CN107372812A - A kind of potato sprouting inhibitor and preparation method thereof - Google Patents

A kind of potato sprouting inhibitor and preparation method thereof Download PDF

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Publication number
CN107372812A
CN107372812A CN201710629744.3A CN201710629744A CN107372812A CN 107372812 A CN107372812 A CN 107372812A CN 201710629744 A CN201710629744 A CN 201710629744A CN 107372812 A CN107372812 A CN 107372812A
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Prior art keywords
parts
potato
control agent
attapulgite
potato sprouting
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CN201710629744.3A
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CN107372812B (en
Inventor
李明浩
蔡冬清
吴丽芳
张慧兰
汤才国
舒宪
胡浩
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Hefei Institutes of Physical Science of CAS
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Hefei Institutes of Physical Science of CAS
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/16Coating with a protective layer; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/154Organic compounds; Microorganisms; Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/157Inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Zoology (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Microbiology (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

The invention discloses a kind of potato sprouting inhibitor, include the raw material of following parts by weight:1 50 parts of adjusting control agent, 1 300 parts of modified silicon oil, 650 998 parts of water are lost in control;Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon according to mass ratio (3 5):(1 2) mix.The invention also discloses a kind of preparation method of potato sprouting inhibitor.The advantage of the invention is that:(1) preparation method is simple, easy to operate, cost is cheap, is produced on a large scale;(2) a kind of nano composite material is prepared using materials such as attapulgite, modified silicon oils, one layer of mesh nano overcoat can be self-assembly of by being sprayed on potato, effectively completely cut off moisture, reduce germination percentage, increase the storage of potato time;The product is natural, green, environmental protection, safely, have no side effect, and potato sprouting rate can be made to reduce by 80 95%, the stabilization of effective guarantee potato yield and quality.

