CN107385628A - Application of the PHB materials as new type natural antiseptic in textile preparation - Google Patents
Application of the PHB materials as new type natural antiseptic in textile preparation Download PDFInfo
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- CN107385628A CN107385628A CN201610327672.2A CN201610327672A CN107385628A CN 107385628 A CN107385628 A CN 107385628A CN 201610327672 A CN201610327672 A CN 201610327672A CN 107385628 A CN107385628 A CN 107385628A
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- Prior art keywords
- phb
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- fabric
- fiber
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Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Abstract
The present invention discloses application of the PHB materials as new type natural antiseptic in textile preparation.Melted in extrusion equipment of the compound injection with heater that pure PHB or PHB polymer is mixed with other polymer or copolymer, 190~225 DEG C, 300~1500m/ point is lower collects fibers, be made that FDY length is fine or routinely short fibre is made in short fine technique by draw ratio 2~4.When preparing fabric, PHB long filaments or spun yarn line can be used completely, it is also possible to which PHB fiber and other fibrous materials are mixed to be knitted or blending prepares fabric.PHB has the characteristics that antibiotic rate is high, antibiotic property is lasting, nontoxic, good biocompatibility as a kind of new type natural environment-friendly antibacterial material of bio-based completely.The fabric of the obtained various PHB fibers containing different proportion all has excellent antibiotic property, and after the washing of 20 times is undergone, remains on good antibacterial functions.
Description
Technical field
The invention belongs to technical field of polymer materials, is related to a kind of new bio high polymer material：
Applications of the poly- 3-hydroxybutyrate ester PHB as new type natural antiseptic in textile preparation.
Background technology
With sharply increasing for production capacity, China has become the main processing base of world's fiber product,
But due to identicalization of product variety, each manufacturing enterprise is caused inevitably to enter at a low price
Among the vicious circle of competition so that the profit margin of enterprise significantly declines, or even loses.
To change this state, each enterprise all increases the exploitation dynamics of new product, makes every effort to pass through difference
Change, the exploitation of functionalization, create the new market opportunity, increase new profit growth point for enterprise.
Because in daily life, people can constantly touch various microorganisms, wherein wrapping
Included some pathogenic bacteria or possible pathogenic bacteria (under certain condition, such as temperature, humidity, can
It is converted into the microorganism with pathogenicity), so as to influence the health of people and normal life.
All kinds of textiles have high specific surface area, therefore, are usually dwelt as the optimal of these microorganisms
Breath ground.Microorganism after amount reproduction, may make textile peculiar smell occur, and make on the textile
The important propagating source as pathogenic microorganisms.Therefore, weaving of the exploitation with certain antibacterial functions
Product has become a kind of embodiment of textile enterprise's innovation ability.
The preparation method of existing antibiotic fabric can be divided mainly into Physical and chemical method.Physical refers to
By antiseptic by soaking, padding, coating, co-blended spinning the methods of make fabric substrate and antiseptic
With reference to so that fabric has certain antibacterial functions.Antibiotic fabric made from this method is because antibacterial
Agent exists only in the top layer of fabric fibre substantially, so, have it is not washable, antibacterial effect is not lasting
The shortcomings that.Chemical method refers to antiseptic being attached on fabric fibre in a manner of chemical bond, the party
Method can be such that antiseptic is relatively securely attached on fiber, and antibacterial effect is more lasting, compensate for thing
The deficiency of logos.In addition, by by the fibrous material with natural antibacterial, as chitosan is fine
Dimension, hemp, bamboo fibre etc., fabric is made by blending with other fibers, makes it have one
The method of fixed long-term antimicrobial efficiency is also widely used for industry.
Except having the material of natural antibacterial as described above, the antiseptic that industry uses at present is main
Organic/inorganic substance (including the metal such as silver, copper, zinc or its ion, and zinc oxide, cupric oxide, phosphorus
Acid dihydride ammonium, lithium carbonate etc.) and organic matter (carbamide compounds, anilid class, imidazoles,
Thiazoles, isothiazolone derivative, quaternary ammonium salt, double croak classes, phenols etc., organic antibacterial agent
Security is still under study for action.In general organic antibacterial agent heat resistance is poor, easily hydrolysis, effectively
Phase is shorter).
