CN107309093A - It is a kind of to prevent gel and improve collecting agent of agent activity and preparation method thereof - Google Patents
It is a kind of to prevent gel and improve collecting agent of agent activity and preparation method thereof Download PDFInfo
- Publication number
- CN107309093A CN107309093A CN201710502290.3A CN201710502290A CN107309093A CN 107309093 A CN107309093 A CN 107309093A CN 201710502290 A CN201710502290 A CN 201710502290A CN 107309093 A CN107309093 A CN 107309093A
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- Prior art keywords
- parts
- oleic acid
- oil oleic
- agent
- mixed
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/06—Phosphate ores
Abstract
The present invention relates to a kind of collecting agent for preventing gel and improving agent activity and preparation method thereof, collecting agent is made up of following substances, each material is by weight, 40 90 parts of palm oil oleic acid, 10 60 parts of rapeseed oil oleic acid, counted using the mixture after palm oil oleic acid, rapeseed oil oleic acid saponification as 100 parts, then add 5 18 parts of mixed surfactant, preparation method：40 90 parts of palm oil oleic acid, 10 60 parts of rapeseed oil oleic acid are mixed, heat the mixture to 100~120 DEG C of fully dissolving mixing, add 150 170 parts of sodium hydroxides, saponification 50-70 minutes under the conditions of 70 90 DEG C, counted again using the mixture after saponification as 100 parts, add 5 18 parts of mixed surfactant to be well mixed, a kind of collecting agent for preventing gel and improving agent activity is made.Collecting agent of the present invention can not only ensure qualified floatation indicators, moreover it is possible to effectively prevent medicament gel and improve agent activity.
Description
Technical field
The present invention relates to mineral froth flotation collector, more particularly to a kind of collecting for preventing gel and improving agent activity
Agent and preparation method thereof.
Background technology
The important medium that rock phosphate in powder floating agent is sorted as phosphorus ore, largely directly affect select factory cost and
The stabilization of index.On the one hand, some select factory to be reduction equipment cost, and dispensing equipment is very simple and crude, often using a small amount of hot water of burning
Medicament dissolution is then blended into a large amount of hot water causes medicament temperature near room temperature simultaneously as selecting factory to reduce artificial use cost
The drug concentration of configuration is up to 3%-7%, causes the influence production of medicament gel blocking pipeline.On the other hand, some select factory because of field
Ground or fund input limitation, are simplified in flotation flowsheet design, and to may result in flotation not thorough for the shortening of technological process
Bottom index is often unqualified.At this moment candidate factory will express more expectations to floating agent, it is desirable to which flotation collector is thrown in equipment
Cost raising, which is reduced, in the case of entering few not even input selects factory's efficiency.Therefore, gelling performance and activity to floating agent will
Asking becomes more urgent.
The content of the invention
The purpose of the present invention is in order to overcome the defect and problem that above-mentioned prior art is present, and providing one kind prevents gel simultaneously
Improve agent activity collecting agent, the present invention provide it is a kind of prevent gel and improve agent activity collecting agent can meet
Medicament not gel and activity is good is ensured while selecting factory's internal control index.The surfactant used in the collecting agent of the present invention
With extraordinary dispersive property, it can effectively help fatty acid soaps that there is good dispersiveness not gel in aqueous, simultaneously
Assign medicament system good activity, promote medicament that still there is quickly effect speed in the time under normal temperature condition, shorter
Degree, ensures to select in the technological process of medicament at ambient temperature, shorter and stablizes qualified separation index, to select factory to improve sorting
Efficiency reduces equipment investment.
The present invention is realized by following technology：
A kind of collecting agent for preventing gel and improving agent activity, it is characterised in that：It is made up of following substances, each material is pressed
Parts by weight meter, 40-90 parts of palm oil oleic acid, 10-60 parts of rapeseed oil oleic acid, after palm oil oleic acid, rapeseed oil oleic acid saponification
Mixture is 100 parts of meters, then adds 5-18 parts of mixed surfactant, preparation method：By 40-90 parts of palm oil oleic acid, 10-
60 parts of rapeseed oil oleic acid mixing, heat the mixture to 100~120 DEG C of fully dissolving mixing, add 150-170 parts of hydroxides
Sodium, saponification 50-70 minutes under the conditions of 70-90 DEG C, then is counted using the mixture after saponification as 100 parts, adds blending surface activity
5-18 parts of agent is well mixed, and a kind of collecting agent for preventing gel and improving agent activity is made.
