CN106746631B - A kind of sky blue glassware - Google Patents

A kind of sky blue glassware Download PDF

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Publication number
CN106746631B
CN106746631B CN201611103647.2A CN201611103647A CN106746631B CN 106746631 B CN106746631 B CN 106746631B CN 201611103647 A CN201611103647 A CN 201611103647A CN 106746631 B CN106746631 B CN 106746631B
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China
Prior art keywords
content
raw material
melting furnaces
glassware
glass
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CN201611103647.2A
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Chinese (zh)
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CN106746631A (en
Inventor
郑波
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SHANDONG SANHUI GLASS CO Ltd
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SHANDONG SANHUI GLASS CO Ltd
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Priority to CN201611103647.2A priority Critical patent/CN106746631B/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/04Opacifiers, e.g. fluorides or phosphates; Pigments
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B18/00Shaping glass in contact with the surface of a liquid
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/18Stirring devices; Homogenisation
    • C03B5/193Stirring devices; Homogenisation using gas, e.g. bubblers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/235Heating the glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/02Compositions for glass with special properties for coloured glass

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

It is made of glass raw material and colorant raw material, the composition and parts by weight of glass raw material are as follows: SiO the invention discloses a kind of sky blue glassware2The quartz sand 54.5-58%, Al that content is 99%2O3The aluminium hydroxide 3.5-5%, Na that content is 65%2The soda ash 23.3- 26.8% that O content is 57%, the calcite 14.7-18% that CaO content is 56%, the composition and parts by weight of colorant raw material are as follows: the copper oxide 0.5-1% that CuO content is 99%, sky blue glassware produced by the invention has the characteristics that surface is smooth, color profit is tender, color is deep, colorant volatile quantity is low, it ensure that product quality, and production cost is greatly reduced.

