CN107354248B - A kind of fungi-proofing light maintaining agent of fur clothing and preparation method thereof - Google Patents
A kind of fungi-proofing light maintaining agent of fur clothing and preparation method thereof Download PDFInfo
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- CN107354248B CN107354248B CN201710488628.4A CN201710488628A CN107354248B CN 107354248 B CN107354248 B CN 107354248B CN 201710488628 A CN201710488628 A CN 201710488628A CN 107354248 B CN107354248 B CN 107354248B
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- fur clothing
- fungi
- maintaining agent
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- 238000002360 preparation method Methods 0.000 title claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 50
- 108010022355 Fibroins Proteins 0.000 claims abstract description 44
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 31
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 31
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 27
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003112 inhibitor Substances 0.000 claims abstract description 22
- 239000004615 ingredient Substances 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 239000002480 mineral oil Substances 0.000 claims abstract description 10
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 10
- -1 propyl amide amine Chemical class 0.000 claims abstract description 10
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims abstract description 9
- 238000000605 extraction Methods 0.000 claims abstract description 9
- 229920002545 silicone oil Polymers 0.000 claims abstract description 9
- 239000004359 castor oil Substances 0.000 claims abstract description 8
- 235000019438 castor oil Nutrition 0.000 claims abstract description 8
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 8
- MKYLOMHWHWEFCT-UHFFFAOYSA-N Manthidine Natural products C1C2=CC=3OCOC=3C=C2C2C3=CC(OC)C(O)CC3N1C2 MKYLOMHWHWEFCT-UHFFFAOYSA-N 0.000 claims abstract description 7
- SNFRINMTRPQQLE-JQWAAABSSA-N Montanin Chemical compound O[C@H]([C@@]1(CO)O[C@H]1[C@H]1[C@H]2O3)[C@]4(O)C(=O)C(C)=C[C@H]4[C@]11OC3(CCCCCCCCCCC)O[C@@]2(C(C)=C)C[C@H]1C SNFRINMTRPQQLE-JQWAAABSSA-N 0.000 claims abstract description 7
- SNFRINMTRPQQLE-OFGNMXNXSA-N Montanin Natural products O=C1[C@@]2(O)[C@@H](O)[C@@]3(CO)O[C@H]3[C@@H]3[C@H]4[C@@]5(C(=C)C)O[C@](CCCCCCCCCCC)(O4)O[C@@]3([C@H](C)C5)[C@@H]2C=C1C SNFRINMTRPQQLE-OFGNMXNXSA-N 0.000 claims abstract description 7
- QTZPBQMTXNEKRX-UHFFFAOYSA-N Voacristine pseudoindoxyl Natural products N1C2=CC=C(OC)C=C2C(=O)C21CCN(C1)C3C(C(C)O)CC1CC32C(=O)OC QTZPBQMTXNEKRX-UHFFFAOYSA-N 0.000 claims abstract description 7
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940043264 dodecyl sulfate Drugs 0.000 claims abstract description 6
- 241001122767 Theaceae Species 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 11
- 108090000623 proteins and genes Proteins 0.000 claims description 9
- 102000004169 proteins and genes Human genes 0.000 claims description 9
- 239000001110 calcium chloride Substances 0.000 claims description 8
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 8
- 235000019441 ethanol Nutrition 0.000 claims description 8
- 229910001868 water Inorganic materials 0.000 claims description 8
- 238000000502 dialysis Methods 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- YAZSBRQTAHVVGE-UHFFFAOYSA-N 2-aminobenzenesulfonamide Chemical compound NC1=CC=CC=C1S(N)(=O)=O YAZSBRQTAHVVGE-UHFFFAOYSA-N 0.000 claims description 5
- HLTDBMHJSBSAOM-UHFFFAOYSA-N 2-nitropyridine Chemical compound [O-][N+](=O)C1=CC=CC=N1 HLTDBMHJSBSAOM-UHFFFAOYSA-N 0.000 claims description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical group [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 5
- JZFICWYCTCCINF-UHFFFAOYSA-N Thiadiazin Chemical compound S=C1SC(C)NC(C)N1CCN1C(=S)SC(C)NC1C JZFICWYCTCCINF-UHFFFAOYSA-N 0.000 claims description 5