The palm oil oleic acid is the palm oil oleic acid that palmitic acid content reaches 50-95%.
The rapeseed oil oleic acid is that oleic acid and linoleic acid total content reach 10-60%, and content of myristic acid reaches 5%-
30% rapeseed oil oleic acid.
The mixed surfactant is by 1-9 parts of 4- terpenols, 2-8 parts of neopelexes, 1-10 portions of lemons
Acid compounding composition.
A kind of preparation method for preventing gel and improving the collecting agent of agent activity, each material by weight, its feature
It is to carry out according to the following steps：40-90 parts of palm oil oleic acid, 10-60 parts of rapeseed oil oleic acid are mixed, heated the mixture to
100~120 DEG C of fully dissolving mixing, add 150-170 parts of sodium hydroxides, saponification 50-70 minutes under the conditions of 70-90 DEG C, then
Counted using the mixture after saponification as 100 parts, add 5-18 parts of mixed surfactant and be well mixed, obtained one kind prevents gel simultaneously
Improve the collecting agent of agent activity.
The oily oleic acid of described palm oil, rapeseed oil oleic acid are all purchased from market.
Described 4- terpenols are purchased for market.
Described neopelex is purchased for market.
Described citric acid is purchased for market.
The collecting agent that the present invention is provided have stable pharmaceutical collecting ability, alleviate high concentration low temperature medicament gel, solve because
Technological process causes the problem of incomplete index fluctuation of ore dressing is larger compared with short-range missile, can not only effectively reduce concentrator equipment input, right
Ensure that production target is stable even more significant.
The present invention collecting agent can use in all phosphate rock floating workshop sections, especially for need solve medicament gel problem
And improve agent activity select factory.Compared with other flotation collectors, the collecting agent can not only ensure qualified floatation indicators, more
Can have to low temperature and high concentration more preferable adaptability and meanwhile for flotation process it is shorter select factory also to realize efficiently
Mineral processing index.
Embodiment
With reference to embodiment, the invention will be further described, but does not limit the present invention, and each material of following examples is pressed
Parts by weight meter.The oily oleic acid of described palm oil, rapeseed oil oleic acid, 4- terpenols, neopelex, citric acid Dou Cong cities
Purchase field.
Embodiment 1：40 parts of palm oil oleic acid, 60 parts of rapeseed oil oleic acid raw materials are mixed, the palm oil grease is soft
Resin acid content is 80% palm oil oleic acid；The rapeseed oil oleic acid is oleic acid and linoleic acid total content is 60%, myristic acid
Content reaches 10% rapeseed oil oleic acid；Heating the mixture to 100 DEG C makes raw material fully dissolve and mix, and adds 153 parts of hydrogen
Sodium oxide molybdena, by saponification under the conditions of 70 DEG C of raw material 65 minutes, using the mixture after saponification as 100 parts of additions, 2 parts of 4- terpenols, 4 parts
Neopelex, 9 parts of citric acids are well mixed, and are obtained preventing gel and are improved the collecting agent finished product of agent activity.
Gel will be prevented made from the present embodiment 1 and the collecting agent of agent activity is improved being configured to 4% mass concentration
Solution, is placed on 24 hours non-gels of medicament of constant temperature in the water-bath that temperature is 25 DEG C.The medicament that this has been configured simultaneously is in lake
Certain selects progress laboratory flotation checking on factories and miness stone in north, in the case where flotation time shortens 30 seconds, can still select and meet visitor
The index that family is required, shows that the collecting agent all produces a desired effect on gelling performance and agent activity.
Embodiment 2：50 parts of palm oil oleic acid, 50 parts of rapeseed oil oleic acid raw materials are mixed, the palm oil grease is soft
Resin acid content is 75% palm oil oleic acid；The rapeseed oil oleic acid is oleic acid and linoleic acid total content is 30%, myristic acid
Content reaches 5% rapeseed oil oleic acid；Heating the mixture to 100 DEG C makes raw material fully dissolve and mix, and adds 160 parts of hydrogen-oxygens
Change sodium, by saponification under the conditions of 80 DEG C of raw material 60 minutes, be 100 parts using the mixture after saponification and add 4 parts of 4- terpenols, 5 part ten
Dialkyl benzene sulfonic acids sodium, 3 parts of citric acids are well mixed, and are obtained preventing gel and are improved the collecting agent finished product of agent activity.
