invention: A Decolorizing Agent for Reducing Aflatoxin Content in Peanut Oil Effective date of registration: 20221229 Granted publication date: 20191203 Pledgee: Industrial and Commercial Bank of China Limited Junan sub branch Pledgor: SHANDONG YUHUANG GRAIN & OIL FOOD CO.,LTD. Registration number: Y2022980029562 |
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