Description

A kind of sky blue glassware
Technical field
The present invention relates to a kind of glasswares, and in particular to a kind of sky blue glassware.
Background technique
In recent years, the use with the continuous improvement of people's living standard and quality of life, life pursuit, to glassware It is required that also higher and higher.Demand of the people to glassware is also not solely restricted to it using functionally, it is often more important that in day When normal personal consumption, a kind of life taste is pursued, and enjoy to colorful glassware aesthetic feeling.It therefore, is constantly satisfaction The growing life requirement of people occurs carrying out glassware appearance the spraying of the environment-friendly water-based paint of multicolour in recent years Processing, i.e. sprayed glass product.Although sprayed glass product be from the appearance it is colourful, lose the transparent of glass Sense, thus make one to be obstructed on visual perception, lack a kind of relaxing feeling, and the stained glass work of ecosystem is not only It is sparkling and crystal-clear from outside to inside thorough, and give people a kind of pure and fresh and simple feeling, allow people to feel especially comfortable, especially sky blue glass Glass product, the fine and smooth oil of quality is tender, even more to a kind of wide blue sky of people as deep sense, be that a kind of class is high, the market demand The glass product having a high potential.And production uses crucible furnace production technology before, belongs to intermittent production not only low output, and And restricted by production technology, material matter and material color are extremely unstable, and poor product quality, production limitation is big, thus whether Yield or quality are all far from satisfying the demand in market.
Summary of the invention
For existing blue tinted glass poor transparency, texture is coarse, the deficiency of the technical aspects such as low output, and the present invention passes through excellent Change formula, a kind of process with electric smelter production sky blue glassware is provided.
A kind of sky blue glassware, it is characterised in that: it is the glassware made of glass raw material and colorant raw material,
The composition and parts by weight of the glass raw material are as follows:
SiO2The quartz sand 54.5-58% that content is 99%
Al2O3The aluminium hydroxide 3.5-5% that content is 65%
Na2The soda ash 23.3-26.8% that O content is 57%
The calcite 14.7-18% that CaO content is 56%
The composition and parts by weight of the colorant raw material are as follows:
The copper oxide 0.5-1% that CuO content is 99%.
A kind of sky blue glassware, it is characterised in that: it is the glassware made of glass raw material and colorant raw material,
Preferably, the composition of the glass raw material and parts by weight are as follows:
SiO2The quartz sand 56.75% that content is 99%
Al2O3The aluminium hydroxide 4.05% that content is 65%
Na2The soda ash 23.6% that O content is 57%
The calcite 14.85% that CaO content is 56%
Preferably, the composition of the colorant raw material and parts by weight are as follows:
The copper oxide 0.75% that CuO content is 99%.
After mixing by glass raw material and colorant raw material, batch enters melting furnaces.Controlling melting furnaces hot(test)-spot temperature is 1585℃;Melting furnaces Nei Liaotan area's atmosphere is that reducing atmosphere is (still unfused to match after the area Liao Tan refers to that glass batch enters melting furnaces Close the region of material aggregation);Adjusting burner gun angle is 14 degree (angle on horizontal alignment);Air excess system is controlled simultaneously Number is 0.95.Bubbler is opened, 14 nozzles are bubbled jet, and gas source is H2And N2Mixed gas, H2Bulk density be 3.8%, mixed gas flow 2.5m3/h;Melting furnaces pull amount is the 85% of melting furnaces full load condition;Melten glass liquid is through equal After changing, clarify, being cooling, pulls and form into molten tin bath.
Test the presentation quality survey report of sky blue glass of the present invention:
Test the quality inspection report of sky blue glass of the present invention:
Using sky blue glassware produced by the invention, quality is fine and smooth, not only has and manages thorough, pure and fresh honesty Effect also has the characteristics that surface is smooth, color profit is tender, and without carrying out deep processing, can obtain extremely strong sky blue color depth Remote sense.And the invention can be in the enterprising professional etiquette modelling continuous and stable production of electric smelter, and colorant volatile quantity is low, not only can be big The big quality for improving product, can also reduce product cost, production kind can produce glassware, glass bar, glass extensively There is the glasswares such as glass pipe good market development space to have filled up the country with high economic benefits and social benefits The blank of electric smelter production sky blue glassware.
Specific embodiment
Embodiment one, a kind of sky blue glassware, it is characterised in that: be made of glass raw material and colorant raw material Glassware,
The composition and parts by weight of glass raw material are as follows:
SiO2The quartz sand 54.5% that content is 99%
Al2O3The aluminium hydroxide 3.8% that content is 65%
Na2The soda ash 25.9% that O content is 57%
The calcite 15.2% that CaO content is 56%
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.6% that CuO content is 99%.
After mixing by glass raw material and colorant raw material, batch enters melting furnaces.Controlling melting furnaces hot(test)-spot temperature is 1585℃;Melting furnaces Nei Liaotan area's atmosphere is that reducing atmosphere is (still unfused to match after the area Liao Tan refers to that glass batch enters melting furnaces Close the region of material aggregation);Adjusting burner gun angle is 14 degree (angle on horizontal alignment);Air excess system is controlled simultaneously Number is 0.95.Bubbler is opened, 14 nozzles are bubbled jet, and gas source is H2And N2Mixed gas, H2Bulk density be 3.8%, mixed gas flow 2.5m3/h;Melting furnaces pull amount is the 85% of melting furnaces full load condition;Melten glass liquid is through equal After changing, clarify, being cooling, pulls and form into molten tin bath.
Embodiment two, a kind of sky blue glassware, it is characterised in that: be made of glass raw material and colorant raw material Glassware,
The composition and parts by weight of glass raw material are as follows:
SiO2The quartz sand 56.75% that content is 99%
Al2O3The aluminium hydroxide 4.05% that content is 65%
Na2The soda ash 23.6% that O content is 57%
The calcite 14.85% that CaO content is 56%
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.75% that CuO content is 99%.
After mixing by glass raw material and colorant raw material, batch enters melting furnaces.Controlling melting furnaces hot(test)-spot temperature is 1585℃;Melting furnaces Nei Liaotan area's atmosphere is that reducing atmosphere is (still unfused to match after the area Liao Tan refers to that glass batch enters melting furnaces Close the region of material aggregation);Adjusting burner gun angle is 14 degree (angle on horizontal alignment);Air excess system is controlled simultaneously Number is 0.95.Bubbler is opened, 14 nozzles are bubbled jet, and gas source is H2And N2Mixed gas, H2Bulk density be 3.8%, mixed gas flow 2.5m3/h;Melting furnaces pull amount is the 85% of melting furnaces full load condition;Melten glass liquid is through equal After changing, clarify, being cooling, pulls and form into molten tin bath.
Embodiment three, a kind of sky blue glassware, it is characterised in that: be made of glass raw material and colorant raw material Glassware,
The composition and parts by weight of glass raw material are as follows:
SiO2The quartz sand 56.2% that content is 99%
Al2O3The aluminium hydroxide 4.1% that content is 65%
Na2The soda ash 23.9% that O content is 57%
The calcite 15.1% that CaO content is 56%
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.7% that CuO content is 99%.
After mixing by glass raw material and colorant raw material, batch enters melting furnaces.Controlling melting furnaces hot(test)-spot temperature is 1585℃;Melting furnaces Nei Liaotan area's atmosphere is that reducing atmosphere is (still unfused to match after the area Liao Tan refers to that glass batch enters melting furnaces Close the region of material aggregation);Adjusting burner gun angle is 14 degree (angle on horizontal alignment);Air excess system is controlled simultaneously Number is 0.95.Bubbler is opened, 14 nozzles are bubbled jet, and gas source is H2And N2Mixed gas, H2Bulk density be 3.8%, mixed gas flow 2.5m3/h;Melting furnaces pull amount is the 85% of melting furnaces full load condition;Melten glass liquid is through equal After changing, clarify, being cooling, pulls and form into molten tin bath.

