CN101983776A - Collophane low-temperature reverse flotation collector and preparation method thereof - Google Patents
Collophane low-temperature reverse flotation collector and preparation method thereof Download PDFInfo
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- CN101983776A CN101983776A CN 201010537936 CN201010537936A CN101983776A CN 101983776 A CN101983776 A CN 101983776A CN 201010537936 CN201010537936 CN 201010537936 CN 201010537936 A CN201010537936 A CN 201010537936A CN 101983776 A CN101983776 A CN 101983776A
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- fatty acid
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Abstract
The invention relates to a collophane low-temperature reverse flotation collector and a preparation method thereof. The collector is prepared by mixing basic substance with water in a weight ratio of 1:20-100, wherein the basic substance comprise the following components by weight percent: 90-95% of higher fatty acid soap with the fatty acid content of no less than 40% and 5-10% of terpenol. The collector is characterized in that the grade of the selected crude ore is low, the applicable scope is wide, the recovery rate of the concentrate is high, the MgO content of the concentrate is low and the cost of ore dressing is low. Compared with the prior art, the gelation of the collector is difficult to appear below 10 DEG C, the flotation index is qualified and the collector can adapt to the low-temperature flotation.
Description
Technical field
The present invention relates to a kind of collophane low temperature collecting agent in reverse floatation and preparation method thereof.
Background technology
Phosphorus ore is the important strategic resource, is mainly used in preparation phosphate and phosphate fertilizer.The production of phosphate and phosphate fertilizer is P to the requirement of rock phosphate in powder raw material
2O
5Content is high more, and MgO content is low more good more.General high-quality rock phosphate in powder P
2O
5Content is more than 32%, and MgO content is below 1%.Occurring in nature, the rock phosphate in powder that can reach index like this is limited, and most low-phosphorous high-magnesium-phosphorus ore stone need carry out ore dressing, in the hope of reaching the requirement of high-quality rock phosphate in powder.The collecting agent that uses in the floating separation technology has reasonable separating effect under the normal temperature at present.But when water temperature was lower than 10 ℃, collecting agent easily formed micelle, active decline, and production target does not reach requirement.
Summary of the invention
The object of the present invention is to provide a kind of collophane low temperature collecting agent in reverse floatation and preparation method thereof, when selected head grade 21% when above, the product of being produced still can reach the qualified concentrate containing index.And concentrate rate of recovery height, concentrate MgO content is low, and beneficiation cost is low; In addition, reasonable separating effect is arranged under the low temperature.
Technical scheme of the present invention is:
Collophane low temperature collecting agent in reverse floatation is mixed by base substance and water; The mass ratio of base substance and water is 1: 20~100; Wherein the component of base substance is that content of fatty acid is not less than 40% higher fatty acids soap 90~95%, terpenol (BK201) 5~10%.
In the above-mentioned collophane low temperature collecting agent in reverse floatation, described higher fatty acids soap is got by 50~60% saturated higher fatty acid and 40~50% unsaturated high-grade fatty acid saponification.
In the above-mentioned collophane low temperature collecting agent in reverse floatation, described higher fatty acids soap is a potash soap.
Compared with the prior art, the present invention has adopted new material component.The selected head grade of collecting agent of the present invention is 21% when above, and the product of being produced still can reach the qualified concentrate containing index.This has important effect for the utilization of a large amount of low-grade phosphate ore stone resource of China.The present invention also has concentrate rate of recovery height, concentrate MgO content is low, beneficiation cost is low characteristics.The present invention not only has floatation indicators preferably under the normal temperature, is lower than 10 ℃ in temperature, and floatation indicators still can reach production requirement.The present invention not only is applicable to the flotation at low temperature production of collophane, and can be applied in the flotation at low temperature production of various rocks phosphate in powder.
The specific embodiment
Embodiments of the invention are raw materials used all to be purchased from market.
Embodiment 1: get the saturated higher fatty acid of 500kg and the unsaturated high-grade fatty acid of 500kg, the back KOH saponification 6h with 250kg of mixing obtains content of fatty acid and is higher than 40% higher fatty acids potash soap; Get this higher fatty acids potash soap 90kg, terpenol (BK201) 10kg obtains base substance after the mixing; Add and obtain collecting agent after water 2000kg stirs, utilize this collecting agent under 8 ℃ flotation temperature to P
2O
521.3%, the raw ore of MgO 7.2% is handled, and obtains P
2O
534.1%, the concentrate of MgO 0.8%, the rate of recovery 92.7%.
