CN109502974A - Blue tinted glass product - Google Patents
Blue tinted glass product Download PDFInfo
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- CN109502974A CN109502974A CN201910084889.9A CN201910084889A CN109502974A CN 109502974 A CN109502974 A CN 109502974A CN 201910084889 A CN201910084889 A CN 201910084889A CN 109502974 A CN109502974 A CN 109502974A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of blue tinted glass products, it is characterised in that: the glassware made of glass raw material and colorant raw material, the composition and parts by weight of the glass raw material are as follows: SiO2The quartz sand 71-76%, Al that content is 99%2O3The aluminium hydroxide 1-4%, Na that content is 65%2The soda ash 13-16% that O content is 57%, the calcite 5-10% that CaO content is 56%；The composition and parts by weight of the colorant raw material are as follows: the copper oxide 0.4-1.0%, composite coloration agent 0.0-1% that CuO content is 99%.The present invention uses above-mentioned blue tinted glass product, and surface is smooth, color profit is tender, color is deep, and colorant volatile quantity is low, ensure that product quality, and production cost substantially reduces.
Description
Technical field
The present invention relates to glassware technical fields, more particularly to a kind of blue tinted glass product.
Background technique
In recent years, the use with the continuous improvement of people's living standard and quality of life, life pursuit, to glassware
It is required that also higher and higher.Demand of the people to glassware is also not solely restricted to it using functionally, it is often more important that in day
When normal personal consumption, a kind of life taste is pursued, and enjoy to colorful glassware aesthetic feeling.It therefore, is constantly satisfaction
The growing life requirement of people occurs carrying out glassware appearance the spray treatment of the environment-friendly water-based paint of multicolour,
That is sprayed glass product.
Although sprayed glass product be from the appearance it is colourful, lose the transparent feel of glass, thus make one
It is obstructed on visual perception, lacks a kind of relaxing feeling, and the stained glass work of ecosystem is not only brilliant from outside to inside
It is lustrous and transparent thorough, and give people a kind of pure and fresh and simple feeling, allow people to feel especially comfortable, especially sky blue glassware, matter
The fine and smooth oil in ground is tender, even more to a kind of wide blue sky of people as deep sense, be that a kind of class is high, what there is a huge market demand potential
Glass product.Also, production uses crucible furnace production technology before, belongs to intermittent production not only low output, and produced
The restriction of technique, material matter and material color it is extremely unstable, poor product quality, production limitation it is big, thus whether yield or
Quality is all far from satisfying the demand in market.
Summary of the invention
The object of the present invention is to provide a kind of blue tinted glass product, surface is smooth, color profit is tender, color is deep, colorant
Volatile quantity is low, ensure that product quality, and production cost is greatly reduced.
To achieve the above object, the present invention provides a kind of blue tinted glass products, by glass raw material and colorant raw material system
At glassware, the composition and parts by weight of the glass raw material be as follows:
The composition and parts by weight of the colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
The composite coloration agent is one or both of cobalt oxide, chromium oxide.
Preferably, the composition of the glass raw material and parts by weight are as follows:
The composition and parts by weight of the colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
The composite coloration agent is one or both of cobalt oxide, chromium oxide.
Preferably, the composition of the glass raw material and parts by weight are as follows:
The composition and parts by weight of the colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
The composite coloration agent is one or both of cobalt oxide, chromium oxide.
Preferably, the manufacture craft of the blue tinted glass product includes the following steps:
S1, by glass raw material and colorant raw material after mixing, melted；
S2, the material after mixing is added in tank furnace, control melting furnaces hot(test)-spot temperature is 1520-1580 DEG C, expects blanket in melting furnaces
Area's atmosphere is reducing atmosphere (after the area Liao Tan refers to that glass batch enters melting furnaces, the region of still unfused batch aggregation),
It 0.6-1.5 Kgfs of pipeline pressure, Secondary Air frequency 20-30HZ, adjusts flame angle 0-15 degree (angle on horizontal alignment),
Controlling coefficient of excess air simultaneously is 5-10%；
Bottom of pond bubbler is opened, carries out jet bubbling using 6-10 nozzle, 0.15-0.25 kilograms of compressed air pressure
Power；Melting furnaces pull amount is the 85% of melting furnaces full load condition；Melten glass liquid is homogenized, clarifies, after cooling, raw into supply channel
It produces.