- 229930013930 alkaloid Natural products 0.000 claims description 5
- 125000003275 alpha amino acid group Chemical group 0.000 claims description 5
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 5
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims description 5
- 229960002218 sodium chlorite Drugs 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 150000003797 alkaloid derivatives Chemical class 0.000 claims description 4
- 125000005605 benzo group Chemical group 0.000 claims 1
- 235000011148 calcium chloride Nutrition 0.000 claims 1
- 150000002460 imidazoles Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 22
- 238000012423 maintenance Methods 0.000 abstract description 19
- 230000002688 persistence Effects 0.000 abstract description 6
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 244000269722 Thea sinensis Species 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 241000233866 Fungi Species 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 210000000170 cell membrane Anatomy 0.000 description 3
- 210000002421 cell wall Anatomy 0.000 description 3
- 230000002538 fungal effect Effects 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- 230000002779 inactivation Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000010534 mechanism of action Effects 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 230000004060 metabolic process Effects 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 230000004763 spore germination Effects 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- DECCMEWNXSNSDO-ZLUOBGJFSA-N Ala-Cys-Ala Chemical compound C[C@H](N)C(=O)N[C@@H](CS)C(=O)N[C@@H](C)C(O)=O DECCMEWNXSNSDO-ZLUOBGJFSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- HQIZDMIGUJOSNI-IUCAKERBSA-N Arg-Gly-Arg Chemical compound N[C@@H](CCCNC(N)=N)C(=O)NCC(=O)N[C@@H](CCCNC(N)=N)C(O)=O HQIZDMIGUJOSNI-IUCAKERBSA-N 0.000 description 1
- LFAUVOXPCGJKTB-DCAQKATOSA-N Arg-Ser-His Chemical compound C1=C(NC=N1)C[C@@H](C(=O)O)NC(=O)[C@H](CO)NC(=O)[C@H](CCCN=C(N)N)N LFAUVOXPCGJKTB-DCAQKATOSA-N 0.000 description 1
- SPIPSJXLZVTXJL-ZLUOBGJFSA-N Asn-Cys-Ser Chemical compound NC(=O)C[C@H](N)C(=O)N[C@@H](CS)C(=O)N[C@@H](CO)C(O)=O SPIPSJXLZVTXJL-ZLUOBGJFSA-N 0.000 description 1
- XGIAHEUULGOZHH-GUBZILKMSA-N Cys-Arg-Val Chemical compound CC(C)[C@@H](C(=O)O)NC(=O)[C@H](CCCN=C(N)N)NC(=O)[C@H](CS)N XGIAHEUULGOZHH-GUBZILKMSA-N 0.000 description 1
- ABLJDBFJPUWQQB-DCAQKATOSA-N Cys-Leu-Arg Chemical compound CC(C)C[C@@H](C(=O)N[C@@H](CCCN=C(N)N)C(=O)O)NC(=O)[C@H](CS)N ABLJDBFJPUWQQB-DCAQKATOSA-N 0.000 description 1
- MHXKHKWHPNETGG-QWRGUYRKSA-N Gly-Lys-Leu Chemical compound [H]NCC(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CC(C)C)C(O)=O MHXKHKWHPNETGG-QWRGUYRKSA-N 0.000 description 1
- DGLAHESNTJWGDO-SRVKXCTJSA-N His-Ser-His Chemical compound C1=C(NC=N1)C[C@@H](C(=O)N[C@@H](CO)C(=O)N[C@@H](CC2=CN=CN2)C(=O)O)N DGLAHESNTJWGDO-SRVKXCTJSA-N 0.000 description 1
- 244000147568 Laurus nobilis Species 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- WRLPVDVHNWSSCL-MELADBBJSA-N Leu-His-Pro Chemical compound CC(C)C[C@@H](C(=O)N[C@@H](CC1=CN=CN1)C(=O)N2CCC[C@@H]2C(=O)O)N WRLPVDVHNWSSCL-MELADBBJSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 241000719239 Oligoplites altus Species 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- VVKVHAOOUGNDPJ-SRVKXCTJSA-N Ser-Tyr-Ser Chemical compound [H]N[C@@H](CO)C(=O)N[C@@H](CC1=CC=C(O)C=C1)C(=O)N[C@@H](CO)C(O)=O VVKVHAOOUGNDPJ-SRVKXCTJSA-N 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- KLGFILUOTCBNLJ-IHRRRGAJSA-N Tyr-Cys-Arg Chemical compound C1=CC(=CC=C1C[C@@H](C(=O)N[C@@H](CS)C(=O)N[C@@H](CCCN=C(N)N)C(=O)O)N)O KLGFILUOTCBNLJ-IHRRRGAJSA-N 0.000 description 1
- XJFXZQKJQGYFMM-GUBZILKMSA-N Val-Cys-Val Chemical compound CC(C)[C@@H](C(=O)N[C@@H](CS)C(=O)N[C@@H](C(C)C)C(=O)O)N XJFXZQKJQGYFMM-GUBZILKMSA-N 0.000 description 1
