CN107365055A - A kind of snuffbottle and preparation technology of double-deck color structure - Google Patents

A kind of snuffbottle and preparation technology of double-deck color structure Download PDF

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Publication number
CN107365055A
CN107365055A CN201710596972.5A CN201710596972A CN107365055A CN 107365055 A CN107365055 A CN 107365055A CN 201710596972 A CN201710596972 A CN 201710596972A CN 107365055 A CN107365055 A CN 107365055A
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parts
snuffbottle
double
color structure
crystal
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CN201710596972.5A
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CN107365055B (en
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伊兵
陈京田
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ZIBO ZICHUAN ZHENHUA GLASS PRODUCT Co Ltd
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ZIBO ZICHUAN ZHENHUA GLASS PRODUCT Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B9/00Blowing glass; Production of hollow glass articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Surface Treatment Of Glass (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)

Abstract

A kind of snuffbottle and preparation technology of double-deck color structure, belong to glassware technical field.It is characterized in that:There is frosted image layer on crystal layer inwall(4), outer crystal layer(1)With interior crystal layer(3)Between be partly or entirely provided with toner image layer(2).Preparation process is:The brilliant material melten glass liquid of water intaking is blow molded into glass envelope;It is tempered after dipping in 950 DEG C ~ 1050 DEG C of colorant after glass envelope cooling again;Then 1400 DEG C ~ 1450 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, temperature is moved back and obtains bottle;Then sandblasting is carried out to the inwall of bottle and inside-paint produces.The drawing of this snuffbottle has a sense of hierarchy, and far and near scape stereoeffect can be presented in bi level image.