Gel will be prevented made from the present embodiment 2 and the collecting agent of agent activity is improved being configured to 3% mass concentration
Solution, is placed on 24 hours non-gels of medicament of constant temperature in the water-bath that temperature is 25 DEG C.The medicament that this has been configured simultaneously is four
Progress laboratory flotation checking on factories and miness stone is selected in river, in the case where flotation time shortens 40 seconds, can still be selected and be met visitor
The index that family is required, shows that the collecting agent all produces a desired effect on gelling performance and agent activity.
Embodiment 3：60 parts of palm oil oleic acid, 40 parts of rapeseed oil oleic acid raw materials are mixed, the palm oil grease is soft
Resin acid content is 60% palm oil oleic acid；The rapeseed oil oleic acid is oleic acid and linoleic acid total content is 10%, myristic acid
Content reaches 15% rapeseed oil oleic acid；Heating the mixture to 100 DEG C makes raw material fully dissolve and mix, and adds 155 parts of hydrogen
Sodium oxide molybdena, by saponification under the conditions of 85 DEG C of raw material 70 minutes, using the mixture after saponification as 100 parts of additions, 1 part of 4- terpenol, 7 parts
Neopelex, 10 parts of citric acids are well mixed, and are obtained preventing gel and are improved the collecting agent finished product of agent activity.
Gel will be prevented made from the present embodiment 3 and the collecting agent of agent activity is improved being configured to 5% mass concentration
Solution, is placed on 24 hours non-gels of medicament of constant temperature in the water-bath that temperature is 25 DEG C.The medicament that this has been configured simultaneously is in cloud
Certain selects progress laboratory flotation checking on factories and miness stone in south, in the case where flotation time shortens 25 seconds, can still select and meet visitor
The index that family is required, shows that the collecting agent all produces a desired effect on gelling performance and agent activity.
Embodiment 4：55 parts of palm oil oleic acid, 45 parts of rapeseed oil oleic acid raw materials are mixed, the palm oil grease is soft
Resin acid content is 65% palm oil oleic acid；The rapeseed oil oleic acid is oleic acid and linoleic acid total content is 25%, myristic acid
Content reaches 20% rapeseed oil oleic acid；Heating the mixture to 100 DEG C makes raw material fully dissolve and mix, and adds 168 parts of hydrogen
Sodium oxide molybdena, by saponification under the conditions of 75 DEG C of raw material 55 minutes, using the mixture after saponification as 100 parts of additions, 3 parts of 4- terpenols, 6 parts
Neopelex, 6 parts of citric acids are well mixed, and are obtained preventing gel and are improved the collecting agent finished product of agent activity.
Gel will be prevented made from the present embodiment 4 and the collecting agent of agent activity is improved being configured to 6% mass concentration
Solution, is placed on 24 hours non-gels of medicament of constant temperature in the water-bath that temperature is 25 DEG C.The medicament that this has been configured simultaneously is expensive
Progress laboratory flotation checking on factories and miness stone is selected in state, in the case where flotation time shortens 50 seconds, can still be selected and be met visitor
The index that family is required, shows that the collecting agent all produces a desired effect on gelling performance and agent activity.
Embodiment 5：65 parts of palm oil oleic acid, 35 parts of rapeseed oil oleic acid raw materials are mixed, the palm oil grease is soft
Resin acid content is 50% palm oil oleic acid；The rapeseed oil oleic acid is oleic acid and linoleic acid total content is 15%, myristic acid
Content reaches 25% rapeseed oil oleic acid；Heating the mixture to 120 DEG C makes raw material fully dissolve and mix, and adds 170 parts of hydrogen
Sodium oxide molybdena, by saponification under the conditions of 90 DEG C of raw material 50 minutes, using the mixture after saponification as 100 parts of additions, 6 parts of 4- terpenols, 5 parts
Neopelex, 4 parts of citric acids are well mixed, and are obtained preventing gel and are improved the collecting agent finished product of agent activity.
Gel will be prevented made from the present embodiment 5 and the collecting agent of agent activity is improved being configured to 4.5% mass concentration
Solution, it is 24 hours non-gels of medicament of constant temperature in 25 DEG C of water-bath to be placed on temperature.The medicament configured is existed simultaneously
Progress laboratory flotation checking on factories and miness stone is selected in Hunan, in the case where flotation time shortens 35 seconds, can still be selected and be met
The index of customer requirement, shows that the collecting agent all produces a desired effect on gelling performance and agent activity.