- DJFOTTYJRUVOFU-MRXNPFEDSA-N [(3r)-3-(2-ethylbenzimidazol-1-yl)pyrrolidin-1-yl]-(5-fluoro-1h-indol-2-yl)methanone Chemical group FC1=CC=C2NC(C(=O)N3CC[C@H](C3)N3C4=CC=CC=C4N=C3CC)=CC2=C1 DJFOTTYJRUVOFU-MRXNPFEDSA-N 0.000 description 1
- QVEGWYOUJZKXIV-INIZCTEOSA-N [(3s)-3-(2-ethylbenzimidazol-1-yl)pyrrolidin-1-yl]-(5-methoxy-1h-indol-2-yl)methanone Chemical group COC1=CC=C2NC(C(=O)N3CC[C@@H](C3)N3C4=CC=CC=C4N=C3CC)=CC2=C1 QVEGWYOUJZKXIV-INIZCTEOSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002546 antimould Substances 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 108010040030 histidinoalanine Proteins 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000005494 tarnishing Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses fungi-proofing light maintaining agent of a kind of fur clothing and preparation method thereof, the ingredients and its parts by weight of maintaining agent are as follows: fibroin -12-15 parts of acrylic resin, 0.5-0.7 parts of cocamidopropyl propyl amide amine oxide, 0.6-0.9 parts of sldium lauryl sulfate, 2-3 parts of silicone oil, 1-2 parts of castor oil, 7-10 parts of glycerol, 2-3 parts of White Mineral Oil, 1-3 parts of montanin wax liquid, 0.1-0.3 parts of sodium lignin sulfonate, 2-3 parts of mould inhibitor, 4-7 parts of tea extraction object, 5-15 parts of ethyl acetate.Have the beneficial effect that maintaining agent compatibility of the present invention is reasonable, with excellent fungi-proofing anti-mold effect, fur clothing can be softened, improve gloss and the brightness of fur clothing, extend the service life of fur clothing, making treated, fur clothing has smooth, soft feel, plays the role of fabulous maintenance to fur clothing, and maintenance effect persistence is long.
Description
Technical field
The present invention relates to garment care field, in particular to a kind of fungi-proofing light maintaining agent of fur clothing and preparation method thereof.
Background technique
With the raising of people's level of consumption, requirement of the people to material life be also it is higher and higher, fur clothing has been very
Mrs man is crossed to be liked.Fur clothing is using Animal Skin, such as ox-hide, sheepskin, snakeskin, fish-skin Animal Skin, by special process
The clothes that the leather being processed into is made into, since the hair eye of Animal Skin has gas permeability, with it come tailoring, people is as one layer more
Skin, thus it be to the outstanding contributions of the mankind it is cold-proof, also have many good qualities certainly, such as it is beautiful, noble, be not easy it is dirty.But
The raw material skin as used in fur clothing production is rich in nutriments such as protein, fat, and after long-time is worn, surface holds fur clothing
Easy contamination spot, tarnishing is hardened with cortex, meanwhile, fur clothing is very suitable to the growth of microorganism when the resting period is longer,
Be easy dampness, rise it is mould, infested.Therefore, when wearing leather jacket, the substances such as greasy dirt, acidity and alkalinity to be avoided contact with.Either skin
Clothing surface or back boxing are all easy a large amount of dirt of accumulation, mould and various germs.But fur clothing is special due to its material
Property, it cannot wash, it is therefore desirable to be handled with special cleaning and maintaining agent, if fur clothing without maintaining well, is easy
It wrinkles, is mouldy, be hardened, be dimmed, will affect beautiful and service life.So maintaining agent has the service life of fur clothing in very big side
It helps, but maintaining agent currently on the market is also undesirable, comprehensive performance is bad, lacks anti-corrosive properties and bactericidal properties, at high cost, Er Qiezuo
It is short with the time, now have been unable to meet the market demand.A kind of exploitation of comprehensive stronger maintaining agent is extremely urgent at present, and
The maintaining agent has the biggish market space.
