CN107375062A - A kind of extract containing persimmon without silicone oil shampoo and preparation method thereof - Google Patents

A kind of extract containing persimmon without silicone oil shampoo and preparation method thereof Download PDF

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Publication number
CN107375062A
CN107375062A CN201710568309.4A CN201710568309A CN107375062A CN 107375062 A CN107375062 A CN 107375062A CN 201710568309 A CN201710568309 A CN 201710568309A CN 107375062 A CN107375062 A CN 107375062A
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Prior art keywords
persimmon
silicone oil
component
shampoo
extract
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CN201710568309.4A
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CN107375062B (en
Inventor
李燕杰
万洁
李永强
温霖
李爱民
李颖
曹光群
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NEW AGE HEALTH INDUSTRY(GROUP) CO Ltd
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NEW AGE HEALTH INDUSTRY(GROUP) CO Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30Characterized by the absence of a particular group of ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30Characterized by the absence of a particular group of ingredients
    • A61K2800/34Free of silicones

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Botany (AREA)
  • Biotechnology (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to a kind of extract containing persimmon without silicone oil shampoo and preparation method thereof, the shampoo includes:(a) persimmon extract, (b) anion surfactant, (c) cationic surfactant, (d) nonionic surfactant and/or amphoteric surfactant, (e) cosmetic additive agent, and (f) glycerine.The shampoo can have the wet cardability for improving hair and dry cardability, hair is kept bright, smooth.

