CN107372555A - A kind of gel bait for killing insects - Google Patents
A kind of gel bait for killing insects Download PDFInfo
- Publication number
- CN107372555A CN107372555A CN201710698190.2A CN201710698190A CN107372555A CN 107372555 A CN107372555 A CN 107372555A CN 201710698190 A CN201710698190 A CN 201710698190A CN 107372555 A CN107372555 A CN 107372555A
- Authority
- CN
- China
- Prior art keywords
- ethiprole
- arprocarb
- active compound
- killing insects
- gel bait
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a kind of gel bait for killing insects, comprise the following raw materials by weight percent：Ethiprole active compound 0.033 ± 0.008wt% of material, arprocarb active compound 0.667 ± 0.167wt% of material, carrier 75wt%, thickener 2wt%, surplus is water.A kind of gel bait for killing insects shown by the present invention has the advantages of toxicity low good disinsection effect, and need not rely on compressed air and dispensed, with cost it is relatively low and easy to use the advantages of, be very suitable in the indoor environments such as family to various insects kill and Prevention technology, gel bait for killing insects disclosed in this invention also can significantly lower the dosage of ethiprole and arprocarb while ensureing and insect is killed simultaneously, and with than exclusive use ethiprole and arprocarb as effectively killing technical advantage of the glue bait of composition with more preferably insect killing effect.
Description
Technical field
The present invention relates to technical field of insecticide, more particularly to a kind of preventing and treating for being used for domestic hygiene insect and kill one
Kind gel bait for killing insects.
Background technology
Ethiprole is that a kind of Phenylpyrazole insecticides, insecticidal spectrum are wide, to insect based on stomach poison function, have concurrently tag and
Certain systemic action, its mechanism of action are the chloride metabolism for hindering the control of insect γ-aminobutyric acid, thus to aphid,
The important pests such as leafhopper, plant hopper, lepidopterous larvae, flies and coleoptera have very high insecticidal activity, to crop without poisoning.The medicine
Agent can impose on soil, also can foliar spray.Corn root leaf A, wireworm and cutworm can effectively be prevented and treated by imposing on soil.Spray on blade face
When spilling, there is high-level preventive effect to diamondback moth, cabbage butterfly, rice thripses etc., and the lasting period is grown.Due to its environment can be caused it is larger
Pollution, be currently used primarily in the preventing and treating of domestic hygiene insect with killing.
Insecticide is mainly made or using ethiprole using phenyl pyrazole compounds (such as ethiprole) in the prior art
With other there is the component of insecticidal effect to mix so that insecticide is made, for example, notification number discloses for CN102858162B
A kind of Chinese invention patent of Pesticidal combination and application thereof, it is raw material according to setting that it, which uses hydroxyl amide compound and ethiprole,
Ratio mix.But various insecticides of the prior art or its composition can only be sprayed by compressed gas
Penetrate, so as to there is the problem of inconvenient to use.Importantly, there is poison in the insecticide for being conventionally used to kill house pest
The problem of property easily causes murder by poisoning to human body greatly.
The content of the invention
It is same efficiently to be killed to house pest in realization it is an object of the invention to disclose a kind of gel bait for killing insects
When can also to kill insect process it is more convenient, and avoid using and drive insecticide to permeate into sky in a manner of compressed gas
In gas, to reduce to the murder by poisoning caused by human body.
To achieve the above object, the invention provides a kind of gel bait for killing insects, comprise the following raw materials by weight percent：
Ethiprole active compound 0.033 ± 0.008wt% of material,
Arprocarb active compound 0.667 ± 0.167wt% of material,
Carrier 75wt%,
Thickener 2wt%, surplus are water.
As a further improvement on the present invention, the ethiprole purity in the ethiprole active compound material is 96%, the cannibalisation
Arprocarb purity in prestige active compound material is 97%.
As a further improvement on the present invention, the carrier is made up of milk powder, corn flour and sugar.
As a further improvement on the present invention, comprise the following raw materials by weight percent：
Ethiprole active compound 0.033 ± 0.008wt% of material,
Arprocarb active compound 0.667 ± 0.167wt% of material,
Milk powder 10wt%,
Corn flour 25wt%,
Sugared 40wt%,
Thickener 2wt%, surplus are water.
As a further improvement on the present invention, the thickener is selected from starch, gelatin, sodium alginate, casein, Guar
Glue, chitosan, gum arabic, xanthans, soybean protein glue, natural rubber, lanolin are either a kind of or several in agar
The mixture of any ratio of kind.