The prior art such as Authorization Notice No. is the Chinese invention patent of 103666811 B of CN, discloses a kind of fur clothing cleaning
Maintaining agent and preparation method thereof, the cleaning maintaining agent contain following component in terms of mass parts: sodium sulfate of polyethenoxy ether of fatty alcohol 4
~10 parts, 0.8~3.5 part of nonylphenol polyoxyethylene ether, 1~5 part of ammonium hydroxide, 3~8 parts of ethyl alcohol, 6~15 parts of palm oil, hydroxypropyl
0.5~1.5 part of methylcellulose, 0.6~1.4 part of sodium phosphate, 2.5~8 parts of isopropyl palmitate, ethylene glycol monobutyl ether 1~3.5
Part, 0.6~1.5 part of triethanolamine, 13~28 parts of white mineral oil, 0.06~0.15 part of phenol, 40~65 parts of deionized water.This is clear
Clean maintaining agent has the function of good decontamination, maintenance, mould proof and glazing, and increases the gloss and flexibility of fur clothing.But
The fungi-proofing effect of the cleaning maintaining agent is undesirable, and function persistence is poor, and fur clothing is short using the time interval of the cleaning maintaining agent.
Summary of the invention
The purpose of the present invention is to provide a kind of fungi-proofing anti-mold effects, can soften fur clothing, improve gloss and the brightness of fur clothing,
The service life for extending fur clothing, the fur clothing that makes that treated have smooth, soft feel the fungi-proofing light maintaining agent of fur clothing and its
Preparation method.
The present invention in view of the above technology in the problem of mentioning, a kind of technical solution taken are as follows: fungi-proofing light maintenance of fur clothing
Agent, ingredient and its parts by weight are as follows: fibroin -12-15 parts of acrylic resin, 0.5-0.7 parts of cocamidopropyl propyl amide amine oxide, laurel
0.6-0.9 parts of alcohol sodium sulphate, 2-3 parts of silicone oil, 1-2 parts of castor oil, 7-10 parts of glycerol, 2-3 parts of White Mineral Oil, 1-3 parts of montanin wax liquid,
0.1-0.3 parts of sodium lignin sulfonate, 2-3 parts of mould inhibitor, 4-7 parts of tea extraction object, 5-15 parts of ethyl acetate.The maintaining agent compatibility
Rationally, there is excellent fungi-proofing anti-mold effect, fur clothing can be softened, improve gloss and the brightness of fur clothing, extend fur clothing uses the longevity
Life, making that treated, fur clothing has smooth, soft feel, plays the role of fabulous maintenance to fur clothing, and maintenance effect is held
Long property is long, can shorten maintenance interval time, save time and effort.
Preferably, the ingredient and its parts by weight of mould inhibitor are as follows: 8-10 parts of aminobenzene sulfonamide, 0.03-0.05 parts of synergist,
15-25 parts of benzimidazole, 12-14 parts of nitropyridine, 2-3 parts of alkaloid, 7-10 parts of diformazan thiadiazine, increase by 2-3 parts of sodium chlorite
Effect agent is functional protein peptide, amino acid sequence HSHACASYSRSHRGRCYCRCLRCRVLHPGKLCVCVNCSR, the synergy
Agent can significantly increase the fungicidal properties of mould inhibitor, the mechanism of action be the cell wall that booster molecules can make mould or cell membrane not
Stablize, so that mould proof agent molecule is easy to penetrate, diffuses into fungal cell, so that its speed for killing mould is improved, enhancing
The using effect of mould inhibitor;The mould inhibitor toxicity is lower, sterilizing spectrum is wide, anti-mold effect is fine, can inhibit the synthesis of protein,
Thallus is solidified, inhibits the synthesis of the black alcohol of fungi ergot and makes mold inactivation, so that metabolism is obstructed, inhibit to produce spore or spore is sprouted
Hair.
