CN107384015A - A kind of aqueous, environmental protective metal aluminum foil ink and its preparation method and application - Google Patents
A kind of aqueous, environmental protective metal aluminum foil ink and its preparation method and application Download PDFInfo
- Publication number
- CN107384015A CN107384015A CN201710822803.9A CN201710822803A CN107384015A CN 107384015 A CN107384015 A CN 107384015A CN 201710822803 A CN201710822803 A CN 201710822803A CN 107384015 A CN107384015 A CN 107384015A
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- CN
- China
- Prior art keywords
- emulsion
- ink
- aqueous
- aluminum foil
- metal aluminum
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
Abstract
A kind of aqueous, environmental protective metal aluminum foil ink and its preparation method and application, ink comprises the following raw materials by weight percent：Water soluble acrylic acid self-crossing emulsion 10 ~ 30%, not modified aqueous acrylic acid resin 5 ~ 15%, film forming styrene-acrylic emulsion 30 ~ 50%, oxidized polyethylene wax emulsion 5 ~ 7%, pure water 13 ~ 15%, edible ethanol 5 ~ 10%, levelling agent 0.05 ~ 2.5%, dipropylene glycol methyl ether 0.5 ~ 1.0% and defoamer 0.05 ~ 2.5%.Ink print of the present invention is clear, and water-fast, ethanol and alkali, nondiscoloration fade, and production technology is to be carried out under normal temperature and pressure, no waste discharge.
Description
Technical field
The present invention relates to technical field of ink, and in particular to a kind of aqueous, environmental protective metal aluminum foil ink and preparation method thereof and
Using.
Background technology
In recent years, the features such as aluminium foil is because of its light weight, good leak tightness, good covering property, it is widely used in the neck such as food, medicine
Domain, with China's expanding economy and the progress of people's living standard, the health perception and environmental consciousness of people have reached packaging
The stricter quality standard of product.It is presently used for the aluminum foil ink of packaging, generally existing benzophenone content overproof, poisonous VOC
The defects of residual, against the raising of economic level, printing industry constantly develops to green print direction, each ink manufacture
Enterprise starts green engineering in research, it is intended to reduces pollution.
The content of the invention
The present invention is in order to overcome deficiency of the prior art, there is provided a kind of aqueous, environmental protective metal aluminum foil ink and its preparation
Methods and applications.
The technical scheme that the present invention takes is：A kind of aqueous, environmental protective metal aluminum foil ink, ink is by following percentage by weight
Raw material composition：Water soluble acrylic acid self-crossing emulsion 10 ~ 30%, not modified aqueous acrylic acid resin 5 ~ 15%, film forming styrene-acrylic emulsion
30 ~ 50%, oxidized polyethylene wax emulsion 5 ~ 7%, pure water 13 ~ 15%, edible ethanol 5 ~ 10%, levelling agent 0.05 ~ 2.5%, dipropyl two
Alcohol methyl ether 0.5 ~ 1.0% and defoamer 0.05 ~ 2.5%.
Preferably, ink comprises the following raw materials by weight percent：Water soluble acrylic acid self-crossing emulsion 20%, modified water
Property acrylic resin 10%, not film forming styrene-acrylic emulsion 40%, oxidized polyethylene wax emulsion 6%, pure water 13.4%, edible ethanol 10%,
Levelling agent 0.05%, dipropylene glycol methyl ether 0.5% and defoamer 0.05%.
In the present invention, water soluble acrylic acid self-crossing emulsion model A-1127, solid content 44%, viscosity 150mPas/23
DEG C, pH 7.5,7 DEG C of MFT, Tg：-18℃.
In the present invention, film forming styrene-acrylic emulsion model is not J-90, and outward appearance is translucent emulsion, solid content 44%, pH 8.3,
Viscosity is 200 cps/25 DEG C, acid number 76, MFT>85 DEG C, Tg：110℃.
In the present invention, oxidized polyethylene wax emulsion model 7605, solid content 35%, pH is 8.5 ~ 9.5, viscosity ＜ 200
MPas/25 DEG C, particle diameter 40nm.
The viscosity of ink of the present invention is：10 ~ 15 seconds/apply .25 DEG C of 4# cups, the viscosity was suitable, ink is had well
Transfer performance and printing quality, the ink layer of ink after packages printing are uniform.