Description

A kind of snuffbottle and preparation technology of double-deck color structure
Technical field
A kind of snuffbottle and preparation technology of double-deck color structure, belong to glassware technical field.
Background technology
Snuffbottle is a kind of traditional arts and crafts, starts from the Ming Dynasty, is contained in the Qing Dynasty.Interior painted snuff bottle comes across the last years of a dynasty or reign in Jiaqing road light Initial stage.It is with special small hook-shaped paintbrush, draws what is formed in transparent kettle.Initial interior painted snuff bottle is that inwall does not have There is the clear glass kettle of frosted, because inner wall smooth is not easy attachment ink and color, some simple pictures and pattern can only be drawn, than Such as:Katydid Chinese cabbage, dragon, the scenery with hills and waters of phoenix and simple pen, personage etc., later, artists' iron sand and diamond dust add water in snuffbottle Inner face back and forth shake mill, the ground glass for so making the inwall of snuffbottle be creamy white is fine and smooth and rough, easily attachment ink Color, effect is the same as rice paper, and some finer works occurred later in interior painted snuff bottle, developed into poetry calligraphy and painting still later And luxuriant art piece.Present snuffbottle only has the technique of this frosted drawing substantially, can be only formed the image of two dimension.This figure The Picture Showing power of picture is poor, can not form obvious third dimension.
The content of the invention
The technical problem to be solved in the present invention is:Overcome the deficiencies in the prior art, there is provided a kind of Picture Showing power is more preferable The snuffbottle and preparation technology of double-deck color structure.
The technical solution adopted for the present invention to solve the technical problems is:The snuffbottle of the double-deck color structure, including water Frosted image layer on crystal layer and crystal layer inwall, it is characterised in that:Described crystal layer is by outer crystal layer and interior crystal layer group Into outer crystal layer and interior crystal interlayer are partly or entirely provided with toner image layer.
A kind of snuffbottle with double-deck color structure of offer of the present invention, this snuffbottle is in kettle pars intramuralis in forming process In add toner image layer, the frosted image interlayer of the toner image layer and snuffbottle inwall has one layer of crystal layer, so makes The drawing for obtaining this snuffbottle has a sense of hierarchy, and far and near scape stereoeffect can be presented in bi level image.It can realize that internal layer Chinese realistic painting, outer layer are write The effect that the painting style actual situation of meaning combines.
Described frosted image layer is overlapping with toner image layer segment.Frosted image layer is overlapping with toner image layer segment Afterwards, two kinds of images are combined more naturally, image combination is closer, more aesthetic feeling.
A kind of preparation technology of the snuffbottle of above-mentioned double-deck color structure, it is characterised in that preparation process is:
1)1400 DEG C ~ 1450 DEG C of crystal material melten glass liquid is taken to be blow molded into glass envelope;
2)Glass envelope is cooled to 950 DEG C ~ 1050 DEG C of colorant is dipped in after 800 DEG C ~ 900 DEG C again after be tempered, adjusted in drawing process Whole body composition;
3)Then 1400 DEG C ~ 1450 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, moves back temperature Obtain bottle;
4)Then sandblasting is carried out to the inwall of bottle and inside-paint produces.
A kind of preparation technology of the snuffbottle with double-deck color structure of offer of the present invention, is frothed using glass metal Afterwards, toner image layer is preceded by, covers crystal again outside toner image layer so that the toner image that colorant transmutation generates in drawing process It is clipped among two glassy layers;So the frosted image interlayer of toner image layer and snuffbottle inwall is through forming one layer of crystal layer, water Crystal layer reaches a kind of fuzzy cloud and mist effect, drawing is formed strong stereovision, and the three-dimensional effect of far and near scape can be presented in bi level image Fruit.Two tomographic images, two kinds of image generation techniques realize the effect that the enjoyable painting style actual situation of internal layer Chinese realistic painting, outer layer combines.
Preferably, the parts by weight of raw materials composition of described crystal material melten glass liquid is:38 ~ 43 parts of soda ash, silica flour 94 ~ 101 parts, 1.5 ~ 2.5 parts of Fluorspar Powder, 0.7 ~ 1.3 part of aluminum oxide, 2.5 ~ 3.5 parts of sodium nitrate, 0.7 ~ 1.3 part of fining agent, calcium carbonate 8 ~ 12 parts.Base material of this crystal material as the present invention, it is the more crucial technical characteristic of of the invention one that it, which is formed,.This The toughness for the glass envelope that the composition for the crystal material that invention provides not only is blown is higher, and the attached property of extension for melting slurry to colorant is more preferable.And And its light transmittance and refractive index are more obvious to the stereovision of figure.
Preferably, the parts by weight of raw materials composition of described crystal material melten glass liquid is:40 parts of soda ash, 97 parts of silica flour, 2 parts of Fluorspar Powder, 1 part of aluminum oxide, 3 parts of sodium nitrate, 1 part of fining agent, 10 parts of calcium carbonate.The toughness of preferable crystal material glass envelope is most Height, the stereovision of imaging are most strong.
