CN107385888A - A kind of preparation method of fire resistant carbon cloth - Google Patents
A kind of preparation method of fire resistant carbon cloth Download PDFInfo
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- CN107385888A CN107385888A CN201710631191.5A CN201710631191A CN107385888A CN 107385888 A CN107385888 A CN 107385888A CN 201710631191 A CN201710631191 A CN 201710631191A CN 107385888 A CN107385888 A CN 107385888A
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- carbon cloth
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- carbon
- cloth
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- 239000004744 fabric Substances 0.000 title claims abstract description 84
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 63
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 230000009970 fire resistant effect Effects 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000004140 cleaning Methods 0.000 claims abstract description 25
- 238000005470 impregnation Methods 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 20
- 238000002803 maceration Methods 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 239000012530 fluid Substances 0.000 claims abstract description 14
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 13
- 230000003647 oxidation Effects 0.000 claims abstract description 10
- 230000009467 reduction Effects 0.000 claims abstract description 10
- 239000007789 gas Substances 0.000 claims abstract description 9
- 238000009832 plasma treatment Methods 0.000 claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 9
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002657 fibrous material Substances 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims description 45
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 35
- 239000004917 carbon fiber Substances 0.000 claims description 35
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 31
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000001914 filtration Methods 0.000 claims description 12
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 10
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 9
- 235000011201 Ginkgo Nutrition 0.000 claims description 8
- 235000008100 Ginkgo biloba Nutrition 0.000 claims description 8
- 235000003181 Panax pseudoginseng Nutrition 0.000 claims description 8
- 244000131316 Panax pseudoginseng Species 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229910052593 corundum Inorganic materials 0.000 claims description 8
- 238000012545 processing Methods 0.000 claims description 8
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 8
- 229930182490 saponin Natural products 0.000 claims description 8
- 150000007949 saponins Chemical class 0.000 claims description 8
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 8
- 240000004784 Cymbopogon citratus Species 0.000 claims description 7
- 235000017897 Cymbopogon citratus Nutrition 0.000 claims description 7
- 240000000233 Melia azedarach Species 0.000 claims description 7
- 235000008075 Pistacia terebinthus Nutrition 0.000 claims description 7
- 240000006705 Pistacia terebinthus Species 0.000 claims description 7
- 229920006231 aramid fiber Polymers 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 4
- 230000001186 cumulative effect Effects 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 244000194101 Ginkgo biloba Species 0.000 claims 2
- 240000006240 Linum usitatissimum Species 0.000 claims 2
- 238000002386 leaching Methods 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 1
- 239000006210 lotion Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 238000006722 reduction reaction Methods 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 9
- 238000004332 deodorization Methods 0.000 abstract description 4
- 241000208202 Linaceae Species 0.000 description 12
- 238000001179 sorption measurement Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 10
- 241000218628 Ginkgo Species 0.000 description 6
- 238000007711 solidification Methods 0.000 description 6
- 230000008023 solidification Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- 235000007320 Avena fatua Nutrition 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000009965 odorless effect Effects 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 229960004424 carbon dioxide Drugs 0.000 description 2
- 229910002090 carbon oxide Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000008104 plant cellulose Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/34—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxygen, ozone or ozonides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/40—Fibres of carbon
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of preparation method of fire resistant carbon cloth, it is characterised in that including following aspect：（1）Blending, each fibrous material blending is made into carbon cloth；（2）Cleaning, drying, carbon cloth is immersed in cleaning fluid and carries out heated wash, moisture 7% 10% is dried to after taking-up；（3）Surface reduction, reduction reaction is carried out to carbon cloth in a kettle using CO gases；（4）Impregnation, reduction carbon cloth is immersed into maceration extract, carries out impregnation；（5）Plasma, carbon cloth is placed in plasma processor and carries out plasma treatment, and carry out double-steeping；（6）Oxidation processes, ozone is passed through into reactor, oxidation processes are carried out to carbon cloth.The made carbon cloth of the present invention, have fire resistance good, there is preferable occlusion effect to ultraviolet light and sunlight, and there are deodorization functions.
Description
Technical field
The invention belongs to technical field of textile processing, and in particular to a kind of preparation method of fire resistant carbon cloth.