Preferably, the manufacture craft of the blue tinted glass product includes the following steps:
S1, by glass raw material and colorant raw material after mixing, melted；
S2, it after being added to the material after mixing and being completely melt in electric smelter, flows into balancing reservoir and is homogenized, finally casting is
It can；
The use parameter of electric smelter is as follows:
The use parameter of balancing reservoir is as follows:
Therefore, the present invention uses above-mentioned blue tinted glass product, and using blue tinted glass product produced by the invention, quality is thin
It is greasy, not only have the effect of managing thorough, pure and fresh honesty also have the characteristics that surface is smooth, color profit is tender, and without carrying out
Deep processing can obtain the extremely strong deep sense of blue.Copper has two kinds of forms of monovalence and divalent in glass, and bivalent cupric ion makes
Blue-green is presented in glass, and under 1500 DEG C or so of high-temperature condition, copper ion only occurs with the state of divalent.Cobalt in glass one
As with Co2+Form exist, make glass that blue be presented, and it is coloring stabilized, be not affected by other factors.Chromium can make glass cause Huang
Green or yellow coloring.Colorant is suitably cooperated, the glassware of different blue casts can be made.
The present invention can have more obvious advantage, the present invention compared to common crucible in electric smelter, natural gas kiln
Scale continuous and stable production can be achieved, colorant volatile quantity is low, can not only greatly improve the quality of product, can also reduce
Product cost, production kind can produce the glasswares such as glassware, glass bar, glass tube extensively, have good city
Field development space has filled up domestic electric smelter, natural gas kiln produces blue glass with high economic benefits and social benefits
The blank of glass product.
Test the presentation quality survey report of sky blue glassware of the present invention:
Test the quality inspection report of sky blue glassware of the present invention:
| Detection project title | Technical requirements | Inspection result | Individual event determines |
| Thermal shock resistance, DEG C | ≥35 | Crack-free at 35 DEG C | It is qualified |
| Aluminium, mg/L | ≤1.5 | < 0.5 | It is qualified |
| Cadmium, mg/L | ≤0.5 | < 0.1 | It is qualified |
| Arsenic, mg/L | ≤0.2 | < 0.001 | It is qualified |
| Antimony, mg/L | ≤1.2 | 0.06 | It is qualified |
Below by embodiment, technical scheme of the present invention will be described in further detail.
Specific embodiment
Embodiments of the present invention are described further below.
Embodiment one
A kind of blue tinted glass product, the glassware made of glass raw material and colorant raw material, the composition of glass raw material
And parts by weight are as follows:
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
Composite coloration agent is one or both of cobalt oxide, chromium oxide.
The manufacture craft of blue tinted glass product includes the following steps:
S1, by glass raw material and colorant raw material after mixing, melted；
S2, the material after mixing is added in tank furnace, control melting furnaces hot(test)-spot temperature is 1520-1580 DEG C, expects blanket in melting furnaces
Area's atmosphere is reducing atmosphere (after the area Liao Tan refers to that glass batch enters melting furnaces, the region of still unfused batch aggregation),
It 0.6-1.5 Kgfs of pipeline pressure, Secondary Air frequency 20-30HZ, adjusts flame angle 0-15 degree (angle on horizontal alignment),
Controlling coefficient of excess air simultaneously is 5-10%；
Bottom of pond bubbler is opened, carries out jet bubbling using 6-10 nozzle, 0.15-0.25 kilograms of compressed air pressure
Power；Melting furnaces pull amount is the 85% of melting furnaces full load condition；Melten glass liquid is homogenized, clarifies, after cooling, raw into supply channel
It produces.
Embodiment two
A kind of blue tinted glass product, the glassware made of glass raw material and colorant raw material, the composition of glass raw material
And parts by weight are as follows:
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
Composite coloration agent is one or both of cobalt oxide, chromium oxide.
The manufacture craft of blue tinted glass product includes the following steps:
S1, by glass raw material and colorant raw material after mixing, melted；
S2, it after being added to the material after mixing and being completely melt in electric smelter, flows into balancing reservoir and is homogenized, finally casting is
It can；
The use parameter of electric smelter is as follows:
The use parameter of balancing reservoir is as follows:
Embodiment three
The composition and parts by weight of glass raw material are as follows:
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
Composite coloration agent is one or both of cobalt oxide, chromium oxide.
Example IV
The composition and parts by weight of glass raw material are as follows:
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
Composite coloration agent is one or both of cobalt oxide, chromium oxide.
Embodiment five
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.9% that CuO content is 99%
Cobalt oxide 0.05%.