Colorant can use toner or/and coloured glaze material, when all toners are upper toner 4min ~ 5min, when all coloured glazes Glass material or time of painting during added with part coloured glaze material are 15 min ~ 20min.
Preferably, the temperature of the crystal material melten glass liquid is 1420 DEG C ~ 1430 DEG C.The temperature of glass metal mainly influences Viscosity and flow regime and then influence to froth state, the intensity for the glass envelope that preferable temperature of glass liquid is blown out is of a relatively high.
Preferably, the temperature of the tempering is 1200 DEG C ~ 1300 DEG C, time 120s ~ 180s.What the present invention provided returns The image that ignition technique is advantageous to toner image layer is presented, and color is more gorgeous.
Preferably, the furnace temperature that enters for moving back temperature is 450 DEG C ~ 500 DEG C.The process for moving back temperature takes around the time of one day, Entering furnace temperature and can influenceing the smoothness on snuffbottle surface to a certain extent for temperature is moved back, preferably moving back temperature and entering furnace temperature to make The feel of snuffbottle is more preferable.
Preferably, the glass envelope dips in colorant again after being cooled to 850 DEG C ~ 870 DEG C.
Compared with prior art, it is beneficial possessed by a kind of snuffbottle of double-deck color structure of the invention and preparation technology Effect is:The offer a kind of snuffbottle and preparation technology with double-deck color structure of the present invention, after being frothed using glass metal, Toner image layer is preceded by, covers crystal again outside toner image layer so that the toner image folder that colorant transmutation generates in drawing process Among two glassy layers;So the frosted image interlayer of toner image layer and snuffbottle inwall is through forming one layer of crystal layer, crystal Layer reaches a kind of fuzzy cloud and mist effect, drawing is formed strong stereovision, far and near scape stereoeffect can be presented in bi level image. Two tomographic images, two kinds of image generation techniques realize the effect that the enjoyable painting style actual situation of internal layer Chinese realistic painting, outer layer combines.So cause This snuffbottle is more to the expression way of image, and Picture Showing power is more preferable, and the image that can be imaged is more abundant, overall aesthetic feeling It is stronger.
Brief description of the drawings
Fig. 1 is the Product Rendering of the made snuffbottle of embodiments of the invention 1.
Fig. 2 is a kind of kettle body layer structure schematic diagram of the snuffbottle of double-deck color structure of the present invention.
Wherein:1st, outer crystal layer 2, toner image layer 3, the frosted image layer of interior crystal layer 4.
Embodiment
Fig. 1 is that the present invention will be further described for highly preferred embodiment of the present invention, below in conjunction with the accompanying drawings 2 and embodiment.
Referring to the drawings 2:A kind of snuffbottle of double-deck color structure of the present invention, its kettle body layer structure is from outside to inside successively For outer crystal layer 1, toner image layer 2, interior crystal layer 3, frosted image layer 4, frosted image layer 4 and the part of toner image layer 2 weight It is folded or not overlapping.
Embodiment 1
40 parts of soda ash by weight, 97 parts of silica flour, 2 parts of Fluorspar Powder, 1 part of aluminum oxide, 3 parts of sodium nitrate, 1 part of fining agent, carbonic acid 10 parts of preparation crystal material of calcium;
1)The melten glass liquid for being 1425 DEG C by the melting of crystal material, feeding are simultaneously blow molded into glass envelope;
2)Glass envelope is cooled to 1000 DEG C of colorant is dipped in after 860 DEG C again after be tempered, the temperature of tempering is 1250 DEG C, the time 150s, overall composition is adjusted in drawing process;
3)Then 1425 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, temperature is moved back and obtains bottle Body, that moves back temperature enters furnace temperature for 475 DEG C;
4)Then sandblasting is carried out to the inwall of bottle and inside-paint produces.The yield rate of the technique is 99.8%, two tomographic images of product With strong stereovision, stronger far and near scape stereoeffect is showed.
Embodiment 2
39 parts of soda ash by weight, 98 parts of silica flour, 1.7 parts of Fluorspar Powder, 1.1 parts of aluminum oxide, 2.7 parts of sodium nitrate, fining agent 1.2 Part, 9 parts of preparation crystal material of calcium carbonate;
1)The melten glass liquid for being 1420 DEG C by the melting of crystal material, feeding are simultaneously blow molded into glass envelope;
2)Glass envelope is cooled to 1025 DEG C of colorant is dipped in after 850 DEG C again after be tempered, the temperature of tempering is 1225 DEG C, the time 165s, overall composition is adjusted in drawing process;
3)Then 1420 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, temperature is moved back and obtains bottle Body, that moves back temperature enters furnace temperature for 460 DEG C;
4)Then sandblasting is carried out to the inwall of bottle and inside-paint produces.The yield rate of the technique is 99.4%, two tomographic images of product With strong stereovision, stronger far and near scape stereoeffect is showed.
