CN1073895A - Flotation agent for ore foam flotation method - Google Patents
Flotation agent for ore foam flotation method Download PDFInfo
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- CN1073895A CN1073895A CN 92106802 CN92106802A CN1073895A CN 1073895 A CN1073895 A CN 1073895A CN 92106802 CN92106802 CN 92106802 CN 92106802 A CN92106802 A CN 92106802A CN 1073895 A CN1073895 A CN 1073895A
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- flotation
- ore
- agent
- fatty acid
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Abstract
The invention provides a flotation agent suitable for a foam flotation method of oxidized ores and nonmetallic ores. The agent can be used alone or mixed with other fatty acid collecting agents in the flotation process of oxidized ores and nonmetallic ores. The method has the advantages of low reagent dosage, high selectivity, low temperature resistance and wide applicable pH range, and particularly when the method is used for reverse flotation of fluorite from iron ore, the flotation recovery rate is improved by 4.8 percent. The flotation synthesis process is simple, stable in product performance, non-toxic, convenient and reliable to use and low in cost.
Description
The invention belongs to ore froth flotation field, what relate to is a kind of collecting agent that is applicable to oxide ore and nonmetallic ore froth flotation.
At present, in oxide ore and nonmetallic ore froth flotation process, particularly when iron oxide ore, fluorite ore deposit or magnesite flotation, several floating agents commonly used mainly are that oleic acid, oxidation paraffin wax soap, tal fibre wet goods fatty acid collecting agent (are seen " Mineral Processing Technology " that B.A.Wills writes, Britain Pergamo publishing house, 1988, the 4th edition, P456).Perhaps one of above-mentioned fatty acid collecting agent is mixed use (see Russian Patent SU 1602578, October 30 nineteen ninety, application and Chinese patent CN 1032631A applied on September 17th, 1988) with other medicament.The selectivity of these medicaments is low, and is big to the sensitiveness of slurry pH and flotation temperature, and bad dispersibility, reagent consumption are big in faintly acid and low temperature ore pulp.Because the influence of above-mentioned these factors cause such medicament service condition harshness, and flotation effect is bad.
Fatty acid-based aryl sulfonic acid is a class surfactant.Though in textile industry, be used as (C.A.73:99934z such as making catalyst among dyeing auxiliaries, the grease water Jie, 1970 and C.A.75:112274x, 1971), but be used for the consonance agent that the ore foam flotation method is made flotation collector and made fatty acid collecting agent, both at home and abroad beyond example still.
The objective of the invention is to, it is strong to explore a kind of good dispersion, selectivity height, collecting ability, the collecting agent composition for flotation of coal that can use under the pH of broad value scope and low temperature.Perhaps this medicament is mixed use by a certain percentage with above-mentioned fatty acid flotation collector, to reach another best separating effect.
Particular content of the present invention is described below: at first with broken and fine grinding ore and water be modulated into ore pulp, add fatty acid-based arylsulphonate collecting agent 100～200 gram/tons then and give the ore deposit, after the stirred for several minute, add conventional foaming agent and adjust agent, again after the stirred for several minute, wherein purpose oxide mineral or nonmetallic mineral are also collected as the froth pulp emersion, but not the purpose mineral will be discharged as the deep gouge product.Wherein used fatty acid-based aromatic sulfonic acid salt accords with following molecular formula in this method:
In the formula: Ar is aryl or the aryl that replaced by one or more hydroxyls, halogen, ether, alkoxyl;
R
1, R
2Be respectively C
1-8, C
1-10Alkyl;
M is alkaline earth metal cation (K, Na).
Above-mentioned collecting agent except can using separately, also can with oleic acid, stearic acid, laurate, tall oil, oxidation paraffin wax soap, aphthenic acids by 0.5～1.5: 1 weight ratio is mixed use.
Collecting agent used in the ore floatation method of the present invention is compared with conventional fatty acid flotation collector, has following advantage:
1. good dispersion, collecting ability is strong, the selectivity height;
2. concentrate quality is good, the yield height of purpose mineral;
3. reagent consumption is low, and collector dosage is 70～150 gram/tons only, adjusts the agent consumption and reduces by 66～100%, and the inhibitor consumption reduces by 50～68%;
4. the flotation pH value wide ranges of Shi Yonging, mixed reagent can use about pH=3～10;
5. the flotation temperature of Shi Yonging is low, can use down at 5～10 ℃;
6. strong to water quality adaptability, can use the backwater in ore dressing plant;
7. synthesis technique is simple, is easy to control, grasps, and raw material sources are extensive, and properties of product are stable, and are nontoxic, and cost is low and easy to use.
Flotation collector or mixed reagent used in the inventive method are applicable to oxide ore and the use of nonmetallic ore flotation field.
Embodiment one
The medicament preparation: (Ar is unsubstituted aryl with fatty acid-based aryl sulfonic acid sodium salt; Effective component content 38～40%) weighs up by weight 1: 1 with oxidation paraffin wax soap, heat water-solubleization, be mixed with 5% solution, mix standby (is the SLM collecting agent to call this mixture in the following text).
Mog-200 order is accounted for 85～90%, add water for the hematite sample ore of ore deposit iron grade 54.18%, fluorine-containing 2.27% and size mixing, adopts reverse flotation flow process of opening a way to concentration 35%.30～35 ℃ of control flotation temperatures add waterglass 500 gram/tons, SLM collecting agent 70～90 gram/tons, and slurry pH 7～8, flotation 7～8 minutes obtains iron ore concentrate productive rate 72.73%, grade 60.19%, yield 80.80%, wherein fluorine-containing 0.55%.Under the condition that adopts same sample ore and technological process, add sodium carbonate 500 gram/tons, waterglass 1000 gram/tons, oxidation paraffin wax soap 70～90 gram/tons, slurry pH 8.5～9.5.Obtain iron ore concentrate productive rate 67.71%, grade 60.67%, yield 75.99%, wherein fluorine-containing 0.54%.