Embodiment six
The composition and parts by weight of glass raw material are as follows:
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.7% that CuO content is 99%.
Embodiment seven
The composition and parts by weight of glass raw material are as follows:
The composition and parts by weight of colorant raw material are as follows:
The copper oxide 0.5% that CuO content is 99%
Chromium oxide 1%.
Therefore, the present invention uses above-mentioned blue tinted glass product, and surface is smooth, color profit is tender, color is deep, colorant volatilization
It measures low, ensure that product quality, and production cost is greatly reduced.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than is limited,
Although the present invention is described in detail with reference to preferred embodiments, those skilled in the art should understand that: its according to
So can be with modification or equivalent replacement of the technical solution of the present invention are made, and these modifications or equivalent replacement cannot also make to repair
Technical solution after changing is detached from the spirit and scope of technical solution of the present invention.
Claims (5)
1. a kind of blue tinted glass product, it is characterised in that: the glassware made of glass raw material and colorant raw material, the glass
The composition and parts by weight of glass raw material are as follows:
The composition and parts by weight of the colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
The composite coloration agent is one or both of cobalt oxide, chromium oxide.
2. blue tinted glass product according to claim 1, it is characterised in that:
The composition and parts by weight of the glass raw material are as follows:
The composition and parts by weight of the colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
The composite coloration agent is one or both of cobalt oxide, chromium oxide.
3. blue tinted glass product according to claim 1, it is characterised in that:
The composition and parts by weight of the glass raw material are as follows:
The composition and parts by weight of the colorant raw material are as follows:
The copper oxide 0.4-1.0% that CuO content is 99%
Composite coloration agent 0.0-1%
The composite coloration agent is one or both of cobalt oxide, chromium oxide.
4. blue tinted glass product according to claim 1, which is characterized in that the manufacture craft packet of the blue tinted glass product
Include following steps:
S1, by glass raw material and colorant raw material after mixing, melted；
S2, the material after mixing is added in tank furnace, control melting furnaces hot(test)-spot temperature is 1520-1580 DEG C, the area melting furnaces Nei Liaotan gas
Atmosphere is reducing atmosphere (after the area Liao Tan refers to that glass batch enters melting furnaces, the region of still unfused batch aggregation), pipeline
It 0.6-1.5 Kgfs of pressure, Secondary Air frequency 20-30HZ, adjusts flame angle 0-15 degree (angle on horizontal alignment), simultaneously
Control coefficient of excess air is 5-10%；
Bottom of pond bubbler is opened, carries out jet bubbling using 6-10 nozzle, 0.15-0.25 Kgfs of compressed air pressure；It is molten
Kiln pull amount is the 85% of melting furnaces full load condition；Melten glass liquid is homogenized, clarifies, after cooling, produces into supply channel.
5. blue tinted glass product according to claim 1, which is characterized in that the manufacture craft packet of the blue tinted glass product
Include following steps:
S1, by glass raw material and colorant raw material after mixing, melted；
S2, it after being added to the material after mixing and being completely melt in electric smelter, flows into balancing reservoir and is homogenized, be finally poured；
The use parameter of electric smelter is as follows:
The use parameter of balancing reservoir is as follows:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910084889.9A CN109502974A (en) | 2019-01-29 | 2019-01-29 | Blue tinted glass product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910084889.9A CN109502974A (en) | 2019-01-29 | 2019-01-29 | Blue tinted glass product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109502974A true CN109502974A (en) | 2019-03-22 |
Family
ID=65758222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910084889.9A Withdrawn CN109502974A (en) | 2019-01-29 | 2019-01-29 | Blue tinted glass product |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109502974A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111635132A (en) * | 2020-06-15 | 2020-09-08 | 山东三汇玻璃有限公司 | Green glass product |
| CN111977978A (en) * | 2020-09-09 | 2020-11-24 | 沂南三汇玻璃有限公司 | Jade-sapphire-blue-imitated glass and preparation method thereof |
-
2019
- 2019-01-29 CN CN201910084889.9A patent/CN109502974A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111635132A (en) * | 2020-06-15 | 2020-09-08 | 山东三汇玻璃有限公司 | Green glass product |
| CN111977978A (en) * | 2020-09-09 | 2020-11-24 | 沂南三汇玻璃有限公司 | Jade-sapphire-blue-imitated glass and preparation method thereof |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190322 |
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| WW01 | Invention patent application withdrawn after publication |