CN102094514A - Sealing agent composition and application thereof to self-leveling ground product - Google Patents
Sealing agent composition and application thereof to self-leveling ground product Download PDFInfo
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- CN102094514A CN102094514A CN2010106187009A CN201010618700A CN102094514A CN 102094514 A CN102094514 A CN 102094514A CN 2010106187009 A CN2010106187009 A CN 2010106187009A CN 201010618700 A CN201010618700 A CN 201010618700A CN 102094514 A CN102094514 A CN 102094514A
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/12—Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1693—Antifouling paints; Underwater paints as part of a multilayer system
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
Abstract
The invention relates to a sealing agent composition and application thereof to a self-leveling ground product, and provides the sealing agent composition. The sealing agent composition consists of a pore filling agent and a surface covering agent, and is suitable for forming a protective coating on the ground, wherein the protective coating comprises at least one pore filling layer and at least one top coating; the pore filling layer is directly formed above the ground; and the top coating is directly formed above the pore filling layer. The invention also discloses the application of the sealing agent composition to the self-leveling ground product, and a method for detecting wear on the self-leveling ground product.
Description
Technical field
The invention belongs to the encapsulant field, relate to a kind of high performance sealant compositions, be applicable to the cement matrix or the loose structure that generally use in SLF (auto-flowing floor) product.The invention still further relates to the application of this sealant compositions in the auto-flowing floor product.
Background technology
The SLF product is a cement-based material, and it will form the material of porous sclerosis after curing and drying.For prevent that it is aging, wearing and tearing and because of leakage causes long pollution, the sealant that need can be used in extensive use provide have anti-scratch property, final application that pollution resistance and good anti-household liquids are polluted.
Organic solvent based sealer is believed to deeper infiltrate in the hole, and waterproof well.But its organic solvent content (accounting for the 50-80% of total formulation weight amount) is a kind of threat for environment and health.And the water-base emulsion sealer is safer usually, cheapness and environmentally friendly.
Yet, though change the benefit that aqueous composition can bring health and safety into from the organic solvent based composition and use thereof in packaging,, the water-base emulsion composition also needs to satisfy, even exceeds the performance standard that solvent-based compositions has.
U.S. Patent application US 5191002A discloses a kind of protective floor maintenance system, and it utilizes low zinc or phosphate prescription to reduce performance is kept in the influence of environment and the protective floor that provides usefulness.
European patent application EP 1371698A1 discloses and a kind ofly has been used to suppress water and infiltrates and comprise the application composition of cementitious material that average grain diameter is the polymer/nanoparticle of 1-50nm.
But the method for above-mentioned prior art only relates to the partial properties of sealant, can not satisfy the comprehensive demand of SLF product.
Therefore, this area presses for the coating preparation of developing a kind of SLF of being applied to product, and it can provide anti-household liquids, improves durability, the scraping of the capable traffic of contragradience and pollution and reduce performance to the needs of maintenance.
Simultaneously, this area also presses for the method that a kind of performance of estimating sealant changes along with pedestrian traffic of developing.Because that these sealants normally clean, colourless, so be very difficult to determine the degree of wearing and tearing.This method can help to determine sealant which point be worn and need and repair.In addition, this method can also be distinguished the difference of different sealing layer.
Summary of the invention
The invention provides a kind of new sealant compositions, thereby overcome the defective that exists in the prior art.
On the one hand; the invention provides a kind of sealant compositions; it is made up of hole filler and surface dopant; described sealant compositions is suitable for forming on ground a protective coating; described protective coating comprises at least one hole packed layer and at least one top coat, and described hole packed layer directly is formed on the described ground, and described top coat directly is formed on the described hole packed layer; wherein
Described hole filler is suitable for forming on the ground described hole packed layer, and described hole filler comprises following component:
(a1) comprise the water soluble acrylic acid base emulsion of acrylic substrate;
(b1) polymer wax emulsion;
(c1) additive;
(d1) water;
Described surface dopant is suitable for forming described top coat on this hole packed layer, and described surface dopant comprises following component:
(a2) comprise the water soluble acrylic acid base emulsion of acrylic substrate, wherein, the acrylic substrate in the described component (a2) is different from the acrylic substrate in the component (a1);
(b2) polymer wax emulsion;
(c2) additive;
(d2) water.
One preferred embodiment in, the molecular weight of the acrylic substrate in the described component (a1) is greater than the molecular weight of the acrylic substrate in the component (a2).
Another preferred embodiment in, acrylic substrate in acrylic substrate in the described component (a1) and the described component (a2) is block polymer or graft polymers, and the molecular weight of the acrylic substrate in the described component (a1) is 200000-350000, and the molecular weight of the acrylic substrate in the described component (a2) is 150000-260000.
Another preferred embodiment in, described hole filler comprises following component:
(a1) the water soluble acrylic acid base emulsion of 20-30 weight portion, described water soluble acrylic acid base emulsion is selected from: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, its copolymer, and composition thereof;
(b1) the polymer wax emulsion of 0.5-5 weight portion, described polymer wax emulsion is selected from: the polythene wax emulsion of oxidation, paraffin wax emulsions, high density polyethylene waxes emulsion, polytetrafluoroethylene (PTFE) wax emulsion, silicone emulsion and synthetic wax emulsion;
(c1) additive of 1.1-18 weight portion
(d1) water of 47-78.4 weight portion.
Another preferred embodiment in, described additive (c1) comprises following component:
(c11) the organic metal huge legendary turtle compound of 0.1-3 weight portion, described organic metal huge legendary turtle compound is selected from: organic titanium huge legendary turtle compound and aluminum-zirconium coupling agent;
(c12) polyfunctional crosslinking agent of 0.5-1 weight portion, described polyfunctional crosslinking agent is selected from multi-functional aziridine;
(c13) the anti-scratch liniment of 0.5-3 weight portion, the coalescents of 5 weight portions at the most, the surfactant of 3 weight portions and the defoamer of 3 weight portions at the most at the most.
Another preferred embodiment in, described anti-scratch liniment is selected from polyether-modified dimethyl silicone polymer.
Another preferred embodiment in, described coalescents is selected from: lactate, butoxy ethanol, phthalic acid ester, ethylene glycol, diethylene glycol, DAA, propane diols and ethylene glycol phenyl ether.
