CN107353752A - A kind of aqueous antistatic antimildew and antibacterial type building coating and its production method - Google Patents
A kind of aqueous antistatic antimildew and antibacterial type building coating and its production method Download PDFInfo
- Publication number
- CN107353752A CN107353752A CN201710667771.XA CN201710667771A CN107353752A CN 107353752 A CN107353752 A CN 107353752A CN 201710667771 A CN201710667771 A CN 201710667771A CN 107353752 A CN107353752 A CN 107353752A
- Authority
- CN
- China
- Prior art keywords
- antimildew
- building coating
- aqueous antistatic
- coating according
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/025—Preservatives, e.g. antimicrobial agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Plant Pathology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of coating, a kind of aqueous antistatic antimildew and antibacterial type building coating and its production method are provided, solve the building coating of prior art without antistatic, without fungicidal properties, do not apply to white and light color based on wall finiss building coating in use the defects of.It is made up of each raw material of following percentage by weight：Propane diols 1~3%, PH conditioning agents 0.1~0.2%, wetting agent 0.1~0.3%, dispersant 0.1~1.0%, defoamer 0.1~0.5%, four acicular type zinc oxide crystal whisker 10~20%, titanium dioxide 1~10%, calcium carbonate 35~50%, in-can preservation agent 0.1~0.3%, coalescents 1~3%, thickener 1~2%, emulsion 15~25%, deionized water surplus.
Description
Technical field
The present invention relates to a kind of coating, more particularly to a kind of aqueous antistatic antimildew and antibacterial type building coating and its production method.
Background technology
Coating is all widely used in the various aspects of national economy.The coating macromolecule material that binding agent is mostly insulation
Material, therefore coating paint film also more has very high resistance and high-insulations.When such paint film is rubbed or extruded, just hold very much
It is also easy to produce and accumulation electrostatic.Electrostatic easily cause dust suction and be difficult to purify and destroy ultrapurification environment, so as to influence precise materials,
The especially production of electronic material and the operation of precision electronic device.More seriously, buildup of static electricity to a certain extent when meeting
Static discharge phenomenon is produced, in electronics industry, static discharge can make various precision instruments, electronic component is breakdown and scraps；
In industries such as explosive, colliery, oil, chemical industry, food, static discharge easily causes inflammable and explosive substances blast on fire, causes personnel
The huge serious accident with property loss.Therefore, it is an important problem to eliminate electrostatic hazard.
The material surface brushing anti-static coatings of electrostatic are easily played in insulation, are to eliminate the most easy and effective of electrostatic hazard to do
Method.Anti-static coatings are resistance values 105Ω~109In the range of Ω, with certain conduction electric current and dissipation electrostatic charge ability
Functional special coating.It is the addition type anti-static coatings prepared using conductive filler at present using more.
Conductive filler mainly has several classes such as metal system, carbon system, metal oxide.Metal system exists expensive or oxidizable
The shortcomings that causing hydraulic performance decline.Though carbon system filler has the advantages that light, nontoxic, not oxidizable, cheap, color
It is dark single, it is not suitable for using in the wall finiss building coating based on white and light color.
The content of the invention
Therefore, a kind of aqueous antistatic antimildew and antibacterial type building coating and its production are provided for above content, the present invention
Method, solve the building coating of prior art without antistatic, without fungicidal properties, do not apply to white and light color based on wall finiss
The defects of being used in building coating.
The present invention is achieved by the following technical solutions：A kind of aqueous antistatic antimildew and antibacterial building coating, by following
Each raw material composition of percentage by weight：
Further improving is：The emulsion is polyacrylate dispersion, solid content 42%, pH=8.0, polyacrylic acid
The particle diameter of ester emulsion is 0.15~0.2 micron, product viscosity 500mPa.s, 18 DEG C of product MFT, product glass
Change 42 DEG C of temperature.
Further improving is：The propane diols is colorless viscous shape transparency liquid, proportion 1.04.
Further improving is：Described pH adjusting agent is 2-amino-2-methyl-1-propanol, dimethylethanolamine, ethanol
Any one in amine, water-soluble silicate or the two or more mixtures with any ratio mixing.