Description

A kind of potato sprouting inhibitor and preparation method thereof
Technical field
The present invention relates to technical field of ecological agriculture, more particularly to a kind of potato sprouting inhibitor and preparation method thereof.
Background technology
Potato is one of most important grain, dish dual-purpose type crop in the world, turned at present China after corn, rice, The fourth-largest cereal crops after wheat.China is the big producer of potato first, area and the yield Jun Zhan worlds about 1/4.North The potato tubers of square main producing region is adopted will pass through the storage up to 3-6 months mostly afterwards, and the potato tubers after harvesting Will germinate greening after the rest period by some months, during which due to rotting, dehydration, germination, brown stain, see the reasons such as light greening Caused by loss in 18-20%, up to 40-50% when serious.
Germination is the main reason for causing storage of potato to lose, and potato nutritional can be caused to lose, and influences the business of stem tuber Product quality, the growth of potato seed bud is long also to be influenceed to emerge, and especially after potato sprouting, a large amount of black nightshades will be contained around germ pore Element, this is a kind of neurotoxin, can suppress respiratory center, huge potential safety hazard is brought to consumer.The storage of potato phase Between germinate, cause the loss of each nutritional ingredient, reduce the exploitation value of the eating raw of potato tubers, food processing and industrial processes Value.
Chemistry and presses down bud agent such as CIPC (chlorpropham) can play good suckering effect, but it has mutagenesis to animals and plants And carcinogenesis, and the activity of seed potato can be had a strong impact on, and so as to influence the growth of potato bud, chemistry and presses down bud agent at present By the developed countries such as the U.S., Japan, Australia disable or i.e. will be disabled.Therefore, the Ma Ling that exploitation is natural, safe is explored Potato sprout inhibitor, the economic loss that effectively reduction potato sprouting is brought are the upper urgent problems of current production.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of natural, safe and effective potato hair Bud inhibition agent and preparation method thereof.
The present invention is achieved by the following technical solutions:A kind of potato sprouting inhibitor, including following parts by weight Raw material:Adjusting control agent 1-50 parts, modified silicon oil 1-300 parts, water 650-998 parts are lost in control;Wherein, it is recessed by amination to lose adjusting control agent for control Convex rod soil and micro-nano biogenic opal/carbon are according to mass ratio (3-5):(1-2) is mixed.
One of preferred embodiment as the present invention, include the raw material of following parts by weight:20 parts of adjusting control agent, modified silicon are lost in control 150 parts of oil, 830 parts of water;Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon according to mass ratio 4:1.5 Mix.
One of preferred embodiment as the present invention, include the raw material of following parts by weight:10 parts of adjusting control agent, modified silicon are lost in control 90 parts of oil, 900 parts of water;Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon according to mass ratio 3.5:1 Mix.
One of preferred embodiment as the present invention, include the raw material of following parts by weight:40 parts of adjusting control agent, modified silicon are lost in control 200 parts of oil, 760 parts of water;Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon according to mass ratio 4.5:2 Mix.
One of preferred embodiment as the present invention, the modified silicon oil is specially amino-polyether modified organosilicon.
The invention also discloses a kind of method for preparing above-mentioned potato sprouting inhibitor, comprise the following steps:
(1) using oxygen and ammonia as gas source, existed using the plasma that temperature is 500-1000 DEG C, power is 1-3KW Intermittent radiation treatment is carried out to attapulgite powder under vacuum condition, and is kept for total effective irradiation time reach 30-60 minutes, is made Obtain amination attapulgite;
(2) under the anaerobic condition of nitrogen protection, height is carried out to rice straw at a temperature of 500-800 DEG C using Muffle furnace Anneal crack solution 50-100 minutes, obtain micro-nano biogenic opal/carbon;
(3) the micro-nano biogenic opal/carbon for obtaining the amination attapulgite that step (1) obtains with step (2) is according to above-mentioned Mass ratio is mixed, and must be controlled and be lost adjusting control agent;
(4) control of above-mentioned parts by weight is lost into adjusting control agent, modified silicon oil and water fully shaking to mix, potato sprouting is made Inhibitor.
One of preferred embodiment as the present invention, the volume ratio of oxygen and ammonia is (1-2) in the step (1):(3- 5)。
One of preferred embodiment as the present invention, attapulgite powder is specially the absorption of 100-800 mesh in the step (1) The attapulgite powder of level.
One of preferred embodiment as the present invention, step (1) the intermittent radiation treatment mode is:Radiation treatment 5- 10 minutes, stop 5-10 minutes.
One of preferred embodiment as the present invention, fully shaking blending manner is in the step (4):2000-5000rpm 10-60 minutes are handled under rotating speed.
The present invention compared with prior art the advantages of be:
(1) preparation method is simple, easy to operate, cost is cheap, can carry out large-scale production;
(2) a kind of nano composite material is prepared using materials such as attapulgite, modified silicon oils, nano composite material spray One layer of mesh nano overcoat can be self-assembly of by being sprinkled upon on potato, can effectively completely cut off moisture, so as to reduce germination percentage, increase The storage of potato time;The product is natural, green, environmental protection, safely, have no side effect, and potato sprouting rate can be made to reduce 80- 95%, the stabilization of effective guarantee potato yield and quality.
Brief description of the drawings
Fig. 1 is the potato sprouting situation map handled without using sprout inhibitor in the case of potato in embodiment 8;
Fig. 2 is the potato sprouting situation handled using potato sprouting inhibitor in the case of potato in embodiment 8 Figure.
Embodiment
Embodiments of the invention are elaborated below, the present embodiment is carried out lower premised on technical solution of the present invention Implement, give detailed embodiment and specific operating process, but protection scope of the present invention is not limited to following implementation Example.