Another preferred embodiment in, described surfactant is selected from: the carboxylate of acrylic ester copolymer and 2-amino-2-methyl-1-propanol.
Another preferred embodiment in, described defoamer is selected from: mineral oil origin defoamer and silicone antifoam agent.
Another preferred embodiment in, described surface dopant comprises following component:
(a2) the water soluble acrylic acid base emulsion of 20-45 weight portion;
(b2) the polymer wax emulsion of 2-8 weight portion;
(c2) additive of 1.6-20 weight portion.
Another preferred embodiment in, described additive (c2) comprises following component:
(c21) the organic metal huge legendary turtle compound of 0.1-3 weight portion, described organic metal huge legendary turtle compound is selected from: organic titanium huge legendary turtle compound and aluminum-zirconium coupling agent;
(c22) polyfunctional crosslinking agent of 1-3 weight portion, described polyfunctional crosslinking agent is selected from multi-functional aziridine;
(c23) the anti-scratch liniment of 0.5-3 weight portion, the coalescents of 5 weight portions at the most, the surfactant of 3 weight portions and the defoamer of 3 weight portions at the most at the most.
Another preferred embodiment in, described anti-scratch liniment is selected from polyether-modified dimethyl silicone polymer.
Another preferred embodiment in, described coalescents is selected from: lactate, butoxy ethanol, phthalic acid ester, ethylene glycol, diethylene glycol, DAA, propane diols and ethylene glycol phenyl ether.
Another preferred embodiment in, described surfactant is selected from: the carboxylate of acrylic ester copolymer and 2-amino-2-methyl-1-propanol.
Another preferred embodiment in, described defoamer is selected from: mineral oil origin froth breaking silica and alkane defoamer.
Another preferred embodiment in, the water soluble acrylic acid base emulsion in the described component (a1) is selected from: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, its copolymer, and composition thereof.
Another preferred embodiment in, the polymer wax emulsion in the described component (a2) is selected from: the polythene wax emulsion of oxidation, paraffin wax emulsions, high density polyethylene waxes emulsion, polytetrafluoroethylene (PTFE) wax emulsion, silicone emulsion and synthetic wax emulsion.
Another preferred embodiment in, the water soluble acrylic acid base emulsion in the described component (b1) is selected from: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, its copolymer, and composition thereof.
Another preferred embodiment in, the polymer wax emulsion in the described component (b2) is selected from: the polythene wax emulsion of oxidation, paraffin wax emulsions, high density polyethylene waxes emulsion, polytetrafluoroethylene (PTFE) wax emulsion, silicone emulsion and synthetic wax emulsion.
Another preferred embodiment in, comprise the particle that particle mean size is the 0.1-5 micron in the described polymer wax emulsion.
Another preferred embodiment in, the solid content of described hole filler is 20-35 weight %, the solid content of described surface dopant is 25-45 weight %.
Another preferred embodiment in, the thickness of described protective coating is the 10-80 micron.
Another preferred embodiment in, described protective coating swing type friction co-efficient value is 45-80.
On the other hand, the present invention relates to the application of above-mentioned sealant compositions in the auto-flowing floor product.
On the one hand, the invention provides a kind of method that detects the wearing and tearing on the auto-flowing floor product again, this method comprises:
Hole filler in the above-mentioned sealant compositions is coated on the auto-flowing floor, to form the hole packed layer;
Surface dopant in the above-mentioned sealant compositions is coated on the described hole packed layer to form top coat;
Described top coat and the hole packed layer under it are exposed under the abrasive conditions;
Indicate the degree of wear with indicator, it is moistening with it that this indicator infiltrates eroded area;
The percentage of wetted soil on the surface that applies with analyzing and detecting.
One preferred embodiment in, described abrasive conditions is simulation actual traffic load.
Another preferred embodiment in, described abrasive conditions is the scraping test in the experiment.
Another aspect the invention provides a kind of protective coating of auto-flowing floor, comprising:
One hole packed layer is formed on the auto-flowing floor, and the material that wherein is used to form described hole packed layer comprises one first water soluble acrylic acid base emulsion at least; And
One top coat is formed on the described hole packed layer, and the material that wherein is used to form described top coat comprises one second water soluble acrylic acid base emulsion at least;
Wherein, described first water soluble acrylic acid base emulsion and the described second water soluble acrylic acid base emulsion are block polymer or the graft polymers that comprises water soluble acrylic acid matrix, and the molecular weight of the acrylic substrate in the first water soluble acrylic acid base emulsion is greater than the molecular weight of the acrylic substrate in the second water soluble acrylic acid base emulsion.
One preferred embodiment in, the molecular weight of the acrylic substrate in the described first water soluble acrylic acid base emulsion is 200000-350000, the molecular weight of the acrylic substrate in the described second water soluble acrylic acid base emulsion is 150000-260000.
Another preferred embodiment in, the described first water soluble acrylic acid base emulsion is selected from: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, its copolymer, and composition thereof.
Another preferred embodiment in, the described second water soluble acrylic acid base emulsion is selected from: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, its copolymer, and composition thereof.
Another preferred embodiment in, the component of the described first water soluble acrylic acid base emulsion is different from the component of the described second water soluble acrylic acid base emulsion.
Another preferred embodiment in, the described first water soluble acrylic acid base emulsion is the 20-30 weight portion, and the described material that is used to form described hole packed layer further comprises:
0.5-5 the polymer wax emulsion of weight portion, described polymer wax emulsion is selected from: the polythene wax emulsion of oxidation, paraffin wax emulsions, high density polyethylene waxes emulsion, polytetrafluoroethylene (PTFE) wax emulsion, silicone emulsion and synthetic wax emulsion;
1.1-18 the additive of weight portion.
Another preferred embodiment in, described additive comprises following component:
0.1-3 the organic metal huge legendary turtle compound of weight portion, described organic metal huge legendary turtle compound is selected from: organic titanium huge legendary turtle compound and aluminum-zirconium coupling agent;
0.5-1 polyfunctional crosslinking agent of weight portion, described polyfunctional crosslinking agent is selected from multi-functional aziridine;
0.5-3 the anti-scratch liniment of weight portion, the coalescents of 5 weight portions at the most, the surfactant of 3 weight portions and the defoamer of 3 weight portions at the most at the most.