A kind of preparation method of aqueous, environmental protective metal aluminum foil ink, comprises the following steps：Step 1: according to percentage by weight
Each raw material is weighed, part pure water is then taken, according to pure water：Defoamer：Levelling agent is 0.5：0.25：0.25 weight is than mixed
After being combined, 30min is stirred, then adds edible ethanol, dipropylene glycol methyl ether and remaining pure water, stirs 20min,
Diluent is made, it is standby；
Step 2: the oxidized polyethylene wax emulsion weighed is added into mixer, water soluble acrylic acid self-crosslinking is then sequentially added
After emulsion, modified aqueous acrylic acid resin and non-film forming styrene-acrylic emulsion, start mixer and stir 20 ~ 30min, emulsion is made, it is standby
With；
Step 3: diluent made from step 1 is added in emulsion made from step 2,30min is stirred, through 300 mesh sieve mistakes
Filter packaging, is made ink.
Present invention also offers a kind of application of aqueous, environmental protective metal aluminum foil ink in gold and silver paperboard.
Beneficial effect：The raw material of the present invention has good chemical resistance using water soluble acrylic acid self-crossing emulsion, can
For polyolefin, polyester, the surface ink of polyamide and membrane coat of aluminizing；Film forming styrene-acrylic emulsion does not have high glaze, quick-drying
Advantage；Oxidized polyethylene wax emulsion has that hardness height, fusing point height, abrasion-resistant, damage resistant, high glaze, feel be smooth, rapid draing
The advantages of, and particle diameter is small, film forming clear transparent；It is good with polymer emulsion compatibility.The diluent that the present invention uses, it can reduce
The viscosity of ink, it is not necessary to add organic solvent, product non-volatility organic matter and reduces production cost at environmental protection.
Embodiment
Technological means, creation characteristic and the purpose reached to realize the present invention readily appreciate, with reference to specific
Embodiment, the present invention is expanded on further, but scope of the present invention is not limited to be retouched in embodiment
The scope stated.
A kind of aqueous, environmental protective metal aluminum foil ink, ink comprise the following raw materials by weight percent：Water soluble acrylic acid is certainly
Crosslinked emulsions 10 ~ 30%, not modified aqueous acrylic acid resin 5 ~ 15%, film forming styrene-acrylic emulsion 30 ~ 50%, oxidized polyethylene wax emulsion 5
~ 7%, pure water 13 ~ 15%, edible ethanol 5 ~ 10%, levelling agent 0.05 ~ 2.5%, dipropylene glycol methyl ether 0.5 ~ 1.0% and defoamer
0.05~2.5%。
The present invention also provides a kind of application of aqueous, environmental protective metal aluminum foil ink in gold and silver paperboard.
In the present invention, water soluble acrylic acid self-crossing emulsion model A-1127（BASF self-crossing emulsion）, solid content
44%, 150mPas/23 DEG C of viscosity, pH 7.5,7 DEG C of MFT, Tg：-18℃.
In the present invention, film forming styrene-acrylic emulsion model is not J-90（Village minister emulsion）, outward appearance is translucent emulsion, solid content
44%, pH 8.3, viscosity are 200 cps/25 DEG C, acid number 76, MFT>85 DEG C, Tg：110℃.
In the present invention, oxidized polyethylene wax emulsion model 7605（Cray Wei Li waxes/PE waxes）, solid content 35%, pH is
8.5 ~ 9.5, mPas/25 DEG C of viscosity ＜ 200, particle diameter 40nm.
The viscosity of ink of the present invention is：10 ~ 15 seconds/apply .25 DEG C of 4# cups.
In the present invention, defoamer is Henkel DC-51, and levelling agent is Henkel BYK-028.
Embodiment 1
A kind of preparation method of aqueous, environmental protective metal aluminum foil ink, comprises the following steps：Step 1: weighed according to percentage by weight
Each raw material：Water soluble acrylic acid self-crossing emulsion 20%, modified aqueous acrylic acid resin 10%, film forming styrene-acrylic emulsion 40%, oxidation be not poly-
Ethene wax emulsion 6%, pure water 13.4%, edible ethanol 10%, levelling agent 0.05%, dipropylene glycol methyl ether 0.5% and defoamer
0.05%, it is standby；
Step 2: part pure water is then taken, according to pure water：Defoamer：Levelling agent is 0.5：0.25：0.25 weight is than mixed
After being combined, 30min is stirred, then adds edible ethanol, dipropylene glycol methyl ether and remaining pure water, stirs 20min,
Diluent is made, it is standby；
Step 3: the oxidized polyethylene wax emulsion weighed is added into mixer, water soluble acrylic acid self-crosslinking is then sequentially added
After emulsion, modified aqueous acrylic acid resin and non-film forming styrene-acrylic emulsion, start mixer and stir 20 ~ 30min, emulsion is made, it is standby
With；
Step 4: diluent made from step 2 is added in emulsion made from step 3,30min is stirred, through 300 mesh sieve mistakes
Filter packaging, is made ink.