Further improving is：Described wetting agent is polyoxyethylene alkyl ether, polyoxyethylene polyols ether, polyoxyethylene
It is any in polyoxypropylene acid block copolymer, fatty acid polyethylene glycol ester, polyol ester, aliphatic amine polyoxyethylene ether addition product
One or more kinds of mixtures with any ratio mixing.
Further improving is：The dispersant is high-molecular copolymer alkylamine salt, the high score of the affinity groups containing pigment
Any one in sub- block copolymer solution or the two or more mixtures with any ratio mixing.They have fabulous pigment
Dispersion effect, reduce system viscosity, good stable dispersion color stuffing.
Further improving is：The defoamer is organic silicon defoamer, the emulsion of aliphatic hydrocarbon, non-silicone organic ester carbon
Any one in hydrogen compound, mineral oil mixture containing hydrophobic particles or the two or more mixtures with any ratio mixing；Institute
It is different for BIT and the different Anthelvet -3- ketone of 2- methyl-5-chloros -4- and 2- methyl -4- to state in-can preservation agent
The mixture that Anthelvet -3- ketone is mixed by any ratio.
Further improving is：The ZnOw is that reactor preheats vapour phase oxidation process production, has following technical indicator：Outside
See：White loose sprills；Microstructure：Needle-like；Crystal structure：Monocrystalline, Pb-Zn deposits crystal formation；Described calcium carbonate is high speed gas
Stream crushes the white powder of calcite production, has following technical indicator：Particle diameter D60 (μm)≤3.0, whiteness % >=96, oil suction
Amount 20~24.
Further improving is：Described coalescents are lauryl alcohol ester, and it can significantly reduce the film-forming temperature of coating,
The titanium dioxide is rutile-type Chinese white.
Further improving is：The thickener is hydroxyethyl cellulose, polyurethane thickener or modified polyurea thickener
In any one or it is two or more with it is any than mixing mixture, they not only have very good thickening efficiency, and
And there is good water resistance, be advantageous to the water resistance of film.
A kind of preparation method of aqueous antistatic antimildew and antibacterial building coating, has following steps：
(1) material is prepared by the percentage by weight of above-mentioned each component；
(2) in order by deionized water, propane diols, wetting agent, dispersant, the defoamer of half, pH adjusting agent, ZnOw,
Calcium carbonate, titanium dioxide etc. are added in a mixing bowl, are uniformly dispersed are less than 50 μm to fineness at a high speed；
(3) open stirring at low speed, rotating speed control in 300~500r/min, add emulsion, coalescents, in-can preservation agent,
Thickener, second half defoamer, it is stirred for after adding 20 minutes；
(4) product is detected, detects qualified rear filtering, packaging；The sieve mesh number of filter is 80~120 mesh.
By using preceding solution, the beneficial effects of the invention are as follows：The aqueous antistatic antimildew and antibacterial of the present invention is built
Coating is built using four acicular type zinc oxide crystal whisker excellent electric conductivity, antimildew and antibacterial and white appearance, obtained aqueous antistatic
Coating possesses conduction electric current and dissipation electrostatic charge ability well, has that adhesive force is good, fungus and mildew resistance for base materials such as concrete
Property performance it is good, have moderate resistance value aqueous antistatic coating.The coating can be widely used for having antistatic, antimildew and antibacterial
The inner wall of building decoration of strict demand is brushed, for example, by the coating application in precise electronic component workshop or accurate instrument
Device indoor wall, metope is effectively eliminated electrostatic influence, not dust suction, be advantageous to build clean dustless indoor environment, can also use
Decorated in the building wall of the industries such as health care industry, food manufacturing, effective active time is more than 15 years.
Embodiment
Embodiments of the present invention are described in detail below with reference to specific embodiment, and how skill is applied to the present invention whereby
Art means solve technical problem, and the implementation process for reaching technique effect can fully understand and implement according to this.
Unless otherwise specified, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art
Section, used reagent and product are also available commercial.The source of agents useful for same, trade name and it is necessary to list it
Constituent person, indicate on the first appearance.