Another preferred embodiment in, the described second water soluble acrylic acid base emulsion is the 20-45 weight portion, and the described material that is used to form described top coat further comprises:
The polymer wax emulsion of 2-8 weight portion, described polymer wax emulsion is selected from: the polythene wax emulsion of oxidation, paraffin wax emulsions, high density polyethylene waxes emulsion, polytetrafluoroethylene (PTFE) wax emulsion, silicone emulsion and synthetic wax emulsion;
1.6-20 the additive of weight portion.
Another preferred embodiment in, described additive comprises following component:
0.1-3 the organic metal huge legendary turtle compound of weight portion, described organic metal huge legendary turtle compound is selected from: organic titanium huge legendary turtle compound and aluminum-zirconium coupling agent;
Polyfunctional crosslinking agent of 1-3 weight portion, described polyfunctional crosslinking agent is selected from multi-functional aziridine;
0.5-3 the anti-scratch liniment of weight portion, the coalescents of 5 weight portions at the most, the surfactant of 3 weight portions and the defoamer of 3 weight portions at the most at the most.
Another preferred embodiment in, comprise the particle that particle mean size is the 0.1-5 micron in the described polymer wax emulsion.
Another preferred embodiment in, the solid content of described hole filler is 20-35 weight %, the solid content of described surface dopant is 25-45 weight %.
Another preferred embodiment in, the thickness of described protective coating is the 10-80 micron.
On the other hand, the invention provides a kind of method that on auto-flowing floor, forms above-mentioned protective coating, comprising:
The material that is used to form described hole packed layer on auto-flowing floor in the above-mentioned protective coating of coating is to form one first hole packed layer;
Keep the described first hole packed layer and be enough to make its dry time for, the material that is used to form described hole packed layer in the above-mentioned protective coating of coating is to form one second hole packed layer on the described first hole packed layer then, and described first hole packed layer and the described second hole packed layer constitute described hole packed layer jointly;
Keeping the described second hole packed layer is enough to make its dry time for, applies the material that is used to form described top coat in the above-mentioned protective coating then to form one first top coat on the described second hole packed layer;
Keep described first top coat and be enough to make its dry time for, the material that is used to form described top coat in the above-mentioned protective coating of coating is to form one second top coat on described first top coat then, and described first top coat and described second top coat constitute described top coat jointly;
Keeping described second top coat is enough to make its dry time for, makes its drying.
Description of drawings
Fig. 1 shows according to the relation between percentage of wetted soil of the embodiment of the present application 1 and the supermarket customer quantity.
Fig. 2 shows according to the relation between the friction number of times in percentage of wetted soil of the embodiment of the present application 1 and the laboratory.
The specific embodiment
The present inventor finds through after the extensive and deep research, with water-based acrylic polymer emulsion and a series of multifunctional material blending that can be used as the sealant that is used for the SLF product, can make the porous aggregate of the loose structure that is suitable for filling SLF, it can be used for stoping household liquids to pollute the SLF product; When putting on SLF and go up, that this coating provides is continuous, film closely, and this film can stop household liquids (as water, red wine, coffee and catsup) to pollute the SLF floor better; And combinations thereof can form wearing layer on SLF.Based on above-mentioned discovery, the present invention is accomplished.
In a first aspect of the present invention, a kind of sealant compositions that is used for cement matrix or loose structure (it generally is used for the SLF product) is provided, it has special water-based acrylic emulsion formulations, low VOC (VOC), low sliding property, high durability, high anti-household liquids and good abrasion resistance can be provided, it comprises: the hole packed layer, in order to the sealing SLF loose structure so that water proofing property to be provided, and top coat, in order to durability and anti-scratch performance to be provided, specifically comprise following component:
The filming water-base acrylic substrate,
The polymer wax emulsion of mixing with described matrix, so that different glossiness and abrasion resistancies to be provided,
Be selected from the additive of organic metal chelating agent and polyfunctional crosslinking agent, in order to gaining in strength, and
One or more other additives, in order to the shaping of acceptable film, described other additive is selected from: coalescents, defoamer, dispersing agent, anti-scratch liniment and surfactant.
In the present invention, described sealant compositions can be applied to various surfaces how much, is particularly useful for cement SLF base material.
In the present invention, water-based acrylic matrix demonstrates excellent flowability and special compactness, and does not have surface blemishes.Its viscosity is the about 1000Pas of 0.1-, and can be thixotropic.Its solid content is about 20-60 weight %, and preferably, the solid content of hole packed layer is 20-35 weight %, and the solid content of top coat is 25-45 weight %.Described acrylic substrate is preferably block polymer or graft polymers, and its molecular weight is about 60000-800000, and preferably, the molecular weight of hole packed layer is about 200000-350000, and the molecular weight of top coat is about 150000-260000.
In the present invention, described water-based acrylic matrix is selected from following polymer and copolymer: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, and composition thereof, they all are dispersed in the water.
In the present invention, in order to make sealant compositions reach required thixotropic property, can in composition, add polymer wax emulsion and various additive.The particle of described wax emulsion preferably has the particle mean size of 0.1-5 micron.Usually, the wax emulsion adds with the amount of the glossiness that is enough to reach required and abrasion resistance.The consumption of described wax emulsion is less, and is maximum 10%, for the hole packed layer, is about 0.5-5%, for top coat, is about 2-8%.
The example that is applicable to commercially available polymer wax emulsions more of the present invention comprises: the Tissuemat E of oxidation (
Derive from Honeywell company), high density polyethylene waxes emulsion (WE-618B3 derives from Sino-wax company), polytetrafluoroethylene (PTFE) wax emulsion (MPF5003 derives from Joule wax company).
In the present invention, functional additives is selected from: organic metal huge legendary turtle compound, multifunctional crosslinking agent, coalescents, defoamer, surfactant, anti-scratch liniment.
In the present invention, described organic metal huge legendary turtle compound (as coupling agent) is of value to the interface performance that improves other additive, the formation of surface blemishes is minimized, and improve the abrasion resistance of composition.The example that is applicable to commercially available organic metal huge legendary turtle compound of the present invention comprises: (for example, HY-1803 derives from Jessica chem. company to organic titanium huge legendary turtle compound; TiLCOM TET derives from Tioxide UK Co., Ltd); Aluminum-zirconium coupling agent (for example, HY-031 derives from Jessica chem. company).The concentration of this coupling agent is about 0.1-3 weight %, preferably, for the hole packed layer, is about 0.5-2%, for top coat, is about 1-2%.
