CN105086696B - A kind of water paint and preparation method thereof - Google Patents
A kind of water paint and preparation method thereof Download PDFInfo
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- CN105086696B CN105086696B CN201410196578.9A CN201410196578A CN105086696B CN 105086696 B CN105086696 B CN 105086696B CN 201410196578 A CN201410196578 A CN 201410196578A CN 105086696 B CN105086696 B CN 105086696B
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- wetting dispersing
- water paint
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 121
- 239000003973 paint Substances 0.000 title claims abstract description 85
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 48
- 238000009736 wetting Methods 0.000 claims abstract description 44
- 239000002270 dispersing agent Substances 0.000 claims abstract description 41
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 35
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- 239000000839 emulsion Substances 0.000 claims abstract description 29
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 24
- 229960001631 carbomer Drugs 0.000 claims abstract description 24
- 239000000230 xanthan gum Substances 0.000 claims abstract description 23
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 23
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 23
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 23
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 22
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 21
- 239000000417 fungicide Substances 0.000 claims abstract description 21
- 239000000945 filler Substances 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000000243 solution Substances 0.000 claims description 32
- 239000005995 Aluminium silicate Substances 0.000 claims description 17
- 235000012211 aluminium silicate Nutrition 0.000 claims description 17
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 17
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 239000002002 slurry Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 12
- 239000006210 lotion Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- -1 acids amine salt Chemical class 0.000 claims description 9
- 241000276489 Merlangius merlangus Species 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 235000010215 titanium dioxide Nutrition 0.000 claims description 4
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims description 3
- JVTIXNMXDLQEJE-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate 2-octanoyloxypropyl octanoate Chemical compound C(CCCCCCC)(=O)OCC(C)OC(CCCCCCC)=O.C(=O)(CCCCCCCCC)OCC(C)OC(=O)CCCCCCCCC JVTIXNMXDLQEJE-UHFFFAOYSA-N 0.000 claims description 3
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 claims description 3
- 229940082484 carbomer-934 Drugs 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 238000001802 infusion Methods 0.000 claims description 3
- 239000003139 biocide Substances 0.000 claims description 2
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical group O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 2
- 229910052791 calcium Inorganic materials 0.000 claims 2
- 239000011575 calcium Substances 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 30
- 238000003860 storage Methods 0.000 abstract description 7
- 239000003513 alkali Substances 0.000 abstract description 4
- 239000000725 suspension Substances 0.000 abstract description 3
- 238000005299 abrasion Methods 0.000 abstract description 2
- 238000012423 maintenance Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 description 39
- 239000011248 coating agent Substances 0.000 description 16
- 238000000576 coating method Methods 0.000 description 16
- 238000012360 testing method Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000001680 brushing effect Effects 0.000 description 6
- 239000011256 inorganic filler Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 4
- 238000007761 roller coating Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000012855 volatile organic compound Substances 0.000 description 4
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 235000013618 yogurt Nutrition 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 241000589636 Xanthomonas campestris Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229940086737 allyl sucrose Drugs 0.000 description 1
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N alpha-methyl toluene Natural products CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001976 enzyme digestion Methods 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229940059442 hemicellulase Drugs 0.000 description 1
- 108010002430 hemicellulase Proteins 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 229920000344 molecularly imprinted polymer Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of water paint and preparation method thereof, the composition of raw materials of the water paint includes: acrylic emulsion 15.2~50.2%, xanthan gum 0.065~0.09%, inorganic pigment 10.5~18.8%, filler 16.0~29.8%, wetting dispersing agent 0.6~2.3%, defoaming agent 0.1~0.5%, fungicide 0.4~4.0%, carbomer 0.1~3.2%, coalescing agent 0.6~3.0%, antifreezing agent 1.0~4.2% and water 20.0~29.0%.The water paint has good suspension, emulsibility, dispersibility and stability, service performance is good, it is able to satisfy the individual character construction demand of DIY, paint film obtained by it, alkali resistance, abrasion resistance and stain resistance are very excellent, the water paint is suitable for requiring storage stability requirement high, and the construction time limit is short and requires that maintenance cost is low, place of execution conditions rather harsh.
Description
Technical field
The present invention relates to paint fields more particularly to a kind of water paint and preparation method thereof.
Background technique
It as the saying goes " three points of coating seven give work ", coating products performance has extremely important shadow for the application property of coating
It rings.In the work progress of coating, due to the difference of form of construction work, it is larger to will lead to final coating performance difference.Therefore, it is producing
When product are constructed, often there are many limitations to want construction environment, water quality requirement, the requirement of construction personnel's profession, skill requirement etc.