Background technology
Carbon fiber, it is high intensity, the new fiber materials of high modulus fibre of a kind of phosphorus content more than 95%, there is matter
The characteristics of light intensity is high is measured, is widely used in national defence and civilian key areas；Carbon fiber not only has intrinsic property, also has both
The soft machinability of textile fabric, and its axial strength and modulus height, density are low, higher than performance.Carbon fiber is by performance
Carbon fiber can be broadly divided into by different classifications：High intensity, high modulus carbon fiber, ion exchange carbon fiber and activated carbon fiber；
Carbon fiber can be divided into asphaltic base, viscose base, polyacrylonitrile-radical and the major class of lignin-base carbon fiber four according to the difference of raw material.
But in being processed to carbon fiber, because carbon fiber surface inertia is big, surface energy is low, shortage has chemically active function
Group, reactivity is low, the bad adhesion with matrix, directly affects the mechanical property of composite, limits carbon fiber performance
Performance；Its fire protecting performance of carbon fiber is poor, and made carbon fiber clothes occur that chance naked light is inflammable, in emergency circumstances can not be to people
Body plays good protective action；In addition, using carbon fiber as main textile material, weave cotton cloth and expect that its shielding property is low, relatively
In natural fiber material, its clothes produced poor-performing in terms of flexibility and glossiness.
The content of the invention
The present invention is directed to the problem of existing：Carbon fiber property, carbon fiber surface inertia is big, surface energy is low, and shortage has chemistry
The functional group of activity, reactivity is low, the bad adhesion with matrix, directly affects the mechanical property of composite.Fire line,
Compare other fire proofing materials, and carbon fiber processes manufactured dress-goods, the phenomenon met naked light and burnt easily occurs, promptly
In the case of good protective action can not be played to human body.Other features, using carbon fiber as main textile material, material of weaving cotton cloth
Its shielding property is low, relative to natural fiber material, its clothes produced poor-performing in terms of flexibility and glossiness.
To solve the above problems, the invention provides a kind of preparation method of fire resistant carbon cloth.
The present invention is achieved by the following technical solutions：
A kind of preparation method of fire resistant carbon cloth, comprises the following steps:
（1）Blending：Carbon fiber 64-69 parts, aramid fiber 12-16 parts, oil flax fibre 4-8 parts, flax are weighed according to quality meter part
Fiber 4-8 parts, lemongrass fiber 3-6 parts, print chinaberry fiber 1-2 parts, aramid fiber have fire resistance, and flax, flax and lemongrass comfortableness are high,
It is good to print chinaberry fibre antibacterial effect, the fire resistance, comfortableness and antibiotic property of carbon cloth can be improved after blending, by above-mentioned each undulation degree
Material blending is made into carbon cloth；
（2）Cleaning, drying：Carbon cloth is immersed in cleaning fluid and carries out heated wash, the adhesion of design on fabric surface work in-process can be removed
Foreign matter and metal powder, and can to fiber, burr caused by surface and slight crack are repaired in blending product, improve fiber
Comfortable feel and glossiness, moisture 7%-10% is dried to after taking-up, cleaning carbon cloth is made；
（3）Surface reduction：Cleaning carbon cloth is placed in reactor and is passed through reactor cumulative volume 9%-13% CO gases, one
Carbonoxide has stronger reducing power, can destroy the stable oxide layer of fiber surface formation, improves blend fibre surface-active
And adsorption capacity, preferably to adsorb and with reference to packing material, 32-37min to be reacted at a temperature of 120-124 DEG C, is made also
Original carbon fiber cloth；
（4）Impregnation：Reduction carbon cloth is immersed into maceration extract, impregnation is carried out, is configured to using nanoscale maceration extract
Point, its granularity is small, preferably can be combined by fibers adsorption in cloth, is dried after taking-up and impregnation of carbon fibers cloth is made；
（5）Plasma：Impregnation of carbon fibers is arranged in plasma processor, voltage 220-230V, frequency 30-45kHz are set,
Air source pressure intensity 40-60kPa, ionization time 1-2h；Then, maceration extract then by carbon cloth after plasma treatment is immersed, carries out two
Secondary impregnation, dried after taking-up and Treatment of Carbon cloth is made；Adsorption component can be strengthened to be combined with fiber, adsorption component is played
Solidification, the stability of the chemical property of cloth is improved, and plasma treatment can improve fiber surface activity, improve secondary
The effect of dipping；
（6）Oxidation processes：Treatment of Carbon is arranged in the ozone gas that reactor volume 7%-10% is passed through in reactor, reacted
Kettle is heated to 113-117 DEG C, reacts 40-50min, and in reacted kettle after oxidation reaction, carbon cloth surface forms oxide-film, carries
Stability, reflective and the thermal diffusivity of high cloth, and the filler that can be adsorbed to fibrous inside plays solidification, temperature
Decrease speed is 8 DEG C/3min, and fire resistant carbon cloth is made after cooling.