Embodiment 2
A kind of preparation method of aqueous, environmental protective metal aluminum foil ink, comprises the following steps：Step 1: weighed according to percentage by weight
Each raw material：Water soluble acrylic acid self-crossing emulsion 10%, modified aqueous acrylic acid resin 5%, film forming styrene-acrylic emulsion 50%, oxidation be not poly-
Ethene wax emulsion 7%, pure water 15%, edible ethanol 7%, levelling agent 2.5%, dipropylene glycol methyl ether 1.0% and defoamer 2.5%,
It is standby；
Step 2: part pure water is then taken, according to pure water：Defoamer：Levelling agent is 0.5：0.25：0.25 weight is than mixed
After being combined, 30min is stirred, then adds edible ethanol, dipropylene glycol methyl ether and remaining pure water, stirs 20min,
Diluent is made, it is standby；
Step 3: the oxidized polyethylene wax emulsion weighed is added into mixer, water soluble acrylic acid self-crosslinking is then sequentially added
After emulsion, modified aqueous acrylic acid resin and non-film forming styrene-acrylic emulsion, start mixer and stir 20 ~ 30min, emulsion is made, it is standby
With；
Step 4: diluent made from step 2 is added in emulsion made from step 3,30min is stirred, through 300 mesh sieve mistakes
Filter packaging, is made ink.
Embodiment 3
A kind of preparation method of aqueous, environmental protective metal aluminum foil ink, comprises the following steps：Step 1: weighed according to percentage by weight
Each raw material：Water soluble acrylic acid self-crossing emulsion 30%, not modified aqueous acrylic acid resin 14.5%, film forming styrene-acrylic emulsion 30%, oxidation
Polythene wax emulsion 5%, pure water 13%, edible ethanol 5%, levelling agent 1.0%, dipropylene glycol methyl ether 0.5% and defoamer
1.0%, it is standby；
Step 2: part pure water is then taken, according to pure water：Defoamer：Levelling agent is 0.5：0.25：0.25 weight is than mixed
After being combined, 30min is stirred, then adds edible ethanol, dipropylene glycol methyl ether and remaining pure water, stirs 20min,
Diluent is made, it is standby；
Step 3: the oxidized polyethylene wax emulsion weighed is added into mixer, water soluble acrylic acid self-crosslinking is then sequentially added
After emulsion, modified aqueous acrylic acid resin and non-film forming styrene-acrylic emulsion, start mixer and stir 20 ~ 30min, emulsion is made, it is standby
With；
Step 4: diluent made from step 2 is added in emulsion made from step 3,30min is stirred, through 300 mesh sieve mistakes
Filter packaging, is made ink.
The present invention prepares emulsion using plurality of raw materials, and a variety of systems are reasonably combined, right suitable for the printing of senior middle school's low speed
There is the characteristics of sun-proof performance, adhesive force, excellent flexibility in aluminium foil film, and print post-processing cutting function admirable.The present invention
It is added with water, alcohols and a small amount of ethers in diluent, the printing after print is almost non-toxic.
By ink prepared by the present invention coated in gold and silver cardboard material, the performance of test ink after solidification can be water-fast
More than 50h, the ethanol of resistance to more than 100 times, resistance to 100 circle rub above；Ink print of the present invention is clear, water-fast, ethanol and
Alkali, nondiscoloration fade, and production technology is to be carried out under normal temperature and pressure, no waste discharge.
Claims (8)
- A kind of 1. aqueous, environmental protective metal aluminum foil ink, it is characterised in that：Ink comprises the following raw materials by weight percent：It is water-based Self-crosslinking acrylic emulsion 10 ~ 30%, not modified aqueous acrylic acid resin 5 ~ 15%, film forming styrene-acrylic emulsion 30 ~ 50%, the poly- second of oxidation Alkene wax emulsion 5 ~ 7%, pure water 13 ~ 15%, edible ethanol 5 ~ 10%, levelling agent 0.05 ~ 2.5%, dipropylene glycol methyl ether 0.5 ~ 1.0% And defoamer 0.05 ~ 2.5%.
- A kind of 2. aqueous, environmental protective metal aluminum foil ink as claimed in claim 1, it is characterised in that：Ink is by following weight percent The raw material composition of ratio：Water soluble acrylic acid self-crossing emulsion 20%, modified aqueous acrylic acid resin 10%, not film forming styrene-acrylic emulsion 40%, Oxidized polyethylene wax emulsion 6%, pure water 13.4%, edible ethanol 10%, levelling agent 0.05%, dipropylene glycol methyl ether 0.5% and disappear Infusion 0.05%.
- A kind of 3. aqueous, environmental protective metal aluminum foil ink as claimed in claim 1, it is characterised in that：Water soluble acrylic acid self-crosslinking breast Liquid model A-1127, solid content 44%, 150mPas/23 DEG C of viscosity, pH 7.5,7 DEG C of MFT, Tg：-18℃.