Embodiment 6：70 parts of palm oil oleic acid, 30 parts of rapeseed oil oleic acid raw materials are mixed, the palm oil grease is soft
Resin acid content is 55% palm oil oleic acid；The rapeseed oil oleic acid is oleic acid and linoleic acid total content is 20%, myristic acid
Content reaches 18% rapeseed oil oleic acid；Heating the mixture to 100 DEG C makes raw material fully dissolve and mix, and adds 163 parts of hydrogen
Sodium oxide molybdena, by saponification under the conditions of 73 DEG C of raw material 63 minutes, using the mixture after saponification as 100 parts of additions, 8 parts of 4- terpenols, 2 parts
Neopelex, 5 parts of citric acids are well mixed, and are obtained preventing gel and are improved the collecting agent finished product of agent activity.
Gel will be prevented made from the present embodiment 6 and the collecting agent of agent activity is improved being configured to 5.5% mass concentration
Solution, it is 24 hours non-gels of medicament of constant temperature in 25 DEG C of water-bath to be placed on temperature.The medicament configured is existed simultaneously
Progress laboratory flotation checking on factories and miness stone is selected in Yunnan, in the case where flotation time shortens 45 seconds, can still be selected and be met
The index of customer requirement, shows that the collecting agent all produces a desired effect on gelling performance and agent activity.
Embodiment 7：90 parts of palm oil oleic acid, 10 parts of rapeseed oil oleic acid raw materials are mixed, the palm oil grease is soft
Resin acid content is 55% palm oil oleic acid；The rapeseed oil oleic acid is oleic acid and linoleic acid total content is 20%, myristic acid
Content reaches 18% rapeseed oil oleic acid；Heating the mixture to 110 DEG C makes raw material fully dissolve and mix, and adds 150 parts of hydrogen
Sodium oxide molybdena, by saponification under the conditions of 70 DEG C of raw material 63 minutes, using the mixture after saponification as 100 parts of additions, 1 part of 4- terpenol, 2 parts
Neopelex, 2 parts of citric acids are well mixed, and are obtained preventing gel and are improved the collecting agent finished product of agent activity.
Gel will be prevented made from the present embodiment 7 and the collecting agent of agent activity is improved being configured to 5.5% mass concentration
Solution, it is 24 hours non-gels of medicament of constant temperature in 25 DEG C of water-bath to be placed on temperature.The medicament configured is existed simultaneously
Progress laboratory flotation checking on factories and miness stone is selected in Yunnan, in the case where flotation time shortens 40 seconds, can still be selected and be met
The index of customer requirement, shows that the collecting agent all produces a desired effect on gelling performance and agent activity.
Claims (5)
1. a kind of collecting agent for preventing gel and improving agent activity, it is characterised in that：It is made up of following substances, each material is by weight
Measure part meter, 40-90 parts of palm oil oleic acid, 10-60 parts of rapeseed oil oleic acid, with mixed after palm oil oleic acid, rapeseed oil oleic acid saponification
Compound is 100 parts of meters, then adds 5-18 parts of mixed surfactant, preparation method：By 40-90 parts of palm oil oleic acid, 10-60
The oleic acid mixing of part rapeseed oil, heats the mixture to 100~120 DEG C of fully dissolvings and mixes, 150-170 parts of sodium hydroxides of addition,
Saponification 50-70 minutes under the conditions of 70-90 DEG C, then counted using the mixture after saponification as 100 parts, add mixed surfactant
5-18 parts are well mixed, and a kind of collecting agent for preventing gel and improving agent activity is made.
2. a kind of collecting agent for preventing gel and improving agent activity according to claim 1, it is characterised in that：The palm fibre
Palmitic acid oil oleic acid is the palm oil oleic acid that palmitic acid content reaches 50-95%.
3. a kind of collecting agent for preventing gel and improving agent activity according to claim 1, it is characterised in that：The dish
Seed oil oleic acid is that oleic acid and linoleic acid total content reach 10-60%, and content of myristic acid reaches 5%-30% rapeseed oil oleic acid.
4. a kind of collecting agent for preventing gel and improving agent activity according to claim 1, it is characterised in that：It is described mixed
Mould assembly surfactant is by 1-9 parts of 4- terpenols, 2-8 parts of neopelexes, 1-10 parts of citric acid compounding compositions.