Patent 92109288.1,200510024709.6,97198782.3,200410005034.6,
200710015171.1、200680003810.6、01127382.8、200810015190.9、
20051007055.6、201010254804.6、201210386338.6、201210046801.2、
201010285121.7th, 201210311094.5 etc. the technical scheme, all it is by that will have
The inorganic matter and organic matter of antibacterial functions are blended into fabric；Or by the monomer containing antibacterial group
Or fiber or fabric are attached to by chemical reaction containing the monomer that can be converted into antibiotic property group
Surface；Or by the functional group conversions on fabric fibre surface be the group with antibiotic property, so as to real
The antibiotic property of existing fabric.At present, with the sustainable growth of people's environmental consciousness, to using various nothings
Machine and organic matter propose worry as the fabric of antiseptic to the long-term safety of human body and environment,
Therefore, opened using antibiotic fabric of natural, the nontoxic material as antibacterial functions matrix
Hair has increasingly obtained the attention of industry.Patent 201210476977.1,201210475571.1,
200910182606.0 technical schemes used are to gather natural antimicrobial substance hemp, shell respectively
Sugar, bamboo fibre and the blending of other fibrous materials are spinned, and knitting with certain antibacterial functions is then made
Thing.The antibacterial effect of such scheme by the content of antibacterial material influenceed it is huge (referring to comparative example 1,2,
3), or cost is very high (such as chitin fiber), therefore, leverages its extensive industrialization
Application.
Poly- 3-hydroxybutyrate ester (PHB) is using reproducible starch as primary raw material, and utilization is special
Bio-fermentation engineering production new bio high polymer material, be a kind of natural environmentally friendly material
Material.
The content of the invention
The purpose of the present invention is to be directed to current antibiotic fabric industry common problem, there is provided one
Brand-new material-poly- 3-hydroxybutyrate the ester (PHB) with natural special antibacterial functions of kind, is somebody's turn to do
Fiber made of material need not add any inorganic, organic antibacterial agent, i.e., with excellent antibacterial work(
Can, and antibiotic property is lasting, at present, makes without any document and patent using this material as antiseptic
With.
Poly- 3-hydroxybutyrate ester (PHB) has following general structure：
Wherein R is methyl；M is 1；N is 5~25000 random natural number.
PHB materials of the present invention as new type natural antiseptic textile preparation in concrete application such as
Under：
PHB materials are a kind of thermoplastics, it is therefore possible to use the melt spinning legal system of environmental protection
The long filament or short fibre, preferred scheme of standby all size are as follows：(1) it is pure 70 DEG C of PHB polymer is true
Sky is dried；Or PHB polymer is distinguished into 70 DEG C of progress vacuum with other polymer or copolymer and done
It is dry, physical mixed is then carried out in proportion；(2) by pure PHB or compound injection with heating dress
Melted in the extrusion equipment put, then the spinning temperature at 190~225 DEG C, 300~1500m/ point
Spinning speed under collect fiber, be made that FDY length is fine or routinely short fine work by draw ratio 2~4
Short fibre is made in skill.When preparing fabric, PHB long filaments or spun yarn line can be used completely, it is also possible to PHB
Fiber and other fibrous materials are mixed to be knitted or blending prepares fabric.It is obtained various to contain according to experiment
The fabric of different proportion PHB fiber all has excellent antibiotic property, and in the washing for undergoing 20 times
Afterwards, good antibacterial functions are remained on.
Above-mentioned other polymer or copolymer include：PBAT (terephthalic acid (TPA), adipic acid, fourth two
Alcohol copolyesters) etc. resin.Other fibrous materials include：Cotton, silk or spun silk, tencel, copper
Ammonia fiber, viscose rayon etc..
The beneficial effects of the invention are as follows：Anti-biotic material natural environmental-protective, the antibacterial effect that the present invention uses
Well, antibacterial is lasting, cost is low, technique is simple, is adapted to industrialized production.
Embodiment
Technical scheme and effect are made with reference to comparative example and embodiment further
Description, but the invention is not limited in the proportioning and method that embodiment is shown, it is any to be based on these
The change that the combination of materials shown of embodiment and the those skilled in the art of method can associate easily
Change, belong to the scope of the present invention.
Poly- 3-hydroxybutyrate ester (PHB) has following general structure：
Wherein R is methyl；M is 1；N is 5~25000 random natural number.