Claims (2)

1. a kind of sky blue glassware, it is characterised in that: be the glassware made of glass raw material and colorant raw material, institute Composition and the parts by weight for stating glass raw material are as follows:
SiO2The quartz sand 54.5-58% that content is 99%,
Al2O3The aluminium hydroxide 3.5-5% that content is 65%,
Na2The soda ash 23.3-26.8% that O content is 57%,
The calcite 14.7-18% that CaO content is 56%,
The composition and parts by weight of the colorant raw material are as follows:
The copper oxide 0.5-1% that CuO content is 99%;
After mixing by glass raw material and colorant raw material, batch enters melting furnaces;Controlling melting furnaces hot(test)-spot temperature is 1585 DEG C;
Melting furnaces Nei Liaotan area's atmosphere be reducing atmosphere (after the area Liao Tan refers to that glass batch enters melting furnaces, still unfused cooperation Expect the region of aggregation);Adjusting burner gun angle is 14 degree (angle on horizontal alignment);Coefficient of excess air is controlled simultaneously It is 0.95;
Bubbler is opened, 14 nozzles are bubbled jet, and gas source is H2And N2Mixed gas, H2Bulk density be 3.8%, mix Conjunction gas flow is 2.5m3/h;Melting furnaces pull amount is the 85% of melting furnaces full load condition;Melten glass liquid is homogenized, clarifies, is cold But it after, pulls and forms into molten tin bath.
2. a kind of sky blue glassware according to claim 1, it is characterised in that:
The composition and parts by weight of the glass raw material are as follows:
SiO2The quartz sand 56.75% that content is 99%
Al2O3The aluminium hydroxide 4.05% that content is 65%
Na2The soda ash 23.6% that O content is 57%
The calcite 14.85% that CaO content is 56%
The copper oxide 0.75% that CuO content is 99%.
CN201611103647.2A 2016-12-05 2016-12-05 A kind of sky blue glassware Active CN106746631B (en)

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Application Number Priority Date Filing Date Title
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CN106746631B true CN106746631B (en) 2019-06-07

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108314317B (en) * 2018-01-30 2020-06-23 威海畅享海天新材料科技有限公司 Glass tube and manufacturing method thereof
CN109336402A (en) * 2018-12-07 2019-02-15 重庆家喜陶瓷制品有限公司合川分公司 A kind of preparation process of sky blue implosion guard product

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101734856B (en) * 2009-12-31 2012-05-23 山东省药用玻璃股份有限公司 Glaucous medicinal glass bottle and manufacture method thereof
CN105776860A (en) * 2016-02-15 2016-07-20 李贻亚 Sapphire blue glass and preparation technology thereof

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Denomination of invention: Sky blue glass product

Effective date of registration: 20220225

Granted publication date: 20190607

Pledgee: Rizhao Donggang Rural Commercial Bank Co.,Ltd.

Pledgor: SHANDONG SANHUI GLASS Co.,Ltd.

Registration number: Y2022980001889