Embodiment 1
A kind of potato sprouting inhibitor of the present embodiment, include the raw material of following parts by weight:1 part of adjusting control agent is lost in control, 1 part of modified silicon oil, 650 parts of water.
Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon according to mass ratio 3:1 mixes; Modified silicon oil is specially then amino-polyether modified organosilicon.
Embodiment 2
A kind of potato sprouting inhibitor of the present embodiment, include the raw material of following parts by weight:50 parts of adjusting control agent is lost in control, 300 parts of modified silicon oil, 998 parts of water.
Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon according to mass ratio 5:2 mix; Modified silicon oil is specially then amino-polyether modified organosilicon.
Embodiment 3
A kind of potato sprouting inhibitor of the present embodiment, include the raw material of following parts by weight:20 parts of adjusting control agent is lost in control, 150 parts of modified silicon oil, 830 parts of water.
Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon according to mass ratio 4:1.5 mixing and Into;Modified silicon oil is specially then amino-polyether modified organosilicon.
Embodiment 4
A kind of potato sprouting inhibitor of the present embodiment, include the raw material of following parts by weight:10 parts of adjusting control agent is lost in control, 90 parts of modified silicon oil, 900 parts of water.
Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon according to mass ratio 3.5:1 mixing and Into;Modified silicon oil is specially then amino-polyether modified organosilicon.
Embodiment 5
A kind of potato sprouting inhibitor of the present embodiment, include the raw material of following parts by weight:40 parts of adjusting control agent is lost in control, 200 parts of modified silicon oil, 760 parts of water.
Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon according to mass ratio 4.5:2 mixing and Into;Modified silicon oil is specially then amino-polyether modified organosilicon.
Embodiment 6
A kind of method for the potato sprouting inhibitor for preparing above-described embodiment, comprises the following steps:
(1) using oxygen and ammonia, (volume ratio is 1:3) be gas source, using temperature be 500 DEG C, power be 1KW etc. from Daughter carries out intermittent radiation treatment, i.e. radiation treatment 5 to attapulgite powder (for 100 mesh, adsorption stage) under vacuum Minute, stop 5 minutes, kept for total effective irradiation time up to 30 minutes, amination attapulgite is made;
(2) under the anaerobic condition of nitrogen protection, high anneal crack is carried out at a temperature of 500 DEG C to rice straw using Muffle furnace Solution 50 minutes, obtains micro-nano biogenic opal/carbon;
(3) the micro-nano biogenic opal/carbon for obtaining the amination attapulgite that step (1) obtains with step (2) is according to above-mentioned Mass ratio is mixed described in embodiment, must be controlled and be lost adjusting control agent;
(4) control of parts by weight described in above-described embodiment is lost into adjusting control agent, modified silicon oil and water under 2000rpm rotating speeds Processing is mixed for 10 minutes with fully shaking, and potato sprouting inhibitor is made.
Embodiment 7
A kind of method for the potato sprouting inhibitor for preparing above-described embodiment, comprises the following steps:
(1) using oxygen and ammonia, (volume ratio is 2:5) be gas source, using temperature be 1000 DEG C, power be 3KW etc. from Daughter carries out intermittent radiation treatment, i.e. radiation treatment 10 to attapulgite powder (for 800 mesh, adsorption stage) under vacuum Minute, stop 10 minutes, kept for total effective irradiation time up to 60 minutes, amination attapulgite is made;
(2) under the anaerobic condition of nitrogen protection, high anneal crack is carried out at a temperature of 800 DEG C to rice straw using Muffle furnace Solution 100 minutes, obtains micro-nano biogenic opal/carbon;
(3) the micro-nano biogenic opal/carbon for obtaining the amination attapulgite that step (1) obtains with step (2) is according to above-mentioned Mass ratio is mixed described in embodiment, must be controlled and be lost adjusting control agent;
(4) control of parts by weight described in above-described embodiment is lost into adjusting control agent, modified silicon oil and water under 5000rpm rotating speeds Processing is mixed for 60 minutes with fully shaking, and potato sprouting inhibitor is made.
Embodiment 8
A kind of method for the potato sprouting inhibitor for preparing above-described embodiment, comprises the following steps:
(1) using oxygen and ammonia, (volume ratio is 1.5:4) be gas source, using temperature be 800 DEG C, power be 2KW etc. Gas ions carry out intermittent radiation treatment, i.e. radiation treatment to attapulgite powder (for 400 mesh, adsorption stage) under vacuum 8 minutes, stop 8 minutes, kept for total effective irradiation time up to 45 minutes, amination attapulgite is made;
(2) under the anaerobic condition of nitrogen protection, high anneal crack is carried out at a temperature of 650 DEG C to rice straw using Muffle furnace Solution 80 minutes, obtains micro-nano biogenic opal/carbon;
(3) the micro-nano biogenic opal/carbon for obtaining the amination attapulgite that step (1) obtains with step (2) is according to above-mentioned Mass ratio is mixed described in embodiment, must be controlled and be lost adjusting control agent;
(4) control of parts by weight described in above-described embodiment is lost into adjusting control agent, modified silicon oil and water under 4000rpm rotating speeds Processing is mixed for 40 minutes with fully shaking, and potato sprouting inhibitor is made.
The present embodiment prepares a kind of nano composite material using materials such as attapulgite, modified silicon oils, and the nanometer is answered Condensation material, which is sprayed on potato, can be self-assembly of one layer of mesh nano overcoat, effectively completely cut off moisture, so as to reduce germination Rate, increase the storage of potato time.
In the case of Fig. 1, Fig. 2 are respectively without and with the potato sprouting inhibitor processing potato of the present embodiment Potato sprouting situation when potato sprouting situation map, specially normal storage 15 days;As seen from the figure:The Ma Ling of the present embodiment Potato sprout inhibitor can effectively reduce potato sprouting rate.Through later observation:The Ma Ling handled using potato sprouting inhibitor Potato does not have germination phenomenon substantially in normal storage phase, and the inhibitor can make potato sprouting rate reduce 80-95%, effectively protect Hinder the stabilization of potato yield and quality.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.