Step（2）Described cleaning fluid, its compound method are：
Water 100-110 parts, pseudo-ginseng 15-18 parts, ginkgo leaf 12-15 parts, ethanol 10-13 parts, saponin(e 9- are weighed according to quality meter part
11 parts, terebinth 7-9 parts, pseudo-ginseng and ginkgo leaf are immersed in the water and boil heating 1-2h, filtering solution is obtained after filtering, to filtering
Ethanol, saponin(e, terebinth are sequentially added in solution, is heated to 57-62 DEG C, is stirred 15-20min, cleaning fluid is made.
Step（2）Described heated wash, its temperature are 84-89 DEG C, time 40-50min.
Step（3）Described maceration extract, its compound method are：
Water 100-120 parts, nanoscale alundum (Al2O3) 11-13 parts, Firebrake ZB 4-7 parts, nanoscale two are weighed according to quality meter part
Titanium oxide 7-9 parts, nanoscale alundum (Al2O3), Firebrake ZB and Nano titanium dioxide are added after boiling is boiled, is stirred 15-
20min, maceration extract is made.
Step（4）Described impregnation, its temperature are 80-85 DEG C, time 45-50min, and heating and cooling rate are
5℃/3min。
Step（5）Described double-steeping processing, its temperature are 72-76 DEG C, time 0.5-1h.
The present invention has advantages below compared with prior art：Blended material, carbon fiber have light weight intensity height, ductility
Good, suitable textile processing and manufacturing, aramid fiber has good fire protecting performance, can improve the fire resistance of yarn weaved fabric, and flax,
Flax, lemongrass fiber are extracted form natural plant cellulose, soft comfortable, can improve material comfortableness of weaving cotton cloth, and print chinaberry fiber
Element can increase the anti-microbial property of yarn weaved fabric.Carbon cloth after blending is immersed in cleaning fluid and cleaned, design on fabric surface can be removed and existed
The foreign matter and metal powder adhered in processing, and can burr caused by surface and slight crack are repaiied in blending product to fiber
It is multiple, improve fabric hand comfortableness and glossiness；Carbon cloth is placed in reactor and carries out reduction reaction using carbon monoxide,
Carbon monoxide has stronger reducing power, can destroy the stable oxide layer of fiber surface formation, improves blend fibre surface and lives
Property and adsorption capacity, preferably to adsorb and with reference to packing material；Composition, its granularity are prepared using nanoscale maceration extract
It is small, preferably it can be combined by fibers adsorption in cloth, alchlor and Firebrake ZB can improve the fire resistance of blended cloth, titanium dioxide
Titanium has good anti-ultraviolet property；Plasma treatment is carried out after dipping, adsorption component and fibre in blending measuring fiber can be strengthened
Dimension combines, and plays solidification to adsorption component, improves the stability of the chemical property of cloth, and plasma treatment can improve
Fiber surface activity, improve the effect of double-steeping.Carry out ozone Oxidation Treatment after double-steeping, oxidation reaction in reacted kettle
Afterwards, carbon fiber surface forms oxide-film, improves stability, reflective and the thermal diffusivity of cloth, and fibrous inside can be inhaled
Attached filler plays solidification.