It asks, in the case where not being able to satisfy water paint above-mentioned requirements, the property of expected effect and film is not achieved in the coating after construction
Energy level results in product failure, schedule delays in this way and spends a large amount of rework cost.Therefore, existing commercially available coating
The bad practical problem of generally existing workability.
As water paint application property individual demand is constantly expected in market, water paint type in continually developing,
Its construction method is also not necessarily limited to water paint concerned countries, and to standard, (" synthetic resin emulsion interior wall applies such as GB/T9756-2009
Material ", GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ") in brushing mode.And the application property and product of water paint
Viscosity, storage period, shear viscosity, pH value and construction personnel, the factors such as construction environment have a relationship, and above-mentioned each factor it
Between there are reciprocation and effect it is significant.
In addition, water paint currently on the market generallys use hydroxyethyl cellulose as system thickener, dissolved
Requirement of the journey to pH value is stringent, and generating a large amount of mushroom vulnerable to the pollution of water quality in production process causes final products rotten.
Therefore, a kind of water paint that application property is splendid how is developed, can satisfy the individual character construction demand of DIY,
It is not limited when constructing by various factors, and the film performance after construction is excellent, is this field scientific research personnel skill urgently to be resolved
Art problem.
Summary of the invention
Technical problem solved by the invention is to overcome existing water paint by application property condition that (such as product is glued
Spend, be watered the factors such as ratio, pH value and construction personnel, construction environment) limitation, the bad defect of workability provides one
Kind water paint and preparation method thereof.Water paint of the invention not only assigns the decoration and defencive function of coating, meets country
Requirement to the related harmful substance standard of water paint, and its form of construction work is not limited to water paint concerned countries to standard
In (such as GB/T9756-2009 " resin latex dope ", GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ")
Brushing mode, and can using roller coating, spraying, criticize and the forms of construction work such as scrape, and the viscosity to construction, construction environment, apply
The professional of worker person is not strict with, and is suitble to various people DIY to construct, and the stability of the water paint
Good, the film performance after use is good.
The present invention solves above-mentioned technical problem by the following technical programs.
The present invention provides a kind of water paint, composition of raw materials includes the component of following mass percents: propylene yogurt
Liquid 15.2~50.2%, xanthan gum 0.065~0.09%, inorganic pigment 10.5~18.8%, filler 16.0~29.8%, wetting
Dispersing agent 0.6~2.3%, defoaming agent 0.1~0.5%, fungicide 0.4~4.0%, carbomer 0.1~3.2%, coalescing agent
0.6~3.0%, antifreezing agent 1.0~4.2% and water 20.0~29.0%.
Wherein, the acrylic emulsion can be acrylic emulsion commonly used in the art, including pure-acrylic emulsion, silicon third
Lotion or styrene-acrylic emulsion etc..The acrylic emulsion is preferably silicone acrylic emulsion and/or pure-acrylic emulsion.The propylene yogurt
Liquid preferably meets following indexs: high mechanical stability, thermal stability, extremely low VOC, formaldehydeless residual, lower viscosity,
Splendid sprayability and self-leveling, solid content >=49wt%, adhesive force≤1 grade carry out water resistance survey by GB/T1733-1993
Examination, 168 hours lotions passed through.The acrylic emulsion is more preferably the SD-168 of Nantong Shengda Chemical Co., Ltd.'s production
In the AC-261P lotion of lotion, the BLJ-998AD lotion of Shanghai Bao Lijia Chemical Co., Ltd. production and ROHM AND HAAS production
It is one or more.
Wherein, the xanthan gum refers to sends out liquor-saturated by carbohydrate through Xanthomonas campestris, the extracellular microbial polysaccharide of generation, tool
There are macromolecular special construction and colloid property, there is extremely strong anti-oxidant and resistance to enzymolysis ability.The 1wt% of the xanthan gum is water-soluble
Viscosity of the liquid at 23 DEG C preferably≤100000mPas (test method: 23 ± 0.5 DEG C using Grade H viscosity measure
Examination).The xanthan gum is more preferably that xanthan gum, Henan Kang Wei biotechnology that Shandong Zhong Xuan limited liability company produces are limited
One of xanthan gum that the xanthan gum of company's production and Shanghai Li Qi auxiliary chemicals Co., Ltd produce is a variety of.
Wherein, the inorganic pigment can be for weatherability commonly used in the art up to 5 grades and light resistance is up to 7 grades of nothing
Machine pigment can select the type and color of inorganic pigment according to conventional method in that art.The inorganic pigment is preferably gold
Red stone titanium white, carbon black or iron oxide yellow.