PHB materials of the present invention as new type natural antiseptic textile preparation in concrete application such as
Under：
PHB materials are a kind of thermoplastics, it is therefore possible to use the melt spinning legal system of environmental protection
The long filament or short fibre, preferred scheme of standby all size are as follows：(1) it is pure 70 DEG C of PHB polymer is true
Sky is dried；Or PHB polymer is distinguished into 70 DEG C of progress vacuum with other polymer or copolymer and done
It is dry, physical mixed is then carried out in proportion；(2) by pure PHB or compound (PHB in compound
Mass content be 1~45 ﹪) injection with heater extrusion equipment in melt, Ran Hou
Fiber is collected under 190~225 DEG C of spinning temperature, 300~1500m/ points of spinning speed, by leading
Stretch and be made that FDY is long fine or routinely short fibre is made in short fine technique than 2~4., can when preparing fabric
Use PHB long filaments or spun yarn line completely, it is also possible to PHB fiber and other fibrous materials are mixed knit or
Blending prepares fabric.According to experiment, the fabric of the obtained various PHB fibers containing different proportion is all
With excellent antibiotic property, and after the washing of 20 times is undergone, remain on good antibacterial work(
Energy.
Above-mentioned other polymer or copolymer include：PBAT (terephthalic acid (TPA), adipic acid, fourth two
Alcohol copolyesters) etc. resin.Other fibrous materials include：Cotton, silk or spun silk, tencel, copper
Ammonia fiber, viscose rayon etc..
Comparative example 1：Chitosan CS and polylactic acid PLA mixing Static Spinning non-woven cloth
Using chitosan and the Static Spinning non-woven cloth of polylactic acid blend, by GB15979-2002, shake
The method of swinging is measured.The measurement result of antibiotic rate is following (quoted from document《Material Leader B：Research
》, in September, 2012 the 9th phase of volume 26)：.
From Analysis of test results, when chitosan mass content >=20%, the antibiotic rate of fabric just may be used
95% can be higher than.
Comparative example 2：Hemp
Fabric is made into using pure hemp and hemp and silk/cotton blended yarn respectively, antibiotic rate
Measurement result is as follows：(quoted from document《Hemp is knitted the research of product natural antibacterial》,《Knitting
Industry》In December, 2009, antibiotic property measure establishing criteria FZ/T73023--2006《Antibiosis knitting
Product》The succusion of middle AA ranks is carried out)
Comparative example 3：The resistance to cleaning experiment of commercial antimicrobial fabric.Wash conditions：Neutral detergent, often
Warm water, wash 30 minutes, rinsed clean, 50 DEG C of dryings, be repeated 20 times.Antibacterial tests：Press
Standard AATCC-100-2012, absorption process are measured.Test strain：Staphylococcus aureus
ATCC6538,
Comparative example 3：The resistance to cleaning experiment of commercial antimicrobial fabric.Wash conditions：Neutral detergent, often
Warm water, wash 30 minutes, rinsed clean, 50 DEG C of dryings, be repeated 20 times.Antibacterial tests：Press
Standard AATCC-100-2012, absorption process are measured.Test strain：Staphylococcus aureus
ATCC6538,
In following examples, standard AATCC-100-2012 is all pressed in the detection of antibiotic rate, and absorption process is entered
Row measure.PHB, PLA, PBAT specimen material respectively from Ningbo Tianan Biological Material Co., Ltd.,
NATUREWORKS companies of the U.S., BASF Corp. of Germany.Tencel, viscose rayon, cotton, copper
Ammonia fiber, silk, spun silk are short fine directly from the purchase of textile raw material market.
Embodiment 1：Pure PHB fiber, FDY filament
2000 grams of PHB samples are taken, 70 DEG C of vacuum drying, 225 DEG C of spinning temperatures, 300m/ points are spun
Silk speed, melt spinning, then 2 times of drawing-offs are made FDY fiber, and knitting is into cloth.Cleaning is spun
After silk oiling agent, drying, sample preparation, antibiotic property is detected.
Embodiment 2：PHB (45%) and PLA (55%) co-blended spinning, FDY filament
450 grams of PHB, 550 grams of PLA samples are taken, are made respectively after 70 DEG C of vacuum drying with twin-screw
Grain machine mixing granulation, blending resin is dried in vacuo, and 215 DEG C of spinning temperatures, 600m/ divide spinning fast
Degree, melt spinning, then 2.5 times of drawing-offs are made PHB/PLA alloy FDY fibers, knitting into
Cloth.After cleaning spinning oil, drying, sample preparation, antibiotic property is detected.