Embodiment
Embodiment 1：
A kind of preparation method of fire resistant carbon cloth, comprises the following steps:
（1）Blending：According to quality meter part weigh 65 parts of carbon fiber, 13 parts of aramid fiber, 5 parts of oil flax fibre, 5 parts of flax fiber,
3.6 parts of lemongrass fiber, 1.3 parts of print chinaberry fiber, aramid fiber have fire resistance, and flax, flax and lemongrass comfortableness are high, print chinaberry resistant fiber
Bacterium effect is good, and the fire resistance, comfortableness and antibiotic property of carbon cloth can be improved after blending, and above-mentioned each fibrous material blending is made into
Carbon cloth；
（2）Cleaning, drying：Carbon cloth is immersed in cleaning fluid and carries out heated wash, the adhesion of design on fabric surface work in-process can be removed
Foreign matter and metal powder, and can to fiber, burr caused by surface and slight crack are repaired in blending product, improve fiber
Comfortable feel and glossiness, moisture 7.5% is dried to after taking-up, cleaning carbon cloth is made；
（3）Surface reduction：Cleaning carbon cloth is placed in reactor and is passed through the CO gases of reactor cumulative volume 10.4%, one
Carbonoxide has stronger reducing power, can destroy the stable oxide layer of fiber surface formation, improves blend fibre surface-active
And adsorption capacity, preferably to adsorb and with reference to packing material, to react 34min at a temperature of 121 DEG C, be made and go back original carbon fiber
Cloth；
（4）Impregnation：Reduction carbon cloth is immersed into maceration extract, impregnation is carried out, is configured to using nanoscale maceration extract
Point, its granularity is small, preferably can be combined by fibers adsorption in cloth, is dried after taking-up and impregnation of carbon fibers cloth is made；
（5）Plasma：Impregnation of carbon fibers is arranged in plasma processor, voltage 220V, frequency 45kHz, source of the gas pressure are set
Strong 43kPa, ionization time 1.5h；Then, maceration extract then by carbon cloth after plasma treatment is immersed, is carried out at double-steeping
Reason, dried after taking-up and Treatment of Carbon cloth is made；Adsorption component can be strengthened to be combined with fiber, solidification is played to adsorption component and is made
With improving the stability of the chemical property of cloth, and plasma treatment can improve fiber surface activity, improve double-steeping
Effect；
（6）Oxidation processes：Treatment of Carbon is arranged in the ozone gas that reactor volume 8.6% is passed through in reactor, reactor
It is heated to 114 DEG C, reacts 44min, in reacted kettle after oxidation reaction, carbon cloth surface forms oxide-film, improves cloth
Stability, reflective and thermal diffusivity, and the filler that can be adsorbed to fibrous inside plays solidification, temperature drop rate
For 8 DEG C/3min, fire resistant carbon cloth is made after cooling.
Step（2）Described cleaning fluid, its compound method are：
103 parts of water, 15.6 parts of pseudo-ginseng, 12.8 parts of ginkgo leaf, 11 parts of ethanol, 9.5 parts of saponin(e, terebinth are weighed according to quality meter part
7.5 parts, pseudo-ginseng and ginkgo leaf are immersed in the water and boil heating 1.5h, obtains filtering solution after filtering, into filtering solution successively
Ethanol, saponin(e, terebinth are added, 59 DEG C is heated to, is stirred 16min, cleaning fluid is made.
Step（2）Described heated wash, its temperature are 86 DEG C, time 42min.
Step（3）Described maceration extract, its compound method are：
104 parts of water, 11.4 parts of nanoscale alundum (Al2O3), 5 parts of Firebrake ZB, Nano titanium dioxide are weighed according to quality meter part
7.2 parts, nanoscale alundum (Al2O3), Firebrake ZB and Nano titanium dioxide are added after boiling is boiled, is stirred 16min, made
Obtain maceration extract.
Step（4）Described impregnation, its temperature be 82 DEG C, time 46min, heating and cooling rate be 5 DEG C/
3min。
Step（5）Described double-steeping processing, its temperature are 74 DEG C, time 0.5h.
Embodiment 2：
Compared with embodiment 1, step changes in the following areas the present embodiment 2：
Step（1）Described carbon cloth, it is respectively configured to sub-prime gauge part and is：
68 parts of carbon fiber, 15 parts of aramid fiber, 7 parts of oil flax fibre, 7 parts of flax fiber, 5.5 parts of lemongrass fiber, print chinaberry fiber 1.8
Part.