Embodiment one
A kind of aqueous antistatic antimildew and antibacterial building coating, it is made up of each raw material of following parts by weight：
The solid content of the polyacrylate dispersion is 42%, and the solid content is solid content in volume, pH=8.0, is gathered
The particle diameter of acrylic acid ester emulsion is 0.15 micron, product viscosity 500mPa.s, 18 DEG C of product MFT, product glass
Change 42 DEG C of temperature.The propane diols is colorless viscous shape transparency liquid, proportion 1.04.The ZnOw is the pre- hot phase oxygen of reactor
Change method produces, and has following technical indicator：Outward appearance：White loose sprills；Microstructure：Needle-like；Crystal structure：Monocrystalline, lead
Zinc ore crystal formation；Described calcium carbonate is the white powder that high velocity air crushes calcite production, has following technical indicator：Particle diameter
D60 (μm)≤3.0, whiteness % >=96, oil absorption 20.
A kind of preparation method of aqueous antistatic antimildew and antibacterial building coating, has following steps：
(1) material is prepared by the percentage by weight of above-mentioned each component；
(2) in order by deionized water, propane diols, polyoxyethylene alkyl ether, high-molecular copolymer alkylamine salt, half
Organic silicon defoamer, 2-amino-2-methyl-1-propanol, ZnOw, calcium carbonate, titanium dioxide etc. are added in a mixing bowl, scattered equal at a high speed
It is even to fineness be less than 50 μm；
(3) stirring at low speed is opened, rotating speed control is in 300~500r/min, addition emulsion, lauryl alcohol ester, 1,2- benzisoxas
Different Anthelvet -3- the ketone of thiazoline -3- ketone, 2- methyl-5-chloros -4-, the different Anthelvet -3- ketone of 2- methyl -4-, hydroxyethyl cellulose,
Second half organic silicon defoamer, it is stirred for after adding 20 minutes；
(4) product is detected, detects qualified rear filtering, packaging；The sieve mesh number of filter is 80 mesh.
Embodiment two
A kind of aqueous antistatic antimildew and antibacterial building coating, it is made up of each raw material of following parts by weight：
The solid content of the polyacrylate dispersion is 42%, pH=8.0, the particle diameter of polyacrylate dispersion for 0.15~
0.2 micron, product viscosity 500mPa.s, 18 DEG C of product MFT, 42 DEG C of product glass transition temperature.The propane diols
For colorless viscous shape transparency liquid, proportion 1.04.The ZnOw is that reactor preheats vapour phase oxidation process production, has following technology
Index：Outward appearance：White loose sprills；Microstructure：Needle-like；Crystal structure：Monocrystalline, Pb-Zn deposits crystal formation；Described calcium carbonate
The white powder of calcite production is crushed for high velocity air, there is following technical indicator：Particle diameter D60 (μm)≤3.0, whiteness % >=
96, oil absorption 22.
Its preparation method, there are following steps：
(1) material is prepared by the percentage by weight of above-mentioned each component；
(2) it is in order that the macromolecule of deionized water, propane diols, polyoxyethylene polyols ether, the affinity groups containing pigment is embedding
Section copolymer solution, the emulsion of aliphatic hydrocarbon of half, dimethylethanolamine, ZnOw, calcium carbonate, titanium dioxide etc. add a mixing bowl
In, it is uniformly dispersed be less than 50 μm to fineness at a high speed；
(3) stirring at low speed is opened, rotating speed control is in 400r/min, addition polyacrylate dispersion, lauryl alcohol ester, 1,2- benzene
And the different Anthelvet -3- ketone of isothiazoline -3- ketone, 2- methyl-5-chloros -4-, the different Anthelvet -3- ketone of 2- methyl -4-, lauryl alcohol ester,
The emulsion of hydroxyethyl cellulose, second half aliphatic hydrocarbon, it is stirred for after adding 20 minutes；
(4) product is detected, detects qualified rear filtering, packaging；The sieve mesh number of filter is 100 mesh.