Wherein, the filler can be filler commonly used in the art, its general oil absorption is less than 50g/100g, easily divides
It dissipates, there is anti-powdering, anti-settling property is good.The filler is preferably one of sericite in powder, kaolin and powdered whiting
Or it is a variety of.The sericite in powder is preferably wet process sericite in powder, the more preferably production for Chuzhou Ge Rui mining industry Co., Ltd
GA-4 wet process sericite in powder.The kaolin be eluriated it is selected, bleach, brighten, calcining and the techniques such as air flow super
Refined, mesh number is preferably 1250 mesh or more, and kaolinic strong covering power has fabulous titanium white ductility, divides
Scattered property and suspension are good, have good anti-settling effect, can be improved application property, the weatherability of coating, can improve the storage of coating
Deposit stability.The kaolin is preferably calcined kaolin, the more preferably DB-1 for China Kaolin Clay Co., Ltd.'s production
In the BM V60 calcined kaolin of calcined kaolin, DB-2 calcined kaolin and the production of Guangdong Bang Le industrial chemicals Co., Ltd
It is one or more.The powdered whiting should be free of heavy metal, and preferably Jiangxi Ao Te fine powder Co., Ltd produces
AT-0026 powdered whiting and/or AT-0028 powdered whiting.
Wherein, the wetting dispersing agent can be wetting dispersing agent commonly used in the art, can reduce surface
Power has fabulous wetting and spreading ability, and the additional amount of pigment and filler can be improved without increasing viscosity.The wetting point
Powder is preferably polycarboxylic acids amine salt wetting dispersing agent.The polycarboxylic acids amine salt wetting dispersing agent preferably meets following performances
Index: the cloud point of the aqueous solution of polycarboxylic acids amine salt wetting dispersing agent described in 1wt% is 27~30 DEG C and the polycarboxylic acids amine salt
The density of wetting dispersing agent is 1.05~1.08g/cm3, the density measures at 20 DEG C.The wetting dispersing agent is most preferably
For the wetting dispersing agent WA200 of Rhodia (Rhodia) group production, the wetting dispersing agent CF-10 of Dow Chemical and wetting
One of dispersing agent X-405 or a variety of.
Wherein, the carbomer (Carbomer) is the height that acrylic acid is bonded allyl sucrose or pentaerythrite allyl ether
Molecularly Imprinted Polymer.The carbomer is preferably one of carbomer 934, Acritamer 940 and Carbopol 941 or a variety of.
Wherein, the defoaming agent can be defoaming agent commonly used in the art, generally have both brokenly bubble and antifoaming ability.
The preferably modified methyl polysilicone alkanes defoaming agent of the defoaming agent.The modification methyl polysilicone alkanes defoaming agent compared with
Meet following performance indicators: 0.89~0.95g/cm of density goodly3, the density measures at 20 DEG C.The defoaming agent is more
What the defoaming agent RH-900 that provides goodly for Guangzhou Rui He new material Science and Technology Ltd., DOW Chemical Co., Ltd provided disappears
One of infusion BD-405 and defoaming agent BD-109 or a variety of.
Wherein, the fungicide can be fungicide commonly used in the art, preferably isothiazolinone biocide
Agent can be stable in water and not discharge free formaldehyde, and to gram-positive bacterium, gramnegative bacterium, fungi and ferment
Female bacterium is highly effective.The fungicide is more preferably the fungicide MIRECIDE- of Lamirsa Experimental Study College, Spain production
KW/600。
Wherein, the coalescing agent can be coalescing agent commonly used in the art, and preferably coalescing agent is her scholar
The coalescing agent Texanol of graceful Chemical Co., Ltd. (Eastman) production.
Wherein, the antifreezing agent can be antifreezing agent commonly used in the art, preferably propylene glycol and/or second two
Alcohol.
Wherein, the water can routinely use water, preferably deionized water for this field.
In a preferred embodiment of the present invention, the water paint, composition of raw materials include following quality percentages
The component of ratio: the acrylic emulsion 15.2~50.2%, the xanthan gum 0.065~0.09%, the inorganic pigment
10.5~18.8%, the filler 16.0~29.8%, the wetting dispersing agent 0.6~2.3%, the defoaming agent
0.1~0.5%, the fungicide 0.4~4.0%, the carbomer 0.1~3.2%, the coalescing agent 0.6~
3.0%, the antifreezing agent 1.0~4.2% and the water 20.0~29.0%.
In the more preferably embodiment of one in the present invention, the water paint, composition of raw materials is by following quality percentages
The group of ratio is grouped as: the acrylic emulsion 15.2~47.6%, the xanthan gum 0.065~0.09%, the nothing
Machine pigment 10.5~18.8%, the wetting dispersing agent 0.6~2.3%, described disappears at the filler 16.0~29.8%
Infusion 0.1~0.5%, the fungicide 0.4~4.0%, the carbomer 0.2~3.2%, the coalescing agent
0.6~3.0%, the antifreezing agent 1.0~4.2% and the water 20.0~29.0%.