Step（2）Described cleaning fluid, its compound method are：
107 parts of water, 17.4 parts of pseudo-ginseng, 14.5 parts of ginkgo leaf, 12.5 parts of ethanol, 10.3 parts of saponin(e, pine are weighed according to quality meter part
8.5 parts of grease, pseudo-ginseng and ginkgo leaf are immersed in the water boil heating 2h, after filtering filtering solution, into filtering solution according to
Secondary addition ethanol, saponin(e, terebinth, are heated to 61 DEG C, are stirred 19min, cleaning fluid is made.
Step（2）Described heated wash, its temperature are 87 DEG C, time 49min.
Step（3）Surface reduction, its technological parameter are：
CO gases intake is reactor cumulative volume 12%, and temperature is 123 DEG C, time 36min.
Step（3）Described maceration extract, its compound method are：
109 parts of water, 12.8 parts of nanoscale alundum (Al2O3), 6.7 parts of Firebrake ZB, Nano titanium dioxide are weighed according to quality meter part
8.6 parts, nanoscale alundum (Al2O3), Firebrake ZB and Nano titanium dioxide are added after boiling is boiled, is stirred 18min, made
Obtain maceration extract.
Step（4）Described impregnation, its temperature be 84 DEG C, time 48min, heating and cooling rate be 5 DEG C/
3min。
Step（5）Plasma, its technological parameter are：
Voltage 230V, frequency 40kHz, air source pressure intensity 50kPa, ionization time 2h.
Step（5）Described double-steeping processing, its temperature are 75 DEG C, time 1h.
Step（6）Oxidation processes, its technological parameter are：
Ozone intake is reactor volume 9.4%, and reaction temperature is 116 DEG C, reaction time 46min.
Contrast 1：
This contrast 1 does not carry out step compared with embodiment 1（2）Middle cleaning fluid is prepared and used, other steps and the phase of embodiment 1
Together.
Contrast 2：
This contrast 2 does not carry out step compared with embodiment 2（3）Middle CO reduction reactions, other steps are same as Example 2.
Contrast 3：
This contrast 3 does not carry out step compared with embodiment 2（4）Impregnation, other steps are same as Example 2.
Contrast 4：
This contrast 4 does not carry out step compared with embodiment 1（5）Middle plasma processor processing, other steps and the phase of embodiment 1
Together.
Contrast 5：
This contrast 5 does not carry out step compared with embodiment 1（6）Oxidation processes, other steps are identical with water embodiment 1.
Control group：
Control group, into cloth, is not used at other fibers, cleaning fluid, surface reduction, maceration extract and oxidation using carbon fiber textile
Reason.
To embodiment 1, embodiment 2, contrast 1, contrast 2, contrast 3, contrast 4, contrast 5 and control group experimental program, statistics
Fire resistance, ultraviolet lighting intensity, thermal diffusivity test and the deodorization of carbon cloth.
Fire resistance is：Carbon cloth is placed in alcolhol burner flame top, counts its burning time；
Ultraviolet lighting intensity：Under identical sunlight condition, UV power meter is placed in test ultraviolet light below carbon cloth
According to intensity, it is 327lux to test ultraviolet lighting intensity above carbon cloth.
Thermal diffusivity is tested：Under identical sunlight condition, thermometer is placed in test temperature below carbon fiber, and in carbon
Fiber cloth surface test temperature is 30.4 DEG C.
Experimental data：
| Project | Fire resistance S | Ultraviolet irradiation light intensity lux | Thermal diffusivity test DEG C | Deodorization |
| Embodiment 1 | 29 | 73.6 | 24.3 | Odorless |
| Embodiment 2 | 28 | 76.4 | 24.6 | Odorless |
| Contrast 1 | 27 | 87.3 | 24.5 | Odorless |
| Contrast 2 | 25 | 103.9 | 25.2 | Odorless |
| Contrast 3 | 24 | 107.6 | 25.8 | Slightly stink |
| Contrast 4 | 26 | 54.2 | 25.3 | Slightly stink |
| Contrast 5 | 24 | 36.8 | 25.6 | Slightly stink |
| Control group | 16 | 207.3 | 28.7 | There is stink |
Synthesis result：The made carbon cloth of the present invention, it is good with fire resistance, there is preferable blocking property to ultraviolet light and sunlight,
And there is deodorization functions, carbon fiber fabric soft comfortable.Using CO restoring method, fire resistance 3S, ultraviolet irradiation light can be improved
Strong to reduce 27.5lux, exothermic temperature reduces by 0.6 DEG C；Using maceration extract and plasma treatment, fire resistance 4S, 3S can be improved, it is ultraviolet
Irradiating light intensity reduces 31.2lux, 19.4lux, and exothermic temperature reduces by 1.2 DEG C, 1 DEG C；And oxidation processes are used, fire resistance can be improved
5S, ultraviolet irradiation light intensity reduce 36.8lux, and exothermic temperature reduces by 1.3 DEG C.