Embodiment three
A kind of aqueous antistatic antimildew and antibacterial building coating, it is made up of each raw material of following parts by weight：
The solid content of the polyacrylate dispersion is 42%, pH=8.0, and the particle diameter of polyacrylate dispersion is micro- for 0.2
Rice, product viscosity 500mPa.s, 18 DEG C of product MFT, 42 DEG C of product glass transition temperature.The propane diols is nothing
The thick transparency liquid of color, proportion 1.04.The ZnOw is that reactor preheats vapour phase oxidation process production, and there is following technology to refer to
Mark：Outward appearance：White loose sprills；Microstructure：Needle-like；Crystal structure：Monocrystalline, Pb-Zn deposits crystal formation；Described calcium carbonate is
High velocity air crushes the white powder of calcite production, has following technical indicator：Particle diameter D60 (μm)≤3.0, whiteness % >=
96, oil absorption 20~24.
Its preparation method, there are following steps：
(1) material is prepared by the percentage by weight of above-mentioned each component；
(2) in order by deionized water, propane diols, aliphatic amine polyoxyethylene ether, high-molecular copolymer alkylamine salt, half
Non- silicone organic ester hydrocarbon, monoethanolamine, ZnOw, calcium carbonate, titanium dioxide etc. add in a mixing bowl, be uniformly dispersed at a high speed
It is less than 50 μm to fineness；
(3) stirring at low speed is opened, rotating speed control is in 300~500r/min, addition emulsion, 1,2- benzisothiazoles -3-
Different Anthelvet -3- the ketone of ketone, 2- methyl-5-chloros -4-, the different Anthelvet -3- ketone of 2- methyl -4-, lauryl alcohol ester, modified polyurea thickening
Agent, second half non-silicone organic ester hydrocarbon, are stirred for 20 minutes after adding；
(4) product is detected, detects qualified rear filtering, packaging；The sieve mesh number of filter is 120 mesh.
The pH adjusting agent of the present invention is 2-amino-2-methyl-1-propanol, dimethylethanolamine, monoethanolamine, water-soluble silicic acid
Any one in salt or the two or more mixtures with any ratio mixing；Described wetting agent is polyoxyethylene alkyl ether, gathered
Oxygen ethene polyol ethers, polyoxyethylene polyoxypropylene acid block copolymer, fatty acid polyethylene glycol ester, polyol ester, fatty amine
Any one in APEO addition product or the two or more mixtures with any ratio mixing；The dispersant is macromolecule
Copolymer alkylamine salt, the affinity groups containing pigment high-molecular block copolymer solution in any one or it is two or more with appoint
Anticipate than the mixture of mixing, they have fabulous pigment dispersion effect, reduce system viscosity, and good stable dispersion face is filled out
Material.The defoamer be organic silicon defoamer, the emulsion of aliphatic hydrocarbon, non-silicone organic ester hydrocarbon, containing hydrophobic particles
Any one in mineral oil mixture or the two or more mixtures with any ratio mixing；The in-can preservation agent is 1,2- benzene
And isothiazoline -3- ketone and the different Anthelvet -3- ketone of 2- methyl-5-chloros -4- and the different Anthelvet -3- ketone of 2- methyl -4- press any ratio
The mixture of mixing；The ZnOw is that reactor preheats vapour phase oxidation process production, has following technical indicator：Outward appearance：White is dredged
Loose sprills；Microstructure：Needle-like；Crystal structure：Monocrystalline, Pb-Zn deposits crystal formation；Described calcium carbonate is high velocity air crushing side
The white powder of Xie Shi productions, has following technical indicator：Particle diameter D60 (μm)≤3.0, whiteness % >=96, oil absorption 20~24；
Described coalescents are lauryl alcohol ester, and it can significantly reduce the film-forming temperature of coating, and the titanium dioxide is that rutile-type is white
Color pigment；The thickener is any one or two in hydroxyethyl cellulose, polyurethane thickener or modified polyurea thickener
With any mixture than mixing more than kind, they not only have very good thickening efficiency, and with water-fast well
Property, be advantageous to the water resistance of film.Present disclosure can be achieved from above-mentioned the next material.
Described in above, only this wound is used using the embodiment of this origination techniques content, any those skilled in the art
Make done modifications and changes, all belong to the scope of the claims of this creation opinion, and be not limited to those disclosed embodiments.