In the present invention, the water paint, the viscosity at 10~50 DEG C is that 110~120KU (uses GB/
Method in T9269-2009 is tested, but test temperature is 10~50 DEG C), pH value at 10~50 DEG C is 8.4~
8.7.The water paint and water are mixed to form feed liquid with the mass ratio of 9:1~8:2, the feed liquid is at 20~25 DEG C
Viscosity is 110~120KU (being tested using the method in GB/T9269-2009, but test temperature is 20~25 DEG C), described
PH value of the feed liquid at 20~25 DEG C is 8.4~8.7.Water paint of the invention, in a situation of use, viscosity and pH value are not
Significant change can occur with temperature and the variation for being watered ratio.
The present invention also provides a kind of preparation methods of above-mentioned water paint comprising following step: conventional by this field
Water paint preparation method, by the composition of raw materials each component be uniformly mixed.
In the present invention, the preparation method preferably carries out in the steps below:
(1) water of the xanthan gum and 48.0~52.0% is mixed, dissolves to obtain solution A；By 50.0~
70.0% wetting dispersing agent, 30.0~50.0% carbomer and 30.0~50.0% the defoaming agent and institute
It states solution A and is uniformly mixed to obtain solution B；It will be described in the solution B, the inorganic pigment, the filler and 21.0~35.0%
Water is uniformly mixed at room temperature, and is dispersed to the partial size of the inorganic pigment, the filler at 45 μm hereinafter, obtaining slurry C；
(2) under stirring, the remaining wetting dispersing agent is added in the slurry C, remaining carbomer, remains
The remaining defoaming agent, the fungicide, the acrylic emulsion, the coalescing agent, the antifreezing agent and remaining described
Water is uniformly mixed；
Wherein, percentage is the mass percent relative to each respective components quality.
In step (1), the mixed method and condition is the method and condition of this field routine.The mixing compared with
It is carried out by the way of being stirred goodly.The step (1) is more preferably carried out by operations described below: by the xanthan gum with
48.0~52.0% water is stirred with the revolving speed of 1000~1200rpm, dissolves to obtain solution A；By 50.0~70.0%
The wetting dispersing agent, 30.0~50.0% carbomer and 30.0~50.0% defoaming agent and the solution
A is uniformly mixed to obtain solution B with the revolving speed of 600~800rpm；By the solution B, the inorganic pigment, the filler and
21.0~35.0% water is uniformly mixed at room temperature with the revolving speed of 1200~1500rpm, and is dispersed to the nothing
Machine pigment, the packing material size are at 45 μm hereinafter, obtaining slurry C；Wherein, percentage is the matter relative to each respective components quality
Measure percentage.
In step (2), the condition of the stirring is the condition of this field routine.The revolving speed of the stirring is preferably 600
~800rpm.
In the present invention, the room temperature is the usual definition of this field, refers generally to 5~40 DEG C.
On the basis of common knowledge of the art, above-mentioned each optimum condition, can any combination to get each preferable reality of the present invention
Example.
The reagents and materials used in the present invention are commercially available.
The positive effect of the present invention is that:
1, water paint of the invention has good suspension, emulsibility, dispersibility.Simple production process produced
Journey eliminates the limitation of technical requirements in water paint process, does not need the requirement of stringent water temperature such as, does not need grinding and sets
It is standby, energy consumption in production process is reduced, the pH value of control product, the waste water of generation and easy to handle are not needed.
2, water paint of the invention has stronger pseudoplastic behavior, has high viscosity under static or low shear action,
It shows as viscosity under high shear forces sharply to decline, but molecular structure is constant.And when shearing force is eliminated, then recover immediately original
The relationship of some viscosity, shearing force and viscosity is completely plastic.
3, water paint of the invention have heat stability, viscosity will not variation with temperature and very big change occurs
Change, to not stringent temperature limits of storing in a warehouse, viscosity has almost no change between 10~80 DEG C, makes it in wide temperature
It can construct in degree range.
4, water paint of the invention, which meets acid-alkali medium, has sufficiently stable property, pH be between 5~10 its viscosity not by
It influences, when pH is less than 4 and greater than 11, viscosity has slight variation.In the range of pH is 3~11, viscosity maxima and minimum
Value differs less than 10%, this characteristic is based on, to the not stringent soda acid processing requirement of construction substrate.
5, water paint of the invention has stability to salt, with many salting liquids (sylvite, sodium salt, calcium salt, magnesium salts etc.)
Miscible, viscosity is unaffected.Under the conditions of higher salt concentrations, does not occur to precipitate and flocculate, viscosity is barely affected, extensively
Suitable for coastal cities.