Compared with prior art, the beneficial effects of the invention are as follows：A kind of gel bait for killing insects shown by the present invention has toxicity
The advantages of low good disinsection effect, and need not rely on compressed air and dispensed, there is the advantages of cost is relatively low and easy to use,
Simultaneously gel bait for killing insects disclosed in this invention ensure insect is killed while also can significantly lower ethiprole with it is residual
Kill the dosage of prestige, and with than ethiprole and arprocarb is used alone as effectively killing the glue bait of composition with even more ideal
Insect killing effect technical advantage.
Brief description of the drawings
Fig. 1 is the high-efficient liquid phase chromatogram of ethiprole standard specimen；
Fig. 2 is the high-efficient liquid phase chromatogram of arprocarb standard specimen；
Fig. 3 is the high-efficient liquid phase color with insecticidal effect ethiprole and arprocarb contained in a kind of gel bait for killing insects of the present invention
Spectrogram.
Embodiment
The present invention is described in detail for shown each embodiment below in conjunction with the accompanying drawings, but it should explanation, these
Embodiment is not limitation of the present invention, those of ordinary skill in the art according to these embodiment institute work energy, method,
Or equivalent transformation or replacement in structure, belong within protection scope of the present invention.
A kind of gel bait for killing insects, is comprised the following raw materials by weight percent：Ethiprole active compound 0.033 ± 0.008wt% of material,
Arprocarb active compound 0.667 ± 0.167wt% of material, carrier 75wt%, thickener 2wt%, surplus is water.Wherein, ethiprole active compound
Ethiprole purity in material is 96%, and the arprocarb purity in the arprocarb active compound material is 97%.Ethiprole active compound material is by river
Su Tuoqiu agrochemical Co., Ltd is produced, and arprocarb active compound material is produced by Hunan Haili Chemical Co., Ltd..Carrier by milk powder,
Corn flour and sugar form.
Specifically, the gel bait for killing insects comprises the following raw materials by weight percent：Ethiprole active compound material 0.033 ±
0.008wt%, arprocarb active compound 0.667 ± 0.167wt% of material, milk powder 10wt%, corn flour 25wt%, sugared 40wt%, thickening
Agent 2wt%, surplus are water.Specifically, the thickener is selected from starch, gelatin, sodium alginate, casein, guar gum, crust
One or several kinds of any ratios in amine, gum arabic, xanthans, soybean protein glue, natural rubber, lanolin or agar
The mixture of example, and it is chosen to be xanthans in present embodiment.
The item controlled index of gel bait for killing insects shown by present embodiment is as shown in Table 1.
Table one
Toxicological experiment
A kind of emergency toxicology of disclosed gel bait for killing insects is tested by section's drug development research in the Western Hills of Suzhou
Co., Ltd completes.
1.1 acute oral toxicity test：The oral LD of rat toxicity50>5000/5000mg/kg (male/female), belongs to micro- poison.
1.2 acute dermal toxicities are tested：The percutaneous LD of rat toxicity50>2000/2000mg/kg (male/female), category low toxicity.
1.3 the irritating experiment with eyes：NZw eye irritation is classified as nonirritant.
1.4 skin irritation test：NZw skin irritatin is classified as nonirritant.
1.5 guinea pig skin sensitizations are tested：Weak sensitization is classified as to guinea pig skin sensitization.
The process detected to a kind of high performance liquid chromatography of the active ingredient of disclosed gel bait for killing insects
It is illustrated.
Unless otherwise indicated, this experiment reagent used is AR, and water should meet three in GB/T6682-2008
Level water specification.
Carried out according to " solid pharmaceutical preparation sampling " method in GB/T 1605-2001, packing for sampling is determined with table of random numbers method
Part, final amount of sampling should typically be no less than 600g.
Outward appearance：Under the conditions of natural light, carried out with visual method.
Discrimination test：High performance liquid chromatography --- this discrimination test can be with the measure of arprocarb, ethiprole mass fraction
Carry out simultaneously.Under identical operation condition of chromatogram, arprocarb, the retention time of ethiprole chromatographic peak and standard specimen in sample solution
Arprocarb, the retention time of ethiprole chromatographic peak, its relative difference should be within 1.5% in solution.
The measure of arprocarb, ethiprole mass fraction：
Sample is dissolved with methanol, using the mixture of methanol and water as mobile phase, use using C18 as filler stainless steel column and
UV-detector (wavelength 254nm), high performance liquid chromatography separation is carried out to the ethiprole in sample and arprocarb, external standard is legal
Amount.
Reagent and solution：Methanol：Chromatographically pure；Arprocarb standard specimen：Known content >=97.0%.Ethiprole standard specimen：It is known to contain
Amount >=97.0%.Water：It is new to steam redistilled water.Mobile phase：Methanol：Water (0.3% formic acid)=75:25(V:V), it is filtered by vacuum,
Loaded in brown bottle, deaerated with ultrasonic echography.