Embodiment 2: get the saturated higher fatty acid of 530kg and the unsaturated high-grade fatty acid of 470kg, obtain content of fatty acid with 250KOH saponification 6h after mixing and be higher than 40% higher fatty acids potash soap; Get this higher fatty acids potash soap 92kg, terpenol (BK201) 8kg obtains base substance after the mixing; Add and obtain collecting agent after water 5000kg stirs, utilize this collecting agent under 8 ℃ flotation temperature to P
2O
521.3%, the raw ore of MgO 7.2% is handled, and obtains P
2O
534.4%, the concentrate of MgO 0.7%, the rate of recovery 91.9%.
Embodiment 3: get the saturated higher fatty acid of 560kg and the unsaturated high-grade fatty acid of 440kg, obtain content of fatty acid with 250kgKOH saponification 6h after mixing and be higher than 40% higher fatty acids potash soap; Get this higher fatty acids potash soap 94kg, terpenol (BK201) 6kg obtains base substance after the mixing; Add and obtain collecting agent after water 8000kg stirs, utilize this collecting agent under 8 ℃ flotation temperature to P
2O
521.3%, the raw ore of MgO 7.2% is handled, and obtains P
2O
534.8%, the concentrate of MgO 0.7%, the rate of recovery 90.7%.
Embodiment 4: get the saturated higher fatty acid of 600kg and the unsaturated high-grade fatty acid of 400kg, obtain content of fatty acid with 250kgKOH saponification 6h after mixing and be higher than 40% higher fatty acids potash soap.Get this higher fatty acids potash soap 95kg, terpenol (BK201) 5kg obtains base substance after the mixing; Add and obtain collecting agent after water 10000kg stirs, utilize this collecting agent under 8 ℃ flotation temperature to P20521.3%, the raw ore of MgO 7.2% is handled, and obtains P2O5 35.3%, the concentrate of MgO 0.6%, the rate of recovery 89.9%.
Claims (3)
1. collophane low temperature collecting agent in reverse floatation is characterized in that: mixed by base substance and water; The mass ratio of base substance and water is 1: 20~100; Wherein the component of base substance is that content of fatty acid is not less than 40% higher fatty acids soap 90~95%, terpenol 5~10%.
2. collophane low temperature collecting agent in reverse floatation according to claim 1 is characterized in that: described higher fatty acids soap is got by 50~60% saturated higher fatty acid and 40~50% unsaturated high-grade fatty acid saponification.
3. collophane low temperature collecting agent in reverse floatation according to claim 1 and 2 is characterized in that: described higher fatty acids soap is a potash soap.
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CN 201010537936 CN101983776A (en) | 2010-11-10 | 2010-11-10 | Collophane low-temperature reverse flotation collector and preparation method thereof |
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Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102259063A (en) * | 2011-06-03 | 2011-11-30 | 湖北富邦科技股份有限公司 | Collophanite obverse-reverse flotation collecting agent and preparation method thereof |
CN102513221A (en) * | 2012-01-10 | 2012-06-27 | 贵州大学 | Carbonate phosphorite reverse flotation combined collecting agent and preparation method thereof |
CN103286007A (en) * | 2013-06-13 | 2013-09-11 | 北京矿冶研究总院 | Reverse flotation collecting agent for silico-calcic collophanite and preparation method thereof |
CN103331212A (en) * | 2013-07-12 | 2013-10-02 | 武汉工程大学 | Carbonate phosphorite reverse flotation collecting agent and preparation method thereof |
CN103341415A (en) * | 2013-07-12 | 2013-10-09 | 武汉工程大学 | Cellophane direct flotation collecting agent and method for preparing same |
CN103350035A (en) * | 2013-05-31 | 2013-10-16 | 武汉工程大学 | Collophanite direct flotation collecting agent and preparation method thereof |
CN103357510A (en) * | 2013-07-26 | 2013-10-23 | 武汉工程大学 | Cellophane positive flotation collector and preparation method of cellophane positive flotation collector |
CN103357509A (en) * | 2013-07-12 | 2013-10-23 | 武汉工程大学 | Reverse flotation collecting agent of cellophane and preparation method thereof |
CN103657862A (en) * | 2013-12-31 | 2014-03-26 | 云南磷化集团有限公司 | Collophanite reverse flotation collecting agent and preparation method thereof |
CN104084313A (en) * | 2014-06-24 | 2014-10-08 | 云南科力新材料有限公司 | Flotation collecting foaming agent and preparation method thereof |