In the present invention, described multifunctional crosslinking agent can add in a large number to improve the final performance of composition, to comprise gives intensity and flexible, improves anti-household liquids, increases coating hardness.For example, when using water-based acrylic matrix such as polystyrene acrylate, the crosslinking agent polyfunctional aziridines (for example,
Derive from Bayer Material Science company, perhaps F-0082 derives from Yoowe Chemical company) adding can improve at least one rank of its hardness.
In the present invention, coalescents can promote the formation of more continuous film.Some examples of coalescents comprise: lactate, butoxy ethanol, phthalic acid ester, ethylene glycol, diethylene glycol, DAA, propane diols, ethylene glycol phenyl ether.Described coalescents comprises outside coalescents and inner coalescents.Outside coalescents as butoxy ethanol, dissolves in the outside aqueous phase of emulsion compositions, and inner coalescents, as the butyl octyl phthalic acid ester, dissolve in inside mutually in.The commercially available prod comprises DALPADA (deriving from Dow Chemical company) and TEXANOL 12 (deriving from Eastman Chemical company), can be used among the present invention.
In the present invention, defoamer is used for the foaming of activities is minimized.Various defoamers can satisfy above-mentioned requirements.Be applicable to that commercially available defoamer of the present invention comprises: mineral oil origin defoamer (for example, Colloids643
TM, derive from Colloid company), silicone antifoam agent (for example, Bubble Breaker 3056A derives from Witco company).
In the present invention, surfactant (or dispersing agent) can be used for increasing the dispersed of additive and the surface blemishes of coating is minimized.Henkel 5040 can be used for the carboxylate by acrylic ester copolymer of the present invention.AMP-95 (deriving from ANGUS Chem. company) is the 2-amino-2-methyl-1-propanol that is used as cosurfactant among the present invention.
In the present invention, anti-scratch liniment can increase surface smoothness consumingly, thereby significantly improves the wettability of base material.In the present invention, polyether-modified dimethyl silicone polymer such as commercially available prod (BYK-333 derives from BYK u s company, or BD-3033, derives from Bald Silicone company) can be used as the anti-scratch liniment and second defoamer.
Composition of the present invention can form as follows: at first, organic metal huge legendary turtle compound is dissolved in the deionized water, adding has the water-based acrylic matrix of specific solid content then; Slowly stir this mixture and add the polymer wax emulsion; Afterwards, in mixture, add coalescents, defoamer, surfactant and anti-scratch liniment successively; Can add polyfunctional crosslinking agent then; Mixed 5 minutes in planetary-type mixer, whole hybrid technique preferably at room temperature carries out; At last, filter whole mixture to separate agglomerated thing with 150 purposes sieve.
In the present invention, described composition comprises hole packed layer and top coat, pollutes the SLF product in order to the porous pore structure of filling SLF to stop, and form wearing layer it be aging to stop, wearing and tearing and anti-pollution.Described hole packed layer has the remarkable characteristic of thixotropic property energy under lower shear rate and higher molecular weight (being generally about 200000-350000).Described top coat has good hardness and high wax emulsion concentration (preferably about 2-8 weight %).
Composition of the present invention can apply with various applicators, for example, and coating combined complete such as 3M
TMEasyShine applicator system perhaps drags manually with wax to apply.For the SLF product, hole packed layer and top coat apply respectively according to final use, apply once-four time.
Composition of the present invention can form film apace and not use any commercially available heater or heating furnace.Along with doing solid work after one week of coating, can obtain the optimal performance of composition.The coating of described drying has unique, excellent anti-household liquids performance, does not have surface blemishes, has better wear resistance and good anti-fouling performance.
In a second aspect of the present invention, provide the method for the wearing and tearing on a kind of SLF of detection product.This method comprises: apply sealant on the SLF product, sealant is worn and torn (sealant is exposed under the different transportation conditions), with indicator indication that can the wet abrasion zone, and use the analyzing and detecting humidification zones.The percentage of wetted soil of sealant is the drop area of the wetted area of indicator divided by indicator.
Preferably, this indicator is deionized water and is controlled by pipette.
In the method for the invention, use the percentage of wetted soil of the related sealant of degree of the lip-deep wearing and tearing that apply.
In the present invention, described abrasive conditions is represented by the percentage of wetted soil on the SLF base material.
In the present invention, described graphical analysis comprises takes pictures, and handles image, and calculates percentage of wetted soil.
In said method of the present invention, the humidification zones of indicator is that the observer is visible, can allow the observer determine the information of relevant surface condition, comprise the different abrasive conditions of the coating on any part that applies on the SLF base material on degree, the degree of wear on it and the SLF base material that covers.The percentage of wetted soil of sealant is by the wetted area of the indicator drop cartographic represenation of area divided by indicator.The relative extent of percentage of wetted soil can be indicated, and coating has experienced wearing and tearing in various degree, but still is present on the SLF base material.
In the present invention, can use several different methods to come accurately to determine the percentage of wetted soil of coating on the SLF base material.In one approach, after applying described composition on the SLF base material, carry out initial zero percentage of wetted soil and measure.Described zero percentage of wetted soil successfully is recorded as the function of pedestrian traffic.Can determine, be higher than 0 corresponding to the initial periods of inactivity of described composition of percentage of wetted soil.This is illustrated in the abrasion resistance of the preceding different components of wearing and tearing.In other method, the percentage of wetted soil in higher traffic loading zone is along with transportation condition increases.This can be provided in the information of the degree of wear in the higher traffic loading zone, and whether the surface needs to repair.Simultaneously, the exposure condition that is used for the wearing and tearing of the present composition can be accelerated the test time of practical application, and simulates the result of the practical application in the another kind of method fast.
In the present invention, described indicator can use the overwhelming majority to have more low viscous liquid, preferably the deionized water of being controlled by pipette.Described wetting image can be by the instrument that can carry out microshot, and preferred field camera is caught.
Compositions display of the present invention goes out good anti-household liquids performance, does not stay any pollution in 24 hours on the SLF product.