Embodiment 3
41 parts of soda ash by weight, 95 parts of silica flour, 2.3 parts of Fluorspar Powder, 0.9 part of aluminum oxide, 3.2 parts of sodium nitrate, fining agent 0.9 Part, 11 parts of preparation crystal material of calcium carbonate;
1)The melten glass liquid for being 1430 DEG C by the melting of crystal material, feeding are simultaneously blow molded into glass envelope;
2)Glass envelope is cooled to 975 DEG C of colorant is dipped in after 870 DEG C again after be tempered, the temperature of tempering is 1275 DEG C, the time 135s, overall composition is adjusted in drawing process;
3)Then 1430 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, temperature is moved back and obtains bottle Body, that moves back temperature enters furnace temperature for 480 DEG C;
4)Then sandblasting is carried out to the inwall of bottle and inside-paint produces.The yield rate of the technique is 99.3%, two tomographic images of product With strong stereovision, stronger far and near scape stereoeffect is showed.
Embodiment 4
38 parts of soda ash by weight, 101 parts of silica flour, 1.5 parts of Fluorspar Powder, 1.3 parts of aluminum oxide, 2.5 parts of sodium nitrate, fining agent 1.3 parts, 8 parts of preparation crystal material of calcium carbonate;
1)The melten glass liquid for being 1400 DEG C by the melting of crystal material, feeding are simultaneously blow molded into glass envelope;
2)Glass envelope is cooled to 950 DEG C of colorant is dipped in after 800 DEG C again after be tempered, the temperature of tempering is 1200 DEG C, the time 180s, overall composition is adjusted in drawing process;
3)Then 1400 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, temperature is moved back and obtains bottle Body, that moves back temperature enters furnace temperature for 450 DEG C;
4)Then sandblasting is carried out to the inwall of bottle and inside-paint produces.The yield rate of the technique is 99.0%, two tomographic images of product With strong stereovision, stronger far and near scape stereoeffect is showed.
Embodiment 5
43 parts of soda ash by weight, 94 parts of silica flour, 2.5 parts of Fluorspar Powder, 0.7 part of aluminum oxide, 3.5 parts of sodium nitrate, fining agent 0.7 Part, 12 parts of preparation crystal material of calcium carbonate;
1)The melten glass liquid for being 1450 DEG C by the melting of crystal material, feeding are simultaneously blow molded into glass envelope;
2)Glass envelope is cooled to 1050 DEG C of colorant is dipped in after 900 DEG C again after be tempered, the temperature of tempering is 1300 DEG C, the time 120s, overall composition is adjusted in drawing process;
3)Then 1450 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, temperature is moved back and obtains bottle Body, that moves back temperature enters furnace temperature for 500 DEG C;
4)Then sandblasting is carried out to the inwall of bottle and inside-paint produces.The yield rate of the technique is 99.1%, two tomographic images of product With strong stereovision, stronger far and near scape stereoeffect is showed.
Comparative example 1
40 parts of soda ash by weight, 97 parts of silica flour, 2 parts of Fluorspar Powder, 1 part of aluminum oxide, 3 parts of sodium nitrate, 1 part of fining agent, carbonic acid 10 parts of preparation crystal material of calcium;
1)The melten glass liquid for being 1425 DEG C by the melting of crystal material, feeding are simultaneously blow molded into glass envelope;
2)Glass envelope is cooled to 860 DEG C of colorant is dipped in after 1000 DEG C again after be tempered, the temperature of tempering is 1250 DEG C, the time 150s, overall composition is adjusted in drawing process;
3)Then 1425 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, temperature is moved back and obtains bottle Body, that moves back temperature enters furnace temperature for 475 DEG C;
4)Then sandblasting is carried out to the inwall of bottle and inside-paint produces.The yield rate of the technique is 95.4%, two tomographic images of product Stereovision is not strong, toner image layer(2)Border unobvious.
Comparative example 2
74.6 parts of quartz sand by weight, 1.01 parts of aluminum oxide, 1.51 parts of aluminium hydroxide, 2.93 parts of boric acid, soda ash 25.19 parts, 8.06 parts of calcite, 5.02 parts of preparation crystal material of potassium carbonate;
1)The melten glass liquid for being 1425 DEG C by the melting of crystal material, feeding are simultaneously blow molded into glass envelope;
2)Glass envelope is cooled to 1000 DEG C of colorant is dipped in after 860 DEG C again after be tempered, the temperature of tempering is 1250 DEG C, the time 150s, overall composition is adjusted in drawing process;
3)Then 1425 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, temperature is moved back and obtains bottle Body, that moves back temperature enters furnace temperature for 475 DEG C;
4)Then sandblasting is carried out to the inwall of bottle and inside-paint produces.The yield rate of the technique is 79.8%, two tomographic images of product Fuzzy pictures, without stereovision.
The above described is only a preferred embodiment of the present invention, being not the limitation for making other forms to the present invention, appoint What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc. Imitate embodiment.But it is every without departing from technical solution of the present invention content, the technical spirit according to the present invention is to above example institute Any simple modification, equivalent variations and the remodeling made, still fall within the protection domain of technical solution of the present invention.