CN104888968A (en) * | 2015-07-03 | 2015-09-09 | 武汉工程大学 | Preparation method of amphoteric collector for reverse flotation of phosphorite |
CN104888970A (en) * | 2015-04-27 | 2015-09-09 | 云南磷化集团有限公司 | Collophanite column type reverse floating collecting agent |
CN106334626A (en) * | 2016-08-25 | 2017-01-18 | 湖北省兴发磷化工研究院有限公司 | Preparation method for novel collophanite reverse flotation collector for decarbonated salt minerals |
CN107309093A (en) * | 2017-06-27 | 2017-11-03 | 湖北富邦科技股份有限公司 | It is a kind of to prevent gel and improve collecting agent of agent activity and preparation method thereof |
CN108212539A (en) * | 2017-12-29 | 2018-06-29 | 云南磷化集团有限公司 | A kind of efficient carbonate-type Collophane anti-floatation collector and preparation method thereof |
CN110369144A (en) * | 2019-07-25 | 2019-10-25 | 瓮福(集团)有限责任公司 | A kind of efficient combination collecting agent and preparation method thereof |
US20220184637A1 (en) * | 2020-03-10 | 2022-06-16 | Institute of Multipurpose Utilization of Mineral Resources, CAGS | Ore dressing process for medium-grade and low-grade mixed collophanite |
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Cited By (20)
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CN102259063A (en) * | 2011-06-03 | 2011-11-30 | 湖北富邦科技股份有限公司 | Collophanite obverse-reverse flotation collecting agent and preparation method thereof |
CN102513221A (en) * | 2012-01-10 | 2012-06-27 | 贵州大学 | Carbonate phosphorite reverse flotation combined collecting agent and preparation method thereof |
CN103350035A (en) * | 2013-05-31 | 2013-10-16 | 武汉工程大学 | Collophanite direct flotation collecting agent and preparation method thereof |
CN103286007B (en) * | 2013-06-13 | 2015-04-08 | 北京矿冶研究总院 | Reverse flotation collecting agent for silico-calcic collophanite and preparation method thereof |
CN103286007A (en) * | 2013-06-13 | 2013-09-11 | 北京矿冶研究总院 | Reverse flotation collecting agent for silico-calcic collophanite and preparation method thereof |
CN103341415A (en) * | 2013-07-12 | 2013-10-09 | 武汉工程大学 | Cellophane direct flotation collecting agent and method for preparing same |
CN103331212A (en) * | 2013-07-12 | 2013-10-02 | 武汉工程大学 | Carbonate phosphorite reverse flotation collecting agent and preparation method thereof |
CN103357509A (en) * | 2013-07-12 | 2013-10-23 | 武汉工程大学 | Reverse flotation collecting agent of cellophane and preparation method thereof |
CN103357510A (en) * | 2013-07-26 | 2013-10-23 | 武汉工程大学 | Cellophane positive flotation collector and preparation method of cellophane positive flotation collector |
CN103657862A (en) * | 2013-12-31 | 2014-03-26 | 云南磷化集团有限公司 | Collophanite reverse flotation collecting agent and preparation method thereof |
CN103657862B (en) * | 2013-12-31 | 2015-11-18 | 云南磷化集团有限公司 | A kind of Collophane anti-floatation collector and preparation method thereof |
CN104084313A (en) * | 2014-06-24 | 2014-10-08 | 云南科力新材料有限公司 | Flotation collecting foaming agent and preparation method thereof |
CN104888970A (en) * | 2015-04-27 | 2015-09-09 | 云南磷化集团有限公司 | Collophanite column type reverse floating collecting agent |
CN104888968A (en) * | 2015-07-03 | 2015-09-09 | 武汉工程大学 | Preparation method of amphoteric collector for reverse flotation of phosphorite |
CN104888968B (en) * | 2015-07-03 | 2017-07-11 | 武汉工程大学 | Preparation method of amphoteric collector for reverse flotation of phosphorite |
CN106334626A (en) * | 2016-08-25 | 2017-01-18 | 湖北省兴发磷化工研究院有限公司 | Preparation method for novel collophanite reverse flotation collector for decarbonated salt minerals |
CN107309093A (en) * | 2017-06-27 | 2017-11-03 | 湖北富邦科技股份有限公司 | It is a kind of to prevent gel and improve collecting agent of agent activity and preparation method thereof |
CN108212539A (en) * | 2017-12-29 | 2018-06-29 | 云南磷化集团有限公司 | A kind of efficient carbonate-type Collophane anti-floatation collector and preparation method thereof |
CN110369144A (en) * | 2019-07-25 | 2019-10-25 | 瓮福(集团)有限责任公司 | A kind of efficient combination collecting agent and preparation method thereof |
US20220184637A1 (en) * | 2020-03-10 | 2022-06-16 | Institute of Multipurpose Utilization of Mineral Resources, CAGS | Ore dressing process for medium-grade and low-grade mixed collophanite |
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Application publication date: 20110309 |