5. a kind of preparation method for preventing gel and improving the collecting agent of agent activity described in claim 1, each material is by weight
Part meter, it is characterised in that carry out according to the following steps：40-90 parts of palm oil oleic acid, 10-60 parts of rapeseed oil oleic acid are mixed, will be mixed
Compound is heated to 100~120 DEG C of fully dissolving mixing, adds 150-170 parts of sodium hydroxides, the saponification under the conditions of 70-90 DEG C
50-70 minutes, then counted using the mixture after saponification as 100 parts, add 5-18 parts of mixed surfactant and be well mixed, be made
A kind of collecting agent for preventing gel and improving agent activity.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710502290.3A CN107309093A (en) | 2017-06-27 | 2017-06-27 | It is a kind of to prevent gel and improve collecting agent of agent activity and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710502290.3A CN107309093A (en) | 2017-06-27 | 2017-06-27 | It is a kind of to prevent gel and improve collecting agent of agent activity and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107309093A true CN107309093A (en) | 2017-11-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710502290.3A Pending CN107309093A (en) | 2017-06-27 | 2017-06-27 | It is a kind of to prevent gel and improve collecting agent of agent activity and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1086438A (en) * | 1965-12-09 | 1967-10-11 | Zuplatec A G Ges Fuer Tech Pla | Concentration of phosphate ores |
| CN101983776A (en) * | 2010-11-10 | 2011-03-09 | 湖北富邦化工科技有限公司 | Collophane low-temperature reverse flotation collector and preparation method thereof |
| CN103056036A (en) * | 2013-01-25 | 2013-04-24 | 中国地质科学院矿产综合利用研究所 | Collophanite normal-temperature direct flotation collecting agent and preparation method thereof |
| CN103920596A (en) * | 2014-04-25 | 2014-07-16 | 中蓝连海设计研究院 | Collophanite combination flotation collector and preparation method and application thereof |
| CN104437884A (en) * | 2014-11-05 | 2015-03-25 | 中国地质科学院矿产综合利用研究所 | Normal-temperature efficient collector for sedimentary silicon-calcium collophanite and preparation method thereof |
| CN104607321A (en) * | 2014-12-11 | 2015-05-13 | 云南铜业胜威化工有限公司 | Collophanite froth flotation collecting agent and preparation method thereof |
| CN105435969A (en) * | 2015-12-09 | 2016-03-30 | 湖北富邦科技股份有限公司 | Collecting agent improving filtering effect for phosphorite floatation and preparing method of collecting agent |
| CN105537003A (en) * | 2015-12-11 | 2016-05-04 | 中国地质科学院矿产综合利用研究所 | Drainage oil type collophanite reverse flotation collecting agent and preparation method thereof |
| CN106861921A (en) * | 2017-02-28 | 2017-06-20 | 武汉工程大学 | A kind of collophane flotation at low temperature collecting agent and preparation method thereof |
-
2017
- 2017-06-27 CN CN201710502290.3A patent/CN107309093A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1086438A (en) * | 1965-12-09 | 1967-10-11 | Zuplatec A G Ges Fuer Tech Pla | Concentration of phosphate ores |
| CN101983776A (en) * | 2010-11-10 | 2011-03-09 | 湖北富邦化工科技有限公司 | Collophane low-temperature reverse flotation collector and preparation method thereof |
| CN103056036A (en) * | 2013-01-25 | 2013-04-24 | 中国地质科学院矿产综合利用研究所 | Collophanite normal-temperature direct flotation collecting agent and preparation method thereof |
| CN103920596A (en) * | 2014-04-25 | 2014-07-16 | 中蓝连海设计研究院 | Collophanite combination flotation collector and preparation method and application thereof |
| CN104437884A (en) * | 2014-11-05 | 2015-03-25 | 中国地质科学院矿产综合利用研究所 | Normal-temperature efficient collector for sedimentary silicon-calcium collophanite and preparation method thereof |
| CN104607321A (en) * | 2014-12-11 | 2015-05-13 | 云南铜业胜威化工有限公司 | Collophanite froth flotation collecting agent and preparation method thereof |
| CN105435969A (en) * | 2015-12-09 | 2016-03-30 | 湖北富邦科技股份有限公司 | Collecting agent improving filtering effect for phosphorite floatation and preparing method of collecting agent |
| CN105537003A (en) * | 2015-12-11 | 2016-05-04 | 中国地质科学院矿产综合利用研究所 | Drainage oil type collophanite reverse flotation collecting agent and preparation method thereof |
| CN106861921A (en) * | 2017-02-28 | 2017-06-20 | 武汉工程大学 | A kind of collophane flotation at low temperature collecting agent and preparation method thereof |
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Application publication date: 20171103 |
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