6, water paint of the invention has stability to enzyme digestion reaction, has extremely strong anti-oxidant and resistance to enzymolysis ability,
The enzymes such as many enzymes such as protease, amylase, cellulase and hemicellulase cannot all make its degradation.
7, water paint of the invention is suitable for brushing, roller coating, spraying, criticizes and scrape, and not stringent to construction personnel is special
Industry or skill requirement are not strict with construction environment, meet the individual character construction demand of DIY.Water paint of the invention is suitable
For requiring storage stability requirement high, the construction time limit is short and requires that maintenance cost is low, place of execution conditions rather harsh.
8, water paint of the invention is without organic solvents and free diisocyanates such as benzene,toluene,xylene and ethylbenzene
Ester etc. requires human body and the harmful substance of environment, volatile organic compounds (abbreviation VOC) far below National Standards Technical, and
And the fire protection requirement not stringent to production, transport, storage.
9, paint film made from water paint of the invention has and surmounts the performance of its water paint national standard, alkali resistance,
Abrasion resistance and stain resistance are very excellent, are applicable not only to interior wall coating, and be suitable for exterior wall coating, are that inner-outer wall is logical
With type coating.
Specific embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to the reality
It applies among a range.In the following examples, the experimental methods for specific conditions are not specified, according to conventional methods and conditions, or according to quotient
The selection of product specification.
In following embodiments and comparative example, rule of origin used is as follows:
SD-168 lotion (acrylic emulsion): Nantong Shengda Chemical Co., Ltd.'s production；
BLJ-998AD lotion (acrylic emulsion): Shanghai Bao Lijia Chemical Co., Ltd. production；
AC-261P lotion (acrylic emulsion): ROHM AND HAAS production；
Xanthan gum: the production of Shandong Zhong Xuan limited liability company, the production of Henan Kang Wei Biotechnology Co., Ltd or Shanghai are vertical
Odd auxiliary chemicals Co., Ltd production；Viscosity≤100000mPas of the 1wt% aqueous solution of those xanthan gum at 23 DEG C (is surveyed
Method for testing: 23 ± 0.5 DEG C are tested using Grade H viscosimeter)；
Rutile titanium white R828: Ke Meiji pigment Co., Ltd, the U.S.；
Carbon black M1300: Cabot Co., Ltd, the U.S.
Iron oxide yellow: Shanghai Yipin Pigments Co., Ltd.'s production；
Powdered whiting AT-0026: Jiangxi Ao Te fine powder Co., Ltd production；
Powdered whiting AT-0028: Jiangxi Ao Te fine powder Co., Ltd production；
Calcined kaolin DB-1: China Kaolin Clay Co., Ltd.'s production；
Calcined kaolin DB-2: China Kaolin Clay Co., Ltd.'s production；
Calcined kaolin BM V60: Guangdong Bang Le industrial chemicals Co., Ltd production；
Sericite in powder GA-4: Chuzhou Ge Rui mining industry Co., Ltd production；
The production of wetting dispersing agent WA200Rhodia:Rhodia group；
Wetting dispersing agent CF-10: DOW Chemical Co., Ltd production；
Wetting dispersing agent X-405: DOW Chemical Co., Ltd production；
Fungicide MIRECIDE-KW/600: the fungicide of LAMIRSA Experimental Study College, Spain production；
Defoaming agent RH-900: Guangzhou Rui He new material Science and Technology Ltd. production；
Defoaming agent BD-405 and BD-109: the production of DOW Chemical Co., Ltd；
Carbomer 934: Langfang Ju Tong Chemical Co., Ltd. production；
Acritamer 940: Langfang Ju Tong Chemical Co., Ltd. production；
Carbopol 941: Langfang Ju Tong Chemical Co., Ltd. production；
Coalescing agent Texanol: Eastman Chemical Company (EASTMAN) production；
Water paint H1000: Huili Coating Co., Ltd., Shanghai's production；
Water paint BC-200: Hanzhou Guanghui Chemical Co., Ltd.'s production.
Embodiment 1
Composition of raw materials (wt%) such as the following table 1 of the water paint of embodiment 1.
Table 1
The preparation method of the water paint includes the following steps:
(1) deionized water of xanthan gum solution and 48.0wt% are stirred under the revolving speed of 1200rpm, mixed dissolution obtains molten
Liquid A；By the wetting dispersing agent of 50.0wt%, the defoaming agent of the carbomer of 50.0wt% and 30.0wt% and solution A with 800rpm
Revolving speed stirring, be uniformly mixed to obtain solution B；At room temperature by the deionized water of solution B, inorganic pigment, filler and 35.0wt%
Stirred, be uniformly mixed with the revolving speed of 1500rpm, and be dispersed to inorganic pigment, inorganic filler partial size at 45 μm hereinafter, slurry
C；
(2) under the speed of agitator of 600rpm, remaining wetting dispersing agent is added in slurry C, remaining carbomer, remains
Remaining defoaming agent, fungicide, acrylic emulsion, coalescing agent, antifreezing agent and remaining deionized water is uniformly mixed；
Wherein, percentage is the weight percent relative to each respective components weight.