Use the formed dry film of composition of the present invention to demonstrate good abrasion resistance, can tolerate most scraping and pollutions from traffic loading.
In a third aspect of the present invention, a kind of protective coating of auto-flowing floor is provided, comprising:
One hole packed layer is formed on the auto-flowing floor, and the material that wherein is used to form described hole packed layer comprises one first water soluble acrylic acid base emulsion at least; And
One top coat is formed on the described hole packed layer, and the material that wherein is used to form described top coat comprises one second water soluble acrylic acid base emulsion at least.
In a fourth aspect of the present invention, a kind of method that forms above-mentioned protective coating on auto-flowing floor is provided, comprising:
The material that is used to form described hole packed layer on auto-flowing floor in the above-mentioned protective coating of coating is to form one first hole packed layer;
Keep the described first hole packed layer and be enough to make its dry time for, the material that is used to form described hole packed layer in the above-mentioned protective coating of coating is to form one second hole packed layer on the described first hole packed layer then, and described first hole packed layer and the described second hole packed layer constitute described hole packed layer jointly;
Keeping the described second hole packed layer is enough to make its dry time for, applies the material that is used to form described top coat in the above-mentioned protective coating then to form one first top coat on the described second hole packed layer;
Keep described first top coat and be enough to make its dry time for, the material that is used to form described top coat in the above-mentioned protective coating of coating is to form one second top coat on described first top coat then, and described first top coat and described second top coat constitute described top coat jointly;
Keeping described second top coat is enough to make its dry time for, makes its drying.
Major advantage of the present invention is:
Sealant compositions of the present invention can provide anti-household liquids, improves durability, the scraping of the capable traffic of contragradience and pollution and reduce performance to the needs of maintenance; Can be used for stoping household liquids to pollute the SLF product; When putting on SLF and go up, continuous, film closely is provided, this film can stop household liquids (as water, red wine, coffee and catsup) to pollute the SLF floor better; And composition of the present invention can form wearing layer on SLF.
Embodiment
Further set forth the present invention below in conjunction with specific embodiment.But, should be understood that these embodiment only are used to the present invention is described and do not constitute limitation of the scope of the invention.The test method of unreceipted actual conditions in the following example, usually according to normal condition, or the condition of advising according to manufacturer.Except as otherwise noted, all percentage and umber are by weight.
In the present invention, the preparation of sample and use program, and being determined under room temperature (23 ℃ ± 2 ℃) and the atmospheric pressure of percentage of wetted soil carry out, except as otherwise noted.
Embodiment 1
At first, the HY-1803 organic titanium huge legendary turtle compound (deriving from Jessica chem. company) with 3 weight portions is dissolved in the deionized water of 150 weight portions.Then, the YODOSOL AD12S water-based acrylic emulsion with clear solution and 100 weight portions (derives from National Starch ﹠amp; Chemical company) places planetary-type mixer.After the homogenising, the WE-618B3 polymer wax emulsion (deriving from Sino-wax company) of 8 weight portions is added to regulate the glossiness and the abrasion resistance of mixture.Slowly stir this mixture, until evenly.In this uniform mixture, add the Henkel 5040 of 3 weight portions (by the carboxylate of acrylic ester copolymer, derive from Henkel company, as dispersing aid), and the Bubble Breaker 3056A siloxy group defoamer (deriving from Witco company) of 1 weight portion, the DALPAD A of 3 weight portions is as coalescents (deriving from Dow Chemical company), the polyether-modified dimethyl silicone polymer of the BD-3033 of 2 weight portions is as anti-scratch liniment (deriving from Bald silicone company), 2 weight portions
Polyfunctional crosslinking agent (deriving from Bayer Material Science company).Further stir the mixture of gained, until evenly.Whole mixed process is at room temperature carried out.At last, filter whole mixture to isolate unwanted agglomerated thing with 150 purposes sieve.Said mixture is used as the hole packed layer in sealant compositions.
Use said procedure, the HY-1803 organic titanium huge legendary turtle compound (deriving from Jessica chem. company) of 3 weight portions is dissolved in the deionized water of 81 weight portions.Then, the acrylic emulsion (have particles of fluoropolymer, derive from Tianyin Chemical company) with the water base carbamate-functional of TC 106F of clear solution and 100 weight portions places planetary-type mixer.After the homogenising, the WE-618B3 polymer wax emulsion (deriving from Sino-wax company) of 8 weight portions is added to regulate the glossiness and the abrasion resistance of mixture.Slowly stir this mixture, until evenly.In this uniform mixture, add the Henkel 5040 of 3 weight portions (by the carboxylate of acrylic ester copolymer, derive from Henkel company, as dispersing aid), and the Bubble Breaker 3056A siloxy group defoamer (deriving from Witco company) of 1 weight portion, the DALPAD A of 3 weight portions is as coalescents (deriving from Dow Chemical company), the polyether-modified dimethyl silicone polymer of the BD-3033 of 3 weight portions is as anti-scratch liniment (deriving from Bald silicone company), 3 weight portions
Polyfunctional crosslinking agent (deriving from BayerMaterial Science company).Further stir the mixture of gained, until evenly.Whole mixed process is at room temperature carried out.At last, filter whole mixture to isolate unwanted agglomerated thing with 150 purposes sieve.Said mixture is used as top coat in sealant compositions.
Then, sealant compositions dragged with wax be applied on the SLF base material,, guarantee to apply the position and be capped to apply the first hole packed layer coating.Apply second coating, make the hole packed layer of winning invisible.About 1 hour of its interbody spacer.Make the second hole packed layer drying not have viscosity until applying top coat prepollex seal.Use wax to drag on the zone that is covered by aforementioned hole packed layer and apply first top coat.Before excessively applying, make the top coat drying at least 1 hour of winning.Apply second top coat.
Described sealant compositions demonstrates extraordinary anti-household liquids performance.It did not stay any pollution on the SLF product in 24 hours.It also has good abrasion resistance, anti-scratch property and stain resistance.