Claims (10)

1. a kind of potato sprouting inhibitor, it is characterised in that include the raw material of following parts by weight:Adjusting control agent 1-50 is lost in control Part, modified silicon oil 1-300 parts, water 650-998 parts;Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biogenic opal/carbon According to mass ratio (3-5):(1-2) is mixed.
2. potato sprouting inhibitor according to claim 1, it is characterised in that include the raw material of following parts by weight: 20 parts of adjusting control agent, 150 parts of modified silicon oil, 830 parts of water are lost in control;Wherein, control is lost adjusting control agent and given birth to by amination attapulgite and micro-nano Thing silicon/carbon is according to mass ratio 4:1.5 mix.
3. potato sprouting inhibitor according to claim 1, it is characterised in that include the raw material of following parts by weight: 10 parts of adjusting control agent, 90 parts of modified silicon oil, 900 parts of water are lost in control;Wherein, control loses adjusting control agent by amination attapulgite and micro-nano biology Silicon/carbon is according to mass ratio 3.5:1 mixes.
4. potato sprouting inhibitor according to claim 1, it is characterised in that include the raw material of following parts by weight: 40 parts of adjusting control agent, 200 parts of modified silicon oil, 760 parts of water are lost in control;Wherein, control is lost adjusting control agent and given birth to by amination attapulgite and micro-nano Thing silicon/carbon is according to mass ratio 4.5:2 mix.
5. according to the potato sprouting inhibitor described in claim any one of 1-4, it is characterised in that the modified silicon oil is specific For amino-polyether modified organosilicon.
A kind of 6. method for preparing the potato sprouting inhibitor as described in claim any one of 1-5, it is characterised in that including Following steps:
(1) using oxygen and ammonia as gas source, using the plasma that temperature is 500-1000 DEG C, power is 1-3KW in vacuum Under the conditions of intermittent radiation treatment is carried out to attapulgite powder, and kept for total effective irradiation time reach 30-60 minutes, obtained ammonia Base attapulgite;
(2) under the anaerobic condition of nitrogen protection, high anneal crack is carried out at a temperature of 500-800 DEG C to rice straw using Muffle furnace 50-100 minutes are solved, obtain micro-nano biogenic opal/carbon;
(3) micro-nano biogenic opal/carbon that the amination attapulgite for obtaining step (1) obtains with step (2) is according to above-mentioned quality Than being mixed, it must control and lose adjusting control agent;
(4) control of above-mentioned parts by weight is lost into adjusting control agent, modified silicon oil and water fully shaking to mix, potato sprouting is made and suppresses Agent.
7. the preparation method of potato sprouting inhibitor according to claim 6, it is characterised in that in the step (1) The volume ratio of oxygen and ammonia is (1-2):(3-5).
8. the preparation method of potato sprouting inhibitor according to claim 6, it is characterised in that in the step (1) Attapulgite powder is specially the attapulgite powder of 100-800 mesh adsorption stages.
9. the preparation method of potato sprouting inhibitor according to claim 6, it is characterised in that in the step (1) Intermittent radiation treatment mode is:Radiation treatment 5-10 minutes, stop 5-10 minutes.
10. the preparation method of potato sprouting inhibitor according to claim 6, it is characterised in that in the step (4) Fully shaking blending manner is:10-60 minutes are handled under 2000-5000rpm rotating speeds.
CN201710629744.3A 2017-07-28 2017-07-28 Potato germination inhibitor and preparation method thereof Active CN107372812B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108208152A (en) * 2018-01-05 2018-06-29 中国科学院合肥物质科学研究院 A kind of potato nanometer fresh-keeping agent, preparation method, application method
CN115316433A (en) * 2022-09-16 2022-11-11 安庆师范大学 Method for inhibiting sprouting of stored potatoes and potato sprouting inhibitor used by same

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CN103299997A (en) * 2013-06-03 2013-09-18 中国科学院合肥物质科学研究院 Preparation method of loss and degradation-controllable novel environment-friendly xylophyta plant type regulating agent

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CN102461658A (en) * 2010-11-14 2012-05-23 重庆市黔江区黔双科技有限公司 Method for preventing potatoes from sprouting
CN103299997A (en) * 2013-06-03 2013-09-18 中国科学院合肥物质科学研究院 Preparation method of loss and degradation-controllable novel environment-friendly xylophyta plant type regulating agent

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108208152A (en) * 2018-01-05 2018-06-29 中国科学院合肥物质科学研究院 A kind of potato nanometer fresh-keeping agent, preparation method, application method
CN115316433A (en) * 2022-09-16 2022-11-11 安庆师范大学 Method for inhibiting sprouting of stored potatoes and potato sprouting inhibitor used by same

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