Embodiment 2
Composition of raw materials (wt%) such as the following table 2 of the water paint of embodiment 2.
Table 2
The preparation method of the water paint includes the following steps:
(1) deionized water of xanthan gum and 50.0wt% are stirred under the revolving speed of 1100rpm, mixed dissolution obtains solution A；
By the wetting dispersing agent of 60.0wt%, the defoaming agent of the carbomer of 50.0wt% and 30.0wt% and solution A turning with 700rpm
Speed stirring, is uniformly mixed to obtain solution B；By the deionized water of solution B, inorganic pigment, filler and 28.0wt% at room temperature with
The revolving speed of 1400rpm stirs, and is uniformly mixed, and is dispersed to the partial size of inorganic pigment, filler at 45 μm hereinafter, obtaining slurry C；
(2) under the speed of agitator of 700rpm, remaining wetting dispersing agent is added in slurry C, remaining carbomer, remains
Remaining defoaming agent, fungicide, acrylic emulsion, coalescing agent, antifreezing agent and remaining deionized water is uniformly mixed；
Wherein, percentage is the weight percent relative to each respective components weight.
Embodiment 3
Composition of raw materials (wt%) such as the following table 3 of the water paint of embodiment 3.
Table 3
The preparation method of the water paint includes the following steps:
(1) deionized water of xanthan gum and 52.0wt% are stirred under the revolving speed of 1000rpm, mixed dissolution obtains solution A；
By the wetting dispersing agent of 50.0wt%, the defoaming agent of the carbomer of 30.0wt% and 50.0wt% and solution A turning with 600rpm
Speed stirring, is uniformly mixed to obtain solution B；By the deionized water of solution B, inorganic pigment, filler and 28.0wt% at room temperature with
The revolving speed of 1200rpm stirs, and is uniformly mixed, and is dispersed to the partial size of inorganic pigment, filler at 45 μm hereinafter, obtaining slurry C；
(2) under the speed of agitator of 800rpm, remaining wetting dispersing agent is added in slurry C, remaining carbomer, remains
Remaining defoaming agent, fungicide, acrylic emulsion, coalescing agent, antifreezing agent and remaining deionized water is uniformly mixed；
Wherein, percentage is the weight percent relative to each respective components weight.
Comparative example 1
Composition of raw materials (wt%) such as the following table 4 of water paint.
Table 4
The water paint the preparation method is as follows:
(1) by the deionized water of xanthan gum and 25.0wt% to stir under the revolving speed of 1100rpm, mixed dissolution obtains solution A；
By the wetting dispersing agent of 60.0wt%, the defoaming agent of the carbomer of 50.0wt% and 30.0wt% and solution A turning with 700rpm
Speed stirring, is uniformly mixed to obtain solution B；By the deionized water of solution B, inorganic pigment, filler and 40wt% at room temperature mix with
The revolving speed of 1400rpm stirs, and is uniformly mixed, and is dispersed to the partial size of inorganic pigment, filler at 45 μm hereinafter, obtaining slurry C；
(2) under the speed of agitator of 700rpm, remaining wetting dispersing agent is added in slurry C, remaining carbomer, remains
Remaining defoaming agent, fungicide, acrylic emulsion, coalescing agent, antifreezing agent and remaining deionized water is uniformly mixed；
Wherein, percentage is the weight percent relative to each respective components weight.
Effect example
To the water paint of Examples 1 to 3, commercially available water paint H1000, water paint BC-200 and comparative example
1 water paint carries out every experiment of performance and environmental protection index, and concrete outcome is shown in Table 5 and table 6.
Each product performance index of table 5
6 environmental protection index of table
As seen from Table 5, the performance of water paint of the invention is stablized, long time without deposit phenomenon, service performance
Good, drying time is fast, and alkali resistance, brushing resistance, stain resistance and temperature-change resistance are good, and artificial weathering ageing resistance is good, and excellent
The water paint made from commercially available water paint H1000, water paint BC-200 and comparative example 1.In addition, to embodiment
It is found in the detection of 1~3 water paint, in the case where pH is 5~10 test condition, the viscosity of each water paint is unaffected,
When pH is less than 4 and greater than 11, viscosity has slight variation.In the range of pH is 3~11, viscosity maxima and minimum value phase
Difference is less than 10%.Based on this, water paint of the invention wants the not stringent soda acid processing of construction substrate in construction
It asks.