Description

A kind of extract containing persimmon without silicone oil shampoo and preparation method thereof
Technical field
The present invention relates to one kind without silicone oil shampoo, more particularly to a kind of extract containing persimmon without silicone oil shampoo, category In field of daily chemicals.
Background technology
One of shampoo cleaning supplies indispensable in daily life, the purpose of shampoo are that removing is attached to Dirt and taste on hair, keep the cleaning of hair attractive in appearance.Nowadays requirement of the people to shampoo not only stops In cleaning action, and more focus on carefully enriching, detergency well degreasing within reason again using the details such as sensation, such as foam, be easy to Rinse, it is non-stimulated etc..
The common shampoo of in the market is Two-in-one shampoo mostly, so-called Two-in-one shampoo, that is to say, that previous washes Hair only has cleaning capacity, and this shampoo that with the addition of the conditioners such as silicone oil is that have nursing function simultaneously, " cleaning+ Nursing ", it is exactly the core of Two-in-one shampoo.For many years, the shampoo 99% on domestic market is above is the tune of addition silicone oil Manage Two-in-one shampoo.
Silicone oil is added in shampoo, the main correct submissive effect of initiation, but it is not soluble in water, easy film forming, encases hair Hole.How to be washed by water again when hair washing, can all there is certain residual on hair and scalp, so can just build submissive sense Feel.But the shampoo of long-term use of silicate-containing oil, hair can follow the string, hair follicle be blocked and can not eubolism.It is if long-term Using siliceous shampoo, silicone oil deposited on hair it is more, just occur the more wash the more oily, scalp itch, even continue a large amount of The problem of alopecia.
The problem of due to above-mentioned silicone oil, occur currently on the market much without silicone oil shampoo, but washed mostly without silicone oil Shampoo is using wax and grease as hair conditioner, and its cardability effect is far away from there is silicone oil shampoo.
Persimmon is a kind of very common fruit, and persimmon mainly contains glucide, there is fructose, glucose, sucrose, and black bearberry is pungent The pentacyclic triterpenoids such as ester, ursolic acid cyclohexyl, fragrant resin alcohol hexyl ether, armomadendrin, black bearberry methyl esters.Also containing perfume in persimmon The mineral matters such as oxalic acid, tannin, the calcium of niacin and needed by human body, phosphorus, magnesium, iron.In addition, also containing protein and enriched in persimmon Vitamin, inorganic salts, pectin, starch etc..Persimmon typically in medicine and dye field, is used for detergents and cosmetic by the purposes of persimmon Had not been reported in product, especially shampoo.
The content of the invention
For drawbacks described above, the present inventor is to provide one kind without silicone oil shampoo by Improvement purpose, and it is than Know that product can preferably meet the needs of consumers in general, its dry and wet cardability effect surpasses prior art, and being capable of holding head It is luminance, smooth.
To achieve the above object, the present invention includes following technical scheme:
A kind of extract containing persimmon without silicone oil shampoo, it includes following components:
(a) persimmon extract,
(b) anion surfactant,
(c) cationic surfactant,
(d) nonionic surfactant and/or amphoteric surfactant,
(e) cosmetic additive agent, and
(f) glycerine.
As described above the extract containing persimmon without silicone oil shampoo, it is preferable that it is total that the persimmon extract accounts for shampoo (0.1~5) % of weight.
As described above the extract containing persimmon without silicone oil shampoo, it is preferable that the shampoo includes:
(a) (0.1~5) weight % persimmon extract,
(b) 5~25 weight % anion surfactant,
(c) 0.01~0.5 weight % cationic surfactant,
(d) 1~15 weight % nonionic surfactant and/or amphoteric surfactant,
(e) 1~10% cosmetic additive agent, and
(f) 100 weight % glycerine is added to.
As described above the extract containing persimmon without silicone oil shampoo, it is preferable that the anion surfactant is:Alkane Base sulfate, fatty alcohol ether sulphate, aliphatic acid isethionate, fatty acyl sarcosinates, fatty acyl group glutamate and/ Or N- acyl methyl taurine salts.More preferably poly alkyl alcohol ether sulfate, such as sodium laureth sulfate;With fatty acyl group paddy ammonia Hydrochlorate, such as sodium lauroyl glutamate.
As described above the extract containing persimmon without silicone oil shampoo, it is preferable that the cationic surfactant is:Third The homopolymer of olefin(e) acid or methacrylic acid ethyl-trimethyl salmiac (polyquaternium -37), hydroxyethyl cellulose and diallyl The quaternary copolymer (polyquaternium -4) of ammonium chloride, the polymerization of the hydroxyethyl cellulose of the epoxide modification substituted with trimethylammonium Quaternary ammonium salt (Polyquaternium-10), quaternized depolymerised guar gum derivative (guar hydroxypropyltrimonium ammonium chloride), cation Cellulose and derivative, cation guar gum and derivative and/or quaternary ammonium compound.Preferably polyquaternium -7, polyquaternium - 10 and/or guar hydroxypropyltrimonium ammonium chloride.
As described above the extract containing persimmon without silicone oil shampoo, it is preferable that the other surfaces activating agent is:It is polynary Alcohol fatty acid ester, APG and/or aliphatic acid N- alkyl glucose amides, alkyl betaine, alkyl amido betaine, imidazoles Quinoline glycine betaine and/or sulfobetaines.
As described above the extract containing persimmon without silicone oil shampoo, it is preferable that the cosmetic additive agent be emulsifying agent, Pearling agent, stabilizer, salt, thickener, consistency modifiers, pigment, preservative, antioxidant, anti-dandruff agent and/or biological source activity Composition.
As described above the extract containing persimmon without silicone oil shampoo, it is preferable that the biological source active component is plant Extract, hyaluronic acid, protein hydrolysate, peptide and/or vitamin complexes.
As described above the extract containing persimmon without silicone oil shampoo, it is preferable that the plant extracts be ginseng, He Shou Crow, mulberry leaf, the extract of radix glycyrrhizae and/or ginger.
As described above the extract containing persimmon without silicone oil shampoo, it is preferable that the preparation method of the persimmon extract Comprise the steps of:
(1) persimmon of maturation is cleaned with water, then surface sterilization is carried out with 5~15%NaOH solution, then again with net Water is rinsed well;