Claims (6)
1. a kind of preparation method of fire resistant carbon cloth, it is characterised in that comprise the following steps:
（1）Blending：Carbon fiber 64-69 parts, aramid fiber 12-16 parts, oil flax fibre 4-8 parts, flax are weighed according to quality meter part
Fiber 4-8 parts, lemongrass fiber 3-6 parts, print chinaberry fiber 1-2 parts, carbon cloth is made into by above-mentioned each fibrous material blending；
（2）Cleaning, drying：Carbon cloth is immersed in cleaning fluid and carries out heated wash, moisture 7%- is dried to after taking-up
10%, cleaning carbon cloth is made；
（3）Surface reduction：Cleaning carbon cloth is placed in reactor and is passed through reactor cumulative volume 9%-13% CO gases,
32-37min is reacted at a temperature of 120-124 DEG C, reduction carbon cloth is made；
（4）Impregnation：Carbon cloth will be reduced and immerse maceration extract, carry out impregnation, dried after taking-up and impregnated carbon fibre is made
Wei Bu；
（5）Plasma：Impregnation of carbon fibers is arranged in plasma processor, voltage 220-230V, frequency 30-45kHz are set,
Air source pressure intensity 40-60kPa, ionization time 1-2h；Then, maceration extract then by carbon cloth after plasma treatment is immersed, carries out two
Secondary impregnation, dried after taking-up and Treatment of Carbon cloth is made；
（6）Oxidation processes：Treatment of Carbon is arranged in the ozone gas that reactor volume 7%-10% is passed through in reactor, reacted
Kettle is heated to 113-117 DEG C, reacts 40-50min, and temperature drop rate is 8 DEG C/3min, and fire resistant carbon is made after cooling
Fiber cloth.
2. the preparation method of fire resistant carbon cloth as claimed in claim 1, it is characterised in that step（2）Described is clear
Washing lotion, its compound method are：
Water 100-110 parts, pseudo-ginseng 15-18 parts, ginkgo leaf 12-15 parts, ethanol 10-13 parts, saponin(e 9- are weighed according to quality meter part
11 parts, terebinth 7-9 parts, pseudo-ginseng and ginkgo leaf are immersed in the water and boil 1-2h, filtering solution are obtained after filtering, to filtering solution
In sequentially add ethanol, saponin(e, terebinth, be heated to 57-62 DEG C, be stirred 15-20min, be made cleaning fluid.
3. the preparation method of fire resistant carbon cloth as claimed in claim 1, it is characterised in that step（2）Described adds
Thermal cleaning, its temperature are 84-89 DEG C, time 40-50min.
4. the preparation method of fire resistant carbon cloth as claimed in claim 1, it is characterised in that step（3）Described leaching
Stain liquid, its compound method are：
Water 100-120 parts, nanoscale alundum (Al2O3) 11-13 parts, Firebrake ZB 4-7 parts, nanoscale two are weighed according to quality meter part
Titanium oxide 7-9 parts, nanoscale alundum (Al2O3), Firebrake ZB and Nano titanium dioxide are added after boiling is boiled, is stirred 15-
20min, maceration extract is made.
5. the preparation method of fire resistant carbon cloth as claimed in claim 1, it is characterised in that step（4）Described leaching
Stain processing, its temperature are 80-85 DEG C, time 45-50min, and heating and cooling rate are 5 DEG C/3min.
6. the preparation method of fire resistant carbon cloth as claimed in claim 1, it is characterised in that step（5）Described two
Secondary impregnation, its temperature are 72-76 DEG C, time 0.5-1h.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111172769A (en) * | 2020-02-25 | 2020-05-19 | 廖国庆 | Manufacturing process of anti-ultraviolet real silk fabric |
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