As seen from Table 6, the VOC content of water paint of the invention is far below conventional water paint, and trip is not detected
It is a kind of environment-friendly water-based paint for meeting current generation demand, indices from formaldehyde, benzene, toluene and heavy metal substance
It is superior to water paint made from commercially available water paint H1000, water paint BC-200 and comparative example 1.
To the water paint of Examples 1 to 3, commercially available water paint H1000, water paint BC-200 and comparative example
1 water paint it is different using temperature and being watered carry out under ratio viscosity, pH value variation and can construction method test,
It the results are shown in Table 7.Wherein, storage viscosity is tested according to the method in GB/T9269-2009, but temperature when test is practical
Temperature.Wherein, working viscosity is tested according to the method in GB/T9269-2009, but temperature when test is actual temperature,
And revolving speed is 400r/min when testing.
The viscosity of 7 water paint of table, pH value, can workability test result
As seen from Table 7, commercially available water paint H1000, water paint BC-200 and comparative example 1 are then with using temperature
It spends, be watered the variation of ratio and the variation of viscosity and pH value occurs, identical product cannot be real simultaneously after causing condition to change
Brushing, roller coating, spraying, knife-coat application mode are applied, is not able to satisfy the individual character construction demand of DIY.
The viscosity of water paint of the invention with being watered ratio, had almost no change using temperature, and can be used brushing,
The modes such as roller coating, spraying, blade coating are constructed, and pH value not with the ratio that is watered, temperature variation and change, can satisfy
The individual character construction demand of DIY, overcoming commercially available water paint, (viscosity of such as product, storage period, shearing are viscous to application property condition
Degree, pH value and construction personnel, construction environment) limitation.
Claims (9)
1. a kind of water paint, which is characterized in that its composition of raw materials includes the component of following mass percents: acrylic emulsion
15.2~50.2%, xanthan gum 0.065~0.09%, inorganic pigment 10.5~18.8%, filler 16.0~29.8%, wetting dispersing agent
0.6~2.3%, defoaming agent 0.1~0.5%, fungicide 0.4~4.0%, carbomer 0.1~3.2%, coalescing agent 0.6~3.0%,
Antifreezing agent 1.0~4.2% and water 20.0~29.0%；The carbomer is in carbomer 934, Acritamer 940 and Carbopol 941
It is one or more.
2. water paint as described in claim 1, which is characterized in that the acrylic emulsion is silicone acrylic emulsion and/or pure
Acrylic emulsion；And/or viscosity≤100000mPa s of the 1wt% aqueous solution of the xanthan gum at 23 DEG C；And/or the nothing
Machine pigment is rutile titanium white, carbon black or iron oxide yellow；And/or the filler is sericite in powder, kaolin and heavy carbonic acid
One of calcium is a variety of；And/or the wetting dispersing agent is polycarboxylic acids amine salt wetting dispersing agent；And/or described disappear
Infusion is modified methyl polysilicone alkanes defoaming agent；And/or the fungicide is isothiazolinone biocide agent；And/or
Wherein, the coalescing agent is coalescing agent Texanol；And/or the antifreezing agent is propylene glycol and/or ethylene glycol；
And/or the water is deionized water.
3. water paint as claimed in claim 2, which is characterized in that the acrylic emulsion is SD-168 lotion, BLJ-
One of 998AD lotion and AC-261P lotion are a variety of；
And/or the sericite in powder is wet process sericite in powder；The kaolin is calcined kaolin；The heavy carbon
Sour calcium is AT-0026 powdered whiting and/or AT-0028 powdered whiting；
And/or the polycarboxylic acids amine salt wetting dispersing agent meets following performance indicators: the wetting point of polycarboxylic acids amine salt described in 1wt%
The cloud point of the aqueous solution of powder is 27~30 DEG C and the density of the polycarboxylic acids amine salt wetting dispersing agent is 1.05~1.08g/
cm3, the density measures at 20 DEG C；
And/or the modification methyl polysilicone alkanes defoaming agent meets following performance indicators: 0.89~0.95g/cm of density3,
The density is measured at 20 DEG C；
And/or the fungicide is fungicide MIRECIDE-KW/600.
4. water paint as claimed in claim 3, which is characterized in that the sericite in powder is GA-4 wet process sericite in powder；Institute
The kaolin stated is one of DB-1 calcined kaolin, DB-2 calcined kaolin and BM V60 calcined kaolin or a variety of；
And/or the wetting dispersing agent is wetting dispersing agent WA 200, wetting dispersing agent CF-10 and wetting dispersing agent X-405
One of or it is a variety of；
And/or the defoaming agent is one of defoaming agent RH-900, defoaming agent BD-405 and defoaming agent BD-109 or more
Kind.