(2) persimmon obtained by step (1) is put into pulverizer and breaks into pulpous state;
(3) by persimmon slurries obtained by step (2), its use is more than 500 mesh filter-cloth filterings, collects filtrate;
(4) preservative is added to filtrate obtained by step (3).
As described above the extract containing persimmon without silicone oil shampoo preparation method, it is preferable that this method includes following step Suddenly:
(1) the stabilizer EDTA- disodiums in component (b), component (d) and component (e) are mixed together stirring, dissolved by heating And to 80~90 DEG C, obtain component one;
(2) component (c) is added in component (f), is heated to 80~90 DEG C or so, obtains component two;
(3) component one and component two are mixed evenly, add component (a) and the biological source activity in component (e) into Point, stir, be cooled to 50~55 DEG C, the essence added in component (e), with lemon acid for adjusting pH 5.5~6.5, stirring is extremely Room temperature.
It is carrier to substitute water with glycerine in the present invention, on the one hand makes whole formula system moistening effect more preferable, in addition a side Moisture is few in surface compositions system, can be not added with formula or lack adding preservative agent, it is possible to reduce preservative is to hair and head The side effect that belt comes.
The beneficial effects of the present invention are:The present invention adds persimmon extract, persimmon extract in without silicone oil shampoo In contain the materials such as carbohydrate, abundant vitamin and pectin, hence it is evident that the cardability of no silicone oil shampoo can be improved, its dry and wet comb Rationality exceedes similar no silicone oil shampoo, and hair can be kept smooth, bright;Glycerine is used to make additionally, due in the present invention For carrier, moisture is few in formula system, thus can less plus or do not add preservative, so as to reduce preservative to hair And the excitant of scalp.
Brief description of the drawings
The wet cardability of Fig. 1 inventive formulation 1-5 shampoos compares.
Fig. 2 inventive formulation 1-5 shampoos are done cardability and compared.
The shampoo of Fig. 3 inventive formulations 5 is compared with the commercially available no wet cardability of silicone oil shampoo.
Compared with the shampoo of Fig. 4 inventive formulations 5 does cardability with commercially available no silicone oil shampoo.
Embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.
The preparation of the persimmon extract of embodiment 1
(1) first the ripe persimmons of 10kg are placed in clear water reserviors and wash away surface soil dust, then put it into 30L10% In NaOH solution, cleaning, soak 1 hour, carry out surface sterilization, then rinsed well again with water purification.
(2) persimmon obtained by above-mentioned steps (1) is put into pulverizer and breaks into pulpous state.
(3) by persimmon slurries obtained by step (2), it is filtered by vacuum with 500 mesh sieves, collection filtrate, obtains filtrate 5.1kg.
(4) it is standby to add 0.03% preservative for filtrate obtained by step (3).
Embodiment 2
Table 1 below list different ratio containing persimmon extract without silicone oil shampoo, the content of each component is with weight Percentage represents.
The different ratio of table 1 containing persimmon extract without silicone oil shampoo
Preparation method:
(1) (b) anion surfactant in being formulated:Sodium laureth sulfate, sodium lauroyl glutamate, Sodium lauroyl sarcosine, sodium methyl cocoyl taurate, (d) cocamidopropyl betaine, dodecanamide propyl hydroxyl sulphur EDTA- disodiums in base glycine betaine, C12-16 alkyl glucosides and (e) cosmetic additive agent are mixed together stirring, dissolve by heating And to 85 DEG C or so.
(2) (c) cationic surfactant polyquaternium -7, Polyquaternium-10 are added in (f) glycerine, is heated to 85 DEG C or so.
(3) above-mentioned (1) and (2) are mixed evenly, add (a) persimmon extract and (e) cosmetic additive agent ginseng Extract, hydrolysis fibroin, stir, are cooled to 55 DEG C, add essence in (e) cosmetic additive agent, adjusted with citric acid PH 5.5~6.5 is saved, is stirred to room temperature.
The dry and wet cardability of embodiment 3 is tested
1. tester HM-1 Hair setting testers
2. test philosophy
Comb caused frictional force during combing hair is gathered by digital calculation balance, inputs microcomputer.Microcomputer Calculation machine draws out the curve that caused frictional force changes with the time (hair lengths) in carding process after processing data.
3. method of testing
In Example 2 present invention of formula 1~5 containing persimmon extract without each 5g of silicone oil shampoo, with same Topknot carries out wet cardability test, topknot is carried out into ungrease treatment with 10g 10% sodium dodecyl sulfate solution first, so Shampoo is uniformly applied on hair afterwards, gently rubbed, tow sides each half a minute, then rinses half with the water of suitable temperature Minute, moisture is gently extracted with hand, is tested with HM-1 Hair settings tester, every group of topknot surveys 3 groups of data, and identical product is surveyed 3 beam hairs, totally 9 groups of data average;Dry cardability is under the conditions of identical temperature and humidity, and HM-1 is used after topknot is naturally dry Hair setting tester tests the data obtained average value.
4. test result
It is formulated 1~5 wet cardability and dry cardability comparative result such as Fig. 1 and Fig. 2.It can be seen that addition from Fig. 1 and Fig. 2 The dry and wet cardability positive effect without silicone oil shampoo of the most formula 5 of persimmon extract is better than other 4 group of formula, adds persimmon The minimum dry and wet cardability effect of formula 1 of seed extract is worst, adds same amount of persimmon extract on different anions surface The dry and wet cardability effect of formula 3 and formula 4 is similar in the formula of activating agent.
The dry and wet cardability contrast test of embodiment 4
With the method for testing of embodiment 3,5 will be formulated in embodiment 2 compared with commercially available no silicone oil shampoo A, B and C, As a result Fig. 3 and Fig. 4 are seen, it can be seen that wet cardability and dry cardability of the inventive formulation 5 without silicone oil shampoo are better than commercially available Brand is without silicone oil shampoo.
Above-described is only the preferred embodiment of the present invention, and the present invention is not limited to above example, this area skill The oher improvements and changes that art personnel directly export or associated without departing from the spirit and concept in the present invention, all should Think comprising within the scope of the present invention.