A kind of preparation method of the fungi-proofing light maintaining agent of fur clothing, including silk fibroin solution preparation, fibroin-acrylic resin system
Standby, maintaining agent preparation, specifically includes the following steps:
Silk fibroin solution preparation: fibroin fiber is added in the ternary solvent prepared with the bath raio of 1:9-11, ternary solvent
Ingredient is CaCl2、H2O、C2H5OH, molar ratio 1:7-9:2-3 are stirred at 68-72 DEG C to being completely dissolved, then will be molten
Liquid pours into bag filter, with deionized water dialysis 3-4h to get silk fibroin solution, generates when salt dissolves in water in the step
Ion can promote the polarity of hydrone to increase, reduce the active force between silk fibroin molecular, to promote the swelling of fibroin molten
Solution, the silk fibroin solution prepared through the step are not likely to produce gelatin phenomenon, can place the long period, and CaCl2It is cheap, it can
Production cost is greatlyd save, the requirement of production is met;
Fibroin-acrylic resin preparation: silk fibroin solution and acrylic resin are blended than the proportion for 1:2-3 by solid content
Liquid stirs evenly to get fibroin-acrylic resin, with the method for acrylic resin blending and modifying, preferably improves fibroin membrane
Performances, the addition of olefin(e) acid resin such as brittle destroy intermolecular original active force such as hydrogen bond of fibroin etc., fibroin made to become soft
It is tough, adhesive property is improved, and gloss and feel keep preferable situation;
Maintaining agent preparation: fibroin-acrylic resin, cocamidopropyl propyl amide amine oxide, laruyl alcohol sulfuric acid are measured by formula
Sodium, silicone oil, castor oil, glycerol, White Mineral Oil, montanin wax liquid, sodium lignin sulfonate, mould inhibitor, tea extraction object, ethyl acetate,
It is uniformly mixed to get the fungi-proofing light maintaining agent of fur clothing, which has excellent fungi-proofing anti-mold effect, can soften fur clothing, mention
The gloss of high fur clothing and brightness extend the service life of fur clothing, and making that treated, fur clothing has smooth, soft feel, to skin
Clothing plays the role of fabulous maintenance, and maintenance effect persistence is long, can shorten maintenance interval time, saves time and essence
Power.
Compared with the prior art, the advantages of the present invention are as follows:
1. maintaining agent compatibility of the present invention is reasonable, there is excellent fungi-proofing anti-mold effect, fur clothing can be softened, improve the light of fur clothing
Pool and brightness, extend the service life of fur clothing, and making that treated, fur clothing has smooth, soft feel, play pole to fur clothing
Good maintenance effect, and maintenance effect persistence is long, can shorten maintenance interval time, save time and effort.
2. the method that the present invention uses acrylic resin blending and modifying preferably improves the performances such as brittle of fibroin membrane, alkene
The addition of acid resin destroys intermolecular original active force such as hydrogen bond of fibroin etc., and fibroin is made to become flexible, improves adhesive property,
And gloss and feel keep preferable situation.
3. the waste liquid discharge of nonpollution environment, environmentally friendly in preparation step of the present invention, meet the standard of green production,
And cost of material is lower, has the market development space increased.
Specific embodiment
The present invention program is described further below by embodiment:
Embodiment 1:
A kind of fungi-proofing light maintaining agent of fur clothing, ingredient and its parts by weight are as follows: 13 parts of fibroin-acrylic resin, coconut oleoyl amine
0.6 part of propyl amine oxide, 0.8 part of sldium lauryl sulfate, 2.5 parts of silicone oil, 1.6 parts of castor oil, 8 parts of glycerol, 2.6 parts of White Mineral Oil,
2 parts of montanin wax liquid, 0.2 part of sodium lignin sulfonate, 2.3 parts of mould inhibitor, 6 parts of tea extraction object, 8 parts of ethyl acetate.
The ingredient and its parts by weight of above-mentioned mould inhibitor are as follows: 9 parts of aminobenzene sulfonamide, 0.04 part of synergist, benzimidazole 18
Part, 13 parts of nitropyridine, 2 parts of alkaloid, 8 parts of diformazan thiadiazine, 3 parts of sodium chlorite, synergist is functional protein peptide, amino
Acid sequence is HSHACASYSRSHRGRCYCRCLRCRVLHPGKLCVCVNCSR, which can significantly increase the anti-of mould inhibitor
Mouldiness energy, the mechanism of action is that booster molecules can make the cell wall of mould or cell membrane unstable, so that mould proof agent molecule is easy
In penetrating, diffusing into fungal cell, to improve its speed for killing mould, the using effect of mould inhibitor is enhanced;It should
Mould inhibitor toxicity is lower, sterilizing spectrum is wide, anti-mold effect is fine, can inhibit the synthesis of protein, solidify thallus, inhibits fungi wheat
The synthesis of the black alcohol in angle and make mold inactivation, so that metabolism is obstructed, inhibit to produce spore or spore germination.