Embodiment 2
Use the method for embodiment 1, the HY-1803 organic titanium huge legendary turtle compound (deriving from Jessica chem. company) of 2 weight portions is dissolved in the deionized water of 55 weight portions.Then, this mixture is added in the epoxy functionalized acrylic acid ester emulsion of 100 weight portion HD2535 (deriving from HUA JIN SI Trading company).The DALPAD A of Bubble Breaker 3056A siloxy group defoamer, 2 weight portions that adds Henkel 5040 (by the carboxylate of acrylic ester copolymer), 1 weight portion of WE-618B3 polymer wax emulsion (deriving from Sino-wax company), 2 weight portions of 5 weight portions in this mixture is as coalescents (deriving from Dow Chemical company) and 2 weight portions
The pre-composition of polyfunctional crosslinking agent (deriving from Bayer Material Science company).Said mixture is used as the hole packed layer in sealant compositions.
As the top coat in the sealant compositions, the HY-1803 organic titanium huge legendary turtle compound (deriving from Jessica chem. company) of 3 weight portions is dissolved in the deionized water of 80 weight portions; Then, the acrylic emulsion (deriving from Tianyin Chemical company) that this mixture is added the water base carbamate-functional of 100 weight portion TC 106F; The MPF5003 polytetrafluoroethylene (PTFE) wax emulsion (deriving from Joule wax company) that in this mixture, adds 8 weight portions, the Henkel 5040 of 3 weight portions (by the carboxylate of acrylic ester copolymer), the Bubble Breaker3056A siloxy group defoamer of 1 weight portion, the DALPAD A of 3 weight portions is as coalescents (deriving from Dow Chemical company), the polyether-modified dimethyl silicone polymer of the BD-3033 of 3 weight portions makes as the pre-composition of F-0082 polyfunctional crosslinking agent (deriving from Yoowe chemical company) of anti-scratch liniment (deriving from Baldsilicone company) and 3 weight portions.
Embodiment 3
Use detects the sealant compositions among the method evaluation embodiment 1 that weares and teares on the SLF product.Four coatings (comprising two hole packed layer coatings and two top coats) of sealant compositions are coated on the SLF floor.Be exposed under the current load of height in the supermarket.Main load resource flows from client.After 2 months, obtain result as shown in Figure 1.
Embodiment 4
Use the sealant compositions identical, be exposed in the reciprocal back and forth equipment in the laboratory with embodiment 3.Main source of wear is knocked from drift.After 8 hours, obtain result as shown in Figure 2.
Comparing embodiment 3-4 as can be known, for sealant compositions of the present invention, the different conditions that are exposed to wearing and tearing obtain the similar degree of wear.Therefore, the method for the wearing and tearing on the described mensuration SLF product can expand to the relevance between the practical application of setting up described sealant compositions and the quick evaluation test.
All quote in this application as a reference at all documents that the present invention mentions, just quoted as a reference separately as each piece document.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after having read above-mentioned instruction content of the present invention, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Claims (40)
1. sealant compositions; it is made up of hole filler and surface dopant; described sealant compositions is suitable for forming on ground a protective coating; described protective coating comprises at least one hole packed layer and at least one top coat; described hole packed layer directly is formed on the described ground; described top coat is formed on the described hole packed layer, wherein
Described hole filler is suitable for forming on the ground described hole packed layer, and described hole filler comprises following component:
(a1) comprise the water soluble acrylic acid base emulsion of acrylic substrate;
(b1) polymer wax emulsion;
(c1) additive;
(d1) water;
Described surface dopant is suitable for forming described top coat on this hole packed layer, and described surface dopant comprises following component:
(a2) comprise the water soluble acrylic acid base emulsion of acrylic substrate, wherein, the acrylic substrate in the described component (a2) is different from the acrylic substrate in the component (a1);
(b2) polymer wax emulsion;
(c2) additive;
(d2) water.
2. composition as claimed in claim 1 is characterized in that, the molecular weight of the acrylic substrate in the described component (a1) is greater than the molecular weight of the acrylic substrate in the component (a2).
3. composition as claimed in claim 2, it is characterized in that, acrylic substrate in acrylic substrate in the described component (a1) and the described component (a2) is block polymer or graft polymers, and the molecular weight of the acrylic substrate in the described component (a1) is 200000-350000, and the molecular weight of the acrylic substrate in the described component (a2) is 150000-260000.
4. composition as claimed in claim 1 is characterized in that, described hole filler comprises following component:
(a1) the water soluble acrylic acid base emulsion of 20-30 weight portion;
(b1) the polymer wax emulsion of 0.5-5 weight portion;
(c1) additive of 1.1-18 weight portion;
(d1) water of 47-78.4 weight portion.
5. composition as claimed in claim 1 is characterized in that, described additive (c1) comprises following component:
(c11) the organic metal huge legendary turtle compound of 0.1-3 weight portion, described organic metal huge legendary turtle compound is selected from: organic titanium huge legendary turtle compound and aluminum-zirconium coupling agent;
(c12) polyfunctional crosslinking agent of 0.5-1 weight portion, described polyfunctional crosslinking agent is selected from multi-functional aziridine;
(c13) the anti-scratch liniment of 0.5-3 weight portion, the coalescents of 5 weight portions at the most, the surfactant of 3 weight portions and the defoamer of 3 weight portions at the most at the most.
6. composition as claimed in claim 5 is characterized in that, described anti-scratch liniment is selected from polyether-modified dimethyl silicone polymer.
7. composition as claimed in claim 5 is characterized in that, described coalescents is selected from: lactate, butoxy ethanol, phthalic acid ester, ethylene glycol, diethylene glycol, DAA, propane diols and ethylene glycol phenyl ether.
8. composition as claimed in claim 5 is characterized in that, described surfactant is selected from: the carboxylate of acrylic ester copolymer and 2-amino-2-methyl-1-propanol.
9. composition as claimed in claim 5 is characterized in that, described defoamer is selected from: mineral oil origin defoamer and silicone antifoam agent.
10. composition as claimed in claim 1 is characterized in that, described surface dopant comprises following component:
(a2) the water soluble acrylic acid base emulsion of 20-45 weight portion;
(b2) the polymer wax emulsion of 2-8 weight portion;
(c2) additive of 1.6-20 weight portion;
(d2) water of 27-76.4 weight portion.