Claims (10)

1. a kind of extract containing persimmon without silicone oil shampoo, it is characterised in that it includes following components:
(a) persimmon extract,
(b) anion surfactant,
(c) cationic surfactant,
(d) nonionic surfactant and/or amphoteric surfactant,
(e) cosmetic additive agent, and
(f) glycerine.
2. as claimed in claim 1 the extract containing persimmon without silicone oil shampoo, it is characterised in that the persimmon extract accounts for (0.1~5) % of shampoo gross weight.
3. as claimed in claim 1 or 2 the extract containing persimmon without silicone oil shampoo, it is characterised in that the shampoo bag Contain:
(a) 0.1~5 weight % persimmon extract,
(b) 5~25 weight % anion surfactant,
(c) 0.01~0.5 weight % cationic surfactant,
(d) 1~15 weight % nonionic surfactant and/or amphoteric surfactant,
(e) 1~10 weight % cosmetic additive agents, and
(f) 100 weight % glycerine is added to.
4. the extract containing persimmon as described in claim 1 or 3 without silicone oil shampoo, it is characterised in that the anion table Face activating agent is:Alkyl sulfate, fatty alcohol ether sulphate, aliphatic acid isethionate, fatty acyl sarcosinates, fatty acyl Base glutamate and/or N- acyl methyl taurine salts.
5. the extract containing persimmon as described in claim 1 or 3 without silicone oil shampoo, it is characterised in that the cation form Face activating agent is:Homopolymer, hydroxyethyl cellulose and the diallyl of acrylic or methacrylic acid ethyl-trimethyl salmiac The quaternary copolymer of ammonium chloride, with trimethylammonium substitute epoxide modification hydroxyethyl cellulose polymeric quaternary ammonium salts, quaternary ammonium Depolymerised guar gum derivative, cationic cellulose and the derivative of change, cation guar gum and derivative and/quaternary ammonium compound.
6. the extract containing persimmon as described in claim 1 or 3 without silicone oil shampoo, it is characterised in that the other surfaces Activating agent is:Polyol fatty acid ester, APG and/or aliphatic acid N- alkyl glucose amides, alkyl betaine, alkylamide Base glycine betaine, imidazolinium betaine and/or sulfobetaines.
7. the extract containing persimmon as described in claim 1 or 3 without silicone oil shampoo, it is characterised in that the cosmetics add Add agent for emulsifying agent, pearling agent, stabilizer, salt, thickener, consistency modifiers, pigment, preservative, antioxidant, anti-dandruff agent And/or biological source active component.
8. as claimed in claim 7 the extract containing persimmon without silicone oil shampoo, it is characterised in that the biological source activity into It is divided into plant extracts, hyaluronic acid, protein hydrolysate, peptide and/or vitamin complexes.
9. if the extract according to any one of claims 1 to 8 containing persimmon is without silicone oil shampoo, it is characterised in that described The preparation method of persimmon extract comprises the steps of:
(1) persimmon of maturation is cleaned with water, then surface sterilization is carried out with 5~15%NaOH solution, then rushed again with water purification Wash clean;
(2) persimmon obtained by step (1) is put into pulverizer and breaks into pulpous state;
(3) by persimmon slurries obtained by step (2), its use is more than 500 mesh filter-cloth filterings, collects filtrate;
(4) preservative is added to filtrate obtained by step (3).
10. if the extract according to any one of claims 1 to 9 containing persimmon is without silicone oil shampoo preparation method, its feature It is, this method comprises the following steps:
(1) the stabilizer EDTA- disodiums in component (b), component (d) and component (e) are mixed together stirring, dissolved by heating and extremely 80~90 DEG C, obtain component one;
(2) component (c) is added in component (f), is heated to 80~90 DEG C or so, obtains component two;
(3) component one and component two are mixed evenly, the biological source active component added in component (a) and component (e), stirred Mix uniformly, be cooled to 50~55 DEG C, the essence added in component (e), with lemon acid for adjusting pH 5.5~6.5, stir to room temperature .
CN201710568309.4A 2017-07-12 2017-07-12 Silicone-oil-free shampoo containing persimmon extract and preparation method thereof Active CN107375062B (en)

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CN114686322A (en) * 2022-04-25 2022-07-01 上海和黄白猫有限公司 Laundry detergent with softening function and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN112156041A (en) * 2020-10-16 2021-01-01 花安堂生物科技集团有限公司 Dry-cleaning spray composition for hair and preparation method thereof
CN114686322A (en) * 2022-04-25 2022-07-01 上海和黄白猫有限公司 Laundry detergent with softening function and preparation method thereof
CN114686322B (en) * 2022-04-25 2024-02-27 上海和黄白猫有限公司 Liquid laundry detergent with softening function and preparation method thereof

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