A kind of preparation method of the fungi-proofing light maintaining agent of fur clothing, including silk fibroin solution preparation, fibroin-acrylic resin system
Standby, maintaining agent preparation, specifically includes the following steps:
1) prepared by silk fibroin solution: fibroin fiber is added in the ternary solvent prepared with the bath raio of 1:10, ternary solvent
Ingredient is CaCl2、H2O、C2H5OH, molar ratio 1:8:2 are stirred to being completely dissolved at 70 DEG C, are then poured into solution
It analyses in bag, with deionized water dialysis 4h to get silk fibroin solution, the ion generated when salt dissolves in water in the step can promote
Increase the polarity of hydrone, reduce the active force between silk fibroin molecular, to promote the swelling of fibroin to dissolve, through the step
Suddenly the silk fibroin solution prepared is not likely to produce gelatin phenomenon, can place the long period, and CaCl2It is cheap, it can greatly save
Production cost meets the requirement of production;
2) fibroin-acrylic resin preparation: by solid content than being total to silk fibroin solution and acrylic resin for the proportion of 1:2.5
Mixed liquid, stirs evenly to get fibroin-acrylic resin, with the method for acrylic resin blending and modifying, preferably improves fibroin
Performances, the addition of olefin(e) acid resin such as brittle of film destroy intermolecular original active force such as hydrogen bond of fibroin etc., become fibroin
It is flexible, adhesive property is improved, and gloss and feel keep preferable situation;
3) prepared by maintaining agent: measuring fibroin-acrylic resin, cocamidopropyl propyl amide amine oxide, laruyl alcohol sulfuric acid by formula
Sodium, silicone oil, castor oil, glycerol, White Mineral Oil, montanin wax liquid, sodium lignin sulfonate, mould inhibitor, tea extraction object, ethyl acetate,
It is uniformly mixed to get the fungi-proofing light maintaining agent of fur clothing, which has excellent fungi-proofing anti-mold effect, can soften fur clothing, mention
The gloss of high fur clothing and brightness extend the service life of fur clothing, and making that treated, fur clothing has smooth, soft feel, to skin
Clothing plays the role of fabulous maintenance, and maintenance effect persistence is long, can shorten maintenance interval time, saves time and essence
Power.
Embodiment 2:
A kind of fungi-proofing light maintaining agent of fur clothing, ingredient and its parts by weight are as follows: 14 parts of fibroin-acrylic resin, coconut oleoyl amine
0.7 part of propyl amine oxide, 3 parts of silicone oil, 1 part of castor oil, 9 parts of glycerol, 2.6 parts of White Mineral Oil, covers denier at 0.6 part of sldium lauryl sulfate
2 parts of wax liquor, 0.3 part of sodium lignin sulfonate, 2 parts of mould inhibitor, 6 parts of tea extraction object, 11 parts of ethyl acetate.The ingredient of mould inhibitor and
Its parts by weight are as follows: 8 parts of aminobenzene sulfonamide, 0.05 part of synergist, 22 parts of benzimidazole, 13 parts of nitropyridine, 2 parts of alkaloid,
9 parts of diformazan thiadiazine, 3 parts of sodium chlorite, synergist is functional protein peptide, amino acid sequence HSHACASYSRSHRGRCY
CRCLRCRVLHPGKLCVCVNCSR, the synergist can significantly increase the fungicidal properties of mould inhibitor, and the mechanism of action is synergist
Molecule can make the cell wall of mould or cell membrane unstable, so that mould proof agent molecule is easy to penetrate, diffuses into fungal cell, from
And its speed for killing mould is improved, enhance the using effect of mould inhibitor;The mould inhibitor toxicity is lower, sterilizing spectrum is wide, anti-
Mould effect is fine, can inhibit the synthesis of protein, solidify thallus, inhibits the synthesis of the black alcohol of fungi ergot and makes mold inactivation,
So that metabolism is obstructed, inhibits to produce spore or spore germination.