11. composition as claimed in claim 1 is characterized in that, described additive (c2) comprises following component:
(c21) the organic metal huge legendary turtle compound of 0.1-3 weight portion, described organic metal huge legendary turtle compound is selected from: organic titanium huge legendary turtle compound and aluminum-zirconium coupling agent;
(c22) polyfunctional crosslinking agent of 1-3 weight portion, described polyfunctional crosslinking agent is selected from multi-functional aziridine;
(c23) the anti-scratch liniment of 0.5-3 weight portion, the coalescents of 5 weight portions at the most, the surfactant of 3 weight portions and the defoamer of 3 weight portions at the most at the most.
12. composition as claimed in claim 11 is characterized in that, described anti-scratch liniment is selected from polyether-modified dimethyl silicone polymer.
13. composition as claimed in claim 11 is characterized in that, described coalescents is selected from: lactate, butoxy ethanol, phthalic acid ester, ethylene glycol, diethylene glycol, DAA, propane diols and ethylene glycol phenyl ether.
14. composition as claimed in claim 11 is characterized in that, described surfactant is selected from: the carboxylate of acrylic ester copolymer and 2-amino-2-methyl-1-propanol.
15. composition as claimed in claim 11 is characterized in that, described defoamer is selected from: mineral oil origin defoamer and silicone antifoam agent.
16. composition as claimed in claim 1, it is characterized in that the water soluble acrylic acid base emulsion in the described component (a1) is selected from: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, its copolymer, and composition thereof.
17. composition as claimed in claim 1, it is characterized in that the polymer wax emulsion in the described component (a2) is selected from: the polythene wax emulsion of oxidation, paraffin wax emulsions, high density polyethylene waxes emulsion, polytetrafluoroethylene (PTFE) wax emulsion, silicone emulsion and synthetic wax emulsion.
18. composition as claimed in claim 1, it is characterized in that the water soluble acrylic acid base emulsion in the described component (b1) is selected from: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, its copolymer, and composition thereof.
19. composition as claimed in claim 1, it is characterized in that the polymer wax emulsion in the described component (b2) is selected from: the polythene wax emulsion of oxidation, paraffin wax emulsions, high density polyethylene waxes emulsion, polytetrafluoroethylene (PTFE) wax emulsion, silicone emulsion and synthetic wax emulsion.
20. composition as claimed in claim 1 is characterized in that, comprises the particle that particle mean size is the 0.1-5 micron in the described polymer wax emulsion.
21. composition as claimed in claim 1 is characterized in that, the solid content of described hole filler is 20-35 weight %, and the solid content of described surface dopant is 25-45 weight %.
22. composition as claimed in claim 1 is characterized in that, the thickness of described protective coating is the 10-80 micron.
23. composition as claimed in claim 1 is characterized in that, the swing type friction co-efficient value of described protective coating is 45-80.
24. the application of each sealant compositions in the auto-flowing floor product among the claim 1-23.
25. a method that detects the wearing and tearing on the auto-flowing floor product, this method comprises:
Hole filler in each the sealant compositions among the claim 1-24 is coated on the auto-flowing floor, to form the hole packed layer;
Surface dopant in each the sealant compositions among the claim 1-24 is coated on the described hole packed layer to form top coat;
Described top coat and the hole packed layer under it are exposed under the abrasive conditions;
Indicate the degree of wear with indicator, it is moistening with it that this indicator infiltrates eroded area;
The percentage of wetted soil on the surface that applies with analyzing and detecting.
26. method as claimed in claim 25 is characterized in that, described abrasive conditions is simulation actual traffic load.
27. method as claimed in claim 26 is characterized in that, described abrasive conditions is the test of the scraping in the experiment.
28. the protective coating of an auto-flowing floor comprises:
One hole packed layer is formed on the auto-flowing floor, and the material that wherein is used to form described hole packed layer comprises one first water soluble acrylic acid base emulsion at least; And
One top coat is formed on the described hole packed layer, and the material that wherein is used to form described top coat comprises one second water soluble acrylic acid base emulsion at least
Wherein, described first water soluble acrylic acid base emulsion and the described second water soluble acrylic acid base emulsion are block polymer or the graft polymers that comprises water soluble acrylic acid matrix, and the molecular weight of the acrylic substrate in the first water soluble acrylic acid base emulsion is greater than the molecular weight of the acrylic substrate in the second water soluble acrylic acid base emulsion.
29. protective coating as claimed in claim 28; it is characterized in that; the molecular weight of the acrylic substrate in the described first water soluble acrylic acid base emulsion is 200000-350000, and the molecular weight of the acrylic substrate in the described second water soluble acrylic acid base emulsion is 150000-260000.
30. protective coating as claimed in claim 28; it is characterized in that the described first water soluble acrylic acid base emulsion is selected from: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, its copolymer, and composition thereof.
31. protective coating as claimed in claim 28; it is characterized in that the described second water soluble acrylic acid base emulsion is selected from: the acrylate of the acrylate of polymethacrylates, polystyrene acrylate, poly-aromatics acrylate, polyalcohols acid propylene acid esters, epoxy functionalized acrylate, carbamate-functional, the acrylate of hydroxyl-functional, self-crosslinking, its copolymer, and composition thereof.
32. protective coating as claimed in claim 28 is characterized in that, the component of the described first water soluble acrylic acid base emulsion is different from the component of the described second water soluble acrylic acid base emulsion.
33. protective coating as claimed in claim 28 is characterized in that, the described first water soluble acrylic acid base emulsion is the 20-30 weight portion, and the described material that is used to form described hole packed layer further comprises:
0.5-5 the polymer wax emulsion of weight portion, described polymer wax emulsion is selected from: the polythene wax emulsion of oxidation, paraffin wax emulsions, high density polyethylene waxes emulsion, polytetrafluoroethylene (PTFE) wax emulsion, silicone emulsion and synthetic wax emulsion;
1.1-18 the additive of weight portion.
34. protective coating as claimed in claim 33 is characterized in that, described additive comprises following component:
0.1-3 the organic metal huge legendary turtle compound of weight portion, described organic metal huge legendary turtle compound is selected from: organic titanium huge legendary turtle compound and aluminum-zirconium coupling agent;
0.5-1 polyfunctional crosslinking agent of weight portion, described polyfunctional crosslinking agent is selected from multi-functional aziridine;
0.5-3 the anti-scratch liniment of weight portion, the coalescents of 5 weight portions at the most, the surfactant of 3 weight portions and the defoamer of 3 weight portions at the most at the most.