Claims (9)

1. a kind of snuffbottle of double-deck color structure, including the frosted image layer on crystal layer and crystal layer inwall(4), its feature It is:Described crystal layer is by outer crystal layer(1)With interior crystal layer(3)Composition, outer crystal layer(1)With interior crystal layer(3)Between portion Divide or all provided with toner image layer(2).
A kind of 2. snuffbottle of double-deck color structure according to claim 1, it is characterised in that:Described frosted image layer (4)With toner image layer(2)Partly overlap.
3. the preparation technology of the snuffbottle of the double-deck color structure described in a kind of claim 1 or 2, it is characterised in that prepare step Suddenly it is:
1)1400 DEG C ~ 1450 DEG C of crystal material melten glass liquid is taken to be blow molded into glass envelope;
2)Glass envelope is cooled to 950 DEG C ~ 1050 DEG C of colorant is dipped in after 800 DEG C ~ 900 DEG C again after be tempered, adjusted in drawing process Whole body composition;
3)Then 1400 DEG C ~ 1450 DEG C of crystal material melten glass liquid is dipped again carries out set crystal;After-blow manufacture type is taken out, moves back temperature Obtain bottle;
4)Then sandblasting is carried out to the inwall of bottle and inside-paint produces.
A kind of 4. preparation technology of the snuffbottle of double-deck color structure according to claim 3, it is characterised in that:Described The parts by weight of raw materials of crystal material melten glass liquid forms:38 ~ 43 parts of soda ash, 94 ~ 101 parts of silica flour, Fluorspar Powder 1.5 ~ 2.5 Part, 0.7 ~ 1.3 part of aluminum oxide, 2.5 ~ 3.5 parts of sodium nitrate, 0.7 ~ 1.3 part of fining agent, 8 ~ 12 parts of calcium carbonate.
A kind of 5. preparation technology of the snuffbottle of double-deck color structure according to claim 3 or 4, it is characterised in that:Institute The parts by weight of raw materials for the crystal material melten glass liquid stated forms:40 parts of soda ash, 97 parts of silica flour, 2 parts of Fluorspar Powder, aluminum oxide 1 Part, 3 parts of sodium nitrate, 1 part of fining agent, 10 parts of calcium carbonate.
A kind of 6. preparation technology of the snuffbottle of double-deck color structure according to claim 3, it is characterised in that:The water The temperature of crystalline substance material melten glass liquid is 1420 DEG C ~ 1430 DEG C.
A kind of 7. preparation technology of the snuffbottle of double-deck color structure according to claim 3, it is characterised in that:The institute The temperature for stating tempering is 1200 DEG C ~ 1300 DEG C, time 120s ~ 180s.
A kind of 8. preparation technology of the snuffbottle of double-deck color structure according to claim 3, it is characterised in that:It is described to move back Temperature enters furnace temperature for 450 DEG C ~ 500 DEG C.
A kind of 9. preparation technology of the snuffbottle of double-deck color structure according to claim 3, it is characterised in that:The glass Glass bubble dips in colorant again after being cooled to 850 DEG C ~ 870 DEG C.
CN201710596972.5A 2017-07-20 2017-07-20 Preparation process of snuff bottle with double-layer color structure Active CN107365055B (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101746943A (en) * 2009-12-10 2010-06-23 大连通宝工艺品有限公司 Glass pierced process
CN105948514A (en) * 2016-05-17 2016-09-21 齐鲁工业大学 Method for manufacturing colorful transparent colored glass ceramics with high degree of crystallinity by adopting fusing-cooling method for crystallization

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101746943A (en) * 2009-12-10 2010-06-23 大连通宝工艺品有限公司 Glass pierced process
CN105948514A (en) * 2016-05-17 2016-09-21 齐鲁工业大学 Method for manufacturing colorful transparent colored glass ceramics with high degree of crystallinity by adopting fusing-cooling method for crystallization

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