A kind of preparation method of the fungi-proofing light maintaining agent of fur clothing, specifically includes the following steps:
1) fibroin fiber is added in the ternary solvent prepared with the bath raio of 1:10, the ingredient of ternary solvent is CaCl2、
H2O、C2H5OH, molar ratio 1:8:2.5 are stirred to being completely dissolved at 72 DEG C, are then poured into solution in bag filter, are used
For deionized water dialysis 4h to get silk fibroin solution, the ion generated when salt dissolves in water in the step can promote hydrone
Polarity increases, and reduces the active force between silk fibroin molecular, so that the swelling of fibroin is promoted to dissolve, the silk prepared through the step
Plain solution is not likely to produce gelatin phenomenon, can place the long period, and CaCl2It is cheap, production cost can be greatlyd save, is accorded with
The requirement that symphysis produces;
2) solid content is pressed than the proportion for 1:3 by silk fibroin solution and acrylic resin blended liquid, is stirred evenly to get silk
Element-acrylic resin preferably improves the performances such as brittle of fibroin membrane, olefin(e) acid with the method for acrylic resin blending and modifying
The addition of resin destroys intermolecular original active force such as hydrogen bond of fibroin etc., and fibroin is made to become flexible, improves adhesive property, and
Gloss and feel keep preferable situation;
3) fibroin-acrylic resin, cocamidopropyl propyl amide amine oxide, sldium lauryl sulfate, silicone oil, castor are measured by formula
Sesame oil, glycerol, White Mineral Oil, montanin wax liquid, sodium lignin sulfonate, mould inhibitor, tea extraction object, ethyl acetate are uniformly mixed, i.e.,
The fungi-proofing light maintaining agent of fur clothing is obtained, which has excellent fungi-proofing anti-mold effect, can soften fur clothing, improve the gloss of fur clothing
And brightness, extend the service life of fur clothing, making that treated, fur clothing has smooth, soft feel, plays to fur clothing fabulous
Maintenance effect, and maintenance effect persistence is long, can shorten maintenance interval time, save time and effort.
Embodiment 3:
A kind of fungi-proofing light maintaining agent of fur clothing, ingredient and its parts by weight are as follows: 13 parts of fibroin-acrylic resin, coconut oleoyl amine
0.5 part of propyl amine oxide, 2.4 parts of silicone oil, 1.6 parts of castor oil, 8 parts of glycerol, 2 parts of White Mineral Oil, covers 0.7 part of sldium lauryl sulfate
1.5 parts of denier wax liquor, 0.15 part of sodium lignin sulfonate, 2 parts of mould inhibitor, 5 parts of tea extraction object, 6 parts of ethyl acetate.Above-mentioned mould inhibitor
Ingredient and its parts by weight are as follows: it is 8 parts of aminobenzene sulfonamide, 0.04 part of synergist, 16 parts of benzimidazole, 12 parts of nitropyridine, raw
2.5 parts of alkaloids, 10 parts of diformazan thiadiazine, 2 parts of sodium chlorite, synergist is functional protein peptide, amino acid sequence HSHACA
SYSRSHRGRCYCRCLRCRVLHPGKLCVCVNCSR。
A kind of preparation method of the fungi-proofing light maintaining agent of fur clothing, specifically: fibroin fiber is added with the bath raio of 1:9 and is prepared
Ternary solvent in, the ingredient of ternary solvent is CaCl2、H2O、C2H5OH, molar ratio 1:7:2 are stirred at 68 DEG C to complete
Then fully dissolved is poured into solution in bag filter, with deionized water dialysis 3h to get silk fibroin solution;By solid content than for 1:2's
Proportion stirs evenly silk fibroin solution and acrylic resin blended liquid to get fibroin-acrylic resin;Ingredient is measured by formula,
It is uniformly mixed to get the fungi-proofing light maintaining agent of fur clothing.
Routine operation in operating procedure of the invention is well known to those skilled in the art, herein without repeating.
Technical solution of the present invention is described in detail in embodiment described above, it should be understood that the above is only
For specific embodiments of the present invention, it is not intended to restrict the invention, all any modifications made in spirit of the invention,
Supplement or similar fashion substitution etc., should all be included in the protection scope of the present invention.