35. protective coating as claimed in claim 28 is characterized in that, the described second water soluble acrylic acid base emulsion is the 20-45 weight portion, and the described material that is used to form described top coat further comprises:
The polymer wax emulsion of 2-8 weight portion, described polymer wax emulsion is selected from: the polythene wax emulsion of oxidation, paraffin wax emulsions, high density polyethylene waxes emulsion, polytetrafluoroethylene (PTFE) wax emulsion, silicone emulsion and synthetic wax emulsion;
1.6-20 the additive of weight portion.
36. protective coating as claimed in claim 35 is characterized in that, described additive comprises following component:
0.1-3 the organic metal huge legendary turtle compound of weight portion, described organic metal huge legendary turtle compound is selected from: organic titanium huge legendary turtle compound and aluminum-zirconium coupling agent;
Polyfunctional crosslinking agent of 1-3 weight portion, described polyfunctional crosslinking agent is selected from multi-functional aziridine;
0.5-3 the anti-scratch liniment of weight portion, the coalescents of 5 weight portions at the most, the surfactant of 3 weight portions and the defoamer of 3 weight portions at the most at the most.
37. protective coating as claimed in claim 28 is characterized in that, comprises the particle that particle mean size is the 0.1-5 micron in the described polymer wax emulsion.
38. protective coating as claimed in claim 28 is characterized in that, the solid content of described hole filler is 20-35 weight %, and the solid content of described surface dopant is 25-45 weight %.
39. protective coating as claimed in claim 28 is characterized in that, the thickness of described protective coating is the 10-80 micron.
40. a method that forms on auto-flowing floor as each protective coating among the claim 28-39 comprises:
On auto-flowing floor, apply material as hole packed layer as described in being used to form in each described protective coating among the claim 28-39 to form one first hole packed layer;
Keep the described first hole packed layer and be enough to make its dry time for, the material of hole packed layer is to form one second hole packed layer, the described hole packed layer of the common formation of the described first hole packed layer and the described second hole packed layer as described in being used to form in applying as claim 28-39 then on the described first hole packed layer in each described protective coating;
Keeping the described second hole packed layer is enough to make its dry time for, on the described second hole packed layer, apply as claim 28-39 then in as described in being used to form in each described protective coating the material of top coat to form one first top coat;
Keep described first top coat and be enough to make its dry time for, the material of top coat is to form one second top coat, the described top coat of the common formation of described first top coat and described second top coat as described in being used to form in applying as claim 28-39 then on described first top coat in each described protective coating;
Keeping described second top coat is enough to make its dry time for, makes its drying.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106187009A CN102094514A (en) | 2010-12-31 | 2010-12-31 | Sealing agent composition and application thereof to self-leveling ground product |
| ARP110104963A AR084614A1 (en) | 2010-12-31 | 2011-12-27 | SEALING COMBINATION AND ITS APPLICATION IN SELF-LEVELING FLOORS |
| PCT/CN2011/084799 WO2012089120A1 (en) | 2010-12-31 | 2011-12-28 | Sealing combination and its application in a self-leveling floor product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106187009A CN102094514A (en) | 2010-12-31 | 2010-12-31 | Sealing agent composition and application thereof to self-leveling ground product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102094514A true CN102094514A (en) | 2011-06-15 |
Family
ID=44127762
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010106187009A Pending CN102094514A (en) | 2010-12-31 | 2010-12-31 | Sealing agent composition and application thereof to self-leveling ground product |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN102094514A (en) |
| AR (1) | AR084614A1 (en) |
| WO (1) | WO2012089120A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012089120A1 (en) * | 2010-12-31 | 2012-07-05 | Saint-Gobain Weber S.A. | Sealing combination and its application in a self-leveling floor product |
| CN102633533A (en) * | 2012-04-17 | 2012-08-15 | 滨州学院 | Cement concrete penetration repair cream |
| CN103382331A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Water-based chipping resistant coating for automobiles |
| CN109082174A (en) * | 2018-08-13 | 2018-12-25 | 上海英诺威新材料科技有限公司 | High performance floor coatings |
| CN110815961A (en) * | 2019-11-18 | 2020-02-21 | 天津市嘉惠宝地毯有限公司 | Carpet with good antistatic performance |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5645664A (en) * | 1996-03-21 | 1997-07-08 | Floor Seal Technology, Inc. | High moisture emission concrete floor covering and method |
| JP4357929B2 (en) * | 2003-11-05 | 2009-11-04 | 宇部興産株式会社 | Concrete floor structure and construction method thereof |
| CN101379007B (en) * | 2006-01-31 | 2013-03-27 | 威士伯采购公司 | Coating system for cement composite articles |
| CN101490181B (en) * | 2006-05-19 | 2013-08-28 | 威士伯采购公司 | Coating system for cement composite articles |
| GB2460239B (en) * | 2008-05-20 | 2012-03-21 | Anthony Lehane | A process for applying a moisture tolerant floor coating |
| CN102094514A (en) * | 2010-12-31 | 2011-06-15 | 圣戈班研发（上海）有限公司 | Sealing agent composition and application thereof to self-leveling ground product |
-
2010
- 2010-12-31 CN CN2010106187009A patent/CN102094514A/en active Pending
-
2011
- 2011-12-27 AR ARP110104963A patent/AR084614A1/en unknown
- 2011-12-28 WO PCT/CN2011/084799 patent/WO2012089120A1/en active Application Filing
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012089120A1 (en) * | 2010-12-31 | 2012-07-05 | Saint-Gobain Weber S.A. | Sealing combination and its application in a self-leveling floor product |
| CN102633533A (en) * | 2012-04-17 | 2012-08-15 | 滨州学院 | Cement concrete penetration repair cream |
| CN103382331A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Water-based chipping resistant coating for automobiles |
| CN109082174A (en) * | 2018-08-13 | 2018-12-25 | 上海英诺威新材料科技有限公司 | High performance floor coatings |
| CN110815961A (en) * | 2019-11-18 | 2020-02-21 | 天津市嘉惠宝地毯有限公司 | Carpet with good antistatic performance |
Also Published As
| Publication number | Publication date |
|---|---|
| AR084614A1 (en) | 2013-05-29 |
| WO2012089120A1 (en) | 2012-07-05 |
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