Instrument：High performance liquid chromatograph：Agilent 1200-DAD types；Chromatographic data processor or chromatographic work station.Color
Compose post:250mm × 4.6mm (id) stainless steel chromatographic column, built-in Eclipse XDB-C18 fillers, 5 μm of particle diameter.Auto injection
Device.Filter：0.45 μm of filter sizes.Ultrasonic cleaner.
High performance liquid chromatography operating condition：Mobile phase：Methanol：Water (0.3% formic acid)=75：25；, through 0.45 μm of filter membrane mistake
Filter, and the 20min that deaerates.Detection wavelength：274nm.Flow velocity：1.0mL/min.Column temperature：30±2℃.Sample size：5μL.During reservation
Between：Arprocarb about 2.9min；Ethiprole about 4.8min.
Aforesaid operations condition, it is typical operation parameter.Can be according to different instrument traits, it is appropriate that given operating parameter is made
Adjustment, to obtain optimum efficiency.
Ethiprole standard specimen in gel bait for killing insects, arprocarb standard specimen, sample liquid chromatogram as shown in Figure 1, Figure 2 and Figure 3.
A kind of disclosed gel bait for killing insects can especially have to the various insects of interior to termite, blattaria, ant
It is good to kill and control effect, next physical simulation insect killing test data are shown.
Disease prevention and control center of Nanjing Military Command (indoor harmacological effect effect) is as shown in following table two.
Table two
Disease prevention and control center of Nanjing Military Command (in-site modeling result) is as shown in following table three.
Table three
Jinan Disease Prevention and Control Centre's (indoor harmacological effect effect) is as shown in following table four.
Table four
Jinan Disease Prevention and Control Centre's (in-site modeling result) is as shown in following table five.
Table five
The test of pesticide effectiveness on the spot of comprehensive disease prevention and control center of Nanjing Military Command and Center for Disease Control of Jinan City, it was demonstrated that this
A kind of gel bait for killing insects disclosed in embodiment is killed in a manner of launching through indoor pharmacodynamic test and Simulation field test to blattaria
Effect of going out is B levels, and the killing effect to ant is A levels.
Next, 1.5wt% arprocarb and 0.05wt% ethiprole system are added in identical carrier and thickener
Into glue bait the insect killing effect of blattaria and ant is shown, and join respectively shown in table six and table seven.
Table six
From table six it will be evident that the examination that the glue bait that 1.5wt% arprocarbs are used alone is killed to blattaria and ant
Testing effect proves, its somatic death rate is less than the death rate of disclosed gel bait for killing insects, and the death of blattaria and ant
Speed is overall partially slow.
Table seven
From table seven it will be evident that the examination that the glue bait that 0.05wt% ethiproles are used alone is killed to blattaria and ant
Testing effect proves, its somatic death rate is less than the death rate of disclosed gel bait for killing insects, and the death of blattaria and ant
Speed is overall partially slow.
Comparatively disclosed gel bait for killing insects individually is made to have for glue bait using arprocarb kills speed
It hurry up, the good technical advantage of insect killing effect.Although being individually mixed into, arprocarb kill is fast, and somatic death rate is bad, and palatability
Difference.Ethiprole is used alone and the problem of slow that works then be present.In the present invention, by the way that both mixtures can be realized into complementary effect,
While dosage each other is reduced, while more preferable insect killing effect is realized with faster eradicative rate, there is less toxic ring
Protect the technique effect efficiently killed.
Those listed above is a series of to be described in detail only for feasibility embodiment of the invention specifically
Bright, they simultaneously are not used to limit the scope of the invention, all equivalent implementations made without departing from skill spirit of the present invention
Or change should be included in the scope of the protection.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.Any reference in claim should not be considered as to the involved claim of limitation.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.
Claims (5)
1. a kind of gel bait for killing insects, it is characterised in that comprise the following raw materials by weight percent：
Ethiprole active compound 0.033 ± 0.008wt% of material,
Arprocarb active compound 0.667 ± 0.167wt% of material,
Carrier 75wt%,
Thickener 2wt%, surplus are water.
2. gel bait for killing insects according to claim 1, it is characterised in that the ethiprole purity in the ethiprole active compound material is
96%, the arprocarb purity in the arprocarb active compound material is 97%.
3. gel bait for killing insects according to claim 1, it is characterised in that the carrier is made up of milk powder, corn flour and sugar.
4. gel bait for killing insects according to claim 3, it is characterised in that comprise the following raw materials by weight percent：
Ethiprole active compound 0.033 ± 0.008wt% of material,
Arprocarb active compound 0.667 ± 0.167wt% of material,
Milk powder 10wt%,
Corn flour 25wt%,
Sugared 40wt%,
Thickener 2wt%, surplus are water.