- A kind of 4. aqueous, environmental protective metal aluminum foil ink as claimed in claim 1, it is characterised in that：Not film forming styrene-acrylic emulsion model For J-90, outward appearance is translucent emulsion, solid content 44%, pH 8.3, and viscosity is 200 cps/25 DEG C, acid number 76, it is minimum into Film temperature>85 DEG C, Tg：110℃.
- A kind of 5. aqueous, environmental protective metal aluminum foil ink as claimed in claim 1, it is characterised in that：Oxidized polyethylene wax emulsion type Number be 7605, solid content 35%, pH be 8.5 ~ 9.5, mPas/25 DEG C of viscosity ＜ 200, particle diameter 40nm.
- A kind of 6. aqueous, environmental protective metal aluminum foil ink as claimed in claim 1, it is characterised in that：The viscosity of ink：10~15 .25 DEG C of second/painting 4# cups.
- 7. prepare a kind of method of aqueous, environmental protective metal aluminum foil ink as described in claim any one of 1-6, it is characterised in that Comprise the following steps：Step 1: weighing each raw material according to percentage by weight, part pure water is then taken, according to pure water：Defoamer：Levelling agent For 0.5：0.25：After 0.25 weight ratio mixes, stir 30min, then add edible ethanol, dipropylene glycol methyl ether with And remaining pure water, 20min is stirred, diluent is made, it is standby；Step 2: the oxidized polyethylene wax emulsion weighed is added into mixer, water soluble acrylic acid self-crosslinking is then sequentially added After emulsion, modified aqueous acrylic acid resin and non-film forming styrene-acrylic emulsion, start mixer and stir 20 ~ 30min, emulsion is made, it is standby With；Step 3: diluent made from step 1 is added in emulsion made from step 2,30min is stirred, through 300 mesh sieve mistakes Filter packaging, is made ink.
- A kind of 8. application of aqueous, environmental protective metal aluminum foil ink in gold and silver paperboard described in claim any one of 1-6.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710822803.9A CN107384015A (en) | 2017-09-13 | 2017-09-13 | A kind of aqueous, environmental protective metal aluminum foil ink and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710822803.9A CN107384015A (en) | 2017-09-13 | 2017-09-13 | A kind of aqueous, environmental protective metal aluminum foil ink and its preparation method and application |
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| Publication Number | Publication Date |
|---|---|
| CN107384015A true CN107384015A (en) | 2017-11-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710822803.9A Pending CN107384015A (en) | 2017-09-13 | 2017-09-13 | A kind of aqueous, environmental protective metal aluminum foil ink and its preparation method and application |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093079A (en) * | 2019-06-04 | 2019-08-06 | 中山市海恒包装材料有限公司 | Ensure the environment protecting water-based paint and production technology of cigarette wrapper printing planarization |
| CN115058149A (en) * | 2022-06-29 | 2022-09-16 | 深圳市凌普鑫科技有限公司 | Quick-drying composite water-based ink and preparation method thereof |
| CN115449244A (en) * | 2022-09-05 | 2022-12-09 | 苏州海顺包装材料有限公司 | Water-based primer coating for PTP and PTP cover film |
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| US20060092253A1 (en) * | 2002-12-11 | 2006-05-04 | Murray Figov | Offset printing blank and method of imaging by ink jet |
| CN102286229A (en) * | 2011-08-24 | 2011-12-21 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Environment-friendly aqueous aluminum foil ink and preparation method thereof |
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| CN106566400A (en) * | 2016-10-26 | 2017-04-19 | 上海维凯光电新材料有限公司 | Water varnish for protection of printable aluminum foil for drug packing and preparation method of water varnish |
-
2017
- 2017-09-13 CN CN201710822803.9A patent/CN107384015A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060092253A1 (en) * | 2002-12-11 | 2006-05-04 | Murray Figov | Offset printing blank and method of imaging by ink jet |
| CN102286229A (en) * | 2011-08-24 | 2011-12-21 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Environment-friendly aqueous aluminum foil ink and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093079A (en) * | 2019-06-04 | 2019-08-06 | 中山市海恒包装材料有限公司 | Ensure the environment protecting water-based paint and production technology of cigarette wrapper printing planarization |
| CN115058149A (en) * | 2022-06-29 | 2022-09-16 | 深圳市凌普鑫科技有限公司 | Quick-drying composite water-based ink and preparation method thereof |
| CN115449244A (en) * | 2022-09-05 | 2022-12-09 | 苏州海顺包装材料有限公司 | Water-based primer coating for PTP and PTP cover film |
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Application publication date: 20171124 |
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