Claims (10)
- A kind of 1. aqueous antistatic antimildew and antibacterial building coating, it is characterised in that：It is made up of each raw material of following percentage by weight：
- A kind of 2. aqueous antistatic antimildew and antibacterial building coating according to claim 1, it is characterised in that：The emulsion is Polyacrylate dispersion, solid content 42%, pH=8.0, the particle diameter of polyacrylate dispersion is 0.15~0.2 micron, product Viscosity is 500mPa.s, 18 DEG C of product MFT, 42 DEG C of product glass transition temperature.
- A kind of 3. aqueous antistatic antimildew and antibacterial building coating according to claim 1, it is characterised in that：Described pH is adjusted Section agent is any one or two kinds in 2-amino-2-methyl-1-propanol, dimethylethanolamine, monoethanolamine, water-soluble silicate Above with any mixture than mixing.
- A kind of 4. aqueous antistatic antimildew and antibacterial building coating according to claim 1, it is characterised in that：Described wetting Agent is polyoxyethylene alkyl ether, polyoxyethylene polyols ether, polyoxyethylene polyoxypropylene acid block copolymer, fatty acid polyglycol second two Any one in alcohol ester, polyol ester, aliphatic amine polyoxyethylene ether addition product or the two or more mixing with any ratio mixing Thing.
- A kind of 5. aqueous antistatic antimildew and antibacterial building coating according to claim 1, it is characterised in that：The dispersant For high-molecular copolymer alkylamine salt, the affinity groups containing pigment high-molecular block copolymer solution in any one or two kinds Above with any mixture than mixing.
- A kind of 6. aqueous antistatic antimildew and antibacterial building coating according to claim 1, it is characterised in that：The defoamer For in organic silicon defoamer, the emulsion of aliphatic hydrocarbon, non-silicone organic ester hydrocarbon, mineral oil mixture containing hydrophobic particles Any one or it is two or more with it is any than mixing mixture；The in-can preservation agent is 1,2- benzisothiazoles -3- The mixture that ketone and the different Anthelvet -3- ketone of 2- methyl-5-chloros -4- and the different Anthelvet -3- ketone of 2- methyl -4- are mixed by any ratio.
- A kind of 7. aqueous antistatic antimildew and antibacterial building coating according to claim 1, it is characterised in that：The ZnOw is Reactor preheating vapour phase oxidation process production, has following technical indicator：Outward appearance：White loose sprills；Microstructure：Needle-like； Crystal structure：Monocrystalline, Pb-Zn deposits crystal formation；Described calcium carbonate is the white powder that high velocity air crushes calcite production, is had Following technical indicator：Particle diameter D60 (μm)≤3.0, whiteness % >=96, oil absorption 20~24.
- A kind of 8. aqueous antistatic antimildew and antibacterial building coating according to claim 1, it is characterised in that：Described film forming Auxiliary agent is lauryl alcohol ester, and the titanium dioxide is rutile-type Chinese white.
- A kind of 9. aqueous antistatic antimildew and antibacterial building coating according to claim 1, it is characterised in that：The thickener For any one in hydroxyethyl cellulose, polyurethane thickener or modified polyurea thickener or two or more with any ratio mixing Mixture.