5. gel bait for killing insects according to any one of claim 1 to 4, it is characterised in that the thickener is selected from starch, bright
Glue, sodium alginate, casein, guar gum, chitosan, gum arabic, xanthans, soybean protein glue, natural rubber, lanolin
Or the mixture of one or several kinds of any ratios in agar.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710698190.2A CN107372555A (en) | 2017-08-15 | 2017-08-15 | A kind of gel bait for killing insects |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710698190.2A CN107372555A (en) | 2017-08-15 | 2017-08-15 | A kind of gel bait for killing insects |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107372555A true CN107372555A (en) | 2017-11-24 |
Family
ID=60355916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710698190.2A Pending CN107372555A (en) | 2017-08-15 | 2017-08-15 | A kind of gel bait for killing insects |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107372555A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110074125A (en) * | 2019-05-27 | 2019-08-02 | 南京荣诚化工有限公司 | It is a kind of efficiently to kill compound bait formulation of roach and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103734155A (en) * | 2013-12-27 | 2014-04-23 | 广西科技大学 | Cockroach bait gel |
| CN105076189A (en) * | 2015-04-28 | 2015-11-25 | 乌鲁木齐市疾病预防控制中心 | Cockroach-killing glue bait |
| CN105340885A (en) * | 2015-11-02 | 2016-02-24 | 安徽康宇生物科技工程有限公司 | Cockroach killing soft capsule and preparation method thereof |
| CN106818840A (en) * | 2017-01-05 | 2017-06-13 | 广州翼鲲环境科技有限公司 | A kind of cockroach bait and preparation method thereof |
-
2017
- 2017-08-15 CN CN201710698190.2A patent/CN107372555A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103734155A (en) * | 2013-12-27 | 2014-04-23 | 广西科技大学 | Cockroach bait gel |
| CN105076189A (en) * | 2015-04-28 | 2015-11-25 | 乌鲁木齐市疾病预防控制中心 | Cockroach-killing glue bait |
| CN105340885A (en) * | 2015-11-02 | 2016-02-24 | 安徽康宇生物科技工程有限公司 | Cockroach killing soft capsule and preparation method thereof |
| CN106818840A (en) * | 2017-01-05 | 2017-06-13 | 广州翼鲲环境科技有限公司 | A kind of cockroach bait and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110074125A (en) * | 2019-05-27 | 2019-08-02 | 南京荣诚化工有限公司 | It is a kind of efficiently to kill compound bait formulation of roach and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103689017B (en) | A kind of composite plant source pesticide and preparation method thereof | |
| CN105594747A (en) | Precisely-oriented and efficient pest prevention and control insect disinfestation composition and use method thereof | |
| CN103385251B (en) | A kind of Pesticidal combination of pyriproxyfen-containing | |
| CN104686561B (en) | Microcapsule formulation containing allyl group isosulfocyanate and preparation method and application | |
| CN101803605B (en) | Insecticidal composition of butene-fipronil and spinosad | |
| CN105410013A (en) | Insecticide-pesticide mixture preparation | |
| CN107372555A (en) | A kind of gel bait for killing insects | |
| Ota | Historical development of pesticides in Japan | |
| CN110623002A (en) | Preparation method of sweet wormwood wax oil insect repellent | |
| CN102379288A (en) | Pesticide composition containing dicyclanil and spinosad | |
| CN102246800A (en) | Insecticidal composition containing indoxacarb and dinotefuran | |
| CN102246806A (en) | Insecticidal composition containing pyriproxyfen and lambda-cyhalothrin | |
| CN102177915A (en) | Apriona germari poisoning agent | |
| CN102265885B (en) | Mixed herbicide containing bentazone, rimsulfuron and atrazine, and application thereof | |
| JPH0640809A (en) | Mating behavior disturbing agent for lawn insect pest | |
| CN109497086A (en) | A kind of microfoam insecticide and preparation method thereof | |
| CN103651386A (en) | Insecticidal composition containing chlorfenapyr | |
| CN108522558A (en) | A kind of crops insecticide and its preparation method and application | |
| CN102246758A (en) | Insecticidal composition | |
| CN106689155A (en) | Mikania micrantha eliminating pesticide and method for eliminating mikania micrantha by using mikania micrantha eliminating pesticide | |
| CN105941429A (en) | Compound aqueous solution of 2-methyl-4-chloro-isooctyl ester and bentazone and preparation method thereof | |
| Thakur et al. | Impact of pesticides used in agriculture: Their benefits and hazards | |
| CN106070294B (en) | A kind of composition pesticide of clothianidin-containing and triaguron | |
| CN105494354B (en) | A kind of mixed herbicide of the pyrazoles of grass containing sulphonyl and fluoroglycofen-ethyl | |
| CN105410006A (en) | Dinotefuran and nitenpyram compound water dispersible granule and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171124 |