Embodiment 3：PHB (20%) and PLA (80%) co-blended spinning, FDY filament
200 grams of PHB, 800 grams of PLA samples are taken, are made respectively after 70 DEG C of vacuum drying with twin-screw
Grain machine mixing granulation, blending resin is dried in vacuo, and 210 DEG C of spinning temperatures, 900m/ divide spinning fast
Degree, then 2 times of drawing-offs are made PHB/PLA alloy FDY fibers, and knitting is into cloth.Clean spinning
After finish, drying, sample preparation, antibiotic property is detected.
Embodiment 4：PHB (30%) and PLA (70%) co-blended spinning, FDY filament
300 grams of PHB, 700 grams of PLA samples are taken, are made respectively after 70 DEG C of vacuum drying with twin-screw
Grain machine mixing granulation, blending resin is dried in vacuo, 190 DEG C of spinning temperatures, 1000m/ divide spinning
Speed, then 3 times of drawing-offs are made PHB/PLA alloy FDY fibers, and knitting is into cloth.Cleaning is spun
After silk oiling agent, drying, sample preparation, antibiotic property is detected.
Embodiment 5：PHB (10%) and PLA (90%) co-blended spinning, FDY filament
100 grams of PHB, 900 grams of PLA samples are taken, are made respectively after 70 DEG C of vacuum drying with twin-screw
Grain machine mixing granulation, blending resin is dried in vacuo, 210 DEG C of spinning temperatures, 1500m/ divide spinning
Speed, then 2.5 times of drawing-offs are made PHB/PLA alloy FDY fibers, and knitting is into cloth.Cleaning
After spinning oil, drying, sample preparation, antibiotic property is detected.
Embodiment 6：PHB/PLA blend staples (55%) and spun silk (45%) yarn
PHB/PLA long filaments made from Example 2, routinely short fine technique length 38mm is made
Short fine (draw ratio 3), take 550 grams of this short fibres, made after being sufficiently mixed with 450 grams of short fibres of spun silk
Into yarn, knitting is into cloth.After the finish of cleaning gained cloth, drying, sample preparation, antibacterial is detected
Property.
Embodiment 7：PHB/PLA blend staples (40%) and cotton (60%) yarn
PHB/PLA long filaments made from Example 3, routinely short fine technique length 52mm is made
Short fine (draw ratio 3), take 400 grams of this short fibres, yarn be made after being sufficiently mixed with 600 grams of cottons,
Knitting is into cloth.After the finish of cleaning gained cloth, drying, sample preparation, antibiotic property is detected.
Embodiment 8：PHB/PLA blending FDY fibers (50%) and silk (50%)
PHB/PLA alloys FDY fiber made from Example 4.Using silk as warp, PHB/PLA
Alloy FDY fiber is parallel, and tatting method is into cloth.Cloth is cleaned, drying, sample preparation, detects antibacterial
Property.
Embodiment 9：PHB/PLA blending FDY filaments (50%) and CUP long filament (50%)
PHB/PLA alloys FDY fiber made from Example 5.Using CUP long filament as warp,
PHB/PLA alloys FDY fiber is parallel, and tatting method is into cloth.Cloth is cleaned, is dried, sample preparation,
Detect antibiotic property.
Embodiment 10：PHB long filaments (50%) and tencel (50%)
PHB FDY fibers made from Example 1.Using tencel as warp, PHB FDY fiber
For parallel, tatting method is into cloth.Cloth is cleaned, drying, sample preparation, detects antibiotic property.
Embodiment 11：PHB short fine (35%) and short rayon fiber (65%)
PHB long filaments made from Example 1, routinely short fine technique the short of length 52mm is made
Fine (draw ratio 3), takes 350 grams of this short fibres, yarn is made after being sufficiently mixed with 650 grams of short rayon fibers
Line, knitting is into cloth.After the finish of cleaning gained cloth, drying, sample preparation, antibiotic property is detected.
The antibiotic property measurement result such as following table of each embodiment：
Claims (9)
- Application of the 1.PHB materials as new type natural antiseptic in textile preparation.
- 2. application as claimed in claim 1, it is characterised in that PHB materials have following structure Formula：Wherein R is methyl, and m 1, n are 5~25000 random natural number.
- 3. application as claimed in claim 1, it is characterised in that the raw material of textile are only pure PHB。
- 4. application as claimed in claim 1, it is characterised in that the raw material of textile are PHB With other polymer or it is copolymer blended after batch mixing, wherein PHB mass content is 1~45 ﹪.
- 5. application as claimed in claim 4, it is characterised in that other polymer or copolymer bags Include：Terephthalic acid (TPA), adipic acid, butanediol copolyester.