Embodiment two
The medicament preparation is the same.
Mog-200 order is accounted for 95%, give ore deposit iron grade 55.38%, fluorine-containing 0.47% sample ore, add water and size mixing, adopt the open circuit flow process of once top-uping, 30 ℃ of control flotation temperatures to concentration 35%, add prodan 300 gram/tons, above-mentioned SLM collecting agent 400 gram/tons, slurry pH 5.0, flotation 10 minutes, obtain iron ore concentrate productive rate 70.29%, product are 62.97%, yield 79.92%, wherein fluorine-containing 0.36%.
Embodiment three
Medicament preparation: will water-soluble the separating of above-mentioned fatty acid-based aryl sulfonic acid sodium heating, be mixed with concentration and be 2% the aqueous solution, afterwards standby (unmixed thing is hereinafter referred to as the EM-2 collecting agent) stirs.
Mog-200 order is accounted for 70～75%, and giving ore deposit magnesia grade is that 89.62% magnesite sample ore adds water and sizes mixing to concentration 35%, adopts the anti-floating and anti-floating flow process of opening a way of anion of cation one time.6～10 ℃ of flotation temperatures.The anti-floating hydrochloric acid 2000 gram/tons, lauryl amine 120～140 gram/tons of adding of cation.Anion is anti-floating to add CM C50 gram/ton, EM-2 100 gram/tons, and pH values of pulp 3～6, flotation 5 minutes can obtain magnesite concentrate yield 58.20%, magnesia grade 97.53%.
Claims (3)
1, a kind of method that from ore, reclaims burning mineral and nonmetallic mineral, it is characterized in that with broken and fine grinding ore; Water is modulated into ore pulp, carries out froth flotation under interpolation flotation agent condition, and wherein flotation collector is a kind of fatty acid-based arylsulphonate, and meets following molecular formula:
In the formula: Ar is aryl or the aryl that replaced by one or more hydroxyls, halogen, ether, alkoxyl; R
1, R
2Be respectively C
1-8, C
1-10Alkyl; M is alkaline earth metal cation (K, Na).
2, method for floating as claimed in claim 1 is characterized in that this flotation collector can use separately, also can mix use by weight 0.5～1.5: 1 with other fatty acid collecting agent such as oleic acid, laurate, tall oil, oxidation paraffin wax soap or aphthenic acids.
3, method for floating as claimed in claim 1 or 2 is characterized in that can be used for oxide ore and nonmetallic ore flotation field.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92106802 CN1033431C (en) | 1991-12-31 | 1991-12-31 | Method for recovering metal oxide mineral and nonmetal mineral from ore |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92106802 CN1033431C (en) | 1991-12-31 | 1991-12-31 | Method for recovering metal oxide mineral and nonmetal mineral from ore |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1073895A true CN1073895A (en) | 1993-07-07 |
| CN1033431C CN1033431C (en) | 1996-12-04 |
Family
ID=4942434
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92106802 Expired - Fee Related CN1033431C (en) | 1991-12-31 | 1991-12-31 | Method for recovering metal oxide mineral and nonmetal mineral from ore |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1033431C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101983776A (en) * | 2010-11-10 | 2011-03-09 | 湖北富邦化工科技有限公司 | Collophane low-temperature reverse flotation collector and preparation method thereof |
| CN102076419A (en) * | 2008-07-02 | 2011-05-25 | 佐治亚-太平洋化工品有限公司 | Collectors |
| CN102764700A (en) * | 2012-08-01 | 2012-11-07 | 中钢集团马鞍山矿山研究院有限公司 | Preparation method of low temperature resisting fluorite flotation collector |
| CN107206393A (en) * | 2014-12-01 | 2017-09-26 | 德国钾盐集团股份有限公司 | The method of collecting agent selective floation kainite from mineral intermixture is used as by the use of sulfated fatty acid |
| CN108722676A (en) * | 2018-05-31 | 2018-11-02 | 广东省资源综合利用研究所 | A kind of collecting agent and its preparation method and application |
-
1991
- 1991-12-31 CN CN 92106802 patent/CN1033431C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102076419A (en) * | 2008-07-02 | 2011-05-25 | 佐治亚-太平洋化工品有限公司 | Collectors |
| US8403146B2 (en) | 2008-07-02 | 2013-03-26 | Georgia-Pacific Chemicals Llc | Collectors |
| CN102076419B (en) * | 2008-07-02 | 2014-04-09 | 佐治亚-太平洋化工品有限公司 | Collectors |
| US9566589B2 (en) | 2008-07-02 | 2017-02-14 | Georgia-Pacific Chemicals Llc | Collectors |
| CN101983776A (en) * | 2010-11-10 | 2011-03-09 | 湖北富邦化工科技有限公司 | Collophane low-temperature reverse flotation collector and preparation method thereof |
| CN102764700A (en) * | 2012-08-01 | 2012-11-07 | 中钢集团马鞍山矿山研究院有限公司 | Preparation method of low temperature resisting fluorite flotation collector |
| CN107206393A (en) * | 2014-12-01 | 2017-09-26 | 德国钾盐集团股份有限公司 | The method of collecting agent selective floation kainite from mineral intermixture is used as by the use of sulfated fatty acid |
| CN108722676A (en) * | 2018-05-31 | 2018-11-02 | 广东省资源综合利用研究所 | A kind of collecting agent and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1033431C (en) | 1996-12-04 |
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