- A kind of 10. preparation method of aqueous antistatic antimildew and antibacterial building coating, it is characterised in that：With following steps：(1) material is prepared by the percentage by weight of each component of claim 1 to 9 any claim；(2) in order by deionized water, propane diols, wetting agent, dispersant, the defoamer of half, pH adjusting agent, ZnOw, carbonic acid Calcium, titanium dioxide etc. are added in a mixing bowl, are uniformly dispersed are less than 50 μm to fineness at a high speed；(3) stirring at low speed is opened, rotating speed control is in 300~500r/min, addition emulsion, coalescents, in-can preservation agent, thickening Agent, second half defoamer, it is stirred for after adding 20 minutes；(4) product is detected, detects qualified rear filtering, packaging；The sieve mesh number of filter is 80~120 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710667771.XA CN107353752A (en) | 2017-08-07 | 2017-08-07 | A kind of aqueous antistatic antimildew and antibacterial type building coating and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710667771.XA CN107353752A (en) | 2017-08-07 | 2017-08-07 | A kind of aqueous antistatic antimildew and antibacterial type building coating and its production method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107353752A true CN107353752A (en) | 2017-11-17 |
Family
ID=60288375
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710667771.XA Pending CN107353752A (en) | 2017-08-07 | 2017-08-07 | A kind of aqueous antistatic antimildew and antibacterial type building coating and its production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107353752A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880607A (en) * | 2017-12-15 | 2018-04-06 | 侯玉德 | A kind of preparation method of antifouling building coating |
| CN108531003A (en) * | 2018-03-12 | 2018-09-14 | 河北晨阳工贸集团有限公司 | Indoor mould proof, antibacterial, the antistatic coating and preparation method thereof except formaldehyde |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964932A (en) * | 2012-10-26 | 2013-03-13 | 合众（佛山）化工有限公司 | Preparation method of multifunctional humidifying interior wall paint |
| CN105623406A (en) * | 2016-03-18 | 2016-06-01 | 信和新材料股份有限公司 | Water-based conductive electromagnetic shielding building coating based on graphene and production method thereof |
-
2017
- 2017-08-07 CN CN201710667771.XA patent/CN107353752A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964932A (en) * | 2012-10-26 | 2013-03-13 | 合众（佛山）化工有限公司 | Preparation method of multifunctional humidifying interior wall paint |
| CN105623406A (en) * | 2016-03-18 | 2016-06-01 | 信和新材料股份有限公司 | Water-based conductive electromagnetic shielding building coating based on graphene and production method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 金宗哲: "《无机抗菌材料及应用》", 31 August 2004, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880607A (en) * | 2017-12-15 | 2018-04-06 | 侯玉德 | A kind of preparation method of antifouling building coating |
| CN108531003A (en) * | 2018-03-12 | 2018-09-14 | 河北晨阳工贸集团有限公司 | Indoor mould proof, antibacterial, the antistatic coating and preparation method thereof except formaldehyde |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106590268B (en) | A kind of lacquer and preparation method thereof | |
| CN105400239B (en) | A kind of preparation method of modifying super hydrophobicity silica | |
| CN107140911A (en) | Polymer cement waterproof paint that can be scratched and its preparation method and application | |
| CN105884251A (en) | Graphene-based waterborne electric heating coating and preparation method thereof | |
| CN105385274A (en) | Environment-friendly building waterproof paint with low content of VOC and preparation method thereof | |
| CN105086696B (en) | A kind of water paint and preparation method thereof | |
| CN106147441A (en) | Resistance to soiling water-based paint compositions | |
| CN103333559A (en) | Water-based transparent concrete water-proof carbonization-preventing coating and preparation method thereof | |
| CN106700814B (en) | Aqueous high adhesion force dividing joint priming paint and its preparation method and application | |
| CA2629811C (en) | Bactericidal filler composition | |
| CN107353752A (en) | A kind of aqueous antistatic antimildew and antibacterial type building coating and its production method | |
| CN102976705A (en) | Aqueous inorganic nano-ceramic coating binder, coating containing binder, and preparation method of binder | |
| CN103789075B (en) | High-concentration composite nano TiO2/ZnO lubricating additive and preparation method | |
| CN113956705A (en) | Preparation method of hydrophobic modified nano-silica solution, stain-resistant real stone paint and preparation method thereof | |
| CN110358391A (en) | A kind of quick-dry type water soluble acrylic acid container case mark paint and preparation method thereof | |
| CN107011741A (en) | A kind of water paint and its preparation technology | |
| CN102746748B (en) | Aqueous edge-sealing paint and preparation method thereof | |
| CN111534133A (en) | Negative oxygen ion inorganic coating and preparation method thereof | |
| CN114436616B (en) | Inorganic exterior wall mildew-proof stone-like paint | |
| CN109321045A (en) | A kind of water paint and preparation method thereof made of conch meal | |
| CN108587274A (en) | Environment-friendly water-based paint of one kind and preparation method thereof | |
| CN107384062A (en) | A kind of aqueous fire-proof coating factory formula | |
| CN115260812B (en) | Inorganic mineral coating and preparation method thereof | |
| CN104073051A (en) | Novel anticorrosion antirust compound white pigment and preparation method thereof | |
| CN103275539A (en) | Weather-proof pigment composition for painting stone surface |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171117 |
|
| RJ01 | Rejection of invention patent application after publication |