5. such as the described in any item water paints of Claims 1 to 4, which is characterized in that its composition of raw materials is by following quality percentages
The group of ratio is grouped as: the acrylic emulsion 15.2~47.6%, the xanthan gum 0.065 ~ 0.09%, the inorganic face
Expect 10.5~18.8%, the filler 16.0~29.8%, the wetting dispersing agent 0.6~2.3%, the defoaming agent 0.1
~0.5%, the fungicide 0.4~4.0%, the carbomer 0.2~3.2%, the coalescing agent 0.6~3.0%, institute
The antifreezing agent 1.0~4.2% and the water 20.0~29.0% stated.
6. a kind of preparation method of any one of Claims 1 to 5 water paint, which is characterized in that it includes the following steps:
Each component in the composition of raw materials is uniformly mixed.
7. preparation method as claimed in claim 6, which is characterized in that the preparation method carries out in the steps below:
(1) water of the xanthan gum and 48.0~52.0% is mixed, dissolves to obtain solution A；By 50.0~70.0%
The wetting dispersing agent, 30.0~50.0% carbomer and 30.0~50.0% defoaming agent and the solution A are mixed
Close uniform solution B；By the solution B, the inorganic pigment, the filler and 21.0~35.0% the water at room temperature
It is uniformly mixed, and is dispersed to the partial size of the inorganic pigment, the filler at 45 μm hereinafter, obtaining slurry C；
(2) under stirring, the remaining wetting dispersing agent, remaining carbomer, remaining is added in the slurry C
The defoaming agent, the fungicide, the acrylic emulsion, the coalescing agent, the antifreezing agent and the remaining water mix
It closes uniform；
Wherein, percentage is the mass percent relative to each respective components quality.
8. preparation method as claimed in claim 7, which is characterized in that in step (1), what the mixing use was stirred
Mode carries out；And/or in step (2), the revolving speed of the stirring is 600~800rpm.
9. preparation method as claimed in claim 8, which is characterized in that the step (1) is carried out by operations described below: will be described
Xanthan gum be stirred with 48.0~52.0% water with the revolving speed of 1000~1200rpm, dissolve to obtain solution A；By 50.0
~70.0% wetting dispersing agent, 30.0~50.0% carbomer and 30.0~50.0% the defoaming agent and institute
It states solution A and solution B is uniformly mixed to obtain with the revolving speed of 600~800rpm；By the solution B, the inorganic pigment, described fill out
Expect and 21.0~35.0% water is uniformly mixed at room temperature with the revolving speed of 1200~1500rpm, and is dispersed to described
Inorganic pigment, the packing material size are at 45 μm hereinafter, obtaining slurry C；Wherein, percentage is relative to each respective components quality
Mass percent.
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| CN106009882A (en) * | 2016-06-29 | 2016-10-12 | 徐文学 | Multifunctional thickener for waterborne paint |
| CN108034293A (en) * | 2017-12-04 | 2018-05-15 | 杨忠华 | A kind of water-based metal baking vanish |
| CN108219610B (en) * | 2017-12-19 | 2020-04-10 | 江门市肇和制漆化工有限公司 | Anti-cracking and anti-permeability exterior wall emulsion paint |
| CN108841258A (en) * | 2018-05-18 | 2018-11-20 | 中华制漆（深圳）有限公司 | Environmental Protective Water-paint and preparation method thereof |
| CN108912755A (en) * | 2018-05-29 | 2018-11-30 | 佛山市顺德区雅成化工有限公司 | A kind of preparation method of aqueous inorganic paint |
| CN109667398A (en) * | 2018-12-25 | 2019-04-23 | 浙江厦光涂料有限公司 | A kind of master craftsman of the Spring and Autumn period's stone painting design and its construction method |
| CN113980521A (en) * | 2021-11-16 | 2022-01-28 | 霍广文 | Water-based paint and preparation method thereof |
| CN114605877A (en) * | 2022-03-07 | 2022-06-10 | 福建锡安香柏环保新材料有限公司 | Water-based paint scraping composition, four-side paint scraping and coating equipment and paint scraping and coating process |
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| CN102746751A (en) * | 2012-02-20 | 2012-10-24 | 上海三银制漆有限公司 | Anti-blattodea waterborne interior wall coating material, preparation method and application thereof |
| CN103131269A (en) * | 2012-08-06 | 2013-06-05 | 上海三银制漆有限公司 | Synthetic resin emulsion wall coating and preparation method thereof |
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| CN103468068B (en) * | 2013-05-22 | 2016-01-20 | 上海三银制漆有限公司 | Aqueous elastic fluorine carbon building coating covering large crackle and its preparation method and application |
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| CN102746751A (en) * | 2012-02-20 | 2012-10-24 | 上海三银制漆有限公司 | Anti-blattodea waterborne interior wall coating material, preparation method and application thereof |
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