- 6. application as claimed in claim 1, it is characterised in that carried out using melt spinning method Fiber is collected, spinning temperature is 170~225 DEG C, and spinning speed is 300~3000m/ points.
- 7. application as claimed in claim 6, it is characterised in that fiber presses 2~4 times of draw ratio FDY is made and grows fine or short fibre.
- 8. application as claimed in claim 7, it is characterised in that when preparing fabric, can all adopt Fine or spun yarn line is grown with FDY, or PHB fiber and other fibrous materials are mixed knits or blending prepares face Material.
- 9. application as claimed in claim 8, it is characterised in that other fibrous materials include：Cotton, Silk, spun silk, tencel, CUP, viscose rayon etc..
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| CN201610327672.2A CN107385628A (en) | 2016-05-17 | 2016-05-17 | Application of the PHB materials as new type natural antiseptic in textile preparation |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110452121A (en) * | 2018-05-08 | 2019-11-15 | 香港纺织及成衣研发中心 | A kind of bio-based materials and purposes with antibacterial action |
| CN113913474A (en) * | 2020-10-26 | 2022-01-11 | 浙江英玛特生物科技有限公司 | Efficient antibacterial hydroxy acid ester oligomer |
| WO2023241615A1 (en) * | 2022-06-14 | 2023-12-21 | 北京微构工场生物技术有限公司 | Wig fiber and preparation method therefor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1569923A (en) * | 2003-07-23 | 2005-01-26 | 上海塑杰科技有限公司 | Polyamine guanidine salt copolymer and its uses in antibiotic polyester and polyamide materials |
| CN1847477A (en) * | 2004-12-22 | 2006-10-18 | 纤维创新技术公司 | Biodegradable fibers exhibiting storage-stable tenacity |
| CN101735636A (en) * | 2008-11-12 | 2010-06-16 | 福建恒安集团有限公司 | Biodegradation time controlled plastic film and preparation method thereof |
| WO2013062994A1 (en) * | 2011-10-25 | 2013-05-02 | Biomimetic Therapeutics, Inc. | Compositions and methods for treating full thickness burn injuries |
| CN106149127A (en) * | 2015-05-14 | 2016-11-23 | 瑞比奥科技有限公司 | Assorted fibre material |
-
2016
- 2016-05-17 CN CN201610327672.2A patent/CN107385628A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1569923A (en) * | 2003-07-23 | 2005-01-26 | 上海塑杰科技有限公司 | Polyamine guanidine salt copolymer and its uses in antibiotic polyester and polyamide materials |
| CN1847477A (en) * | 2004-12-22 | 2006-10-18 | 纤维创新技术公司 | Biodegradable fibers exhibiting storage-stable tenacity |
| CN101735636A (en) * | 2008-11-12 | 2010-06-16 | 福建恒安集团有限公司 | Biodegradation time controlled plastic film and preparation method thereof |
| WO2013062994A1 (en) * | 2011-10-25 | 2013-05-02 | Biomimetic Therapeutics, Inc. | Compositions and methods for treating full thickness burn injuries |
| CN106149127A (en) * | 2015-05-14 | 2016-11-23 | 瑞比奥科技有限公司 | Assorted fibre material |
Non-Patent Citations (5)
| Title |
|---|
| A.NICOSIA,ECT.: "Air filtration and antimicrobial capabilities of electrospun PLA/PHB containing ionic liquid", 《SEPARATION AND PURIFICATION TECHNOLOGY》 * |
| 戈进杰: "《生物降解高分子材料及其应用》", 30 September 2002, 化学工业出版社 * |
| 李梅等: "环丙沙星-聚羟基丁酸酯电纺纤维毡的制备、性质及抑菌活性研究", 《化学研究与应用》 * |
| 王建龙: "《现代环境生物技术》", 30 September 2008, 清华大学出版社 * |
| 范晓燕等: "聚羟基丁酸酯（PHB）抗菌薄膜的制备与性能研究", 《功能材料》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110452121A (en) * | 2018-05-08 | 2019-11-15 | 香港纺织及成衣研发中心 | A kind of bio-based materials and purposes with antibacterial action |
| CN113913474A (en) * | 2020-10-26 | 2022-01-11 | 浙江英玛特生物科技有限公司 | Efficient antibacterial hydroxy acid ester oligomer |
| WO2023241615A1 (en) * | 2022-06-14 | 2023-12-21 | 北京微构工场生物技术有限公司 | Wig fiber and preparation method therefor |
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Application publication date: 20171124 |