SEQUENCE LISTING
<110>Ningbo City Haishu District Yi Wanka agricultural science and technology Co., Ltd
<120>fungi-proofing light maintaining agent of a kind of fur clothing and preparation method thereof
<130> 1
<160> 1
<170> PatentIn version 3.5
<210> 1
<211> 39
<212> PRT
<213>artificial synthesized
<400> 1
His Ser His Ala Cys Ala Ser Tyr Ser Arg Ser His Arg Gly Arg Cys
1 5 10 15
Tyr Cys Arg Cys Leu Arg Cys Arg Val Leu His Pro Gly Lys Leu Cys
20 25 30
Val Cys Val Asn Cys Ser Arg
35
Claims (8)
1. a kind of fungi-proofing light maintaining agent of fur clothing, it is characterised in that: the ingredient and its parts by weight of the maintaining agent are as follows: fibroin-
12-15 parts of acrylic resin, 0.5-0.7 parts of cocamidopropyl propyl amide amine oxide, 0.6-0.9 parts of sldium lauryl sulfate, silicone oil 2-3
Part, is prevented 1-2 parts of castor oil, 7-10 parts of glycerol, 2-3 parts of White Mineral Oil, 1-3 parts of montanin wax liquid, 0.1-0.3 parts of sodium lignin sulfonate
Mould dose 2-3 parts, 4-7 parts of tea extraction object, 5-15 parts of ethyl acetate;
The ingredient and its parts by weight of the mould inhibitor are as follows: 8-10 parts of aminobenzene sulfonamide, 0.03-0.05 parts of synergist, benzo
15-25 parts of imidazoles, 12-14 parts of nitropyridine, 2-3 parts of alkaloid, 7-10 parts of diformazan thiadiazine, 2-3 parts of sodium chlorite;
The synergist is functional protein peptide, amino acid sequence HSHACASYSRSHRGRCYCRCLRCRVLHPGKLCV
CVNCSR。
2. a kind of preparation method of the fungi-proofing light maintaining agent of fur clothing described in claim 1, including silk fibroin solution preparation, fibroin-
Acrylic resin preparation, maintaining agent preparation, it is characterised in that: the preparation of the fibroin-acrylic resin are as follows: by silk fibroin solution and
Acrylic resin blended liquid stirs evenly to get fibroin-acrylic resin.
3. a kind of preparation method of the fungi-proofing light maintaining agent of fur clothing according to claim 2, it is characterised in that: the silk
The proportion of silk fibroin solution and acrylic resin solid content is 1:2-3 in element-acrylic resin preparation.
4. a kind of preparation method of the fungi-proofing light maintaining agent of fur clothing according to claim 2, it is characterised in that: the silk
Plain solution preparation are as follows: fibroin fiber is added in the ternary solvent prepared, stirs to being completely dissolved, solution is then poured into dialysis
Dialysis is in bag to get silk fibroin solution.
5. a kind of preparation method of the fungi-proofing light maintaining agent of fur clothing according to claim 4, it is characterised in that: the silk
The bath raio of fibroin fiber and ternary solvent is 1:9-11 in plain solution preparation.
6. a kind of preparation method of the fungi-proofing light maintaining agent of fur clothing according to claim 4, it is characterised in that: the silk
The ingredient of ternary solvent is CaCl2, H2O, C2H5OH, molar ratio 1:7-9:2-3 in plain solution preparation.
7. a kind of preparation method of the fungi-proofing light maintaining agent of fur clothing according to claim 2, it is characterised in that: the silk
Solution temperature is 68-72 DEG C in plain solution preparation.
8. a kind of preparation method of the fungi-proofing light maintaining agent of fur clothing according to claim 2, it is characterised in that: the silk
Deionized water dialysis 3-4h is used in plain solution preparation.
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CN102993986A (en) * | 2012-12-14 | 2013-03-27 | 吴江市利达上光制品有限公司 | Spray type mildew-proof leather polishing agent and preparation method thereof |
CN104845534A (en) * | 2015-05-28 | 2015-08-19 | 青岛千帆高新技术有限公司 | Fur coat glazing agent |
CN104846130A (en) * | 2015-05-12 | 2015-08-19 | 湖州吉昌丝绸有限公司 | Novel softening maintenance agent for textile fur clothing and preparation method of novel softening maintenance agent |
CN104893590A (en) * | 2015-05-30 | 2015-09-09 | 青岛康泰鑫环保科技有限公司 | Mildewproof fur coat glazing agent |
CN105039608A (en) * | 2015-05-30 | 2015-11-11 | 青岛康泰鑫环保科技有限公司 | Mould-proof fur clothing maintenance agent |
-
2017
- 2017-06-23 CN CN201710488628.4A patent/CN107354248B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102993986A (en) * | 2012-12-14 | 2013-03-27 | 吴江市利达上光制品有限公司 | Spray type mildew-proof leather polishing agent and preparation method thereof |
CN104846130A (en) * | 2015-05-12 | 2015-08-19 | 湖州吉昌丝绸有限公司 | Novel softening maintenance agent for textile fur clothing and preparation method of novel softening maintenance agent |
CN104845534A (en) * | 2015-05-28 | 2015-08-19 | 青岛千帆高新技术有限公司 | Fur coat glazing agent |
CN104893590A (en) * | 2015-05-30 | 2015-09-09 | 青岛康泰鑫环保科技有限公司 | Mildewproof fur coat glazing agent |
CN105039608A (en) * | 2015-05-30 | 2015-11-11 | 青岛康泰鑫环保科技有限公司 | Mould-proof fur clothing maintenance agent |
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